CN107541950A - A kind of preparation method of flame-proof abrasion-resistant fabric - Google Patents
A kind of preparation method of flame-proof abrasion-resistant fabric Download PDFInfo
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- CN107541950A CN107541950A CN201610528763.2A CN201610528763A CN107541950A CN 107541950 A CN107541950 A CN 107541950A CN 201610528763 A CN201610528763 A CN 201610528763A CN 107541950 A CN107541950 A CN 107541950A
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Abstract
The present invention relates to a kind of preparation method of flame-proof abrasion-resistant fabric, by olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending, fabric lining is prepared；Then the fabric lining is impregnated in dressing liquid, then takes out heat treatment；Then impregnation liquid again, then takes out heat treatment；Last drying is to flame-proof abrasion-resistant fabric；The dressing liquid is by water, ethanol, propylene glycol block polyether, adipic acid two (the methylcyclohexyl formic acid of 3,4 epoxy radicals 6), N, N dimethyl-ethylenediamines, phosphorous acid three (2,4 di-tert-butyl-phenyl) ester, sodium metasilicate composition；The treatment fluid is made up of water, acetone, N vinyl pyrrolidones, trimethylene carbonate, the propanedione of 1,3 diphenyl 1,3, cetyl, bicyclopentadiene diepoxide, caprolactone.The fabric of preparation has good wearability and anti-flammability, suitable for extraordinary place.
Description
Technical field
The present invention relates to a kind of preparation method of extraordinary fabric, and in particular to a kind of preparation method of flame-proof abrasion-resistant fabric.
Background technology
The development of science and technology promotes textile industry constantly to advance, and various functions fabric, functional fabric also obtains extensively
General concern and development.Military clothes and field sport clothes require very high to the durability and use reliability of fabric, especially
It is required that the intensity of fabric is high, wearability is good.Existing fabric is typically made up of a kind of material, and feature is also relatively simple, through excessive
Easy modification after secondary use or washing, while the conductive structure of fabric is fairly simple, influences the visual effect of fabric, even results in
Fabric is scrapped.The wear-resisting high-strength fabric of in the market is generally all formed using the fitting of Multilayer plus material fiber, and thickness is thicker, easily damage
It is bad.Existing fabric is undesirable in terms of the combination property such as wear-resisting, fire-retardant.
The content of the invention
It is an object of the invention to provide a kind of preparation method of flame-proof abrasion-resistant fabric, the fabric by its acquisition is existing excellent
Wearability, there is preferable anti-flammability again, suitable for extraordinary place.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：A kind of preparation method of flame-proof abrasion-resistant fabric, including
Following steps：
(1) polyethylene, polypropylene, methine succinic acid and epoxy prepolymer are well mixed, added through screw rod melting extrusion
Work, olefin particles are prepared；Then by olefin particles and dimethyl tin oxide, the bromo- beta naphthals of 1-, tert-butyl lithium, isomery ten
Triol APEO is well mixed, and obtains compositions of olefines；Recycle melt spinning method that compositions of olefines is prepared into alkene
Fiber；
Bisphenol A cyanate ester monomer is added in reactor, 90~95 DEG C are reacted 12~15 minutes, and it is sweet to add three shrinks
Oil base cyamelide ester monomer, 150~155 DEG C are warming up to, add NPE, reacted 40~55 minutes and prepare
Epoxy prepolymer；
(2) by polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid fourth
Melt spinning method is used after ester mixing, polytetrafluoroethylene fibre is prepared；
(3) by PET, tetraethoxysilane, the different sour alkynes propyl ester of bromo fourth, N, N- dimethyl second two
Melt spinning method is used after amine, diethyl phosphite, ABVN mixing, polyester fiber is prepared；
(4) by olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending, fabric lining is prepared；Then by the fiber
Fabric impregnates 15~20 minutes in dressing liquid, then takes out and is heat-treated 30~35 seconds in 180~190 DEG C；Then place is impregnated again
Manage liquid 35~40 minutes, then take out and be heat-treated 110~125 seconds in 125~130 DEG C；Most arrived after 85~90 DEG C of dryings
Flame-proof abrasion-resistant fabric；The dressing liquid is by water, ethanol, propylene glycol block polyether, (3, the 4- epoxy radicals -6- methyl rings of adipic acid two
Hexyl formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, sodium metasilicate composition；The treatment fluid
By water, acetone, NVP, trimethylene carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, two rings
Pentadiene diepoxide, caprolactone composition.
