CN107556936A - A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof - Google Patents
A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof Download PDFInfo
- Publication number
- CN107556936A CN107556936A CN201710824709.7A CN201710824709A CN107556936A CN 107556936 A CN107556936 A CN 107556936A CN 201710824709 A CN201710824709 A CN 201710824709A CN 107556936 A CN107556936 A CN 107556936A
- Authority
- CN
- China
- Prior art keywords
- water
- sensitive adhesive
- adhesive agent
- diaphragm
- soluble pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof; after being coated with one layer of appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating by substrate surface after corona and be bonded mould release membrance, you can the environmentally friendly diaphragm for touch-control glass screen is made.The diaphragm clear water can be soaked after use terminates and stirring and washing, the water-soluble pressure-sensitive adhesive agent coating on diaphragm are dissolved in water by diaphragm disclosed by the invention.Base material after separation is after washing and drying, you can obtains relatively pure base material and is used for further recycling；The water-soluble pressure-sensitive adhesive agent contained in rinse water can be degraded to carbon dioxide, nitrogen and water by oxidizing.The diaphragm light transmittance of the present invention is high, adhesive property is good, temperature tolerance is good, cull, hold viscosity energy be not outstanding, while preparation method is simple and easy, the base material high purity after recovery, positive effect and good economy performance, society and obvious environment benefit.
Description
Technical field
It is particularly a kind of to be used for touch-control glass screen using ater-soluble adhesive the present invention relates to pressure-sensitive adhesive arts
Environmentally friendly diaphragm and preparation method thereof.
Background technology
Pressure-sensitive adhesive product can show viscosity in the case where that need not heat or use solvent, be widely used in mould
Cut, electronics, medical science, optics, plating protection and material processing etc..
Touch-control glass screen is to be coated with the pressure-sensitive of high transmission rate with all kinds of optical grade polymeric membrane class base materials with diaphragm at present
Adhesive is as functional coat, then is bonded made from Anti adhesive off film.Touch-control glass screen diaphragm applies to pressure-sensitive adhesive agent
Layer requirement be：High transmission rate, not cull, cohesive force is high, holds viscosity is good, heat resistance is good etc..So touch-control glass screen is protected
Requirement of the cuticula to pressure-sensitive adhesive agent coating is that comparison is strict.
The pressure-sensitive adhesive agent main Types of diaphragm common coatings have (organic) solvent-borne type, emulsion-type, heat molten type etc. at present
Several classes.The characteristics of thermotropic pressure sensitive adhesive be adhesive in coating process without using organic solvent, environmental benefit is high, still
Cross-link intensity of thermotropic pressure sensitive adhesive itself is poor, and heatproof and hold viscosity energy are bad, and it is bad cull etc. easily occur, so
It is not typically used as touch screen diaphragm.Contain substantial amounts of surfactant in emulsion based pressure sensitive gluing agent, this will make emulsion-type pressure
Optical property, electric property and the mechanical property of quick adhesive all have undesirable effect；Emulsion based pressure sensitive gluing agent simultaneously is logical
Cross between emulsion particle and emulsion particle and be crosslinked to realize cementation, and the adhesive macromolecule inside emulsion particle is typically physics
Crosslinking, therefore the cohesive force of emulsion based pressure sensitive gluing agent is poor, typically without in coating touch screen diaphragm.(organic) is molten
In formulation pressure-sensitive adhesive agent, adhesive macromolecule is that " free state " is present in organic solvent, passes through appropriate crosslinking side
Formula, the macromolecule of these " independences " each other will be cross-linked into network structure jointly, thus resistance to excellent mechanical property and heatproof
Hou Xing, so, largely use (organic) solvent pressure-sensitive adhesive to stick the diaphragm of agent coating in touch-control glass screen industry.
However, in environmental consciousness ever-increasing today, the recuperability of environmentally friendly material and material increasingly by
To the attention of people, resource, market and environmental requirement more and more higher.And diaphragm class product is belonged to it is difficult to the white rubbish of degraded
Rubbish, as long as some species even may have centuries in natural environment！The environment that we depend on for existence is not only degrading, is endangered
Evil property is more on the rise with the production and a large amount of use of diaphragm product.
But due to the limitation of fund, technology etc., the diaphragm class product of existing market, it is after use, one
As all not as solid dangerous waste but it is many all filled as common rubbish, burn do not make even effectively processing mix with
In common dregs of society, this not only seriously pollutes our living space, and also result in the significant wastage of resource.
The common mass share of diaphragm class product about 80%~90% is base material class and the about 10%-20% matter such as film class
The pressure-sensitive adhesive agent coating of share is measured, stability of these polymer substances in nature is that diaphragm turns into white pollution thing
The main reason for, the particularly indissoluble characteristic of pressure-sensitive adhesive agent coating is dealt with particularly difficult.So some scientific workers
Some water miscible adhesive backers are have also been developed, have begun to be applied to be used for plugging into for paper in paper industry.This paper
Connecting tape is opened using paper as base material, using water-soluble adhesive layer.After adhesive tape use, can directly it be starched together with waste paper
Change.But this connecting tape, because enhancing the water solubility of glue-line, hydrophilic monomer is excessive and alkalization degree is high, causes glue-line
Surface free energy is very big, it is difficult to is coated with macromolecule membrane；Simultaneously adhesive molecular weight very little and include more breast
Agent composition, so the cohesive force and holding power of adhesive are very low, cull is serious, it is difficult to which the use for reaching electronic protective film will
Ask, more can not meet the requirement of touch screen diaphragm.
The processing method of diaphragm substantially has following several ways at present：
1. directly fill or burn：Used diaphragm is directly embedded to garbage disposal landfill yard or burning disposal, this
Kind processing method actually still can polluted underground water or atmospheric environment；
2. solid-state dangerous waste is used as, the professional institution's processing that there please be processing qualification：This processing cost is high, processing per ton
Fare quote is 4000 yuan to 5000 yuan, and general enterprises are difficult to bear.
3. solvent removes glue-line：The diaphragm tentatively cleaned is soaked with the organic solvent for having certain toxic action, waits to protect
After the pressure-sensitive adhesive agent coating of cuticula dissolves or is swelled in organic solvent such as ethyl acetate, toluene, gone with the method for machinery
Remove, obtain relatively pure base material, then by base material recycling.The shortcomings that this processing method is：Because using organic
Solvent, there is security against fire and occupational health potential safety hazard；Organic solvent price is higher to cause economy unreasonable, makes simultaneously
Organic solvent after equally exists pending problem.And generally the functional coat of diaphragm is the pressure sensitive adhesive of cross-linking type,
It is difficult effectively to dissolve in organic solvent, cause processing after base material still band glue it is serious, the recovery for being unfavorable for rear road is sharp again
With.
4. chemical colloidal sol：The diaphragm tentatively cleaned is reacted to reach under the high temperature conditions with strong alkali solutions such as NaOH
Dissolve away the purpose of pressure-sensitive adhesive agent coating.The shortcomings that this processing method is mainly that selectivity is too poor, can only handle polyacrylic acid
The diaphragm of esters coating, the diaphragm treatment effect of other kind of type coating is very poor, at the same exist reaction time length, high energy consumption,
The problems such as caused sewage is more, film class substrate damage.
5. direct mixing granulation absorption method：After the diaphragm tentatively cleaned is shredded, coetrusion is used in the molten state
Directly the diaphragm containing pressure-sensitive adhesive agent coating is granulated, the plastic pellet recycling profit with certain physical property is made
With.The characteristics of this method is that the alternative of diaphragm is too narrow.Because the chemical composition of base material and pressure-sensitive adhesive agent coating and
The reason for chemical constitution, to the base material using polyolefin and the diaphragms of the adhesives such as SBR can only be coated with carry out coextrusion granulation,
And mechanics poor performance；And it is difficult then that coextrusion is granulated to use the diaphragm of non-polyolefin and non-SBR adhesives, so this
The limitation of method is very strong.
