CN107549871A

CN107549871A - It is a kind of to eliminate composition of harmful substance and application thereof in cigarette or air

Info

Publication number: CN107549871A
Application number: CN201710795606.2A
Authority: CN
Inventors: 欧应平; 周健
Original assignee: Chongqing Jiangbei District Environmental Protection New Mstar Technology Ltd
Current assignee: Chongqing Jiangbei District Environmental Protection New Mstar Technology Ltd
Priority date: 2017-09-06
Filing date: 2017-09-06
Publication date: 2018-01-09

Abstract

The present invention discloses composition of harmful substance and application thereof in a kind of elimination cigarette or air, the composition includes the nanometer natural fiber of tool viscosity, metallo-organic compound nano-porous materials and auxiliary material, the purposes includes being used for cigarette filter layer, mouth mask, in-car air filter for molten and indoor air cleaner etc., what nano-porous materials of the composition of the present invention using environmentally friendly recyclable materials and with huge specific surface area formed effectively prevents harmful substance caused by cigarette combustion process from entering human body under the hydrating condition of part, and secondary pollution will not be caused to other people or surrounding enviroment.

Description

It is a kind of to eliminate composition of harmful substance and application thereof in cigarette or air

Technical field

The invention belongs to air purification field, and in particular to one kind eliminates cigarette combustion process to health of smokers hazardous material The composition of harmful substance and its air cleaner and indoor air cleaning in cigarette filter layer, mouth mask, in-car in matter or air Change the purposes in device.

Background technology

China is tobacco consumption state and producing country maximum in the world, and annual turnover reaches 2.5 trillion, accounts for global cigarette The 45% of consumption figure.The scale of Chinese smoker colony is 3.5 hundred million, accounts for the 1/3 of whole world smoker sum.The whole world die from every year with The relevant disease of smoking has nearly 5,000,000 people, wherein about 1,200,000 be Chinese.Predicted according to the World Health Organization, China will have 1 Hundred million young men premature death due to smoking, in the world, because to account for cancer always dead for cancer mortality caused by smoking Die more than the 30% of rate.

Containing more than 3800 kinds of chemical substance in the smog that result of combustion of tobacco process is discharged, the overwhelming majority is harmful, its Middle about 50 kinds have been identified as directly acting carcinogens, including the alkaloid such as carbon monoxide, nicotine, amine, nitrile, liquor-saturated class, phenol Class, alkanes, aldehydes, nitrogen oxides, polycyclic aromatic hydrocarbon, heterocyclics, hydroxy compounds, heavy metal element and organic agriculture Medicine etc..

Nicotine is a kind of potent plan parasympathetic nerve alkaloid for being found in plant of Solanaceae, belongs to nicotinic acetylcholine Acceptor (the Na+/K+ ionophores (sodium potassium pump) on a kind of nerve synapse caudacoria of mammal and insect) activator, it is a kind of Stimulant substance.Nicotine content is between 1.5-3.0 milligrams in cigarette.During result of combustion of tobacco, about 25% Ni Gu Fourth is burned to decompose destruction, and 5% residues in cigarette end, and 50% is diffused into space (may be absorbed by other people) nearby, really quilt The nicotine of smoker is about 20%.Nicotine may cause stomachache and other stomach focuses；Blood pressure rise, the heart can be caused Jump quickening, even cardiac arrhythmia and induce heart disease；Tunica mucosa bronchiorum can be damaged, triggers tracheitis；Poison brain cell, suction can be made There is central nervous system disorder in cigarette person；The formation and breeding of cancer cell can be promoted.

Carbon monoxide is a kind of gas of colorless and odorless, it has often been said that gas poisoning, just refer to anthracemia.One The affinity of carbonoxide and the hemoglobin to heart transmission energy is higher than oxygen 250 times, when people suck a more oxidation During carbon, carbon monoxide combines to form substantial amounts of carbon with hemoglobin and closes hemoglobin, and oxyhemoglobin greatly reduces, and causes Tissue and organ hypoxia, and then a variety of organs such as brain, heart is produced irreversible damage.An oxygen can be produced during every cigarette burning Change 20-30 milligrams of carbon, if many smokers are gathered in crowded and unaired room, the carbonomonoxide concentration in air can Up to 0.05%, close to the concentration that gas poisoning occurs.Carbon conjunction hemoglobin concentration is about in the normal human of non-smoking 0.5%, and carbon in smoking severe patient's body closes hemoglobin and is up to 15% -20%, that is to say, that have 15% -20% it is blood red Albumen loses the function of conveying oxygen, so as to cause anoxic.

Tar is a kind of resin of brown color tool viscosity, is commonly called as " tobacco tar ", tar contains a variety of carcinogenic substances.And can The trachea-bronchial epithelial cell and alveolar surface for being attached to smoker produce physics, stimulation chemically, insulting respiratory function.

BaP is strong carcinogen, and the BaP in cigarette is directly sucked in or diffused in interior by smoker, dense. In the cigarette package that burns, the BaP of 0.24-0.28 microgram can be produced.There is statistical findings to show, the benzo in air Pyrene content often increases by 1 microgram/1000 cubic metre, and lung cancer morbidity rate will be made to increase by 5% -15%.

Radioactive substance:Contain in cigarette smoke²¹⁰Lead and²⁰¹Two kinds of half-rate phases of polonium very long radio isotope, smoking When can be absorbed into lung and lithosomic body.They constantly release ray, long-term damage lung tissue.

Irritant compound:Contain a variety of irritant compounds in tobacco smoke, wherein having hydrogen cyanide, formaldehyde, methacrylaldehyde Deng.The microgram of methacrylaldehyde 45 can be produced without cigarette with filter tip such as 1, the microgram of hydrogen cyanide 100-400, they destroy tunica mucosa bronchiorum, And weaken the function of pulmonary alveolar macrophage, lung and bronchus is easily infected.

Contain the poisonous metals such as arsenic, mercury, cadmium, nickel and lead in tobacco.Wherein cadmium can be accumulated in vivo, cause asthma, pulmonary emphysema； Micro cadmium can kill the sperm in vas deferens, influence to give birth to；Cadmium enters bone tissue, causes bone decalcification, deformation, becomes fragile, pole Easily fracture；Every cigarette microgram containing cadmium 1-2, wherein 5% is absorbed by the body.

Other harmful substances:Still contain a variety of oxious components, such as carcinogen --- N-nitrosodimethylamine, methyl in tobacco Ethyl nitrosamine, diethylnitrosamine, nitrosopyrolidine, hydrazine, vinyl chloride, urethane etc.；Promote cancer material --- formaldehyde benzene alcohol, Aliphatic acid etc..

Smoking is not only harmful in itself to smoker, while also to periphery, other people cause damage.The cigarette for having a suck of cigarette and spraying Contain 4,000,000,000 micronic dusts, hundreds of compounds in mist.Including tens kinds of Toxics and carcinogenic substance.Therefore, in public places It is very harmful with indoor smoke.One people's smoking, neighbouring people turn into " involuntary smoker ".Tar and nicotine in smog The content of content, even more than smoker suction is twice, and carbon monoxide is four times greater, and 3,4- BaPs are big two times, ammonia and nitrous Amine is big 50 times.Research finds that smog can damage the bronchium of the people of non-smoking, causes bronchitis, and having smog Room in, air can be caused dirty, make one to feel uncomfortable in chest, feel suffocated, unsmooth breath, tired mind, or even the disease such as headache, giddy Shape.

Extensive smoking can pollute to local air.Haze is that a kind of atmosphere pollution formed by solid particle shows As.Its core is with suspended particulate micronic dust existing for aerosol state in air, wherein including hundreds of chemical substance.It Can invade in human respiratory tract and the lobe of the lung, long-term exposure can cause respiratory system, cardiovascular system, hematological system, reproduction The diseases such as system, the harm to the elderly and infant is more so.PM2.5 concentration often increases by 10 micro- grams ms³, lung cancer pathogenicity rate meeting Rise 33%.

Haze is specific weather condition and the result of mankind's activity interaction.The economy of high density population and social activities A large amount of fine particles (PM10 or PM2.5) will necessarily be discharged, once discharge exceedes atmospheric air circulation ability and carrying degree, fine particle Concentration gathers continuance area.Now if influenceed by quiet steady weather etc., easily there is large-scale haze.Extensive smoking It is one of main contributions mode of haze phenomenon.

Newest report is shown, in 500 cities of Largest In China, reaches the World Health Organization only less than 1% city The air quality standard of recommendation；At the same time, 10 cities of global air pollution most serious have 7 in China.

So market has huge demand for the individual protection material related to smoking process and technology.Cigarette burns Harm to human body and environment is realized by way of discharge small aerosol particle, so effectively absorption aerosol Grain and to limit it to leave cigarette filter tip be practicable method.

It is to use filter tip to be used to reduce the main method of harmfulness of smoking currently on the market, wherein usually contain activated carbon or Person's acetate fiber class organic high molecular polymer mixes with triacetyl glycerine class plasticizer.But these materials are adsorbed with The species and capacity of evil material have great limitation, especially in dry conditions, effectively eliminate or reduce far from reaching The demand of harmfulness of smoking.

