CN107542552A - Square acid-proof ceramics honeycomb substrate - Google Patents

Square acid-proof ceramics honeycomb substrate Download PDF

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Publication number
CN107542552A
CN107542552A CN201610469698.0A CN201610469698A CN107542552A CN 107542552 A CN107542552 A CN 107542552A CN 201610469698 A CN201610469698 A CN 201610469698A CN 107542552 A CN107542552 A CN 107542552A
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CN
China
Prior art keywords
arc
acid
shaped edges
stomata
next door
Prior art date
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Pending
Application number
CN201610469698.0A
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Chinese (zh)
Inventor
华国金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGYIN HUAYIN CERAMIC ELECTROMECHANICAL TECHNOLOGY Co Ltd
Original Assignee
JIANGYIN HUAYIN CERAMIC ELECTROMECHANICAL TECHNOLOGY Co Ltd
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Application filed by JIANGYIN HUAYIN CERAMIC ELECTROMECHANICAL TECHNOLOGY Co Ltd filed Critical JIANGYIN HUAYIN CERAMIC ELECTROMECHANICAL TECHNOLOGY Co Ltd
Priority to CN201610469698.0A priority Critical patent/CN107542552A/en
Publication of CN107542552A publication Critical patent/CN107542552A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to a kind of square acid-proof ceramics honeycomb substrate.It includes the first end to end arc-shaped edges(1), the second arc-shaped edges(2), three-arc side(3)With the 4th arc-shaped edges(11)The cylindrical body of the quadrangle of composition, cylindrical body are densely covered with stomata in the axial direction(4), stomata(4)One end be opening(9), the other end is provided with closure face(5), the closure face(5)And opening(9)Arranged for interval, two neighboring stomata(4)Between be provided with next door(6), next door(6)On be provided with micropore in cellular arrangement(7), next door(6)It is upper to be coated with catalyst coat(10), ceramic honey comb surface is coated with acid-proof coating.A kind of square acid-proof ceramics honeycomb substrate of the present invention, acid resistance is good, and the micropore on next door can effectively filter the black smoke particle in waste gas, and black smoke particle can be burned off in the presence of catalyst coat, further increase tail gas clean-up effect.