6. the method that foaming agent is mixed using adhesive：This method is to be added to the foaming agent with certain blowing temperature
In pressure-sensitive adhesive agent, after film use to be protected terminates, used diaphragm was entered to certain Temperature Treatment, in pressure-sensitive adhesive agent
Foaming agent foam, pressure-sensitive adhesive agent coating is disintegrated from base material and come off, so as to reach recovery base material purpose.It is this
Method has specific use condition, and the glass transition temperature point for being primarily due to pressure-sensitive adhesive agent is very low (about -20 DEG C
~-70 DEG C), under the conditions of the blowing temperature of foaming agent, pressure-sensitive adhesive agent coating is in viscous state, foaming agent shape at the beginning of foaming
Into gaseous material, quickly pass through pressure-sensitive adhesive agent coating and overflow and dissipate, the foaming condition of foaming agent can not be met at all, cannot
The pressure-sensitive adhesive agent coating of foaming, just do not reach yet and pressure-sensitive adhesive agent coating is disintegrated what is come off from base material by foaming effect
Purpose.So microcapsule-type foaming agent can only be added using the method that foaming agent is added into glue-line.Using microcapsule foamer
The shortcomings that protect film base material recovery, economy was poor it is also obvious that one being the expensive of microcapsule foamer；
Two carry out typically above 20 μm of the average grain diameter of microcapsule foamer, so it is difficult to being adopted on the thick diaphragm less than 20 μm of glue
With；Furthermore after microcapsule foamer foaming, do not ensure that pressure-sensitive adhesive agent coating can be completely fallen off from base material, this is equally not
Effective recovery of protection film base material can be met.
At present CONTINENTAL AREA OF CHINA the diaphragm moon output magnitude be hundreds of millions of square metres, so, no matter be in
The angle that environmental protection or resource reclaim recycle, it is necessary to go to find a kind of simple and easy diaphragm with urgency
The method of goods, materials and equipments recycling.
The content of the invention
It is an object of the invention to provide a kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof,
The base material for the diaphragm that this method makes not only can be with recycling, and water-soluble pressure-sensitive adhesive agent coating can be degraded to
Carbon dioxide, nitrogen and the water of environmental sound.
To realize one of above goal of the invention, the present invention uses following technical scheme：
A kind of environmentally friendly diaphragm for touch-control glass screen, include the base material of optical grade, the substrate surface electricity
Dizzy processing, the substrate surface of sided corona treatment are coated with appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating, and the water-soluble is pressure-sensitive
Mould release membrance is compounded with adhesive coating；
The water-soluble pressure-sensitive adhesive agent coating is the water-soluble polyacrylate adhesive polymerizeing in organic solvent phase
It is made.
Further, the water-soluble pressure-sensitive adhesive agent coating fluid of the water-soluble pressure-sensitive adhesive agent coating is by acrylic acid, first
Base acrylic acid, senecioate-hydroxyl ethyl ester, senecioate-hydroxypropyl acrylate, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxyl
Propyl ester, acrylamide, N hydroxymethyl acrylamide, maleic acid, butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate,
At least two in EHMA, butyl methacrylate, vinyl acetate and molecular weight regulator, organic molten
In agent by adding levelling agent again after radical polymerization, crosslinking agent is made, and the water-soluble pressure-sensitive adhesive agent coating fluid is not
Glass transition temperature point during crosslinking is between -15 DEG C -50 DEG C.
Further, the mass percent of the butt each component of the water-soluble pressure-sensitive adhesive agent coating fluid is：Methyl-prop
Olefin(e) acid 0%-15%, acrylic acid 0-15%, maleic acid 0-10%, ethyl acrylate 0-30%, butyl acrylate 0%-
50%th, Isooctyl acrylate monomer 0-50%, senecioate-hydroxyl ethyl ester 0-10%, N hydroxymethyl acrylamide 0%-1%, molecular weight
Conditioning agent 0-1%, levelling agent 0%-1%, crosslinking agent 0%-3%.
To realize another goal of the invention above, the present invention uses following technical scheme：
A kind of preparation method of environmentally friendly diaphragm for touch-control glass screen, comprises the following steps：
Step 1：Prepare monomer mixed solution；
Step 2：Prepare initiator solution；
Step 3：Initiator solution, monomer mixed solution, molecular weight regulator are passed through into radical polymerization in organic solvent
For polyacrylate water-soluble pressure-sensitive adhesive agent；
Step 4：Water-soluble pressure-sensitive adhesive agent is prepared as water-soluble pressure-sensitive adhesive agent coating fluid；
Step 5：By water-soluble pressure-sensitive adhesive agent coating solution to the optical grade substrate surface Jing Guo sided corona treatment through dry
It is dry to be cured as appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating；
Step 6：The compound mould release membrance on water-soluble pressure-sensitive adhesive agent coating, produced after post curing is handled for touching
Control the environmentally friendly diaphragm of glass screen.
Further, step 1 includes：
By the acrylic acid accurately measured, methacrylic acid, senecioate-hydroxyl ethyl ester, senecioate-hydroxypropyl acrylate, methyl-prop
Olefin(e) acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate, ethyl acrylate, butyl acrylate, butyl methacrylate, acrylic acid
In different monooctyl ester, EHMA, acrylamide, N hydroxymethyl acrylamide, maleic acid, vinyl acetate extremely
The molecular weight regulator of few two kinds of monomers and ormal weight, is well mixed, add ormal weight solvent about 60% mixes to monomer
Close in liquid, stir, obtain monomer mixed solution.
Further, step 2 includes：
By the initiator precise of amount of calculation, dissolved completely with the stirring solvent of more than about 10 times initiator qualities, it is quiet
Put more than 60 minutes, the moisture in agent solution to be triggered precipitates completely, isolates the moisture in solution, takes supernatant to be made and triggers
Agent solution.
Further, step 2 includes：
Azo-initiator is such as used, then using highly polar monomer as solvent, remaining initiator then uses toluene conduct
Solvent.
Further, step 3 includes：
Initiator solution after will be refined is added in monomer mixed solution, and molecular weight regulator is added after stirring, after
Continuous stirring obtains monomer dropping liquid；
The solvent of ormal weight about 30% is added into reactor, backflow is warming up under logical nitrogen protection atmosphere and is stablized 10 minutes
More than；
Monomer dropping liquid is added dropwise into reactor, controls time for adding to be added dropwise for 120 minutes；
With the solvent washing dropping tank and pipeline of ormal weight about 10%；
The reaction temperature in reactor is controlled to control the stabilization of backflow between 78-88 DEG C to prevent slug or implode, after
Continue backflow insulation more than 120 minutes in the case of logical nitrogen protection；
Reaction mass is cooled down, temperature is not higher than in the case of 65 DEG C in reactor, and the alkalescence of ormal weight is added into reactor
Material simultaneously stirs more than 15 minutes；40 DEG C are continued cool to, closes logical nitrogen protection, filtering is discharged in charging basket, closed preservation, obtained
To water-soluble pressure-sensitive adhesive agent.
Further, step 4 includes：
The agent of water-soluble pressure-sensitive adhesive, solvent, tackifier or plasticizer, crosslinking agent, the levelling agent of ormal weight are weighed, is configured to
Water-soluble pressure-sensitive adhesive agent coating fluid.
Diaphragm after use, can be placed in clear water by touch-control glass screen with hydrosol optical protection layer, stirring, be made
Water-soluble pressure-sensitive adhesive agent coating dissolves, the base material cleaned, available for follow-up recycling.Containing few in water after immersion
The water-soluble pressure-sensitive adhesive agent of amount, the oxidisability such as ozone, hydrogen peroxide or sodium hypochlorite, calcium hypochlorite are added into the rinse water
Material is reacted, and water-soluble pressure-sensitive adhesive agent is degraded to CO2、H2O and N2；The BOD and COD of water to be cleaned etc. are qualified
After discharged.
