CN107549313A - Baby milk grease compound method based on triglycerides analysis mode human milk fat - Google Patents
Baby milk grease compound method based on triglycerides analysis mode human milk fat Download PDFInfo
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Abstract
The invention discloses a kind of baby milk grease compound method based on triglycerides analysis mode human milk fat, comprise the following steps：First, the species and corresponding content of triglycerides and aliphatic acid in N number of breast milk sample are determined, active principle m includes triglycerides A, necessary fat acid B, triglycerides C and can digest and assimilate triglycerides D in N number of breast milk sample, active principle m content range R (m)min~R (m)max, average content X (m)；2nd, the content of various active principle m in n kinds vegetable fat to be added is determined, calculates various active principle content H (m) in the compound lard that n kinds vegetable fat to be added obtains under different adding proportions；3rd, 100 points are scored at breast milk active principle, calculate the comprehensive grading of different compound lards, with comprehensive grading closer to 100 compound lard, it is formed closer to human milk fat.The baby milk grease that the method for the present invention is prepared can realize fatty breast milk.
Description
Technical field
The present invention relates to babies ' formula milk powder technical field.It is more particularly related to a kind of be based on triglycerides
The babies ' formula milk powder grease compound method of analysis mode human milk fat structure.
Background technology
With the opening of on January 1st, 2016 " two tire policies ", the neonate in China this year is up to 2000 to 2,500 ten thousand,
And because many mothers are due to personal, culture, society or the selection artificial feeding of economic dispatch reason, this causes in world wide only
35% baby can obtain breast-feeding.Under these circumstances, baby formula milk powder is fed by nutrition recognised by people
The product of supporting.With the demand increase of baby formula milk powder, the formula of each enterprise and research institution to baby formula milk powder
Constantly furtherd investigate, and with " breast milk " for final goal.And the fat in breast milk is study hotspot always, in breast milk
Fat containing 3%-5% but can provide more than 50% energy for baby, and contain in human milk fat sweet more than 98%
Oily three esters, the species of aliphatic acid and the difference of position on its chain, also absorb to infant's digestion and playing vital effect.
The big more options of company for now producing baby formula milk powder are supplied by adding variety classes vegetable oil instead of fat
To baby, and some documents also have been reported that vegetable oil compared with the closer breast milk of cow's milk class fat.The infant of domestic production at present matches somebody with somebody
Grease in square milk powder mainly has two kinds of addition manners, and one kind is to simulate human milk fat by adding OPO, and another kind is to transfer to
Third party provides final miscella；But triglyceride structure important in human milk fat does not only have OPO one kind, the first side
Formula make it that the structure of grease in baby formula milk powder is single, fail to realize " breast milk ", and the drawbacks of the second way
Whether the aliphatic acid Index for examination of miscella that its offer is only provided in third party meets national standard, without inform corresponding enterprise its
The proportioning of miscella, in fact whether its miscella is close with breast milk and unknown, and manufacturing enterprise's situation is passive, while also makes
The situation higher into the price of baby milk.
The content of the invention
It is an object of the invention to solve at least the above, and provide the advantages of at least will be described later.
It is a still further object of the present invention to provide a kind of compound method of baby milk grease, by glycerine in breast milk three
Ester carries out analysis mode, obtains the grease composition closer to human milk fat composition, is carried to produce the enterprise of baby formula milk powder
Facility has been supplied, while has improved the nutrition of baby formula milk powder.