U.S. Patent number US6615843 discloses one kind by antioxidant such as ascorbic acid or citric acid, para hydroxybenzene first The tobacco smog filte r of acid butyl ester, melatonin, resveratrol, selenium, ubiquinone or green tea and " mineral matter " of absorption composition Cooperative compositions, such as activated carbon, clinoptilolite, ferrous chloride and ferrite.Antioxidant is reducing perfume as scavenger It is effective in terms of free radical in cigarette smog, and activated carbon or similar adsorbent " mineral matter " adsorb a large amount of volatile matters.Simultaneously The catalyzing and condensing reaction of the phenol and aldehyde that are considered as noxious material is disclosed in smoke from cigarette.However, the patent is without public affairs Volatile carbonyl compound or phenols are opened to any catalyzed conversion of not volatile chemical substance.

U.S. Patent number US6712471 disclose a kind of method added into cigarette metal oxide nanometer dimension cluster or Nano particle can be catalyzed the toxic gas carbon monoxide (CO) contained in smog and be converted into carbon dioxide (CO 2) or absorption one Carbonoxide is in itself.These cluster compound materials are mixed in the component of smoking article, and wherein component is selected from tobacco cut filler, Cigarette paper and cigarette filter material.However, the patent is without the noxious material disclosed in any reduction smoke from cigarette beyond CO Method.

But these methods have the defects of apparent, the pollutant kind that can be handled is limited, poor efficiency, practicality Lowly.Therefore there is an urgent need to can fully eliminate the efficient new technology of smoking process pollution in market.

The content of the invention

The purpose of the present invention is obtained containing renewable hydrophilic nano-fiber materials and metallorganic porous three-dimensional The composition of framework material, said composition can effectively eliminate cigarette combustion process to smoker, neighbouring personnel and surrounding enviroment Harm.Said composition can also be used for preparing mouth mask and in-car and indoor air cleaner.

A kind of control of the present invention and the composition for eliminating harmful substance in cigarette or air, including containing micro- viscous with surface Nano-fiber materials, the three-dimensional porous system material of metallorganic skeleton of property, wherein, the nano-fiber materials Weight ratio with the three-dimensional porous system material of metallorganic skeleton is 0.1~1.5：6.0~9.7, the metallorganic bone The three-dimensional porous system material of frame, the surface area in multiple holes are greater than about 500m²/g；Preferably from about 500 to about 15000m²/ g, more preferably It is about 1000 to about 10000m²/ g, most preferably about 2000 to about 6000m²/g.Its porous average pore sizes be about 0.005 to About 15cm³/ g, preferably from about 0.05 to about 5cm³/g；And the skeleton of metallorganic stephanoporate framework material have about 0.03 to About 5g/cm³Or about 0.3 to about 1.5g/cm³In the range of density.

The composition of the invention described above, further comprising polymers capable of swelling and auxiliary material.

The composition of the invention described above, nano-fiber materials, the three-dimensional porous system material of metallorganic skeleton, can The weight of swollen polymer and auxiliary material ratio is 0.1~1.5：6.0~9.7：0.1~7.0：0.1~1.5, it is particularly preferred as 0.1：9.7：0.1：0.1, or 0.25：9.25：0.25：0.25；Or 0.5：8.5：0.5：0.5；Or 1.0：7.0：1.0： 1.0；Or 1.5：6.5：1.5：Or 0.1 1.5.：6.5：0.0065：0.023 or 0.1：6.3：0.0063：0.019.

The composition of the invention described above, the nano-fiber materials are selected from one of the following or a variety of：Lignin Sodium sulfonate, corn hemicellulose, corn marrow and sodium alginate.The auxiliary material is selected from maltose, cyamopsis tetragonolobus, glycerine, rosin Resin, calcium chloride and urea.The polymers capable of swelling is selected from cross-linked polyacrylamide；Crosslink part hydrolyzed polyacrylamide； Crosslinked polyacrylate；Crosslinked salt polyacrylate；The salt of crosslinked polyacrylate；It is crosslinked hydrolyzed polyacrylonitrile；It is crosslinked carboxyalkyl The salt of starch；The salt of crosslinked carboxyalkylcellulose；The salt of any crosslinking carboxyalkyl polysaccharide；Acrylamide and acrylate monomer Cross-linked copolymer；The crosslinked starch being grafted with acrylonitrile and acrylate monomer；2- allyl sulphonic acids, 2- acrylamidos -2- In the cross-linked polymer of methyl isophthalic acid-propane sulfonic acid, 3- allyloxy -2- hydroxyl -1- propane sulfonic acid, acrylamide and acrylic monomers It is one or more.

The composition of the invention described above, the three-dimensional porous framework material of metallorganic, wherein, metal is selected from following gold Belong to one or more in ion：Li⁺,Na⁺,K⁺,Rb⁺,Be²⁺,Mg²⁺,Ca²⁺,Sr²⁺,Ba²⁺,Sc³⁺,Y³⁺,Ti⁴⁺,Zr⁴⁺,Hf⁴⁺,V⁴ ⁺,V³⁺,V²⁺,Nb³⁺,Ta³⁺,Cr⁺,Cr²⁺,Cr⁶⁺,Mo³⁺,W³⁺,Mn³⁺,Mn²⁺,Re³⁺,Re²⁺,Fe³⁺,Fe²⁺,Ru³⁺,Ru²⁺,Os³⁺, Os²⁺,Co³⁺,Co²⁺,Rh²⁺,Rh⁺,Ir²⁺,Ir⁺,Ni²⁺,Ni⁺,Pd²⁺,Pd⁺,Pt²⁺,Pt⁺,Cu²⁺,Cu⁺,Ag⁺,Au⁺,Zn²⁺,Cd²⁺, Hg²⁺,Al³⁺,Ga³⁺,In³⁺,Tl³⁺,Si⁴⁺,Si²⁺,Ge⁴⁺,Ge²⁺,Sn⁴⁺,Sn²⁺,Pb⁴⁺,Pb²⁺,As⁵⁺,As³⁺,As⁺,Sb⁵⁺,Sb³⁺, Sb⁺,Bi⁵⁺,Bi³⁺And Bi⁺And its their inorganic salts, wherein, the inorganic salts are selected from by sulfate, nitrate, nitrite, Sulphite, bisulfites, phosphate, hydrophosphate, dihydric phosphate, diphosphate, triphosphate, phosphite, chlorine Compound, chlorate, bromide, bromate, iodate, iodate, carbonate, in the group of bicarbonate composition it is inorganic it is cloudy from Son, specifically include diphosphate, sulfide, disulfate, selenides, selenate, selenate, tellurides, tellurate, telluride Hydrogen, nitride, phosphide, arsenide, arsenate, arsenic acid hydrogen salt, disodium hydrogen arsenate, stibate, stibate, metaantimmonic acid hydrogen salt, boron Hydrochlorate, borate, hydrogen borate salt, perchlorate, chlorite, hypochlorite, perbromate, bromate, hypobromite, high iodine Hydrochlorate, iodate and hypoiodite.The organic matter is selected from saturated aliphatic compound, unsaturated lipid compounds of group, aromatic compounds Thing or aliphatic series and aromatic compounds, and there is a coordination that can be with metal ion and/or with two or more metallic atoms Key forms the functional group of at least two keys.The functional group of the organic matter is selected from：-CO₂H ,-CS₂,-NO₂,-B (OH)₂,-SO₃H ,- Si(OH)₃,-Ge (OH)₃,-Sn (OH)₃,-Si (SH)₄,-Ge (SH)₄,-Sn (SH)₃,-P0₃H ,-As0₃H ,-As0₄H ,-P (SH) (SH)₃,-CH (SH)₂,-C (SH)₃,-CH (NH₂)₂,-C (NH₂)₃,-CH (OH)₂,-C (OH)₃,-CH (CN)₂Or-C (CN)₃,-CH (RSH)₂,-C (RSH)₃,-CH (RNH₂)₂,-(RNH₂)₃,-CH (ROH)₂,-C (ROH)₃With-C (RCN)₃, wherein, R is C₁-C₅'s Alkylidene, substituted or unsubstituted aryl containing one or two aromatic kernel contain N, O and/or S heterocyclic aryl.Its In, the C₁-C₅Alkylidene be selected from methylene, ethylidene, positive acrylic, isopropenyl, n-butene base, isobutenyl, tertiary fourth Alkenyl and n-pentene base.The aliphatic compounds are straight chain and/or side chain and/or the aliphatic compounds of ring-type, comprising comprising 1 to 15 carbon atoms, preferably 2 to 14 carbon atoms, more preferably 3 to about 12 carbon atoms.

The composition of the invention described above, the organic matter are selected from one of the following or a variety of：Alkylamine and its corresponding Alkylammonium salt, it contains the straight chain with 1 to 20 carbon atom, side chain or cyclic aliphatic group, alkarylamine and its corresponding Aryl ammonium salt with 1 to 5 phenyl ring, containing the straight chain with 1 to 20 carbon atom, the alkane of side chain or cyclic aliphatic group Ji phosphonium salts, there is the Fang Ji phosphonium salts of 1 to 5 phenyl ring, alkyl organic acid and its corresponding salt, it contains with 1 to 20 carbon original Straight chain, side chain or the cyclic aliphatic group of son, aryl organic acid and its corresponding salt, have 1 to 5 phenyl ring, contain 1 to 20 The aliphatic alcohol of the straight chain of carbon atom, side chain or cyclic aliphatic group, and the aryl alcohol with 1 to 5 phenyl ring.