Compared with prior art, it has the advantages of notable to the present invention：Preparation method is simple and easy, and existing diaphragm
Preparation technology is good along holding property.The base material that use can be cleaned through simple process later, follow-up recycling of being more convenient for.
Due to using the water-soluble pressure-sensitive adhesive agent polymerizeing in organic phase, emulsification is not contained in water-soluble pressure-sensitive adhesive agent coating
Agent composition, not only water soluble characteristic is good for obtained diaphragm, and the molecular weight of water-soluble pressure-sensitive adhesive agent coating is higher, cohesion
Power is outstanding, hold viscosity energy is good, confining force is high, and heat resistance is good, optics and good electric property, can be used as the protection of touch-control glass screen
Film.Water-soluble pressure-sensitive adhesive agent, which is easily oxidised, is degraded to environmental sound CO2、N2And H2O, environmental benefit are high.
Brief description of the drawings
The structural representation of Fig. 1 one side diaphragms；
The structural representation of Fig. 2 two-sided tapes.
Embodiment
Below will the present invention will be described in detail by embodiment.But these embodiments are not intended to limit
The present invention, structure that one of ordinary skill in the art is made according to these embodiments, method or change functionally
Change and be all contained in protection scope of the present invention.
One embodiment of the present invention presented below.
A kind of environmentally friendly diaphragm for touch-control glass screen, include the base material of optical grade, the substrate surface electricity
Dizzy processing, the substrate surface of sided corona treatment are coated with appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating, and the water-soluble is pressure-sensitive
Mould release membrance is compounded with adhesive coating；
The water-soluble pressure-sensitive adhesive agent coating is the water-soluble polyacrylate adhesive polymerizeing in organic solvent phase
It is made.
Fig. 1 is referred to, the environmentally friendly diaphragm for touch-control glass screen can be made as one side protection form membrane, bag
Include the water-soluble pressure-sensitive adhesive agent coating 2 and mould release membrance 3 being cascading in the side of base material 1.
Fig. 2 is referred to, the environmentally friendly diaphragm for touch-control glass screen can be made as double stick tape form, including
The water-soluble pressure-sensitive adhesive agent coating 2 and mould release membrance 3 being cascading in the both sides of base material 1.
Further, the water-soluble pressure-sensitive adhesive agent coating fluid of the water-soluble pressure-sensitive adhesive agent coating is by acrylic acid, first
Base acrylic acid, senecioate-hydroxyl ethyl ester, senecioate-hydroxypropyl acrylate, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxyl
Propyl ester, acrylamide, N hydroxymethyl acrylamide, maleic acid, butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate,
At least two in EHMA, hexyl methacrylate, vinyl acetate and molecular weight regulator, organic molten
In agent by adding levelling agent again after radical polymerization, crosslinking agent is made, and the water-soluble pressure-sensitive adhesive agent coating fluid is not
Glass transition temperature point during crosslinking is between -15 DEG C -50 DEG C.
Further, the mass percent of the butt each component of the water-soluble pressure-sensitive adhesive agent coating fluid is：Methyl-prop
Olefin(e) acid 0%-15%, acrylic acid 0-15%, maleic acid 0-10%, ethyl acrylate 0-30%, butyl acrylate 0%-
50%th, Isooctyl acrylate monomer 0-50%, senecioate-hydroxyl ethyl ester 0-10%, N hydroxymethyl acrylamide 0%-1%, molecular weight
Conditioning agent 0-1%, levelling agent 0%-1%, crosslinking agent 0%-3%.
A kind of preparation method of environmentally friendly diaphragm for touch-control glass screen, comprises the following steps：
Step 1：Prepare monomer mixed solution；
Step 2：Prepare initiator solution；
Step 3：Initiator solution, monomer mixed solution, molecular weight regulator are passed through into radical polymerization in organic solvent
For polyacrylate water-soluble pressure-sensitive adhesive agent；
Step 4：Water-soluble pressure-sensitive adhesive agent is prepared as water-soluble pressure-sensitive adhesive agent coating fluid；
Step 5：By water-soluble pressure-sensitive adhesive agent coating solution to the optical grade substrate surface Jing Guo sided corona treatment through dry
It is dry to be cured as appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating；
Step 6：The compound mould release membrance on water-soluble pressure-sensitive adhesive agent coating, produced after post curing is handled for touching
Control the environmentally friendly diaphragm of glass screen.
Specifically, comprise the following steps：
The chemical synthesis of step 1 water-soluble pressure-sensitive adhesive agent：
1. select acrylic acid, methacrylic acid, at least one of maleic acid, butyl acrylate, ethyl acrylate,
At least one of Isooctyl acrylate monomer, vinyl acetate, acrylic acid -2- hydroxyl ethyl esters, 2-hydroxypropyl acrylate, metering system
The molecular weight of at least one of acid -2- hydroxyl ethyl esters, Hydroxypropyl methacrylate, N hydroxymethyl acrylamide and ormal weight
Conditioning agent, it is well mixed, adds about the 60% of regulation quantity of solvent into mixed liquor, stir, obtain monomer mixed solution,
It is stand-by；
2. by the initiator precise of amount of calculation, the toluene stirring and dissolving with more than 10 times initiator qualities is complete, quiet
Put more than 30 minutes, the moisture in be triggered dose of toluene solution precipitates completely, isolates the moisture in solution, takes supernatant to treat
With；If using azo-initiator, the highly polar lists such as methacrylic acid, acrylic acid, (methyl) acrylic acid hydroxy alkyl ester are used
Body is as solvent；
3. the initiator solution after will be refined is added in monomer mixed solution, molecular weight regulator is added after stirring,
Continue stirring and obtain monomer dropping liquid；
4. add about 30% solvent into reactor, be warming up under logical nitrogen protection atmosphere backflow stablize 10 minutes with
On；
5. monomer dropping liquid is added dropwise into reactor, time for adding is controlled to be added dropwise for 120 minutes or so；
6. with the solvent washing dropping tank and pipeline of ormal weight about 10%；
7. controlling the reaction temperature in reactor between 78 DEG C -88 DEG C, the stabilization of backflow is controlled to prevent slug or quick-fried
It is poly-, continue backflow insulation more than 120 minutes in the case of logical nitrogen protection；
8. cooling down reaction mass, temperature is not higher than in the case of 65 DEG C in reactor, adds 30 points of antalkali and stirring
It is more than clock；Continue to be cooled to less than about 40 DEG C of temperature in reactor, close logical nitrogen protection, be discharged in charging basket, closed preservation, obtain
Water-soluble pressure-sensitive adhesive agent.
The coating of step 2 water-soluble pressure-sensitive adhesive agent coatings：
1. weighing the agent of water-soluble pressure-sensitive adhesive, tackifier or plasticizer, solvent, crosslinking agent, the levelling agent of ormal weight, treat
With；
2. after respectively diluting tackifier or plasticizer, crosslinking agent with solvent, water-soluble pressure is added under stirring
In quick adhesive, stir；Then levelling agent is slowly added into again, continues to stir, obtain water-soluble pressure-sensitive adhesive agent coating
Liquid；
3. water-soluble pressure-sensitive adhesive agent coating solution is dried in base material corona surface, control highest with multi-function coating machine
Temperature is no more than 140 DEG C, and is bonded Anti adhesive off film in winding station, is packed after being then placed in drier and through solidify afterwards
After processing, the environmentally friendly diaphragm for touch-control glass screen has been made.
Protect the recycling of film base material
1. being stirred being placed in using the diaphragm finished in clear water, dissolve the water-soluble pressure-sensitive adhesive agent coating on base material
In water；Diaphragm size is too big, can cut into less size；Warm water increase dissolution velocity can be used；
2. the diaphragm for cleaning completion is cleaned, dries or dried with deionized water again, you can obtain pure protection
Film base material, it is convenient to carry out reproducing the processing of the subsequent recoveries such as grain.