In above-mentioned technical proposal, in the step (1), the reactive extrursion temperature of screw rod melting extrusion processing is 180~200
DEG C, screw speed control is 110~115 revs/min, and residence time of the material in screw rod is 5~6 minutes；Temperature during melt spinning
Spend for 210~220 DEG C, spinning speed is 600~700 ms/min.
In above-mentioned technical proposal, polyethylene in the step (1), polypropylene, methine succinic acid and epoxy prepolymer
Mass ratio is 1: 0.8: 0.2: 0.1；The bromo- beta naphthal of olefin particles, dimethyl tin oxide, 1-, tert-butyl lithium, isomerous tridecanol gather
The mass ratio of oxygen vinethene is 1: 0.001: 0.3: 0.005: 0.05；Bisphenol A cyanate ester monomer, triglycidyl group trimerization are different
Cyanate ester monomer, the mass ratio of NPE are 1: 2.5: 0.2.
In above-mentioned technical proposal, in the step (2), temperature is 315~330 DEG C during melt spinning, spinning speed 400
~500 ms/min.
In above-mentioned technical proposal, in the step (2), polytetrafluoroethylparticle particle and five nitric hydrate bismuths, ten phosphate dihydrates
Disodium hydrogen, uramit, the mass ratio of butyl acrylate are 1: 0.08: 0.2: 0.1: 0.2.
In above-mentioned technical proposal, in the step (3), temperature is 275~290 DEG C during melt spinning, spinning speed 800
~900 ms/min.
In above-mentioned technical proposal, in the step (3), PET, tetraethoxysilane, bromo fourth are different
Sour alkynes propyl ester, N, N- dimethyl-ethylenediamines, diethyl phosphite, the mass ratio of ABVN are 1: 0.12: 0.14: 0.1:
0.18∶0.0008。
In above-mentioned technical proposal, in the step (4), in dressing liquid, water, ethanol, propylene glycol block polyether, adipic acid two
(3,4- epoxy radicals -6- methylcyclohexyls formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester,
The mass ratio of sodium metasilicate is 100: 25: 24: 12: 6: 19: 8.
In above-mentioned technical proposal, in the step (4), in treatment fluid, water, acetone, NVP, three methylenes
Base carbonic ester, 1,3- diphenyl -1,3- propanedione, cetyl, bicyclopentadiene diepoxide, the mass ratio of caprolactone are
100∶20∶8∶32∶15∶6∶10∶16。
In above-mentioned technical proposal, in the step (4), olefin(e) fibre, polytetrafluoroethylene fibre, the mass ratio of polyester fiber
For 1: 0.3: 0.5.
The present invention compared with prior art, has the following advantages that：
(1) present invention improves the wearability and rigidity of fabric using polytetrafluoroethylene fibre, is carried by olefin(e) fibre
The high toughness of fabric, the mechanical property and intensity of fiber are improved using polyester fiber, and obtained fabric wearability is fabulous.
(2) present invention adds suitable auxiliary agent in spinning process, ignition-proof element is introduced into cellulosic backbone, fundamentally
Improve the anti-flammability of fabric；By compatible between improving various fibers in polytetrafluoroethylene fibre surface formation micropore
Property.
Embodiment
With reference to embodiment, the present invention will be further described in detail.