In order to realize according to object of the present invention and further advantage, there is provided one kind is based on triglycerides analysis mode
The baby milk grease compound method of human milk fat, comprises the following steps：
First, the species and corresponding content, average content for determining triglycerides and aliphatic acid in N number of breast milk sample are more than
1% triglycerides A species has a, respectively A (i), i=1,2 ... ... a；Average content more than 1% aliphatic acid with it is specific
The necessary fat acid B of polyunsaturated fatty acid shares b, and respectively B (j), j=1,2 ... ... b, Sn-2 positions are C14:0、C16:
0 and C18:0 triglycerides C has 3, respectively C (r), r=1,2, and 3, can digest and assimilate triglycerides D classification has 2 kinds,
First category D (1) is the combination of UUU types and USU type triglycerides, second category D (2) be UUU types, USU types and SUS types and
The combination of triglycerides of the carbon number of Sn-1/3 positions saturated fatty acid less than 14 in SSS types；
Defining active principle m in N number of breast milk sample includes triglycerides A, necessary fat acid B, triglycerides C and can digest
Triglycerides D is absorbed, active principle m content range is R (m)min~R (m)max, average content is X (m)；M=A (i), B
(j), C (r), D (1) or D (2)；
2nd, the content of various active principle m in n kinds vegetable fat to be added is determined, calculates n kinds vegetable fat to be added
Various active principle content H (m) in the compound lard obtained under different adding proportions；
3rd, 100 points are scored at breast milk active principle, Q is assigned successively by active principle A, B, C, D importanceA、QB、
QC、QDWeighted value, QA、QB、QCAnd QDSum is 100, calculates the comprehensive grading F=100- ∑ E (m) of different compound lards, with
For comprehensive grading closer to 100 compound lard, it forms the fat composition in breast milk；
Wherein, E (m) represents that the content H (m) of active principle m in compound lard deviates active principle m content ranges in breast milk
The score value reduced, E (m)=Q (m) * W (m) * X (m)/∑ X (m), and meet：
As m=A (i), Q (m)=QA, ∑ X (m) is that a active principle A (i) is average in active principle A in breast milk sample
The sum of content；
As m=B (j), Q (m)=QB；∑ X (m) is that b active principle B (j) is average in active principle B in breast milk sample
The sum of content；
As m=C (r), Q (m)=QC；∑ X (m) is that 3 active principle C (r) are average in active principle C in breast milk sample
The sum of content；
As m=D (1) or D (2), Q (m)=QD；∑ X (m) is 2 active principle D in active principle D in breast milk sample
(1) and D (2) average content sum；
W (m) is float factor, as R (m)min≤H(m)≤R(m)max, W (m)=0；As H (m)<R(m)min, W (m)=| H
(m)-R(m)min|/R(m)min；As H (m)>R(m)max, W (m)=| H (m)-R (m)max|/R(m)max。
Preferably, the baby milk grease compound method based on triglycerides analysis mode human milk fat, put down
Triglycerides A of the equal content more than 1% has 18 kinds, respectively OPO, OPL, OOO, OLO, LPL, POP, LOL, OMO, PLP, SPO,
OLaO, OSO, OPLa, OPM, LLL, LMO, OPPo and OLaL.
Preferably, the baby milk grease compound method based on triglycerides analysis mode human milk fat, it is special
It is C20 to determine polyunsaturated fatty acid:4、C22:6 and C20:5 aliphatic acid.
Preferably, the baby milk grease compound method based on triglycerides analysis mode human milk fat, put down
Equal aliphatic acid of the content more than 1% has 10 kinds, respectively C10:0、C12:0、C14:0、C16:0、C18:0、C22:0、C16:1、
C18:1、C18:2 and C18:3, b=13.
Preferably, the baby milk grease compound method based on triglycerides analysis mode human milk fat, QA、
QB、QC、QDWeighted value be followed successively by 50,25,12.5,12.5.
Preferably, the baby milk grease compound method based on triglycerides analysis mode human milk fat, n kinds
Vegetable fat to be added is the 3-5 in walnut oil, palm oil, linseed oil, soybean oil, rapeseed oil, sunflower oil, corn oil
Kind.