The composition of the invention described above, the organic matter are selected from one of the following or a variety of:Ammonia, carbon dioxide, methane, Oxygen, argon gas, nitrogen, ethene, hexane, benzene, toluene, (T, M, P) dimethylbenzene, chlorobenzene, nitrobenzene, naphthalene, thiophene, pyridine, acetone, 1,2- dichloroethanes, dichloromethane, tetrahydrofuran, monoethanolamine, triethylamine, trifluoromethane sulfonic acid DMF, N, N- diethylformamides, dimethyl sulfoxide (DMSO), chloroform, bromofom, methylene bromide, iodoform, diiodomethane, halogenated organic solvent, N, N- Dimethyl acetamide, N, pyrrolidones, amide solvent, picoline, lutidines, Anaesthetie Ether, and its mixture.Grass Acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane dicarboxylic acid, 4- oxo pyrans -2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, decane dicarboxyl Acid, heptadecane dicarboxylic acid, 1,9- heptadecane dicarboxylic acid, heptadecane dicarboxylic acid, acetylenedicarboxylic acid, 1,2- phthalic acid, 2,3- pyrroles Diphosphoglyceric acid, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxylic acids, Isosorbide-5-Nitrae-phthalic acid, terephthalic acid (TPA), miaow Azoles -2,4- dicarboxylic acids, 2- methylquinoline -3,4- dicarboxylic acids, quinoline -2,4- dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids, 6- chlorine Quinoxaline -2,3- dicarboxylic acids, 4,4'- diamino-phenyl ethane -3,3'- dicarboxylic acids, quinoline -3,4- dicarboxylic acids, 7- chloro-4-hydroxyls Quinoline -2,8- dicarboxylic acids, dicarboxylic acids, di-imidodicarboxylic acid, pyridine -2,6- dicarboxylic acids, 2-methylimidazole -4,5- dicarboxylic acids, Thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyl imidazole-4,5-dicarboxylic acids, oxinane -4,4- dicarboxylic acids, -3,9- dicarboxyls Acid, dioctyl phthalate, Pluriol E 200- dicarboxylic acids, 3,6- dioxaoctane dicarboxylic acids, 3,5- cyclohexadiene -1,2- dicarboxyls Acid, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- diaminostilbenes, 1- diphenyl -3,3'- dicarboxylic acids, 4,4'- diaminourea hexichol Base -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (phenyl amino) benzene -2,5- dicarboxylic acids, 1,1- naphthyl -5, 5'- dicarboxylic acids, chloro- 8- methylquinolines -2, the 3- dicarboxylic acids of 7-, 1- anilino- anthraquinone -2,4'- dicarboxylic acids, PolyTHF -200- Dicarboxylic acids, Isosorbide-5-Nitrae-bis- (carboxymethyl) piperazine -2,3- dioctyl phthalate, 7- chloroquinoline -3,8- dicarboxylic acids, 1- (4- carboxyls) phenyl -3- (4- Chlorine) phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5,6,7,7- chlordene -5- ENB -2,3- dicarboxylic acids, benzene borine dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazolinium -4,5- dicarboxylic acids, Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid, naphthalene -1,8- dicarboxylic acids, 2- benzophenones - 1,3- dicarboxylic acids, 1, the 3- cis dicarboxylic acids of dibenzyl -2- oxo-imidazole alkane -4,5-, 2,2'- diquinoline -4,4'- dicarboxylic acids, pyrrole Pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane dicarboxylic acids, O- hydroxy benzophenone keto-dicarboxylic acids, Pluriol E 300- dicarboxyls Acid, Pluriol E 400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazine dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- diaminodiphenyl ether di-imidodicarboxylic acids, 4,4'- diamino-diphenyl first Alkane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, di-imidodicarboxylic acid, NDA, 1,3- adamantane dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxyl group -2,3- naphthalenedicarboxylic acids, 8- nitro -2,3- naphthalene sulfonic acids, 8- sulfo groups -2,3- Naphthalenedicarboxylic acid, anthracene -2,3- dicarboxylic acids, 2', 3'- diphenyl-para-terpheny -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- dicarboxylic acids, miaow Azoles -4,5- dicarboxylic acids, heterochromatic alkene -2, the 8- dicarboxylic acids of 4 (1H)-oxos, 5- tert-butyl group -1,3- phthalic acids, 7,8- quinoline diformazans Acid, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxylic acids, hexylene glycol dicarboxylic acids, tetradecane dicarboxylic acid, 1,7- heptan dicarboxylic acids, 5- hydroxyls Base -1,3- phthalic acid, pyrazine -2,3- dicarboxylic acids, furans -2-, 5- dicarboxylic acids, 1- nonene -6,9- dicarboxylic acids, 20 carbon diene Acid, 4,4'- dihydroxydiphenyl methane -3,3'- dicarboxylic acids, 1- amino -4- methyl -9,10- dioxo -9,10- dihydro-anthraquinones E-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, cyclohexene -2,3- dicarboxylic acids, 2,9- dichloro fluorine borine -4,11- dicarboxylic acids, 7- Methylquinoline -6,8 dicarboxylic acids between chloro- 3-, 2,4- dichloro benzophenone -2', 5'- dicarboxylic acids, 1,3- phthalic acid, 2,6- pyridines Dicarboxylic acids, 1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles -3,4- dicarboxylic acids, anthraquinone -1,5- dicarboxylic acids, 3,5- pyrroles Azoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, heptane -1,7- dicarboxylic acids, cyclobutane -1,11,4- dicarboxylic acids, 1, the 14- tetradecane Dicarboxylic acids, 5,6- dehydrogenation norbornane -2,3- dicarboxylic acids, 5- ethyls -2,3- pyridinedicarboxylic acid or its esters.2- hydroxyl -1,2, 3- tricarballylic acids, the quinoline tricarboxylic acids of 7- chloro- 2,3,8-, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- phosphines -1,2,4- butane Tricarboxylic acids, 1,3,5- benzenetricarboxylic acid, 1- hydroxyls -1,2,3- tricarballylic acids, 4,5- dihydro -4,5- dioxos -- 1H- pyrrolo-es [2, 3-F] quinoline -2,7,9- tricarboxylic acids, 5- acetyl group -3- amino -6- methylbenzenes -1,2,4- tricarboxylic acids, 3- amino -5- benzoyls Base -6- methylbenzenes -1,2,4- tricarboxylic acids, 1,2,3- tricarballylic acid or laurate and its esters.1,1- dioxolyls [BCD] Thiophene -3,4,9,10- tetrabasic carboxylic acids,-tetrabasic carboxylic acid, -3,4,9,10- tetrabasic carboxylic acids, -1,12- sulfonyls -3,4,9,10 tetracarboxylic acids Acid, 1,2,3,4- BTCA, meso -1,2,3,4- BTCAs, decane -2,4,6,8- tetrabasic carboxylic acids, Isosorbide-5-Nitrae, 7,10, 13,16- hexaoxacyclooctadecane-6s -2,3,11,12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11,12- dodecyl tetracarboxylic acid Acid, 1,2,5,6 hexane tetrabasic carboxylic acid, 1,2,7,8- octane tetrabasic carboxylic acid, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2,9,10- decane tetrabasic carboxylic acid, Benzophenone tetrabasic carboxylic acid, 3,3', 4,4'- benzophenone tetrabasic carboxylic acids, tetrahydrofuran tetrabasic carboxylic acid, pentamethylene tetrabasic carboxylic acid, pentamethylene -1, 2,3,4- tetrabasic carboxylic acids and its salt.

The composition of the invention described above, the three-dimensional porous system material of metallorganic skeleton, the surface area in multiple holes Greater than about 500m²/g；Preferably from about 500 to about 15,000m²/ g, even more preferably about 1,000 to about 10,000m²/ g, it is most preferably About 2,000 to about 6,000m²/g.Its porous average pore sizes is about 0.005 to about 15cm³/ g, preferably from about 0.05 to about 5cm³/g；And the skeleton of metallorganic stephanoporate framework material has about 0.03 to about 5g/cm³Or about 0.3 to about 1.5g/ cm³In the range of density.

The composition of the invention described above, the three-dimensional porous system material of metallorganic skeleton are selected from：

A metallic zincs and organic group (the three-dimensional porous material of 1,3,5- tri- (4- carboxyl phenyls) benzene synthesis,

B metallic irons and the three-dimensional porous material of the benzene tricarbonic acid of organic group 1,3,5- synthesis,

C metallic coppers and the three-dimensional porous material of the benzene tricarbonic acid of organic group 1,3,5- synthesis,

The three-dimensional porous material that D metallic aluminiums synthesize with organic group PETP, and

The three-dimensional porous material that E metallic zincs synthesize with organic group 2-methylimidazole.