Embodiment one
A kind of preparation method of flame-proof abrasion-resistant fabric, comprises the following steps：
(1) polyethylene, polypropylene, methine succinic acid and epoxy prepolymer are well mixed, added through screw rod melting extrusion
Work, olefin particles are prepared；Then by olefin particles and dimethyl tin oxide, the bromo- beta naphthals of 1-, tert-butyl lithium, isomery ten
Triol APEO is well mixed, and obtains compositions of olefines；Recycle melt spinning method that compositions of olefines is prepared into alkene
Fiber；
Bisphenol A cyanate ester monomer is added in reactor, 95 DEG C are reacted 12 minutes, add triglycidyl group trimerization
Isocyanate-monomer, 155 DEG C are warming up to, add NPE, reaction prepares epoxy prepolymer in 55 minutes；
Polyethylene, polypropylene, the mass ratio of methine succinic acid and epoxy prepolymer are 1: 0.8: 0.2: 0.1；Alkene grain
The bromo- beta naphthal of son, dimethyl tin oxide, 1-, tert-butyl lithium, the mass ratio of isomerous tridecanol polyoxyethylene ether are 1: 0.001:
0.3∶0.005∶0.05；Bisphenol A cyanate ester monomer, triglycidyl group cyamelide ester monomer, Nonyl pheno
The mass ratio of ether is 1: 2.5: 0.2；
The reactive extrursion temperature of screw rod melting extrusion processing is 180~200 DEG C, screw speed control for 110~rev/min,
Residence time of the material in screw rod is 5 minutes；Temperature is 210~220 DEG C during melt spinning, and spinning speed is 600 ms/min；
(2) by polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid fourth
Melt spinning method is used after ester mixing, polytetrafluoroethylene fibre is prepared；Temperature is 315~330 DEG C during melt spinning, spinning
Speed is 400 ms/min；Polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid
The mass ratio of butyl ester is 1: 0.08: 0.2: 0.1: 0.2；
(3) by PET, tetraethoxysilane, the different sour alkynes propyl ester of bromo fourth, N, N- dimethyl second two
Melt spinning method is used after amine, diethyl phosphite, ABVN mixing, polyester fiber is prepared；During melt spinning
Temperature is 275~290 DEG C, and spinning speed is 800 ms/min；PET, tetraethoxysilane, bromo fourth are different
Sour alkynes propyl ester, N, N- dimethyl-ethylenediamines, diethyl phosphite, the mass ratio of ABVN are 1: 0.12: 0.14: 0.1:
0.18∶0.0008；
(4) olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending for being 1: 0.3: 0.5 by mass ratio, prepares fiber
Fabric；Then the fabric lining is impregnated 20 minutes in dressing liquid, then takes out and be heat-treated 30 seconds in 180 DEG C；Then again
Impregnation liquid 40 minutes, then take out and be heat-treated 110 seconds in 130 DEG C；Most after 85 DEG C of dryings to flame-proof abrasion-resistant fabric；
The dressing liquid is 100: 25: 24: 12: 6: 19: 8 water, ethanol, propylene glycol block polyether, adipic acid two (3,4- by mass ratio
Epoxy radicals -6- methylcyclohexyls formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, sodium metasilicate
Composition；The treatment fluid is 100: 20: 8: 32: 15: 6: 10: 16 water, acetone, NVP, three by mass ratio
Carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, bicyclopentadiene diepoxide, caprolactone composition.
Wear-resisting 10,000 times, oxygen index (OI) 30.