The present invention comprises at least following beneficial effect：
1) present invention has based on the triglycerides in a large amount of breast milk samples and the content and structure of aliphatic acid with 4 kinds
Effect component is that condition is simulated, and by establishing points-scoring system, draws the proportioning of the compound lard closest to human milk fat structure,
So that the baby milk powder prepared reaches " breast milk "；For enterprise, reduce cost, improve product quality and can
Reliability, moreover it is possible to when avoiding a certain grease shortage, the replacement of different compound lards is carried out, can also be at any time according to different batches grease
Switch proportioning after being detected, improve breast milk degree；For infant, this method can solve the grease of different batches
The problem of rear indigestion is eaten caused by itself lipid structure and content of fatty acid difference, is cry and screamed, improves disappearing for infant
Change absorbability, and because its breast milk degree is high, it is nutritious, contribute to infantile health to grow up；
2) present invention is the simulated offer thinking of the nutriment such as albumen, vitamin in baby formula milk powder.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this
The research and practice of invention and be understood by the person skilled in the art.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, to make those skilled in the art's reference say
Bright book word can be implemented according to this.
It should be noted that experimental method described in following embodiments, is conventional method unless otherwise specified, institute
Reagent and material are stated, unless otherwise specified, is commercially obtained.
A kind of baby milk grease compound method based on triglycerides analysis mode human milk fat, comprises the following steps：
First, the species and corresponding content, average content for determining triglycerides and aliphatic acid in N number of breast milk sample are more than
1% triglycerides A species has a, respectively A (i), i=1,2 ... ... a；Average content more than 1% aliphatic acid with it is specific
The necessary fat acid B of polyunsaturated fatty acid shares b, and respectively B (j), j=1,2 ... ... b, Sn-2 positions are C14:0、C16:
0 and C18:0 triglycerides C has 3, respectively C (r), r=1,2, and 3, can digest and assimilate triglycerides D classification has 2 kinds,
First category D (1) is the combination of UUU types and USU type triglycerides, second category D (2) be UUU types, USU types and SUS types and
The combination of triglycerides of the carbon number of Sn-1/3 positions saturated fatty acid less than 14 in SSS types；
Defining active principle m in N number of breast milk sample includes triglycerides A, necessary fat acid B, triglycerides C and can digest
Triglycerides D is absorbed, active principle m content range is R (m)min~R (m)max, average content is X (m)；M=A (i), B
(j), C (r), D (1) or D (2)；
2nd, the content of various active principle m in n kinds vegetable fat to be added is determined, calculates n kinds vegetable fat to be added
Various active principle content H (m) in the compound lard obtained under different adding proportions；
3rd, 100 points are scored at breast milk active principle, Q is assigned successively by active principle A, B, C, D importanceA、QB、
QC、QDWeighted value, QA、QB、QCAnd QDSum is 100, calculates the comprehensive grading F=100- ∑ E (m) of different compound lards, with
For comprehensive grading closer to 100 compound lard, it forms the fat composition in breast milk；
Wherein, E (m) represents that the content H (m) of active principle m in compound lard deviates active principle m content ranges in breast milk
The score value reduced, E (m)=Q (m) * W (m) * X (m)/∑ X (m), and meet：
As m=A (i), Q (m)=QA, ∑ X (m) is that a active principle A (i) is average in active principle A in breast milk sample
The sum of content；
As m=B (j), Q (m)=QB；∑ X (m) is that b active principle B (j) is average in active principle B in breast milk sample
The sum of content；
As m=C (r), Q (m)=QC；∑ X (m) is that 3 active principle C (r) are average in active principle C in breast milk sample
The sum of content；
As m=D (1) or D (2), Q (m)=QD；∑ X (m) is 2 active principle D in active principle D in breast milk sample
(1) and D (2) average content sum；
W (m) is float factor, as R (m)min≤H(m)≤R(m)max, W (m)=0；As H (m)<R(m)min, W (m)=| H
(m)-R(m)min|/R(m)min；As H (m)>R(m)max, W (m)=| H (m)-R (m)max|/R(m)max。
Supplementary notes：Inventor measures 66 kinds of triglycerides in 40 kinds of ripe breasts of people, according to literature reading, triglycerides
Content>1% for a large amount of triglycerides, it has material impact to human milk fat structure, therefore average content is sweet more than 1%
Oily three esters are as first condition.
Equally, triglycerides is by Fatty acid compositions, therefore important content of fatty acid equally affects triglycerides,
Digested and assimilated so as to affect it.Therefore with content in aliphatic acid>1% aliphatic acid is as second condition.