Description

Square acid-proof ceramics honeycomb substrate
Technical field
The present invention relates to a kind of square acid-proof ceramics honeycomb substrate, for purifying vehicle exhaust.Belong to Ceramic manufacturing equipment Technical field.
Background technology
At present, the automobile exhaust purifier of unobstructed application both at home and abroad, its catalyst carrier are typically all carried using ceramic honeycomb Body, this carrier are to add adhesive with synthesis of dichroite raw material, burn and lose agent, blended spice, pugging, extrusion, drying, sintering, Then impregnated catalyst re-dry is made.In use, it is put into exhaust purifier metal shell stage casing.
Conventional ceramic honeycomb carrier general section is the cylinder of rectangle, and the ceramic honeycomb carrier of such a shape is loaded When in the metal shell of exhaust purifier, often cause the space between ceramic honeycomb carrier and metal shell big so that tail Gas purifier can not effectively utilize the space of automobile chassis, and some producers can add small rule to plug the gap in gap The ceramic honeycomb carrier of lattice, this can cause the globality poor of the ceramic honeycomb carrier in metal-back, during increasing vent gas treatment Resistance, reduce tail gas clean-up effect, and honeycomb substrate is when mounted, complex operation, efficiency is low;Such a cellular set simultaneously The stomata of body is clear opening, poor to the waste gas purification effect containing black smoke particle.
Existing honeycomb substrate can not be effectively acidproof, can not meet the needs of client.
The content of the invention
It is an object of the invention to overcome above-mentioned deficiency, there is provided a kind of square acid-proof ceramics honeycomb substrate, this ceramic honeybee It is nest carrier good integrity, good purification, easy for installation, can be effectively acidproof.
The object of the present invention is achieved like this:
A kind of square acid-proof ceramics honeycomb substrate, including cylindrical body, are characterized in:The section of the cylindrical body is in four sides Shape, including the first end to end arc-shaped edges, the second arc-shaped edges, three-arc side and the 4th arc-shaped edges, first arc-shaped edges, The junction of second arc-shaped edges, three-arc side and the 4th arc-shaped edges uses round-corner transition, and the cylindrical body is in the axial direction Stomata is densely covered with, one end of the stomata is opening, and the other end is provided with closure face, the closure face and open space arrangement, Next door is provided between the two neighboring stomata, the micropore in cellular arrangement is provided with next door, catalysis is coated with next door Agent coating, the honeycomb substrate surface are coated with acid-proof coating, and this acid-proof coating is mainly matched by following raw materials by weight portion It is made:13 parts of quartz sand, 12 parts of petroleum coke, 9 parts of wood chip, 8 parts of sodium chloride, 1 part of titanium dioxide, 13 parts of ethanol, 30 parts of water;
The preparation method of the acid-proof coating, is comprised the steps of:
(1)Quartz sand, petroleum coke and wood chip are pulverized, powder diameter is 400 mesh;
(2)By step(1)In powder and sodium chloride powder the input high temperature resistance furnace of acquisition, radiant heating, temperature is maintained at 1000 DEG C, 0.5 hour;
(3)Through step(2)Powder after pyrolytic semlting is with titania powder by weight 3:It is added to the water after 1 mixing, while stirring Mix side and add ethanol thereto, microelectronics surface acid-proof coating can be obtained to all dissolvings.
A kind of square acid-proof ceramics honeycomb substrate of the present invention, the hole count of its stomata is 600 holes/square inch.
A kind of square acid-proof ceramics honeycomb substrate of the present invention, the thickness in its next door is 0.13 ~ 0.14mm.
Compared with prior art, the beneficial effects of the invention are as follows:
A kind of square acid-proof ceramics honeycomb substrate of the present invention, good integrity, increases filtering surface to greatest extent in the confined space Product, and easy for installation, good purification;Micropore on next door can effectively filter the black smoke particle in waste gas, and in catalyst Black smoke particle can be burned off in the presence of coating, further increase tail gas clean-up effect, and the present invention is by by Raw material processing Into the method for aqua spraying, one kind, which is prepared, can be sprayed directly on ceramic honey comb surface, form one layer of densification, the guarantor of consolidation Sheath.
Brief description of the drawings
Fig. 1 is a kind of structural representation of square acid-proof ceramics honeycomb substrate of the present invention.
Fig. 2 is a kind of partial axial section figure of square acid-proof ceramics honeycomb substrate of the present invention.
Fig. 3 is the structural representation in the next door of the present invention.
In figure:
First arc-shaped edges 1,
Second arc-shaped edges 2,
Three-arc side 3,
Stomata 4,
Closure face 5,
Next door 6,
Micropore 7,
Tail gas 8,
Opening 9,
Catalyst coat 10,
4th arc-shaped edges 11.
Embodiment
Referring to Fig. 1-3, the present invention relates to a kind of square acid-proof ceramics honeycomb substrate, and it includes cylindrical body, the column The section of body is in quadrangle, by the first end to end arc-shaped edges 1, the second arc-shaped edges 2, the circular arc of three-arc side 3 and the 4th Side 11 forms, and first arc-shaped edges 1, the second arc-shaped edges 2, the junction of the arc-shaped edges 11 of three-arc side 3 and the 4th are using circle Angle transition, the cylindrical body are densely covered with stomata 4 in the axial direction, and one end of the stomata 4 is opening 9, and the other end is provided with Closure face 5, the closure face 5 and the arranged for interval of opening 9, next door 6 is provided between the two neighboring stomata 4, is opened on next door 6 There is the micropore 7 in cellular arrangement, catalyst coat 10 is coated with next door 6.
Wherein, the hole count of stomata 4 is 600 holes/square inch, and the thickness in next door 6 is 0.13 ~ 0.14mm.
The ceramic honey comb surface is coated with acid-proof coating, and this acid-proof coating is mainly matched by following raw materials by weight portion It is made:13 parts of quartz sand, 12 parts of petroleum coke, 9 parts of wood chip, 8 parts of sodium chloride, 1 part of titanium dioxide, 13 parts of ethanol, 30 parts of water.
The preparation method of the acid-proof coating, is comprised the steps of:
(1)Quartz sand, petroleum coke and wood chip are pulverized, powder diameter is 400 mesh;
(2)By step(1)In powder and sodium chloride powder the input high temperature resistance furnace of acquisition, radiant heating, temperature is maintained at 1000 DEG C, 0.5 hour;
(3)Through step(2)Powder after pyrolytic semlting is with titania powder by weight 3:It is added to the water after 1 mixing, while stirring Mix side and add ethanol thereto, microelectronics surface acid-proof coating can be obtained to all dissolvings.
Operation principle:The present invention is fabricated to honeycomb ceramic carrier using cordierite, and is built in diesel engine vent gas purification In device, the waste gas with black smoke particle of diesel engine discharge enters from the opening 9 of stomata 4, because stomata 4 is opened at one end Mouthfuls 9, and be then closure face 5 in the other end, therefore waste gas can be by the next door 6 with micropore 7, then opening from adjacent air holes 4 Mouth 9 is discharged, and because the diameter of black smoke particle is big compared with micropore 7, therefore the black smoke particle in waste gas will catch next door 6 by filtering On, air-flow then passes through from micropore 7.
Active rare earth of the catalyst coat 10 containing noble metal, Main Ingredients and Appearance have Pt, Pd, Rh, Al2O3、Ce、La、 Zr, Cu, Mn, the waste gas of diesel combustion(The predominantly pernicious gas such as CO, HC, NOx)During through micropore 7, coat on next door 6 Catalyst coat 10 will strengthen CO, HC, NOxThe activity of three kinds of gas, it is promoted to carry out certain oxidationreduction chemistry anti- Should, wherein CO is oxidized to colourless nontoxic carbon dioxide at high temperature, and HC compounds resolve into water at high temperature(H2O)With Carbon dioxide, NOxIt is reduced into nitrogen and oxygen.
When diesel exhaust gas temperature reaches 375 degrees Celsius, in the presence of catalyst coat 10, the black smoke on next door 6 Particle can progressively burn and aoxidize, and the purifying rate of black smoke particle about reaches more than 85%, when reaction temperature reaches 500 degrees Celsius When catalyst and black smoke particle reaction fall so as to completely burned(Catalysis burning), now the purifying rate of black smoke particle up to 90% with On.