Another object of the present invention is to provide a kind of composition for controlling and eliminating harmful substance in cigarette or air Preparation method, this method comprises the following steps：

1) nano-fiber materials of surface microviscosity are dissolved in water, and form the solution that concentration is 0.1-10%；

2) by weight 1：5 mix solution with the three-dimensional porous system material of metallorganic skeleton, are well mixed；

3) it is placed in the drier being connected with vavuum pump, is dried in vacuo, produces under enough condition of negative pressure.

The preparation method of the invention described above, further comprise adding water-swellable polymer in the solution described in step 1) And auxiliary material.

The preparation method of the invention described above, the nano-fiber materials are selected from following one or more：Sulfomethylated lignin Sour sodium, corn hemicellulose, corn marrow and sodium alginate, the auxiliary material are selected from maltose, cyamopsis tetragonolobus, glycerine, rosin tree Fat, the one or more in calcium chloride and urea.

The preparation method of the invention described above, the percentage by weight of component is in the solution of step 1)：Maltose is 0.1- 5%th, sodium lignin sulfonate 0.1-7%, corn hemicellulose 0.1-10%, corn marrow be 0.1-10%, sodium alginate be 0.1-4%, cyamopsis tetragonolobus 0.1-3%；Glycerine is 0.1-5%；Rosin resin is 0.1-5%, calcium chloride be 0.1-3% and/or Urea is 0.1-8%.

The composition of harmful substance is placed in cigarette production process in the control of the present invention and elimination cigarette or air The interface of cigarette and filter tip and form effective transfer barrier, to eliminate and control harmful substance caused by cigarette combustion process Purposes.

The composition of harmful substance is preparing mouth mask, in-car air filtration in the control of the present invention and elimination cigarette or air Purposes in device and indoor air cleaner.

The composition specific implementation method of harmful substance is as follows in the control of the present invention and elimination cigarette or air.

In a particular embodiment, a kind of control of the invention and the composition of harmful substance in cigarette or air is eliminated, Including containing the nano-fiber materials with surface microviscosity, the three-dimensional porous system material of metallorganic skeleton, further Include polymers capable of swelling and auxiliary material.

Composition based on nanometer microviscosity functional material catches granule micronic dust in different size ranges, absorption Metal, organic matter and bioactive materials steam, it can effectively remove in air the micro- of 10 microns, 2.5 microns and following size Dirt, so as to reduce harm of the multiple pollutant to occupant's health.Purification of the nanometer microviscosity functional material to automotive interior air Effect is derived from nanoscale function surface and the bacterium in air, dust, smog, metal, the powered particulate of organic matter isopolarity It is combined, and is gathered into the particle sedimentation of relatively large-scale and eliminates PM2.5 harm.It is demonstrated experimentally that floating dust diameter is smaller, more hold Easily adsorbed by tacky surfaces, assemble and then settle and be fixed in filter core.With strong hydrophilic above-mentioned material in part Its absorption property can be optimal index under hydrated state.

Polymers capable of swelling includes and is selected from cross-linked polyacrylamide；Crosslink part hydrolyzed polyacrylamide；Crosslinked polypropylene Acid esters；Crosslinked salt polyacrylate；The salt of crosslinked polyacrylate；It is crosslinked hydrolyzed polyacrylonitrile；It is crosslinked the salt of carboxyalkyl starch；Hand over Join the salt of carboxyl alkyl cellulose；The salt of any crosslinking carboxyalkyl polysaccharide；The cross-linked copolymer of acrylamide and acrylate monomer； The crosslinked starch being grafted with acrylonitrile and acrylate monomer；2- allyl sulphonic acids, 2- acrylamido -2- the-the third sulphurs of methyl isophthalic acid The cross-linked polymer of acid, 3- allyloxy -2- hydroxyl -1- propane sulfonic acid, acrylamide and acrylic monomers；And its any combinations.

The three-dimensional porous system material of metallorganic skeleton is the gold for having ultra-large molecular dimension three-dimensional cavity network Belong to organic matter framework material.As there are two bidentate organic compounds of coordinate bond comprising at least one and at least one metal ion Porous metal-organic framework.

Metal in the three-dimensional porous dimension framework material of metallorganic can form porous metals organic matter skeleton Any suitable metal of material, it has the structure for the target chemical substances for allowing reversible load effective dose.For example, metal can With known containing one of metal group in the periodic table of elements, the metal can be Ia, IIa in the periodic table of elements, IIIa races, IIIa races to Villa races and Ib are specifically wrapped but are not limited to VIb races, Li, Na, K, Rb, Cs, Fr, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ro, Os, Co, Rh, Ir, Ni, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Ti, Si, Ge, Sn, Pb, As, Sb and Bi.

In the three-dimensional porous framework material of metallorganic, the organic matter refers to organising comprising at least one functional group Compound, the functional group can be formed with given metal ion and/or with a coordinate bond of two or more metallic atoms At least two keys, such as two coordinate bonds.For example, can form the suitable functional group of coordinate bond includes：-CO₂H ,-CS₂,- NO₂,-B (OH)₂,-SO₃H ,-Si (OH)₃,-Ge (OH)₃,-Sn (OH)₃,-Si (SH)₄,-Ge (SH)₄,-Sn (SH)₃,-P0₃H ,- As0₃H ,-As0₄H ,-P (SH) (SH)₃,-CH (RSH)₂,-C (RSH)₃,-CH (RNH₂)₂,-(RNH₂)₃,-CH (ROH)₂,-C (ROH)₃,-C (RCN)₃, wherein R is the alkylidene for example with 1,2,3,4 or 5 carbon atom, such as methylene, ethylidene, just Propylene, isopropenyl, n-butene, isobutene, tertiary butylene or n-pentene base, or the aryl comprising one or two aromatic kernel, example Such as two C6 rings that can be condensed, and can suitably be substituted at least one substitution in each case independently of one another Base, and/or at least one hetero atom can be included in each case independently of one another, such as N, O and/or S. are in embodiment In, it can also be such as-CH (SH) that the above-mentioned group R of functional group therein, which can be not present,₂,-C (SH)₃,-CH (NH₂)₂,-C (NH₂)₃,-CH (OH)₂,-C (OH)₃,-CH (CN)₂Or-C (CN)₃.Include at least one functional group (or at least two functional groups) Organic compound can be derived from saturated aliphatic compound, unsaturated lipid compounds of group, aromatic compounds or aliphatic series and aromatics Compound.Aliphatic compounds (or aliphatic portion of aliphatic series and aromatic compounds) can be straight chain and/or side chain and/or ring-type 's.For example, aliphatic compounds (or aliphatic portion of aliphatic series and aromatic compounds) can include 1 to about 15 carbon atom, example Such as from about 2 to about 14 carbon atoms, or about 3 to about 12 carbon atom atoms.Aromatic compounds or aromatic series and aliphatic chemical combination The aryl moieties of thing can have one or more rings, such as two, three, four or five rings.This ring can be each other Separate and/or exist in molten form.Independently of one another, each ring can include at least one hetero atom, such as N, O, S, B, P, Si or Al.In embodiments, at least one two bidentate organic compounds can be dicarboxylic acids, tricarboxylic acids, tetrabasic carboxylic acid or imidazoles Or other derivatives of amine.