The processing of rinse water
1. Mechanical Method fishes for the larger mechanical admixture in rinse water；
2. the oxidants such as hydrogen peroxide, sodium hypochlorite, calcium hypochlorite or ozone are added into rinse water, stirring, aeration；
3. detecting the indexs such as COD, BOD of rinse water, after qualified, rinse water is emitted into city planting ductwork.
Embodiment 1
A kind of making and base material recovery method using PET as the environmentally friendly diaphragm for touch-control glass screen of base material
For：
The chemical synthesis of one, water-soluble pressure-sensitive adhesive agent：
1. by the 280g effective contents accurately measured be 75% BPO 3Kg toluene stirring and dissolvings, stand 60 minutes with
On, after solution is changed into clear, the moisture of liquid bottom precipitation is removed, obtains initiator solution；
2. by the 1.75Kg accurately measured methacrylic acid, 5.25Kg acrylic acid, 1.75Kg hydroxy-ethyl acrylate,
12.25Kg Isooctyl acrylate monomer, 14.0Kg butyl acrylate are well mixed in rustless steel container；
3. 37Kg ethyl acetate, initiator solution are added in monomer mixture solution and stirred under stirring respectively
After uniformly, 105 grams of molecular weight regulator lauryl mercaptan is added, continues stirring more than 5 minutes, monomer dropping is made
Liquid；
4. adding 18Kg ethyl acetate into stainless steel cauldron, heating is stirred to reactor under the conditions of logical nitrogen
To 78 DEG C, maintain the reflux for stablizing more than 10 minutes；
5. monomer dropping liquid is uniformly added dropwise into reactor, time for adding is 120 minutes or so；
6. with 7Kg ethyl acetate rinse dropping tank and associated pipe, flushing liquor is uniformly put to anti-with 5-10 minutes
Answer in kettle；
7. careful controlling reaction temperature between 80 DEG C -88 DEG C, avoids slug or implode；Continue between 80 DEG C -88 DEG C
Reaction temperature under the conditions of maintain the reflux for stablizing 120 minutes or so；
8. cooled down under stirring to reactor, when being cooled to about 60 DEG C or so of temperature, minute used time 10-15 is equal
Even addition 2Kg MEA, continue stirring 30 minutes；Continue to be cooled to about 40 DEG C of temperature in reactor, close logical nitrogen protection, stop
Only stir；
9. filtering is discharged in bucket, closed preservation, obtain solid containing about 35% water-soluble pressure-sensitive adhesive agent；It is obtained water-soluble
Glass transition temperature point about -38.6 DEG C of the type pressure-sensitive adhesive agent in the case of uncrosslinked.
The preparation of two, water-soluble pressure-sensitive adhesive agent coating fluids：
1. 30 grams of aluminium acetylacetonate is uniform with 1Kg ethyl acetate stirring and dissolving, obtain crosslinking agent dilution；
2. crosslinking agent dilution is slowly added under stirring in 1Kg water-soluble pressure-sensitive adhesive agent, continue to stir
Mix；
3. 35 grams of German Bi Ke aqueous levelling agents BYK-333 is added under stirring and with the addition of crosslinking agent
In water-soluble pressure-sensitive adhesive agent, continue stirring more than 15 minutes, obtain water-soluble pressure-sensitive adhesive agent coating fluid.
The coating of three, water-soluble pressure-sensitive adhesive agent coatings：
With multi-function coating machine by prepare complete water-soluble pressure-sensitive adhesive agent coating solution to light transmittance more than 90%,
The corona surface (corona value is not less than 52mN/m) of the PET base material of mist degree≤1.0%, 10 microns of control coating dry glue thickness, control
Diaphragm is not less than 1 minute by the time of 130 DEG C of oven drying sections, and is bonded Anti adhesive off film in winding station, is made
Environmentally friendly diaphragm for touch-control glass screen.Diaphragm is sealed with the PE bags of built-in drier, is protected in shady place lucifuge
Deposit.Coating complete diaphragm need to be by 55 DEG C, not less than 48 hours solidify afterwards processing after can just reach it is viscosity stabilized simultaneously
Meet the requirement of client.
Four, water-soluble pressure-sensitive adhesive agent coating water solubility tests：
1. taking the diaphragm of 100 sizes for being cut into 25mm × 25mm sizes, tear the mould release membrance on diaphragm surface off, put
Enter in about 30 DEG C of deionized water, stir more than 30 minutes；Again with about 30 DEG C of deionized water stirring and washing 3 times after taking-up, often
Secondary stirring 5 minutes；
2. the diaphragm after stirring and washing is taken out, the moisture on surface is fallen in centrifugation, is not then put into 80 DEG C true lamination
Dried more than 30 minutes in empty drying box；
3. the PS expanded particles of 10 grams of single-grain-shapeds for being derived from foam battenboard and dried diaphragm are put to connection together
There is mixing in the canister of earthing or grounding means to shake up more than 5 minutes；
4. the diaphragm shaken up will be mixed in canister and PS expanded particles are divided and are placed on plank under ion fan
Room-temperature ion wind waved is used at 0.5 meter 5 minutes；
5. sticky PS expanded particles are not more than 1 when every diaphragm surface after ion blower brushes, it can determine that
The water-soluble pressure-sensitive adhesive agent coating of diaphragm is dissolvable in water water.
Five, protect the recovery of film base material：
1. being stirred being placed in using the diaphragm finished in clear water, dissolve the water-soluble pressure-sensitive adhesive agent coating on base material
In water；Diaphragm size is too big, can cut into less size；Warm water increase dissolution velocity can be used；
2. the diaphragm for cleaning completion is cleaned, dries or dried with deionized water again, you can obtain pure protection
Film base material, it is convenient to carry out reproducing the processing of the subsequent recoveries such as grain.
The processing of six, rinse waters
1. Mechanical Method fishes for the larger mechanical admixture in rinse water；
2. the oxidants such as hydrogen peroxide, sodium hypochlorite, calcium hypochlorite or ozone are added into rinse water, stirring, aeration；
3. detecting the indexs such as COD, BOD of rinse water, after qualified, rinse water is emitted into city planting ductwork.
The basic performance of the environmentally friendly diaphragm for touch-control glass screen prepared by embodiment 1 is shown in Table 1
A kind of 1 PET base material of table is used for the environmentally friendly diaphragm basic performance of touch-control glass screen
It can be seen that the basic performance of the environmentally friendly diaphragm for touch-control glass screen of embodiment 1 can meet touch-control
Glass screen patch screen requirement, water-soluble pressure-sensitive adhesive agent coating water solubility is qualified, while the PET base material reclaimed is clean, is easy to
Further recycling.
Embodiment 2
A kind of making and base material recovery side using BOPP as the environmentally friendly diaphragm for touch-control glass screen of base material
Method is：
The chemical synthesis of one, water-soluble pressure-sensitive adhesive agent：
1. accurately weigh 5.25Kg acrylic acid, after 3.5Kg hydroxy-ethyl acrylate stirs in rustless steel container,
157.5g refined azo-bis-isobutyl cyanide is added, is constantly stirred, until being completely dissolved, obtains initiator solution；
2. the 8.75Kg accurately measured Isooctyl acrylate monomer, 17.5Kg butyl acrylate are mixed in rustless steel container
Close uniform；
3. 37Kg ethyl acetate, initiator solution are added in monomer mixture solution and stirred under stirring respectively
After uniformly, 122.5 grams of molecular weight regulator lauryl mercaptan is added, continues stirring more than 5 minutes, monomer dropping is made
Liquid；
4. adding 18Kg ethyl acetate into stainless steel cauldron, heating is stirred to reactor under the conditions of logical nitrogen
To 78 DEG C, maintain the reflux for stablizing more than 10 minutes；
5. monomer dropping liquid is uniformly added dropwise into reactor, time for adding is 120 minutes or so；
6. with 7Kg ethyl acetate rinse dropping tank and associated pipe, flushing liquor is uniformly put to anti-with 5-10 minutes
Answer in kettle；
7. careful controlling reaction temperature between 78 DEG C -86 DEG C, avoids slug or implode；Continue between 78 DEG C -86 DEG C
Reaction temperature under the conditions of maintain the reflux for stablizing 120 minutes or so；
8. cooled down under stirring to reactor, when being cooled to about 60 DEG C or so of temperature, minute used time 10-15 is equal
Even addition 1.78Kg MEA, continue stirring 30 minutes；Continue to be cooled to about 40 DEG C of temperature in reactor, close logical nitrogen and protect
Shield, stop stirring；
9. filtering is discharged in bucket, closed preservation, obtain solid containing about 35% water-soluble pressure-sensitive adhesive agent；It is obtained water-soluble
Glass transition temperature point about -41.5 DEG C of the type pressure-sensitive adhesive agent in the case of uncrosslinked.