Embodiment two
A kind of preparation method of flame-proof abrasion-resistant fabric, comprises the following steps：
(1) polyethylene, polypropylene, methine succinic acid and epoxy prepolymer are well mixed, added through screw rod melting extrusion
Work, olefin particles are prepared；Then by olefin particles and dimethyl tin oxide, the bromo- beta naphthals of 1-, tert-butyl lithium, isomery ten
Triol APEO is well mixed, and obtains compositions of olefines；Recycle melt spinning method that compositions of olefines is prepared into alkene
Fiber；
Bisphenol A cyanate ester monomer is added in reactor, 90 DEG C are reacted 15 minutes, add triglycidyl group trimerization
Isocyanate-monomer, 150 DEG C are warming up to, add NPE, reaction prepares epoxy prepolymer in 40 minutes；
Polyethylene, polypropylene, the mass ratio of methine succinic acid and epoxy prepolymer are 1: 0.8: 0.2: 0.1；Alkene grain
The bromo- beta naphthal of son, dimethyl tin oxide, 1-, tert-butyl lithium, the mass ratio of isomerous tridecanol polyoxyethylene ether are 1: 0.001:
0.3∶0.005∶0.05；Bisphenol A cyanate ester monomer, triglycidyl group cyamelide ester monomer, Nonyl pheno
The mass ratio of ether is 1: 2.5: 0.2；
The reactive extrursion temperature of screw rod melting extrusion processing is 180~200 DEG C, and screw speed control is 115 revs/min, thing
It is 5 minutes to expect the residence time in screw rod；Temperature is 210~220 DEG C during melt spinning, and spinning speed is 700 ms/min；
(2) by polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid fourth
Melt spinning method is used after ester mixing, polytetrafluoroethylene fibre is prepared；Temperature is 315~330 DEG C during melt spinning, spinning
Speed is 500 ms/min；Polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid
The mass ratio of butyl ester is 1: 0.08: 0.2: 0.1: 0.2；
(3) by PET, tetraethoxysilane, the different sour alkynes propyl ester of bromo fourth, N, N- dimethyl second two
Melt spinning method is used after amine, diethyl phosphite, ABVN mixing, polyester fiber is prepared；During melt spinning
Temperature is 275~290 DEG C, and spinning speed is 900 ms/min；PET, tetraethoxysilane, bromo fourth are different
Sour alkynes propyl ester, N, N- dimethyl-ethylenediamines, diethyl phosphite, the mass ratio of ABVN are 1: 0.12: 0.14: 0.1:
0.18∶0.0008；
(4) olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending for being 1: 0.3: 0.5 by mass ratio, prepares fiber
Fabric；Then the fabric lining is impregnated 15 minutes in dressing liquid, then takes out and be heat-treated 35 seconds in 190 DEG C；Then again
Impregnation liquid 35 minutes, then take out and be heat-treated 110 seconds in 130 DEG C；Most after 90 DEG C of dryings to flame-proof abrasion-resistant fabric；
The dressing liquid is 100: 25: 24: 12: 6: 19: 8 water, ethanol, propylene glycol block polyether, adipic acid two (3,4- by mass ratio
Epoxy radicals -6- methylcyclohexyls formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, sodium metasilicate
Composition；The treatment fluid is 100: 20: 8: 32: 15: 6: 10: 16 water, acetone, NVP, three by mass ratio
Carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, bicyclopentadiene diepoxide, caprolactone composition.
Wear-resisting 10,000 times, oxygen index (OI) 30.
Embodiment three
A kind of preparation method of flame-proof abrasion-resistant fabric, comprises the following steps：
(1) polyethylene, polypropylene, methine succinic acid and epoxy prepolymer are well mixed, added through screw rod melting extrusion
Work, olefin particles are prepared；Then by olefin particles and dimethyl tin oxide, the bromo- beta naphthals of 1-, tert-butyl lithium, isomery ten
Triol APEO is well mixed, and obtains compositions of olefines；Recycle melt spinning method that compositions of olefines is prepared into alkene
Fiber；
Bisphenol A cyanate ester monomer is added in reactor, 90 DEG C are reacted 14 minutes, add triglycidyl group trimerization
Isocyanate-monomer, 150 DEG C are warming up to, add NPE, reaction prepares epoxy prepolymer in 50 minutes；
Polyethylene, polypropylene, the mass ratio of methine succinic acid and epoxy prepolymer are 1: 0.8: 0.2: 0.1；Alkene grain
The bromo- beta naphthal of son, dimethyl tin oxide, 1-, tert-butyl lithium, the mass ratio of isomerous tridecanol polyoxyethylene ether are 1: 0.001:
0.3∶0.005∶0.05；Bisphenol A cyanate ester monomer, triglycidyl group cyamelide ester monomer, Nonyl pheno