In the above-described embodiment, suitable dicarboxylic acids can include such as oxalic acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane Dicarboxylic acids, 4- oxo pyrans -2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, decane dicarboxylic acid, heptadecane dicarboxylic acid, 1,9- ten seven Alkane dicarboxylic acids, heptadecane dicarboxylic acid, acetylenedicarboxylic acid, 1,2- phthalic acid, 2,3- pyridinedicarboxylic acids, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxylic acids, Isosorbide-5-Nitrae-phthalic acid, terephthalic acid (TPA), imidazoles -2,4- dicarboxylic acids, 2- methylquinoline -3, 4- dicarboxylic acids, quinoline -2,4- dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids, 6- chloro-quinoxaline -2,3- dicarboxylic acids, 4,4'- diaminos Base diphenylphosphino ethane -3,3'- dicarboxylic acids, quinoline -3,4- dicarboxylic acids, 7- chloro-4-hydroxyl quinoline -2,8- dicarboxylic acids, dicarboxylic acids, two is sub- Diamino dicarboxylic acid, pyridine -2,6- dicarboxylic acids, 2-methylimidazole -4,5- dicarboxylic acids, thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyls Imidazole-4,5-dicarboxylic acid, oxinane -4,4- dicarboxylic acids, -3,9- dicarboxylic acids, dioctyl phthalate, Pluriol E 200- dicarboxyls Acid, 3,6- dioxaoctane dicarboxylic acids, 3,5- cyclohexadiene -1,2- dicarboxylic acids, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- Diaminostilbene, 1- diphenyl -3,3'- dicarboxylic acids, 4,4'- diamino-diphenyl -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxyl Acid, Isosorbide-5-Nitrae-bis- (phenyl amino) benzene -2,5- dicarboxylic acids, 1,1- naphthyl -5,5'- dicarboxylic acids, the chloro- 8- methylquinolines -2,3- bis- of 7- Carboxylic acid, 1- anilino- anthraquinone -2,4'- dicarboxylic acids, PolyTHF -200- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (carboxymethyl) piperazine -2,3- bis- Formic acid, 7- chloroquinoline -3,8- dicarboxylic acids, 1- (4- carboxyls) phenyl -3- (4- chlorine) phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5, 6,7,7- chlordene -5- ENB -2,3- dicarboxylic acids, benzene borine dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazoliniums -4,5- bis- Carboxylic acid, Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid, naphthalene -1,8- dicarboxylic acids, 2- benzophenone -1,3- dicarboxylic acids, 1,3- dibenzyl -2- oxo miaows The cis dicarboxylic acids of oxazolidine -4,5-, 2,2'- diquinoline -4,4'- dicarboxylic acids, pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane Dicarboxylic acids, O- hydroxy benzophenone keto-dicarboxylic acids, Pluriol E 300- dicarboxylic acids, Pluriol E 400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazine dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- bis- Amino-diphenylethers di-imidodicarboxylic acid, 4,4'- diaminodiphenyl-methane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, two Iminodicarboxylic acid, NDA, 1,3- adamantane dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxies Base -2,3- naphthalenedicarboxylic acid, 8- nitro -2,3- naphthalene sulfonic acids, 8- sulfo group -2,3- naphthalenedicarboxylic acids, anthracene -2,3- dicarboxylic acids, 2', 3'- bis- Phenyl-para-terpheny -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- dicarboxylic acids, imidazole-4,5-dicarboxylic acid, the 4 heterochromatic alkene of (1H)-oxo - 2,8- dicarboxylic acids, 5- tert-butyl group -1,3- phthalic acids, 7,8- quinolinedicarboxylic acids, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxyls Acid, hexylene glycol dicarboxylic acids, tetradecane dicarboxylic acid, 1,7- heptan dicarboxylic acids, 5- hydroxyl -1,3- phthalic acids, pyrazine -2,3- dicarboxyl Acid, furans -2-, 5- dicarboxylic acids, 1- nonene -6,9- dicarboxylic acids, eicosadienoic acid, 4,4'- dihydroxydiphenyl methane -3, 3'- dicarboxylic acids, 1- amino -4- methyl -9,10- dioxo -9,10- dihydro-anthraquinone e-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, Cyclohexene -2,3- dicarboxylic acids, 2,9- dichloro fluorine borine -4,11- dicarboxylic acids, methylquinoline -6,8 dicarboxylic acids between the chloro- 3- of 7-, 2,4- Dichloro benzophenone -2', 5'- dicarboxylic acids, 1,3- phthalic acid, 2, dipicolimic acid 2,1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles -3,4- dicarboxylic acids, anthraquinone -1,5- dicarboxylic acids, 3,5- pyrazoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, Heptane -1,7- dicarboxylic acids, cyclobutane -1,11,4- dicarboxylic acids, 1,14- tetradecane dicarboxylic acid, 5,6- dehydrogenation norbornanes -2,3- Dicarboxylic acids, 5- ethyls -2,3- pyridinedicarboxylic acid or its esters.

In the above-described embodiment, suitable tricarboxylic acids can include such as 2- hydroxyls -1,2,3- tricarballylic acids, and 7- is chloro- 2,3,8- quinoline tricarboxylic acids, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- phosphines -1,2,4- butane tricarboxylic acids, 1,3,5- benzene three Formic acid, 1- hydroxyls -1,2,3- tricarballylic acids, 4,5- dihydro -4,5- dioxos -- 1H- pyrrolo-es [2,3-F] quinoline -2,7,9- tri- Carboxylic acid, 5- acetyl group -3- amino -6- methylbenzenes -1,2,4- tricarboxylic acids, 3- amino -5- benzoyl -6- methylbenzenes -1,2,4- Tricarboxylic acids, 1,2,3- tricarballylic acid or laurate and its esters.

In the above-described embodiment, suitable tetrabasic carboxylic acid can include, for example, 1,1- dioxolyl [BCD] thiophene- 3,4,9,10- tetrabasic carboxylic acids,-tetrabasic carboxylic acid, such as -3,4,9,10- tetrabasic carboxylic acids or -1,12- sulfonyls -3,4,9,10 tetracarboxylic acids Acid, BTCA, such as 1,2,3,4- BTCAs or meso -1,2,3,4- BTCAs, decane -2,4,6,8- tetra- Carboxylic acid, Isosorbide-5-Nitrae, 7,10,13,16- hexaoxacyclooctadecane-6s -2,3,11,12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11, 12- dodecyl tetrabasic carboxylic acids, 1,2,5,6 hexane tetrabasic carboxylic acid, 1,2,7,8- octane tetrabasic carboxylic acid, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2, 9,10- decane tetrabasic carboxylic acids, benzophenone tetrabasic carboxylic acid, 3,3', 4,4'- benzophenone tetrabasic carboxylic acids, tetrahydrofuran tetrabasic carboxylic acid or ring penta Alkane tetrabasic carboxylic acid, such as pentamethylene -1,2,3,4- tetrabasic carboxylic acids and its esters.

The control of the present invention and the composition for eliminating harmful substance in cigarette or air, the suitable metallorganic bone Frame includes multiple holes in the accessible site with multiple reversible intakes for one or more target chemical substancess.Metal Organic matter skeleton, such as the porous metals organic matter skeleton comprising multiple come-at-able holes and/or composition metal organic matter skeleton (the metallorganic framework material of the load coated with polymeric material, such as compound between polymer) can load target chemical Material, such as the chemical entities that target be able to can connect each other with metallorganic skeleton.Porous metals organic matter skeleton it is more Individual hole can include micropore and/or mesoporous." micropore " is defined as the micropore with about 2nm or smaller diameter, such as in about 2nm extremely Diameter or about 1nm about in the range of 0.01nm are to the diameter about in the range of 0.1nm；" mesoporous " is by about 2 to about in the range of 50nm Diameter definition, e.g., from about 5nm is to the diameter about in the range of 40nm, or about 10nm to the about 30nm of the diameter about in the range of 40nm. Can check micropore and/or mesoporous presence by means of absorption measurement, these measurements according to DIN 66135, DIN 66131 and/ Or DIN 66134 determines absorptivity of the metallorganic skeleton for the nitrogen of 77 Kelvins.Target chemical entities can be containing The molecule of complementary at least one functional group with one or more of multiple holes in metallorganic framework material site.This The complementary functional groups of sample can pass through the non-covalent of one or more of multiple holes in metallorganic framework material site Interaction has high-affinity.In such embodiments, metallorganic framework material can include at least one two Bidentate organic compound (or one or more other parts), its can with functionalization to produce the site with required function, such as The One function group of site pre-selected target chemical entities with least complementary functional group.Metallorganic framework material function This ability changed is useful, because hole can be arranged with the orderly site of high concentration, its characteristic such as hydrophobicity, and hydrophily, Polarity, nonpolar and/or spatial character can be customized to match the target chemical entities of degree of functionality, so as to allow to adjust metal Organic matter framework material/target chemical entities system is to realize target chemical entities from the phase in the hole of metallorganic framework material Diffusion/rate of release of prestige.In embodiments, target chemistry entity can be functionalized with one or more functional groups, example Such as, absorption/release dynamics to improve metallorganic framework material intake level and/or adjust target chemistry material.Can be with Include such as halogen in the presence of the functional group of (or addition) to metallorganic framework material and/or target chemical entities, alcohol, ether, Ketone, carboxylic acid, ester, carbonic ester, amine, acid amides, imines, urea, aldehyde, isocyanates, tosylate, alkane, alkene, alkynes or its group Close.It can select and/or further functionalization specific construction unit so that it is organic to obtain the required metal with preset aperture Thing framework material structure.Generally, the molecular dimension of at least one two bidentate organic compound or other parts is bigger, metallorganic The aperture of framework material is bigger.It is also an option that this porous metals organic matter framework material of the present invention, porous metals are organic The aperture of thing framework material can be by selecting suitable part and/or at least one two bidentate organic compounds to control so that Average pore size in the range of about 0.1nm or about 0.5nm to the average pore size about in the range of 10nm or about 1.0nm to about 5nm models Enclose interior average pore size.

Metallorganic framework material can include pore-size distribution.In such embodiments, metal of the invention has Machine thing framework material can be 100% metallorganic framework material, wherein total metallorganic framework material more than 70% Pore volume, 85% is greater than, or more than 99%, its aperture is less than 100nm, is, for example, less than 50nm or less than 40nm.Implementing In scheme, no more than more than 2% or total pore volume of the 5% of total metallorganic framework material pore volume, such as total pore volume The emptying aperture more than 0.5% formed by aperture more than 50nm emptying aperture, or more than 100nm or more than 200nm.

It can include one or more of following characteristics suitable for the porous metals organic matter framework material of the present invention：It is more Surface area (Langmuir surface areas) in individual hole is greater than about 500m²/g；The surface area in multiple holes can be about 500 to about 15000m²/ g, or the surface area in multiple holes can be about 1000 to about 10000m²/ g, or the surface area in multiple holes can be About 2000 to about 6000m²/g；The average pore sizes in multiple holes comprising porous metals organic matter framework material be about 0.005 to About 15cm³/ g, e.g., from about 0.05 to about 5cm³/g；And the skeleton of porous metals organic matter framework material have about 0.03 to About 5g/cm³Or about 0.3 to about 1.5g/cm³In the range of density.