Triglycerides is formed by a glycerine and three aliphatic acid esterifications, and a Sn-2 positions fat is broken on glycerol backbone
Its required energy of fat acid is higher than the aliphatic acid of one Sn-1/3 position of fracture, C14:0、C16:0 and C18:0 long-chain fat in these three
Fat acid is advantageous to digest and assimilate if Sn-2 positions are present in, and pretends as the 3rd condition triglycerides C.
Triglyceride structure can according to branched fatty acid whether saturation (saturation：S；It is unsaturated：U) it is divided into SSS, S2U,SU2With
UUU type aliphatic acid, wherein S2It is U-shaped including SSU, SUS and USS type triglycerides, and SU2Type includes SUU, USU and UUS type glycerine
Three esters.Theory is digested and assimilated according to triglycerides, if Sn-1/3 positions aliphatic acid (aliphatic acid for referring to Sn-1 or Sn-3 positions) is not
If saturated fatty acid or its be saturated fatty acid its carbon number<14, its fusing point is less than body temperature (37 DEG C), then it is believed that such knot
Structure can be digested and assimilated.And in UUU and USU types and SUS and SSS Sn-1/3 positions saturated fatty acid<14 carbon, the then class formation
Can be considered as " can digestibility and utilization structure ", due to UUU+USU structures triglycerides in breast milk content accounting it is more, therefore send out
A person of good sense with its content and be D (1), can as the 4th condition and using the summation of " can digestibility and utilization structure " content as D (2)
Digest and assimilate triglycerides D.
The present invention is combined according to theory and put into practice, the method simulated based on triglycerides analysis to human milk fat, its energy
It is enough the fats portion of formula milk is more nearly breast milk, so as to reach " breast milk ".
40 breast milk samples are measured through this laboratory, obtaining triglycerides A of the average content more than 1% there are 18 kinds, respectively
For OPO (fat of bis- oleic acid -2- palmitic acids of 1,3- three), OPL (fat of 1- oleic acid 2- palmitic acid -3- linoleic acids three), OOO
(fat of tri- oleics of 1,2,3- three), OLO (fat of bis- oleic acid -2- palmitic acids of 1,3- three), LPL (1,3- dilinoleic acids -2- palm fibres
The fat of palmitic acid acid glycerol three), POP (fat of bis- palmitic acid -2- oleics of 1,3- three), LOL (1,3- dilinoleic acid -2- oleics three
Fat), OMO (oleic acid -2- myristic acids triglycerides of 1,3- bis-), PLP (fat of bis- palmitic acid -2- linoleic acids of 1,3- three), SPO
(fat of 1- stearic acid 2- palmitic acid -3- oleics three), OLaO (fat of bis- oleic acid -2- lauric acids of 1,3- three), OSO (1,3-
The fat of two oleic acid -2- glycerol stearates three), OPLa (fat of 1- oleic acid -2- palmitic acid -3- lauric acids three), OPM (1- oleic acid -2-
Palmitic acid -3- myristic acids triglyceride), LLL (fat of tri- linoleic acids of 1,2,3- three), LMO (1- linoleic acid -2- nutmegs
The fat of acid -3- oleics three), OPPo (1- oleic acid -2- palmitic acid -3- palmitoleic acids triglyceride) and the OLaL (1- oleic acid -2- moons
The fat of cinnamic acid -3- linoleic acids three).And aliphatic acid of the average content more than 1% has 10 kinds, respectively C10:0 (carbolic acid),
C12:0 (laurate), C14:0 (myristic acid), C16:0 (palmitic acid), C18:0 (stearic acid), C22:0 (behenic acid),
C16:1 (palmitoleic acid), C18:1 (oleic acid), C18:2 (linoleic acid) and C18:3 (leukotrienes)；Due to C20:4 (ARA, peanuts four
Olefin(e) acid), C22:6 (DHA, docosahexaenoic acids) and C20:The aliphatic acid of 5 (EPA, eicosapentaenoic acids) is to infant physical growth
Growth course plays an important roll polyunsaturated fatty acid, therefore inventor is using above-mentioned 13 kinds of aliphatic acid as simulation breast milk fatty acids
The necessary fat acid B of composition, therefore b=13.However, it is different in breast milk sample, in the case of sample size is different, chemical measurement
The triglycerides A of aliphatic acid of the obtained average content more than 1% or average content more than 1% composition may be slightly different,
Method provided by the invention based on triglycerides analysis mode human milk fat, it is due to the important of triglycerides in human milk fat
Property, in fact, the simulation of fatty breast milk is the lipid structure i.e. simulation of triglycerides, and when breast milk sample size is bigger, it is suitable
More extensive with property, more preferably accurately, the baby milk grease that this method is prepared more preferably forms close to human milk fat.