The mass ratio of ether is 1: 2.5: 0.2；
Screw rod melting extrusion processing reactive extrursion temperature be 180~200 DEG C, screw speed control for 110~115 turns/
Point, residence time of the material in screw rod is 6 minutes；During melt spinning temperature be 210~220 DEG C, spinning speed be 600 meters/
Point；
(2) by polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid fourth
Melt spinning method is used after ester mixing, polytetrafluoroethylene fibre is prepared；Temperature is 315~330 DEG C during melt spinning, spinning
Speed is 500 ms/min；Polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, acrylic acid
The mass ratio of butyl ester is 1: 0.08: 0.2: 0.1: 0.2；
(3) by PET, tetraethoxysilane, the different sour alkynes propyl ester of bromo fourth, N, N- dimethyl second two
Melt spinning method is used after amine, diethyl phosphite, ABVN mixing, polyester fiber is prepared；During melt spinning
Temperature is 275~290 DEG C, and spinning speed is 900 ms/min；PET, tetraethoxysilane, bromo fourth are different
Sour alkynes propyl ester, N, N- dimethyl-ethylenediamines, diethyl phosphite, the mass ratio of ABVN are 1: 0.12: 0.14: 0.1:
0.18∶0.0008；
(4) olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending for being 1: 0.3: 0.5 by mass ratio, prepares fiber
Fabric；Then the fabric lining is impregnated 15~20 minutes in dressing liquid, then takes out and be heat-treated 30 seconds in 185 DEG C；Connect
Impregnation liquid 35 minutes again, then takes out and is heat-treated 115 seconds in 130 DEG C；Most after 90 DEG C of dryings to flame-proof abrasion-resistant
Fabric；The dressing liquid is 100: 25: 24: 12: 6: 19: 8 water, ethanol, propylene glycol block polyether, adipic acid two by mass ratio
(3,4- epoxy radicals -6- methylcyclohexyls formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester,
Sodium metasilicate forms；The water, acetone, N- ethenyl pyrrolidones that the treatment fluid is 100: 20: 8: 32: 15: 6: 10: 16 by mass ratio
Ketone, trimethylene carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, bicyclopentadiene diepoxide, caprolactone
Composition.Wear-resisting 10,000 times, oxygen index (OI) 30.
Claims (10)
1. a kind of preparation method of flame-proof abrasion-resistant fabric, it is characterised in that comprise the following steps：
(1) polyethylene, polypropylene, methine succinic acid and epoxy prepolymer are well mixed, processed through screw rod melting extrusion, system
It is standby to obtain olefin particles；Then olefin particles and dimethyl tin oxide, the bromo- beta naphthals of 1-, tert-butyl lithium, isomerous tridecanol are gathered
Oxygen vinethene is well mixed, and obtains compositions of olefines；Recycle melt spinning method that compositions of olefines is prepared into olefin(e) fibre；
Bisphenol A cyanate ester monomer is added in reactor, 90~95 DEG C are reacted 12~15 minutes, add triglycidyl group
Cyamelide ester monomer, 150~155 DEG C are warming up to, add NPE, reaction prepares epoxy in 40~55 minutes
Performed polymer；
(2) polytetrafluoroethylparticle particle and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, butyl acrylate are mixed
Melt spinning method is used after conjunction, polytetrafluoroethylene fibre is prepared；
(3) by PET, tetraethoxysilane, the different sour alkynes propyl ester of bromo fourth, N, N- dimethyl-ethylenediamines, Asia
Melt spinning method is used after diethyl phosphate, ABVN mixing, polyester fiber is prepared；
(4) by olefin(e) fibre, polytetrafluoroethylene fibre, polyester fiber blending, fabric lining is prepared；Then by the fabric lining
Impregnated 15~20 minutes in dressing liquid, then take out and be heat-treated 30~35 seconds in 180~190 DEG C；Then impregnation liquid again
35~40 minutes, then take out and be heat-treated 110~125 seconds in 125~130 DEG C；Most after 85~90 DEG C of dryings to fire-retardant
Wear-resisting fabric；The dressing liquid is by water, ethanol, propylene glycol block polyether, (3, the 4- epoxy radicals -6- methylcyclohexyls of adipic acid two
Formic acid), N, N- dimethyl-ethylenediamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, sodium metasilicate composition；The treatment fluid by
Water, acetone, NVP, trimethylene carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, two rings penta
Diene diepoxide, caprolactone composition.
2. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (1), screw rod melts
The reactive extrursion temperature for melting extrusion processing is 180~200 DEG C, and screw speed control is 110~115 revs/min, and material is in screw rod
Residence time be 5~6 minutes；Temperature is 210~220 DEG C during melt spinning, and spinning speed is 600~700 ms/min.
3. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：Polyethylene in the step (1),
The mass ratio of polypropylene, methine succinic acid and epoxy prepolymer is 1: 0.8: 0.2: 0.1；Olefin particles, dimethyl tin oxide,
The bromo- beta naphthals of 1-, tert-butyl lithium, the mass ratio of isomerous tridecanol polyoxyethylene ether are 1: 0.001: 0.3: 0.005: 0.05；It is double
Phenol A types cyanate ester monomer, triglycidyl group cyamelide ester monomer, the mass ratio of NPE are 1: 2.5:
0.2。
4. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (2), melting is spun
Temperature is 315~330 DEG C during silk, and spinning speed is 400~500 ms/min.
5. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (2), polytetrafluoro
Beta particles and five nitric hydrate bismuths, disodium hydrogen phosphate, uramit, the mass ratio of butyl acrylate are 1: 0.08:
0.2∶0.1∶0.2。
6. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (3), melting is spun
Temperature is 275~290 DEG C during silk, and spinning speed is 800~900 ms/min.
7. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (3), gather to benzene
The different sour alkynes propyl ester of dioctyl phthalate second diester, tetraethoxysilane, bromo fourth, N, N- dimethyl-ethylenediamines, diethyl phosphite, azo
The mass ratio of two different heptonitriles is 1: 0.12: 0.14: 0.1: 0.18: 0.0008.
8. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (4), dressing liquid
In, water, ethanol, propylene glycol block polyether, adipic acid two (3,4- epoxy radicals -6- methylcyclohexyls formic acid), N, N- dimethyl second
Diamines, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, the mass ratio of sodium metasilicate are 100: 25: 24: 12: 6: 19: 8.
9. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (4), treatment fluid
In, water, acetone, NVP, trimethylene carbonate, 1,3- diphenyl -1,3- propanedione, cetyl, two
Cyclopentadiene diepoxide, the mass ratio of caprolactone are 100: 20: 8: 32: 15: 6: 10: 16.
10. the preparation method of flame-proof abrasion-resistant fabric according to claim 1, it is characterised in that：In the step (4), alkene
Fiber, polytetrafluoroethylene fibre, the mass ratio of polyester fiber are 1: 0.3: 0.5.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2576764A (en) * | 2018-08-31 | 2020-03-04 | Devan Chemicals Nv | Textile Temperature Regulating Agents |
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| CN105199194A (en) * | 2015-09-30 | 2015-12-30 | 南宁市聚祥塑料制品有限责任公司 | Plastic and preparation method thereof |
| CN105411052A (en) * | 2016-01-25 | 2016-03-23 | 靖江强纶新材料有限公司 | Work glove and manufacturing process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102634904A (en) * | 2012-04-16 | 2012-08-15 | 中国人民解放军总后勤部军需装备研究所 | Polyester fiber blended or interwoven fabric with flame retardant property and molten drop resistance |
| CN103304745A (en) * | 2013-06-21 | 2013-09-18 | 浙江荣泰科技企业有限公司 | Polymerizable flame retardant resin |
| WO2015071133A1 (en) * | 2013-11-12 | 2015-05-21 | Dsm Ip Assets B.V. | Abrasion resistant fabric |
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| CN105411052A (en) * | 2016-01-25 | 2016-03-23 | 靖江强纶新材料有限公司 | Work glove and manufacturing process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2576764A (en) * | 2018-08-31 | 2020-03-04 | Devan Chemicals Nv | Textile Temperature Regulating Agents |
| GB2576764B (en) * | 2018-08-31 | 2022-10-19 | Devan Chemicals Nv | Textile Temperature Regulating Agents |
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