It can include but is not limited to following option suitable for the porous metals organic matter framework material of the present invention：

A.MOF-177:Metallic zinc and organic group (the three-dimensional porous material of 1,3,5- tri- (4- carboxyl phenyls) benzene synthesis, Molecular formula is C₅₄H₃₀O₁₃Zn₄, molecular weight 1148.The material has 5200 meters of cm of specific surface area²/ g, porosity 1.75cm³/g。 Chemical Abstracts Registry number：676593-65-0, BASF AG's catalogue codeZ377；

B.Fe-BTC:Metallic iron and the three-dimensional porous material of the benzene tricarbonic acid of organic group 1,3,5- synthesis, molecular formula are C₉H₃O₆Fe, molecular weight 263.The material has specific surface area 1540m²/ g, porosity 1.28cm³/g.Chemical Abstracts Registry number： 1195763-37-1, BASF AG's catalogue codeF300；

C.HKUST-1:Jin Shu Ambassadors and the three-dimensional porous material of the benzene tricarbonic acid of organic group 1,3,5- synthesis, molecular formula are C₁₈H₆O₁₂Cu₃, molecular weight 605.The material has specific surface area 2200m²/ g, porosity 1.93cm³/g.Chemical Abstracts Registry Number：51937-85-0, BASF AG's catalogue codeC300；

D.MIL-53:The three-dimensional porous material that metallic aluminium synthesizes with organic group PETP, molecular formula are C8H5O5Al, molecular weight 208.The material has specific surface area 1600m2/g, porosity 1.93cm3/g.Chemical Abstracts Registry Number：Contain mixture 68-12-2 and 10043-01-3, BASF AG's catalogue codeA100；

E.ZIF-8:The three-dimensional porous material that metallic zinc synthesizes with organic group 2-- methylimidazoles, molecular formula are C₈H₁₀N₄Zn, molecular weight 228.The material has specific surface area 1813m²/ g, porosity 2.14cm²/g.Chemical Abstracts Registry Number：59061-53-9, BASF AG's catalogue codeZIF-8。

The control of the present invention and the preparation method for eliminating the composition of harmful substance in cigarette or air are swellable to gather Compound and/or microviscosity fiber are scattered in aqueous solvent, and then metallorganic framework material is absorbed under condition of negative pressure Three-dimensional cavity system.It can be used after partially dried processing.

Elimination specifically described herein refers to remove in the cigarette and air of burning cigarette by the mode such as filtering, reacting and adsorb Harmful substance or PM2.5.

Brief description of the drawings

Fig. 1 is that the cigarette with filter tip of the composition containing the present invention eliminates tobacco use disorded detection means schematic diagram.

Embodiment

Following examples are used for the essence for furtheing elucidate and understanding the present invention, but do not limit the invention in any way Scope.

The composition of the present invention is packaged into cigarette filter on request and can reach expected detoxication effect.

Embodiment 1：It is first according to the part by weight reagent preparation that following table 1 is indicated；Then with metallorganic skeleton Material MOF-177 presses 1:5 part by weight mixing, is placed in the drier that is connected with vavuum pump.Taken out under air-proof condition Vacuum breaks off the connection with vavuum pump in 10 minutes to form enough negative pressure.The product of acquisition is transferred to outside drier, is wrapped in To dry tack free in filter paper.

Table 1

Preparation forms	Corn marrow	Sodium lignin sulfonate	Sodium alginate	Water
					Weight %	1.5	1.5	17	80

The powdered product of the dry tack free is weighed about 0.05 gram, is uniformly positioned over the interface and again of cigarette and filter tip Sealing.Then transition conduit is inserted in filter tip one end and sealed, the other end of transition conduit and the air inlet of air particles detector It is connected and seals.The principle of such particle detector be based on the granule density in units of measurement volumes of air, with microgram/cube Rice is unit.In the indoor environment of unobvious pollution sources, the reading of such detector is generally between 25-40, in The issue of national environmental protection portion of state《Ambient air quality》(GB3095-2012) one-level high-quality air, is belonged to.And cigarette Caused each pollutant is exactly what is existed in the form of aerosol particle and transmit in combustion process, and its yardstick can be less than 2.5 microns (PM2.5).After lighting the above-mentioned cigarette for having used presently disclosed pollution (harmful substance) composition for eliminating, Air particles detector is then turned on, wherein to start gas caused by continuous exhausting suction cigarette combustion (similar for built-in extraction fan In active smoking process).Reading in cigarette combustion overall process is empty to two level between air quality one-level between 45-60 Gas scope.And the common cigarette with filter tip without presently disclosed abatement of pollution composition is contrasted, corresponding reading is significantly More than 500, belong to the six grades of air above seriously polluted.

Embodiment 2：It is first according to the part by weight reagent preparation that following table 2 is indicated；Then with metallorganic skeleton Material FE-BTC presses 1:5 part by weight mixing, is placed in the drier that is connected with vavuum pump.Taken out under air-proof condition true To form enough negative pressure, break off the connection with vavuum pump within empty 10 minutes.The product of acquisition is transferred to outside drier, is wrapped in filter To dry tack free in paper.

Table 2

Preparation forms	Corn marrow	Sodium lignin sulfonate	Sodium alginate	Water
					Weight %	1.5	1.5	7.0	90

The powdered product of the dry tack free is weighed about 0.05 gram, is uniformly positioned over the interface and again of cigarette and filter tip Sealing.Then transition conduit is inserted in filter tip one end and sealed, the other end of transition conduit and the air inlet of air particles detector It is connected and seals.The principle of such particle detector be based on the granule density in units of measurement volumes of air, with microgram/cube Rice is unit.In the indoor environment of unobvious pollution sources, the reading of such detector is generally between 25-40, in The issue of national environmental protection portion of state《Ambient air quality》(GB3095-2012) one-level high-quality air, is belonged to.And cigarette Caused each pollutant is exactly what is existed in the form of aerosol particle and transmit in combustion process, and its yardstick can be less than 2.5 micron (PM2.5).After lighting the above-mentioned cigarette for having used presently disclosed abatement of pollution composition, air is then turned on Particle detector, wherein built-in extraction fan start continuous exhausting suction cigarette combustion caused by gas (be similar to active smoking Process).Reading in cigarette combustion overall process is between 45-70, between air quality one-level to secondary air scope.It is and right Than the common cigarette with filter tip without presently disclosed abatement of pollution composition, corresponding reading substantially exceeds 500, belonged to The six grades of air above seriously polluted.

Embodiment 3：It is first according to the part by weight reagent preparation that following table 3 is indicated；Then with metallorganic skeleton Material MIL-53 presses 1:5 part by weight mixing, is placed in the drier that is connected with vavuum pump.Taken out under air-proof condition true To form enough negative pressure, break off the connection with vavuum pump within empty 10 minutes.The product of acquisition is transferred to outside drier, is wrapped in filter To dry tack free in paper.

Table 3

Preparation forms	Corn marrow	Sodium lignin sulfonate	Sodium alginate	Water
					Weight %	1.0	1.0	8.0	90

The powdered product of the dry tack free is weighed about 0.05 gram, is uniformly positioned over the interface and again of cigarette and filter tip Sealing.Then transition conduit is inserted in filter tip one end and sealed, the other end of transition conduit and the air inlet of air particles detector It is connected and seals.The principle of such particle detector be based on the granule density in units of measurement volumes of air, with microgram/cube Rice is unit.In the indoor environment of unobvious pollution sources, the reading of such detector is generally between 25-40, in The issue of national environmental protection portion of state《Ambient air quality》(GB3095-2012) one-level high-quality air, is belonged to.And cigarette Caused each pollutant is exactly what is existed in the form of aerosol particle and transmit in combustion process, and its yardstick can be less than 2.5 microns (PM2.5).After lighting the above-mentioned cigarette for having used presently disclosed abatement of pollution composition, air is then turned on Particle detector, wherein built-in extraction fan start continuous exhausting suction cigarette combustion caused by gas (be similar to active smoking Process).Reading in cigarette combustion overall process is between 40-80, between air quality one-level to secondary air scope.It is and right Than the common cigarette with filter tip without presently disclosed abatement of pollution composition, corresponding reading substantially exceeds 500, belonged to The six grades of air above seriously polluted.

Embodiment 4：It is first according to the part by weight reagent preparation that following table 4 is indicated；Then with metallorganic skeleton Material MIL-53 presses 1:5 part by weight mixing, is placed in the drier that is connected with vavuum pump.Taken out under air-proof condition true To form enough negative pressure, break off the connection with vavuum pump within empty 10 minutes.The product of acquisition is transferred to outside drier, is wrapped in filter To dry tack free in paper.