Claims (3)

1. a kind of square acid-proof ceramics honeycomb substrate, including cylindrical body, it is characterised in that:The section of the cylindrical body is in four Side shape, including the first end to end arc-shaped edges(1), the second arc-shaped edges(2), three-arc side(3)With the 4th arc-shaped edges(11), First arc-shaped edges(1), the second arc-shaped edges(2), three-arc side(3)With the 4th arc-shaped edges(11)Junction use fillet Transition, the cylindrical body are densely covered with stomata in the axial direction(4), the stomata(4)One end be opening(9), the other end sets The closure face of being equipped with(5), the closure face(5)And opening(9)Arranged for interval, the two neighboring stomata(4)Between be provided with every Wall(6), next door(6)On be provided with micropore in cellular arrangement(7), next door(6)It is upper to be coated with catalyst coat(10), the honeybee Nest ceramic surface is coated with acid-proof coating, and this acid-proof coating is mainly made up of following raw materials by weight portion proportioning:Quartz sand 13 Part, 12 parts of petroleum coke, 9 parts of wood chip, 8 parts of sodium chloride, 1 part of titanium dioxide, 13 parts of ethanol, 30 parts of water;
The preparation method of the acid-proof coating, is comprised the steps of:
(1)Quartz sand, petroleum coke and wood chip are pulverized, powder diameter is 400 mesh;
(2)By step(1)In powder and sodium chloride powder the input high temperature resistance furnace of acquisition, radiant heating, temperature is maintained at 1000 DEG C, 0.5 hour;
(3)Through step(2)Powder after pyrolytic semlting is with titania powder by weight 3:It is added to the water after 1 mixing, while stirring Mix side and add ethanol thereto, microelectronics surface acid-proof coating can be obtained to all dissolvings.
A kind of 2. square acid-proof ceramics honeycomb substrate according to claim 1, it is characterised in that:The stomata(4)Hole Number is 600 holes/square inch.
A kind of 3. square acid-proof ceramics honeycomb substrate according to claim 1 or 2, it is characterised in that:The next door(6)'s Thickness is 0.13 ~ 0.14mm.
CN201610469698.0A 2016-06-26 2016-06-26 Square acid-proof ceramics honeycomb substrate Pending CN107542552A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610469698.0A CN107542552A (en) 2016-06-26 2016-06-26 Square acid-proof ceramics honeycomb substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610469698.0A CN107542552A (en) 2016-06-26 2016-06-26 Square acid-proof ceramics honeycomb substrate

Publications (1)

Publication Number Publication Date
CN107542552A true CN107542552A (en) 2018-01-05

Family

ID=60960553

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610469698.0A Pending CN107542552A (en) 2016-06-26 2016-06-26 Square acid-proof ceramics honeycomb substrate

Country Status (1)

Country Link
CN (1) CN107542552A (en)

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Application publication date: 20180105

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