The preparation of two, water-soluble pressure-sensitive adhesive agent coating fluids：
1. 30 grams of aluminium acetylacetonate is uniform with 1Kg ethyl acetate stirring and dissolving, obtain crosslinking agent dilution；
2. crosslinking agent dilution is slowly added under stirring in 1Kg water-soluble pressure-sensitive adhesive agent, continue to stir
Mix；
3. 35 grams of German Bi Ke aqueous levelling agents BYK-333 is added under stirring and with the addition of crosslinking agent
In water-soluble pressure-sensitive adhesive agent, continue stirring more than 15 minutes, obtain water-soluble pressure-sensitive adhesive agent coating fluid.
The coating of three, water-soluble pressure-sensitive adhesive agent coatings：
With multi-function coating machine by prepare complete water-soluble pressure-sensitive adhesive agent coating solution to light transmittance more than 90%,
The corona surface (corona value is not less than 46mN/m) of the BOPP base materials of mist degree≤1.0%, 10 microns of control coating dry glue thickness, control
Diaphragm is not less than 1 minute by the time of 110 DEG C of oven drying sections, and is bonded Anti adhesive off film in winding station, is made
Environmentally friendly diaphragm for touch-control glass screen.Diaphragm is sealed with the PE bags of built-in drier, is protected in shady place lucifuge
Deposit.Coating complete diaphragm need to be by 55 DEG C, not less than 48 hours solidify afterwards processing after can just reach it is viscosity stabilized simultaneously
Meet the requirement of client.
Four, water-soluble pressure-sensitive adhesive agent coating water solubility tests：
1. taking the diaphragm of 100 sizes for being cut into 25mm × 25mm sizes, tear the mould release membrance on diaphragm surface off, put
Enter in about 30 DEG C of deionized water, stir more than 30 minutes；Again with about 30 DEG C of deionized water stirring and washing 3 times after taking-up, often
Secondary stirring 5 minutes；
2. the diaphragm after stirring and washing is taken out, the moisture on surface is fallen in centrifugation, is not then put into 80 DEG C true lamination
Dried more than 30 minutes in empty drying box；
3. the PS expanded particles of 10 grams of single-grain-shapeds for being derived from foam battenboard and dried diaphragm are put to connection together
There is mixing in the canister of earthing or grounding means to shake up more than 5 minutes；
4. the diaphragm shaken up will be mixed in canister and PS expanded particles are divided and are placed on plank under ion fan
Room-temperature ion wind waved is used at 0.5 meter 5 minutes；
5. sticky PS expanded particles are not more than 1 when every diaphragm surface after ion blower brushes, it can determine that
The water-soluble pressure-sensitive adhesive agent coating of diaphragm is dissolvable in water water.
Five, protect the recovery of film base material：
1. being stirred being placed in using the diaphragm finished in clear water, dissolve the water-soluble pressure-sensitive adhesive agent coating on base material
In water；Diaphragm size is too big, can cut into less size；Warm water increase dissolution velocity can be used；
2. the diaphragm for cleaning completion is cleaned, dries or dried with deionized water again, you can obtain pure protection
Film base material, it is convenient to carry out reproducing the processing of the subsequent recoveries such as grain.
The processing of six, rinse waters
1. Mechanical Method fishes for the larger mechanical admixture in rinse water；
2. the oxidants such as hydrogen peroxide, sodium hypochlorite, calcium hypochlorite or ozone are added into rinse water, stirring, aeration；
3. detecting the indexs such as COD, BOD of rinse water, after qualified, rinse water is emitted into city planting ductwork.
The basic performance of the environmentally friendly diaphragm for touch-control glass screen prepared by embodiment 2 is shown in Table 2
A kind of BOPP base materials of table 2 are used for the environmentally friendly diaphragm basic performance of touch-control glass screen
It can be seen that the basic performance of the environmentally friendly diaphragm for touch-control glass screen of embodiment 2 can meet touch-control
Glass screen patch screen requirement, water-soluble pressure-sensitive adhesive agent coating water solubility is qualified, while the BOPP base materials reclaimed are clean, are easy to
Further recycling.
Embodiment 3
A kind of making and base material recovery method using PET as the environmentally friendly diaphragm for touch-control glass screen of base material
For：
The chemical synthesis of one, water-soluble pressure-sensitive adhesive agent：
1. by the 300g effective contents accurately measured be 75% BPO 3Kg toluene stirring and dissolvings, stand 60 minutes with
On, after solution is changed into clear, the moisture of liquid bottom precipitation is removed, obtains initiator solution；
2. by the 1.05Kg accurately measured methacrylic acid, 5.95Kg acrylic acid, 1.75Kg hydroxy-ethyl acrylate
After well mixed, add 87.5g N hydroxymethyl acrylamide stirring and dissolving it is complete after, the acrylic acid for adding 17.5Kg is different pungent
Ester, 8.75Kg butyl acrylate are well mixed in rustless steel container；
3. 37Kg ethyl acetate, initiator solution are added in monomer mixture solution and stirred under stirring respectively
After uniformly, 122.5 grams of molecular weight regulator lauryl mercaptan is added, continues stirring more than 5 minutes, monomer dropping is made
Liquid；
4. adding 18Kg ethyl acetate into stainless steel cauldron, heating is stirred to reactor under the conditions of logical nitrogen
To 78 DEG C, maintain the reflux for stablizing more than 10 minutes；
5. monomer dropping liquid is uniformly added dropwise into reactor, time for adding is 120 minutes or so；
6. with 7Kg ethyl acetate rinse dropping tank and associated pipe, flushing liquor is uniformly put to anti-with 5-10 minutes
Answer in kettle；
7. careful controlling reaction temperature between 80 DEG C -88 DEG C, avoids slug or implode；Continue between 80 DEG C -88 DEG C
Reaction temperature under the conditions of maintain the reflux for stablizing 120 minutes or so；
8. cooled down under stirring to reactor, when being cooled to about 60 DEG C or so of temperature, minute used time 10-15 is equal
Even addition 2.32Kg MEA, continue stirring 30 minutes；Continue to be cooled to about 40 DEG C of temperature in reactor, close logical nitrogen and protect
Shield, stop stirring；
9. filtering is discharged in bucket, closed preservation, obtain solid containing about 35% water-soluble pressure-sensitive adhesive agent；It is obtained water-soluble
Glass transition temperature point about -41 DEG C of the type pressure-sensitive adhesive agent in the case of uncrosslinked.
The preparation of two, water-soluble pressure-sensitive adhesive agent coating fluids：
1. 20 grams of aluminium acetylacetonate is uniform with 1Kg ethyl acetate stirring and dissolving, obtain crosslinking agent dilution；
2. crosslinking agent dilution is slowly added under stirring in 1Kg water-soluble pressure-sensitive adhesive agent, stirring is equal
It is even, 10.5g ATBC is then added under stirring, continues to stir；
3. 35 grams of German Bi Ke aqueous levelling agents BYK-333 is added under stirring and with the addition of crosslinking agent
In water-soluble pressure-sensitive adhesive agent, continue stirring more than 15 minutes, obtain water-soluble pressure-sensitive adhesive agent coating fluid.