In another technical solution, the baby milk grease based on triglycerides analysis mode human milk fat is matched somebody with somebody
Method processed, QA、QB、QC、QDWeighted value be followed successively by 50,25,12.5,12.5.Under the proportioning, baby milk of the invention oil
The closer breast milk of the milk powder that fat compound method obtains its grease composition.
In another technical solution, the baby milk grease based on triglycerides analysis mode human milk fat is matched somebody with somebody
Method processed, n kinds vegetable fat to be added are walnut oil, palm oil, linseed oil, soybean oil, rapeseed oil, sunflower oil, corn
3-5 kinds in the vegetable oil such as oil.The method of the present invention can formerly select raw material and then according to different material in different ratio
Under obtained miscella, its active principle contrasted with active principle in breast milk, whether different active principles deducted points,
And total score is calculated, the breast milk degree of miscella is evaluated with this.
Present inventor is illustrated with following examples.Assuming that the active principle A measured through a large amount of breast milk samples,
B, C, D component, content range and average content are shown in Table 1.Invention human desires is with palm oil, linseed oil, soybean oil, rapeseed oil
The grease in configuration baby milk is carried out with corn oil this 5 kinds of raw materials, and measure active principle A in this 5 kinds of raw materials of its acquisition,
B, C, D content, is shown in Table 1.And obtain with 0.213 part of palm oil, 0.028 portion of linseed oil, 0.026 part of soybean oil, 0.299
Part rapeseed oil and 0.434 portion of corn oil are compounded obtained miscella, and the content that its active principle is calculated is shown in Table 1.
Table 1
By each active principle content in each active principle content range, miscella in breast milk in table 1, being calculated each has
The float factor W (m) of component is imitated, by the content average value in each component of active principle A, B, C, D in breast milk, is calculated
Active principle A, B, C, D accumulative average content and ∑ X (m), by formula E (m)=Q (m) * W (m) * X (m)/∑ X (m), QA、
QB、QC、QDWeighted value be followed successively by 50,25,12.5,12.5, each component is calculated in miscella with respect to each component in breast milk
Reduce score value E (m), so as to which obtain active principle A, B, C, D reduces score value ∑ X (m), finally obtain total comprehensive grading F,
It is shown in Table 2, the comprehensive grading of the miscella obtained in the present embodiment under the proportioning is 83.146.According to this method, we can be with
The comprehensive grading for the miscella that some combination matchings obtain is obtained according to computer program, thus, enterprise can comment according to synthesis
Addition grease of the miscella that component selections suitably match as babies ' formula milk powder.
Table 2
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited
In specific details and shown here as the embodiment with description.