Table 4

The powdered product of the dry tack free is weighed about 0.05 gram, is uniformly positioned over the interface and again of cigarette and filter tip Sealing.Then transition conduit is inserted in filter tip one end and sealed, the other end of transition conduit and the air inlet of air particles detector It is connected and seals.The principle of such particle detector be based on the granule density in units of measurement volumes of air, with microgram/cube Rice is unit.In the indoor environment of unobvious pollution sources, the reading of such detector is generally between 20-30, in The issue of national environmental protection portion of state《Ambient air quality》(GB3095-2012) one-level high-quality air, is belonged to.And cigarette Caused each pollutant is exactly what is existed in the form of aerosol particle and transmit in combustion process, and its yardstick can be less than 2.5 microns (PM2.5).After lighting the above-mentioned cigarette for having used presently disclosed abatement of pollution composition, air is then turned on Particle detector, wherein built-in extraction fan start continuous exhausting suction cigarette combustion caused by gas (be similar to active smoking Process).Reading in cigarette combustion overall process is between 40-60, between air quality one-level to secondary air scope.It is and right Than the common cigarette with filter tip without presently disclosed abatement of pollution composition, corresponding reading substantially exceeds 500, belonged to The six grades of air above seriously polluted.

Embodiment 5：It is first according to the part by weight reagent preparation that following form is indicated；Then with metallorganic skeleton Material MIL-53 presses 1:5 part by weight mixing, is placed in the drier that is connected with vavuum pump.Taken out under air-proof condition true To form enough negative pressure, break off the connection with vavuum pump within empty 10 minutes.The product of acquisition is transferred to outside drier, is wrapped in filter To dry tack free in paper.

Table 5

Powdered product after dry tack free processing is weighed about 0.05 gram, is uniformly positioned over the interface of cigarette and filter tip And reseal.Then transition conduit is inserted in filter tip one end and sealed, the other end and the air particles detector of transition conduit Air inlet is connected and sealed.The principle of such particle detector is based on the granule density in units of measurement volumes of air, with micro- Gram/cubic metre is unit.In the indoor environment of unobvious pollution sources, the reading of such detector generally between 20-30, According to the issue of China national Environmental Protection Department《Ambient air quality》(GB3095-2012) one-level high-quality air, is belonged to. And caused each pollutant is exactly to exist in the form of aerosol particle and transmit during cigarette combustion, its yardstick can be with Less than 2.5 microns (PM2.5).After lighting the above-mentioned cigarette for having used presently disclosed abatement of pollution composition, it is then turned on Air particles detector, wherein built-in extraction fan starts gas caused by continuous exhausting suction cigarette combustion (similar to actively Smoking process).The reading of the air particles detector is between 45-65 in cigarette combustion overall process, between air quality one Level is to secondary air scope.

Above-described embodiment shows that presently disclosed composition can effectively control caused a variety of dirts in smoking process Thing is contaminated to smoker, the harm of neighbor's health and the pollution of ambient air.These obvious effects are to be based on having microviscosity Nano-fiber material comprehensive barrier under the hydrating condition of part and caused by the three-dimensional porous system of metallorganic skeleton Effect.

Claims

1. a kind of composition for controlling and eliminating harmful substance in cigarette or air, including containing naturally receiving with surface microviscosity Rice fibrous material and the three-dimensional porous system material of metallorganic skeleton.

2. composition according to claim 1, the three-dimensional porous system material of nano-fiber materials, metallorganic skeleton The weight ratio scope of material and auxiliary material is 0.1~1.5：6.0~9.7.

3. composition according to claim 1, nano-fiber materials are selected from one of the following or a variety of：Lignin Sodium sulfonate, corn hemicellulose, corn marrow and sodium alginate.

4. composition according to claim 1, further comprising polymers capable of swelling, the polymers capable of swelling, which is selected from, to be handed over Join polyacrylamide；Crosslink part hydrolyzed polyacrylamide；Crosslinked polyacrylate；Crosslinked salt polyacrylate；Crosslinked polypropylene The salt of acid esters；It is crosslinked hydrolyzed polyacrylonitrile；It is crosslinked the salt of carboxyalkyl starch；The salt of crosslinked carboxyalkylcellulose；Any crosslinking carboxylic The salt of alkyl polysaccharide；The cross-linked copolymer of acrylamide and acrylate monomer；It is grafted with acrylonitrile and acrylate monomer Crosslinked starch；2- allyl sulphonic acids, AMPS, 3- allyloxy -2- hydroxyls the third sulphurs of -1- One or more in the cross-linked polymer of acid, acrylamide and acrylic monomers.

5. composition according to claim 1, further it is selected from maltose, guanidine comprising auxiliary material, the auxiliary material That beans, glycerine, rosin resin, calcium chloride and urea.

6. composition according to claim 1, the metallorganic of the three-dimensional porous skeleton, wherein metal are selected from following It is one or more in metal ion：Li+,Na+,K+,Rb+,Be2+,Mg2+,Ca2+,Sr2+,Ba2+,Sc3+,Y3+,Ti4+, Zr4+,Hf4+,V4+,V3+,V2+,Nb3+,Ta3+,Cr+,Cr2+,Cr6+,Mo3+,W3+,Mn3+,Mn2+,Re3+,Re2+, Fe3+,Fe2+,Ru3+,Ru2+,Os3+,Os2+,Co3+,Co2+,Rh2+,Rh+,Ir2+,Ir+,Ni2+,Ni+,Pd2+,Pd+, Pt2+,Pt+,Cu2+,Cu+,Ag+,Au+,Zn2+,Cd2+,Hg2+,Al3+,Ga3+,In3+,Tl3+,Si4+,Si2+,Ge4+, Ge2+, Sn4+, Sn2+, Pb4+, Pb2+, As5+, As3+, As+, Sb5+, Sb3+, Sb+, Bi5+, Bi3+ and Bi+ and its they Inorganic salts.

7. composition according to claim 6, described inorganic salts are selected from sulfate, nitrate, nitrite, sulfurous acid Salt, bisulfites, disulfate, phosphate, hydrophosphate, dihydric phosphate, diphosphate, triphosphate, phosphite, Chloride, chlorate, bromide, bromate, iodate, iodate, carbonate, bicarbonate, sulfide, selenides, selenic acid Salt, selenate, tellurides, tellurate, hydrotelluric acid, nitride, phosphide, arsenide, arsenate, arsenic acid hydrogen salt, arsenic acid hydrogen two Sodium, stibate, metaantimmonic acid hydrogen salt, borate, hydrogen borate salt, perchlorate, chlorite, hypochlorite, perbromate, bromic acid Salt, hypobromite, periodate, iodate and hypoiodite.

8. composition according to claim 1, the metallorganic of the three-dimensional porous skeleton, wherein, the organic matter Selected from saturated aliphatic compound, unsaturated lipid compounds of group, aromatic compounds or aliphatic series and aromatic compounds, and with can be with Metal ion and/or the functional group with a coordinate bond at least two keys of formation of two or more metallic atoms.

9. composition according to claim 8, the functional group of the organic matter is selected from：- CO2H ,-CS2 ,-NO2 ,-B (OH) 2 ,-SO3H ,-Si (OH) 3 ,-Ge (OH) 3 ,-Sn (OH) 3 ,-Si (SH) 4 ,-Ge (SH) 4 ,-Sn (SH) 3 ,-P03H ,-As03H ,- As04H ,-P (SH) (SH) 3 ,-CH (SH) 2 ,-C (SH) 3 ,-CH (NH 2) 2 ,-C (NH 2) 3 ,-CH (OH) 2 ,-C (OH) 3 ,-CH (CN) 2 or-C (CN) 3 ,-CH (RSH) 2 ,-C (RSH) 3 ,-CH (RNH 2) 2 ,-(RNH2) 3 ,-CH (ROH) 2 ,-C (ROH) 3 and-C (RCN) 3, wherein R are C1-C5 alkylidene, substituted or unsubstituted aryl containing one or two aromatic kernel or contained N, O and/or S heterocyclic aryl.

10. composition according to claim 9, the alkylidene of the C1-C5 is selected from methylene, ethylidene, positive acrylic, Isopropenyl, n-butene base, isobutenyl, tertiary cyclobutenyl and n-pentene base.

11. composition according to claim 8, the aliphatic compounds are straight chain and/or the aliphatic series of side chain and/or ring-type Compound, comprising including 1 to 15 carbon atom, preferably 2 to 14 carbon atoms, more preferably 3 to about 12 carbon atoms.

12. composition according to claim 1, the organic compound is selected from one of the following or a variety of：Alkylamine And its corresponding alkylammonium salt, it contains the straight chain with 1 to 20 carbon atom, side chain or cyclic aliphatic group, alkarylamine And its corresponding aryl ammonium salt with 1 to 5 phenyl ring, containing the straight chain with 1 to 20 carbon atom, side chain or ring-shaped fat The Wan Ji phosphonium salts of race's group, there is the Fang Ji phosphonium salts of 1 to 5 phenyl ring, alkyl organic acid and its corresponding salt, it contains with 1 To the straight chain, side chain or cyclic aliphatic group of 20 carbon atoms, aryl organic acid and its corresponding salt, there is 1 to 5 phenyl ring, The aliphatic alcohol of straight chain containing 1 to 20 carbon atom, side chain or cyclic aliphatic group, and the aryl alcohol with 1 to 5 phenyl ring.