The coating of three, water-soluble pressure-sensitive adhesive agent coatings：
With multi-function coating machine by prepare complete water-soluble pressure-sensitive adhesive agent coating solution to light transmittance more than 90%,
The corona surface (corona value is not less than 52mN/m) of the PET base material of mist degree≤1.0%, 10 microns of control coating dry glue thickness, control
Diaphragm is not less than 1 minute by the time of 140 DEG C of oven drying sections, and is bonded Anti adhesive off film in winding station, is made
Environmentally friendly diaphragm for touch-control glass screen.Diaphragm is sealed with the PE bags of built-in drier, is protected in shady place lucifuge
Deposit.Coating complete diaphragm need to be by 55 DEG C, not less than 48 hours solidify afterwards processing after can just reach it is viscosity stabilized simultaneously
Meet the requirement of client.
Four, water-soluble pressure-sensitive adhesive agent coating water solubility tests：
1. taking the diaphragm of 100 sizes for being cut into 25mm × 25mm sizes, tear the mould release membrance on diaphragm surface off, put
Enter in about 30 DEG C of deionized water, stir more than 30 minutes；Again with about 30 DEG C of deionized water stirring and washing 3 times after taking-up, often
Secondary stirring 5 minutes；
2. the diaphragm after stirring and washing is taken out, the moisture on surface is fallen in centrifugation, is not then put into 80 DEG C true lamination
Dried more than 30 minutes in empty drying box；
3. the PS expanded particles of 10 grams of single-grain-shapeds for being derived from foam battenboard and dried diaphragm are put to connection together
There is mixing in the canister of earthing or grounding means to shake up more than 5 minutes；
4. the diaphragm shaken up will be mixed in canister and PS expanded particles are placed under ion fan and use room-temperature ion wind
Brush 5 minutes；
5. sticky PS expanded particles are not more than 1 when every diaphragm surface after ion blower brushes, it can determine that
The water-soluble pressure-sensitive adhesive agent coating of diaphragm is dissolvable in water water.
Five, protect the recovery of film base material：
1. being stirred being placed in using the diaphragm finished in clear water, dissolve the water-soluble pressure-sensitive adhesive agent coating on base material
In water；Diaphragm size is too big, can cut into less size；Warm water increase dissolution velocity can be used；
2. the protection film base material for cleaning completion is spent into ionized water to clean, dry or dry again, you can obtain pure
Protect film base material, it is convenient to carry out reproducing the processing of the subsequent recoveries such as grain.
The processing of six, rinse waters
1. Mechanical Method fishes for the larger mechanical admixture in rinse water；
2. the oxidants such as hydrogen peroxide, sodium hypochlorite, calcium hypochlorite or ozone are added into rinse water, stirring, aeration；
3. detecting COD, BOD index of rinse water, after qualified, rinse water is emitted into city planting ductwork.
The basic performance of the environmentally friendly diaphragm for touch-control glass screen prepared by embodiment 3 is shown in Table 3
A kind of 3 PET base material of table is used for the environmentally friendly diaphragm basic performance of touch-control glass screen
It can be seen that the basic performance of the environmentally friendly diaphragm for touch-control glass screen of embodiment 3 can meet touch-control
Glass screen patch screen requirement, water-soluble pressure-sensitive adhesive agent water solubility is qualified, while the PET base material reclaimed is clean, is easy into one
Walk recycling.
Embodiment 4
A kind of making and base material recovery side using PET as the environmentally friendly two-sided tape for touch-control glass screen of base material
Method is：
The chemical synthesis of one, water-soluble pressure-sensitive adhesive agent：
1. 5.25Kg acrylic acid, 1.75Kg maleic acid, 1.75Kg hydroxy-ethyl acrylate accurately are weighed not
After being stirred in rust steel container, 157.5g refined azo-bis-isobutyl cyanide is added, is constantly stirred, until completely molten
Solution；Then after addition addition 70g N hydroxymethyl acrylamide stirring and dissolving is complete, initiator solution is obtained；
2. the 17.5Kg accurately measured Isooctyl acrylate monomer, 8.75Kg butyl acrylate are mixed in rustless steel container
Close uniform；
3. 37Kg ethyl acetate, initiator solution are added in monomer mixture solution and stirred under stirring respectively
After uniformly, 122.5 grams of molecular weight regulator lauryl mercaptan is added, continues stirring more than 5 minutes, monomer dropping is made
Liquid；
4. adding 18Kg ethyl acetate into stainless steel cauldron, heating is stirred to reactor under the conditions of logical nitrogen
To 78 DEG C, maintain the reflux for stablizing more than 10 minutes；
5. monomer dropping liquid is uniformly added dropwise into reactor, time for adding is 120 minutes or so；
6. with 7Kg ethyl acetate rinse dropping tank and associated pipe, flushing liquor is uniformly put to anti-with 5-10 minutes
Answer in kettle；
7. careful controlling reaction temperature between 78 DEG C -86 DEG C, avoids slug or implode；Continue between 78 DEG C -86 DEG C
Reaction temperature under the conditions of maintain the reflux for stablizing 120 minutes or so；
8. cooled down under stirring to reactor, when being cooled to about 60 DEG C or so of temperature, minute used time 10-15 is equal
Even addition 2.68Kg MEA, continue stirring 30 minutes；Continue to be cooled to about 40 DEG C of temperature in reactor, close logical nitrogen and protect
Shield, stop stirring；
9. filtering is discharged in bucket, closed preservation, obtain solid containing about 35% water-soluble pressure-sensitive adhesive agent；It is obtained water-soluble
Glass transition temperature point about -42 DEG C of the type pressure-sensitive adhesive agent in the case of uncrosslinked.
The preparation of two, water-soluble pressure-sensitive adhesive agent coating fluids：
1. 18 grams of aluminium acetylacetonate is uniform with 1Kg ethyl acetate stirring and dissolving, obtain crosslinking agent dilution；
2. crosslinking agent dilution is slowly added under stirring in 1Kg water-soluble pressure-sensitive adhesive agent, continue to stir
Mix；
3. 35 grams of German Bi Ke aqueous levelling agents BYK-333 is added under stirring and with the addition of crosslinking agent
In water-soluble pressure-sensitive adhesive agent, continue stirring more than 15 minutes, obtain water-soluble pressure-sensitive adhesive agent coating fluid.
The coating of three, water-soluble pressure-sensitive adhesive agent coatings：
The water-soluble pressure-sensitive adhesive agent coating solution of completion will be prepared to the printing opacity of two-sided corona with multi-function coating machine
The corona surface (corona value is not less than 52mN/m) of rate more than 90%, the PET base material of mist degree≤1.0%, control coating dry glue thickness
25 microns, control two-sided tape is not less than 1 minute by the time of 120 DEG C of oven drying sections, and anti-sticking in winding station fitting
Mould release membrance；Another corona surface then proceeded in PET base material be coated one time 25 microns coated face and stick mould release membrance, be made
It is used for the environmentally friendly two-sided tape of touch-control glass screen.Two-sided tape is sealed with the PE bags of built-in drier, in shady place
It is kept in dark place.It can just reach viscous after the solidify afterwards processing that the two-sided tape that coating is completed need to be by 55 DEG C, not less than 48 hours
Property is stablized and meets the requirement of client.
Four, water-soluble pressure-sensitive adhesive agent coating water solubility tests：
1. taking the two-sided tape of 100 sizes for being cut into 25mm × 25mm sizes, the anti-sticking of two-sided tape surface is torn off
Mould release membrance, it is put into about 30 DEG C of deionized water, stirs more than 30 minutes；It is clear with about 30 DEG C of deionized water stirring again after taking-up
Wash 3 times, every time stirring 5 minutes；
2. the two-sided tape base material after stirring and washing is taken out, the moisture on surface is fallen in centrifugation, is not then put into 80 lamination
DEG C vacuum drying chamber in dry more than 30 minutes；
3. by the PS expanded particles of 10 grams of single-grain-shapeds for being derived from foam battenboard and dried two-sided tape base material together
Mixing is put into the canister for be associated with earthing or grounding means to shake up more than 5 minutes；
4. the two-sided tape base material shaken up will be mixed in canister and PS expanded particles are divided and ion is placed on plank
Room-temperature ion wind waved is used at lower 0.5 meter of fan 5 minutes；
5. sticky PS expanded particles are not more than 1 when every plate substrate surface after ion blower brushes, it can determine that double
The water-soluble pressure-sensitive adhesive agent coating of face adhesive tape is dissolvable in water water.