Claims (6)
- A kind of 1. baby milk grease compound method based on triglycerides analysis mode human milk fat, it is characterised in that including Following steps：First, the species and corresponding content of triglycerides and aliphatic acid in N number of breast milk sample are determined, average content is more than 1% Triglycerides A species have a, respectively A (i), i=1,2 ... ... a；Average content more than 1% aliphatic acid with it is specific more The necessary fat acid B of unrighted acid shares b, and respectively B (j), j=1,2 ... ... b, Sn-2 positions are C14:0、C16:0 And C18:0 triglycerides C has 3, respectively C (r), r=1,2, and 3, can digest and assimilate triglycerides D classification has 2 kinds, and One classification D (1) is the combination of UUU types and USU type triglycerides, second category D (2) be UUU types, USU types and SUS types and The combination of triglycerides of the carbon number of Sn-1/3 positions saturated fatty acid less than 14 in SSS types；Defining active principle m in N number of breast milk sample includes triglycerides A, necessary fat acid B, triglycerides C and can digest and assimilate Triglycerides D, active principle m content range are R (m)min~R (m)max, average content is X (m)；M=A (i), B (j), C (r), D (1) or D (2)；2nd, the content of various active principle m in n kinds vegetable fat to be added is determined, calculates n kinds vegetable fat to be added not With various active principle content H (m) in the compound lard obtained under adding proportion；3rd, 100 points are scored at breast milk active principle, Q is assigned successively by active principle A, B, C, D importanceA、QB、QC、QD's Weighted value, QA、QB、QCAnd QDSum is 100, calculates the comprehensive grading F=100- ∑ E (m) of different compound lards, is commented with synthesis Divide the compound lard closer to 100, it forms the fat in breast milk and formed；Wherein, E (m) represents that the content H (m) of active principle m in compound lard deviates active principle m content ranges in breast milk and detained The score value subtracted, E (m)=Q (m) * W (m) * X (m)/∑ X (m), and meet：As m=A (i), Q (m)=QA, ∑ X (m) is a active principle A (i) average content in active principle A in breast milk sample Sum；As m=B (j), Q (m)=QB；∑ X (m) is b active principle B (j) average content in active principle B in breast milk sample Sum；As m=C (r), Q (m)=QC；∑ X (m) is 3 active principle C (r) average contents in active principle C in breast milk sample Sum；As m=D (1) or D (2), Q (m)=QD；∑ X (m) is 2 active principle D (1) and D in active principle D in breast milk sample (2) sum of average content；W (m) is float factor, as R (m)min≤H(m)≤R(m)max, W (m)=0；As H (m)<R(m)min, W (m)=| H (m)-R (m)min|/R(m)min；As H (m)>R(m)max, W (m)=| H (m)-R (m)max|/R(m)max。
- 2. the baby milk grease compound method based on triglycerides analysis mode human milk fat as claimed in claim 1, its Be characterised by, triglycerides A of the average content more than 1% has 18 kinds, respectively OPO, OPL, OOO, OLO, LPL, POP, LOL, OMO, PLP, SPO, OLaO, OSO, OPLa, OPM, LLL, LMO, OPPo and OLaL.
- 3. the baby milk grease compound method based on triglycerides analysis mode human milk fat as claimed in claim 1, its It is characterised by, specific polyunsaturated fatty acid is C20:4、C22:6 and C20:5 aliphatic acid.
- 4. the baby milk grease compound method based on triglycerides analysis mode human milk fat as claimed in claim 3, its It is characterised by, aliphatic acid of the average content more than 1% has 10 kinds, respectively C10:0、C12:0、C14:0、C16:0、C18:0、 C22:0、C16:1、C18:1、C18:2 and C18:3, b=13.
- 5. the baby milk grease compound method based on triglycerides analysis mode human milk fat as claimed in claim 1, its It is characterised by, QA、QB、QC、QDWeighted value be followed successively by 50,25,12.5,12.5.
- 6. the baby milk grease compound method based on triglycerides analysis mode human milk fat as claimed in claim 1, its It is characterised by, n kinds vegetable fat to be added is walnut oil, palm oil, linseed oil, soybean oil, rapeseed oil, sunflower oil, jade 3-5 kinds in rice bran oil.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112741163A (en) * | 2019-10-31 | 2021-05-04 | 内蒙古伊利实业集团股份有限公司 | Oil composition and application thereof in food |
| CN116235884A (en) * | 2023-01-09 | 2023-06-09 | 瑞哺恩(上海)科技有限公司 | Fat composition similar to breast milk fat, preparation method and application thereof, and infant formula milk powder |
| WO2024021694A1 (en) * | 2022-07-29 | 2024-02-01 | 北京三元食品股份有限公司 | Method for evaluating milk products according to lipidic components |
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