13. composition according to claim 1, the organic compound is selected from one of the following or a variety of:Ammonia, dioxy Change carbon, methane, oxygen, argon gas, nitrogen, ethene, hexane, benzene, toluene, (T, M, P) dimethylbenzene, chlorobenzene, nitrobenzene, naphthalene, thiophene, Pyridine, acetone, 1,2- dichloroethanes, dichloromethane, tetrahydrofuran, monoethanolamine, triethylamine, trifluoromethane sulfonic acid N, N- dimethyl Formamide, N, N- diethylformamides, dimethyl sulfoxide (DMSO), chloroform, bromofom, methylene bromide, iodoform, diiodomethane, halo are organic Solvent, DMA, N, pyrrolidones, amide solvent, picoline, lutidines, Anaesthetie Ether, and its it is mixed Compound；Oxalic acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane dicarboxylic acid, 4- oxo pyrans -2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, Decane dicarboxylic acid, heptadecane dicarboxylic acid, 1,9- heptadecane dicarboxylic acid, heptadecane dicarboxylic acid, acetylenedicarboxylic acid, 1,2- benzene diformazan Acid, 2,3- pyridinedicarboxylic acids, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxylic acids, Isosorbide-5-Nitrae-phthalic acid, to benzene two Formic acid, imidazoles -2,4- dicarboxylic acids, 2- methylquinoline -3,4- dicarboxylic acids, quinoline -2,4- dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids Acid, 6- chloro-quinoxaline -2,3- dicarboxylic acids, 4,4'- diamino-phenyl ethane -3,3'- dicarboxylic acids, quinoline -3,4- dicarboxylic acids, 7- Chloro-4-hydroxyl quinoline -2,8- dicarboxylic acids, dicarboxylic acids, di-imidodicarboxylic acid, pyridine -2,6- dicarboxylic acids, 2-methylimidazole -4, 5- dicarboxylic acids, thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyl imidazole-4,5-dicarboxylic acids, oxinane -4,4- dicarboxylic acids, - 3,9- dicarboxylic acids, dioctyl phthalate, Pluriol E 200- dicarboxylic acids, 3,6- dioxaoctane dicarboxylic acids, 3,5- cyclohexadiene -1, 2- dicarboxylic acids, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- diaminostilbenes, 1- diphenyl -3,3'- dicarboxylic acids, 4,4'- diaminos Base diphenyl -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (phenyl amino) benzene -2,5- dicarboxylic acids, 1,1- naphthalene Base -5,5'- dicarboxylic acids, chloro- 8- methylquinolines -2, the 3- dicarboxylic acids of 7-, 1- anilino- anthraquinone -2,4'- dicarboxylic acids, poly- tetrahydrochysene furan Mutter -200- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (carboxymethyl) piperazine -2,3- dioctyl phthalate, 7- chloroquinoline -3,8- dicarboxylic acids, 1- (4- carboxyls) benzene Base -3- (4- chlorine) phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5,6,7,7- chlordene -5- ENB -2,3- dicarboxylic acids, benzene boron Alkane dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazolinium -4,5- dicarboxylic acids, Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid, naphthalene -1,8- dicarboxylic acids, 2- Benzophenone -1,3- dicarboxylic acids, 1, the 3- cis dicarboxylic acids of dibenzyl -2- oxo-imidazole alkane -4,5-, 2,2'- diquinolines -4,4'- Dicarboxylic acids, pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane dicarboxylic acids, O- hydroxy benzophenone keto-dicarboxylic acids, Pluriol E 300- dicarboxylic acids, Pluriol E400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazines Dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- diaminodiphenyl ether di-imidodicarboxylic acids, 4,4'- diaminourea Diphenyl methane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, di-imidodicarboxylic acid, NDA, 1,3- adamantane Dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxyl group -2,3- naphthalenedicarboxylic acids, 8- nitro -2,3- naphthalene sulfonic acids, 8- sulphurs Base -2,3- naphthalenedicarboxylic acid, anthracene -2,3- dicarboxylic acids, 2', 3'- diphenyl-para-terpheny -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- bis- Carboxylic acid, imidazole-4,5-dicarboxylic acid, heterochromatic alkene -2, the 8- dicarboxylic acids of 4 (1H)-oxos, 5- tert-butyl group -1,3- phthalic acids, 7,8- quinolines Quinoline dioctyl phthalate, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxylic acids, hexylene glycol dicarboxylic acids, tetradecane dicarboxylic acid, 1,7- heptan dicarboxyl Acid, 5- hydroxyl -1,3- phthalic acids, pyrazine -2,3- dicarboxylic acids, furans -2-, 5- dicarboxylic acids, 1- nonene -6,9- dicarboxylic acids, two Eicosadienoic acid, 4,4'- dihydroxydiphenyl methane -3,3'- dicarboxylic acids, 1- amino -4- methyl -9,10- dioxos -9,10- Dihydro-anthraquinone e-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, cyclohexene -2,3- dicarboxylic acids, 2,9- dichloro fluorine borines -4,11- bis- Carboxylic acid, methylquinoline -6,8 dicarboxylic acids between the chloro- 3- of 7-, 2,4- dichloro benzophenone -2', 5'- dicarboxylic acids, 1,3- phthalic acid, 2, dipicolimic acid 2,1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles -3,4- dicarboxylic acids, anthraquinone -1,5- dicarboxyl Acid, 3,5- pyrazoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, heptane -1,7- dicarboxylic acids, cyclobutane -1,11,4- dicarboxylic acids, 1, 14- tetradecane dicarboxylic acids, 5,6- dehydrogenation norbornane -2,3- dicarboxylic acids, 5- ethyls -2,3- pyridinedicarboxylic acid or its esters；2- Hydroxyl -1,2,3- tricarballylic acids, the quinoline tricarboxylic acids of 7- chloro- 2,3,8-, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- phosphine -1, 2,4- butane tricarboxylic acids, 1,3,5- benzenetricarboxylic acid, 1- hydroxyls -1,2,3- tricarballylic acids, 4,5- dihydro -4,5- dioxo -- 1H- Pyrrolo- [2,3-F] quinoline -2,7,9- tricarboxylic acids, 5- acetyl group -3- amino -6- methylbenzenes -1,2,4- tricarboxylic acids, 3- amino - 5- benzoyl -6- methylbenzenes -1,2,4- tricarboxylic acids, 1,2,3- tricarballylic acid or laurate and its esters；1,1- dioxanes Amyl group [BCD] thiophene -3,4,9,10- tetrabasic carboxylic acids,-tetrabasic carboxylic acid, -3,4,9,10- tetrabasic carboxylic acids, -1,12- sulfonyl -3, 4,9,10 tetrabasic carboxylic acids, 1,2,3,4- BTCA, meso -1,2,3,4- BTCAs, decane -2,4,6,8- tetracarboxylic acids Acid, Isosorbide-5-Nitrae, 7,10,13,16- hexaoxacyclooctadecane-6s -2,3,11,12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11,12- Dodecyl tetrabasic carboxylic acid, 1,2,5,6 hexane tetrabasic carboxylic acid, 1,2,7,8- octane tetrabasic carboxylic acid, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2,9, 10- decane tetrabasic carboxylic acids, benzophenone tetrabasic carboxylic acid, 3,3', 4,4'- benzophenone tetrabasic carboxylic acids, tetrahydrofuran tetrabasic carboxylic acid, pentamethylene four Carboxylic acid, pentamethylene -1,2,3,4- tetrabasic carboxylic acids and its salt.

14. according to any described compositions of claim 1-13, the three-dimensional porous system material of metallorganic skeleton, its Surface area in multiple holes is greater than about 500m 2/g；The surface area in multiple holes can be about 500 to about 15000m 2/g, Huo Zheduo The surface area in individual hole can be about 1000 to about 10000m 2/g, or the surface area in multiple holes can be about 2000 to about 6000m 2/g。

15. according to any described compositions of claim 1-13, the three-dimensional porous system material of metallorganic skeleton, its Porous average pore sizes are about 0.005 to about 15cm 3/g, preferably from about 0.05 to about 5cm3/g；And porous metals organic matter The skeleton of framework material has the density in the range of about 0.03 to about 5g/cm 3 or about 0.3 to about 1.5g/cm 3.

16. composition according to claim 1, the three-dimensional porous system material of metallorganic skeleton is selected from：

17. a kind of method for the composition for preparing claim 1, comprises the following steps

2) by the three-dimensional porous system material of metallorganic skeleton, by weight 1：5 add the solution for walking to obtain, and mixing is equal It is even；

18. according to the method for claim 17, in the solution described in step 1) further add swollen polymer and/or Auxiliary material, wherein, the nano-fiber materials are selected from following one or more：Sodium lignin sulfonate, corn hemicellulose Element, corn marrow and sodium alginate, the auxiliary material are selected from maltose, cyamopsis tetragonolobus, glycerine, rosin resin, calcium chloride and urea.

19. according to the method for claim 18, the content of nano-fiber material or auxiliary material is in the solution of step 1)： Maltose is 0.1-5%, sodium lignin sulfonate 0.1-7%, corn hemicellulose 0.1-10%, corn marrow be 0.1-10%, Sodium alginate is 0.1-4%, cyamopsis tetragonolobus 0.1-3%；Glycerine is 0.1-5%；Rosin resin is 0.1-5%, calcium chloride is 0.1-3% and/or urea are 0.1-8%.

20. any combination thing described in claim 1-5 is in manufacture elimination or cigarette, the in-car air filtration of filtering out harmful matter Purposes in device, indoor air cleaner and mouth mask.