The recovery of five, two-sided tape base materials：
1. being stirred being placed in using the two-sided tape finished in clear water, make the water-soluble pressure-sensitive adhesive agent coating on base material molten
In Xie Shui；Two-sided tape size is too big, can cut into less size；Warm water increase dissolution velocity can be used；
2. the two-sided tape base material for cleaning completion is cleaned, dries or dried with deionized water again, you can obtained pure
Two-sided tape base material, it is convenient to carry out reproducing the processing of the subsequent recovery such as grain.
The processing of six, rinse waters
1. Mechanical Method fishes for the larger mechanical admixture in rinse water；
2. the oxidants such as hydrogen peroxide, sodium hypochlorite, calcium hypochlorite or ozone are added into rinse water, stirring, aeration；
3. detecting the indexs such as COD, BOD of rinse water, after qualified, rinse water is emitted into city planting ductwork.
The basic performance of the environmentally friendly two-sided tape for touch-control glass screen prepared by embodiment 4 is shown in Table 4
A kind of 4 PET base material of table is used for the environmentally friendly two-sided tape basic performance of touch-control glass screen
It can be seen that the basic performance of the environmentally friendly two-sided tape for touch-control glass screen of embodiment 4 can meet to touch
Glass screen patch screen requirement is controlled, water-soluble pressure-sensitive adhesive agent coating water solubility is qualified, while the PET base material reclaimed is clean, just
In further recycling.
The present invention cannot be only used for one side diaphragm class described in above-described embodiment, two-sided tape class pressure-sensitive adhesive product
The recycling of base material, other different substrate materials can also be extended to and be coated with the diaphragm class of different glue systems, adhesive tape class pressure sensitive adhesive
It is sticked the base material recycle and reuse of product.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all according to the present invention
The equivalent change or modification that Spirit Essence is made, it should all be included within the scope of the present invention.
Claims (9)
- A kind of 1. environmentally friendly diaphragm for touch-control glass screen, it is characterised in that：Base material including optical grade, the base The processing of material surface corona, the substrate surface of sided corona treatment are coated with appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating, the water Mould release membrance is compounded with molten type pressure-sensitive adhesive agent coating；The water-soluble pressure-sensitive adhesive agent coating is made up of the water-soluble polyacrylate adhesive polymerizeing in organic solvent phase.
- A kind of 2. environmentally friendly diaphragm for touch-control glass screen according to claim 1, it is characterised in that：It is described The water-soluble pressure-sensitive adhesive agent coating fluid of water-soluble pressure-sensitive adhesive agent coating is by acrylic acid, methacrylic acid, senecioate-hydroxyl second Ester, senecioate-hydroxypropyl acrylate, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate, acrylamide, N- methylols Acrylamide, maleic acid, butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate, EHMA, methyl At least two in Hexyl 2-propenoate, vinyl acetate and molecular weight regulator, in organic solvent by radical polymerization after Levelling agent is added again, crosslinking agent is made, and glass transition temperature of the water-soluble pressure-sensitive adhesive agent coating fluid when uncrosslinked Degree point is between -15 DEG C -50 DEG C.
- A kind of 3. environmentally friendly diaphragm for touch-control glass screen according to claim 2, it is characterised in that：It is described The mass percent of the butt each component of water-soluble pressure-sensitive adhesive agent coating fluid is：Methacrylic acid 0%-15%, acrylic acid 0- 15%th, maleic acid 0-10%, ethyl acrylate 0-30%, butyl acrylate 0%-50%, Isooctyl acrylate monomer 0-50%, Senecioate-hydroxyl ethyl ester 0-10%, N hydroxymethyl acrylamide 0%-1%, molecular weight regulator 0-1%, levelling agent 0%- 1%th, crosslinking agent 0%-3%.
- A kind of 4. preparation method of environmentally friendly diaphragm for touch-control glass screen, it is characterised in that：Comprise the following steps：Step 1：Prepare monomer mixed solution；Step 2：Prepare initiator solution；Step 3：Initiator solution, monomer mixed solution, molecular weight regulator are combined into by radical polymerization in organic solvent poly- Esters of acrylic acid water-soluble pressure-sensitive adhesive agent；Step 4：Water-soluble pressure-sensitive adhesive agent is prepared as water-soluble pressure-sensitive adhesive agent coating fluid；Step 5：By water-soluble pressure-sensitive adhesive agent coating solution to the optical grade substrate surface dry solidification Jing Guo sided corona treatment For appropriately crosslinked water-soluble pressure-sensitive adhesive agent coating；Step 6：The compound mould release membrance on water-soluble pressure-sensitive adhesive agent coating, is produced after post curing is handled for touch-control glass The environmentally friendly diaphragm of glass screen.
- 5. a kind of preparation method of environmentally friendly diaphragm for touch-control glass screen according to claim 4, it is special Sign is：Step 1 includes：By the acrylic acid accurately measured, methacrylic acid, senecioate-hydroxyl ethyl ester, senecioate-hydroxypropyl acrylate, methacrylic acid- Beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate, ethyl acrylate, butyl acrylate, butyl methacrylate, acrylic acid are different pungent At least two in ester, EHMA, acrylamide, N hydroxymethyl acrylamide, maleic acid, vinyl acetate The molecular weight regulator of kind monomer and ormal weight, it is well mixed, add ormal weight solvent about 60% arrives monomer mixed solution In, stir, obtain monomer mixed solution.
- 6. a kind of preparation method of environmentally friendly diaphragm for touch-control glass screen according to claim 4, it is special Sign is：Step 2 includes：By the initiator precise of amount of calculation, complete, standing 60 is dissolved with the stirring solvent of more than about 10 times initiator qualities More than minute, the moisture in agent solution to be triggered precipitates completely, isolates the moisture in solution, takes supernatant that initiator is made molten Liquid.
- 7. a kind of preparation method of environmentally friendly diaphragm for touch-control glass screen according to claim 6, it is special Sign is：Step 2 includes：Azo-initiator is such as used, then using highly polar monomer as solvent, remaining initiator then uses toluene as solvent.
- 8. a kind of preparation method of environmentally friendly diaphragm for touch-control glass screen according to claim 4, it is special Sign is：Step 3 includes：Initiator solution after will be refined is added in monomer mixed solution, is added molecular weight regulator after stirring, is continued to stir Mix to obtain monomer dropping liquid；Into reactor add ormal weight about 30% solvent, be warming up under logical nitrogen protection atmosphere backflow stablize 10 minutes with On；Monomer dropping liquid is added dropwise into reactor, controls time for adding to be added dropwise for 120 minutes；With the solvent washing dropping tank and pipeline of ormal weight about 10%；The reaction temperature in reactor is controlled to control the stabilization of backflow to continue to prevent slug or implode between 78-88 DEG C Backflow insulation more than 120 minutes in the case of logical nitrogen protection；Reaction mass is cooled down, temperature is not higher than in the case of 65 DEG C in reactor, and the alkaline matter of ormal weight is added into reactor And stir more than 15 minutes；Less than 40 DEG C are continued cool to, closes logical nitrogen protection, filtering is discharged in charging basket, closed preservation, obtained To water-soluble pressure-sensitive adhesive agent.
- 9. a kind of preparation method of environmentally friendly diaphragm for touch-control glass screen according to claim 4, it is special Sign is：Step 4 includes：The agent of water-soluble pressure-sensitive adhesive, solvent, tackifier or plasticizer, crosslinking agent, the levelling agent of ormal weight are weighed, is configured to water-soluble Type pressure-sensitive adhesive agent coating fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710824709.7A CN107556936A (en) | 2017-09-08 | 2017-09-08 | A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710824709.7A CN107556936A (en) | 2017-09-08 | 2017-09-08 | A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107556936A true CN107556936A (en) | 2018-01-09 |
Family
ID=60980908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710824709.7A Pending CN107556936A (en) | 2017-09-08 | 2017-09-08 | A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107556936A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110577810A (en) * | 2019-10-14 | 2019-12-17 | 太仓斯迪克新材料科技有限公司 | Adhesive and preparation method thereof, and explosion-proof membrane and preparation method thereof |
| CN110628336A (en) * | 2019-09-25 | 2019-12-31 | 苏州德佑胶带技术有限公司 | Can realize plane materiel recycle's no substrate double-sided tape |
| CN110734711A (en) * | 2019-09-18 | 2020-01-31 | 广东东立新材料科技股份有限公司 | Pressure-sensitive adhesive for polarizer protective film and preparation method thereof |
| CN111334215A (en) * | 2018-12-19 | 2020-06-26 | 安徽明讯新材料科技股份有限公司 | Base material recyclable protective film with moisture-proof performance and manufacturing method thereof |
| CN112552837A (en) * | 2020-12-08 | 2021-03-26 | 湖南优多新材料科技有限公司 | Formula and processing technology of thermal viscosity reduction protective film |
| CN112549732A (en) * | 2019-09-25 | 2021-03-26 | 苏州德佑新材料科技股份有限公司 | Recoverable plane materiel coupling mechanism |
| CN112552831A (en) * | 2019-09-25 | 2021-03-26 | 苏州德佑新材料科技股份有限公司 | Operation method of double-sided adhesive tape without base material |
| CN112724873A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved adhesive and polyolefin substrate co-granulable protective film and protective film |
| CN112724855A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved degradable adhesive tape and adhesive tape |
| CN112724872A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved degradable adhesive tape and adhesive tape |
| CN112724876A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved protective film capable of being granulated together with glue and polyolefin base material and protective film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1190665A (en) * | 1997-02-14 | 1998-08-19 | 琳得科株式会社 | Pressure sensitive adhesive composition and use thereof |
| CN101687560A (en) * | 2007-06-29 | 2010-03-31 | 汉高两合股份公司 | Labels with water-soluble uv curable adhesives |
| CN101921552A (en) * | 2009-06-11 | 2010-12-22 | 日东电工株式会社 | Pressure-sensitive adhesive tape for optical member |
-
2017
- 2017-09-08 CN CN201710824709.7A patent/CN107556936A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1190665A (en) * | 1997-02-14 | 1998-08-19 | 琳得科株式会社 | Pressure sensitive adhesive composition and use thereof |
| CN101687560A (en) * | 2007-06-29 | 2010-03-31 | 汉高两合股份公司 | Labels with water-soluble uv curable adhesives |
| CN101921552A (en) * | 2009-06-11 | 2010-12-22 | 日东电工株式会社 | Pressure-sensitive adhesive tape for optical member |
Non-Patent Citations (1)
| Title |
|---|
| 柯利茨基等: "《电工材料手册》", 31 August 1963, 中国工业出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111334215A (en) * | 2018-12-19 | 2020-06-26 | 安徽明讯新材料科技股份有限公司 | Base material recyclable protective film with moisture-proof performance and manufacturing method thereof |
| CN110734711A (en) * | 2019-09-18 | 2020-01-31 | 广东东立新材料科技股份有限公司 | Pressure-sensitive adhesive for polarizer protective film and preparation method thereof |
| CN110734711B (en) * | 2019-09-18 | 2021-09-21 | 广东东立新材料科技股份有限公司 | Pressure-sensitive adhesive for polarizer protective film and preparation method thereof |
| CN110628336A (en) * | 2019-09-25 | 2019-12-31 | 苏州德佑胶带技术有限公司 | Can realize plane materiel recycle's no substrate double-sided tape |
| CN112549732A (en) * | 2019-09-25 | 2021-03-26 | 苏州德佑新材料科技股份有限公司 | Recoverable plane materiel coupling mechanism |
| CN112552831A (en) * | 2019-09-25 | 2021-03-26 | 苏州德佑新材料科技股份有限公司 | Operation method of double-sided adhesive tape without base material |
| CN110577810A (en) * | 2019-10-14 | 2019-12-17 | 太仓斯迪克新材料科技有限公司 | Adhesive and preparation method thereof, and explosion-proof membrane and preparation method thereof |
| CN112552837A (en) * | 2020-12-08 | 2021-03-26 | 湖南优多新材料科技有限公司 | Formula and processing technology of thermal viscosity reduction protective film |
| CN112724873A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved adhesive and polyolefin substrate co-granulable protective film and protective film |
| CN112724855A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved degradable adhesive tape and adhesive tape |
| CN112724872A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved degradable adhesive tape and adhesive tape |
| CN112724876A (en) * | 2020-12-31 | 2021-04-30 | 安徽明讯新材料科技股份有限公司 | Preparation method of improved protective film capable of being granulated together with glue and polyolefin base material and protective film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107556936A (en) | A kind of environmentally friendly diaphragm for touch-control glass screen and preparation method thereof | |
| CN107488417A (en) | Base material recoverable version touch screen hydrosol optical protection layer and preparation method thereof | |
| CN107459941A (en) | A kind of water-soluble glue-type touch screen environmental protection protective film and preparation method thereof | |
| CN107446516A (en) | Recyclable diaphragm of a kind of base material and preparation method thereof | |
| CN102471642B (en) | Actinic-energy-ray-curable adhesive composition for plastic film or sheet | |
| TW316277B (en) | ||
| CN101362929B (en) | Emulsion type adhesive for paper and plastics and preparation method thereof | |
| CN104592462B (en) | A kind of silica sol modified acrylic emulsion and its preparation, application | |
| CN102888161A (en) | Environment-friendly water-based high-adhesion PET (polyethylene terephthalate) precoat coating composition as well as preparation method and application | |
| CN102449093B (en) | Photocurable adhesive composition, photocurable adhesive layer, and photocurable adhesive sheet | |
| CN103305143A (en) | Double-sided adhesive tape | |
| CN111334215A (en) | Base material recyclable protective film with moisture-proof performance and manufacturing method thereof | |
| CN105259737A (en) | Transfer processing method for glass base material of cover board | |
| CN102399501A (en) | Re-stripping type adhesive piece | |
| CN104962161B (en) | A kind of water-based Stripable paint | |
| JP2008045057A (en) | Method for producing acrylic adhesive | |
| CN105131849A (en) | Production method of ultraviolet light curing pressure-sensitive adhesive film | |
| CN102648261B (en) | Photocurable pressure-sensitive adhesive composition, photocurable pressure-sensitive adhesive layer, and photocurable pressure-sensitive adhesive sheet | |
| CN111117503A (en) | Protective film with adhesive and PET (polyethylene terephthalate) base material capable of being granulated together and manufacturing method thereof | |
| CN105189580A (en) | Acrylic emulsion resin having excellent adhesive property and preparation method therefor | |
| JP3964264B2 (en) | Synthetic resin water-based emulsion type pressure-sensitive adhesive and method for producing the same | |
| CN111171739A (en) | Improved protective film capable of being co-granulated with PET (polyethylene terephthalate) base material and manufacturing method thereof | |
| CN106957626A (en) | A kind of peelable blue glue of volatile-type and preparation method thereof | |
| CN105885745B (en) | The polyacrylate pressure-sensitive lotion and preparation method and application that PVC High temperature-resistanadhesive adhesive tapes fluosilicic is modified | |
| CN112851852A (en) | Acrylate polymer for polarizer protective film and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180109 |
|
| RJ01 | Rejection of invention patent application after publication |