CN108385389A - The anti-fire processing method of dacron - Google Patents

The anti-fire processing method of dacron Download PDF

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Publication number
CN108385389A
CN108385389A CN201810166172.4A CN201810166172A CN108385389A CN 108385389 A CN108385389 A CN 108385389A CN 201810166172 A CN201810166172 A CN 201810166172A CN 108385389 A CN108385389 A CN 108385389A
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China
Prior art keywords
dacron
processing method
acrylamide
flame retardant
fire processing
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Pending
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CN201810166172.4A
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Chinese (zh)
Inventor
沈学如
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Aoyang Group Co Ltd
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Aoyang Group Co Ltd
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Priority to CN201810166172.4A priority Critical patent/CN108385389A/en
Publication of CN108385389A publication Critical patent/CN108385389A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/14Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

Abstract

This application discloses a kind of anti-fire processing methods of dacron, including step:(1), dacron pre-processes, to remove the oil stain and impurity on dacron surface;(2), dacron is modified, modifying agent includes glycidyl methacrylate and acrylamide, and the mass ratio of glycidyl methacrylate and acrylamide is (8~12):1;(3), modified dacron is immersed in flame retardant solution, carries out flame retardant treatment.The present invention is used as modifying agent by glycidyl methacrylate and acrylamide and is grafted, and can not only improve the flame retardant property of dacron, and dacron is made to have anti-dropping, and its grafting rate and limit oxygen index are improved significantly.

Description

The anti-fire processing method of dacron
Technical field
This application involves textile technology fields, more particularly to a kind of anti-fire processing method of dacron.
Background technology
Terylene is an important kind in synthetic fibers, is the simplest one kind of technique, price in five big synthetic fibers Also relatively cheap.Terylene have the characteristics that it is durable, be unlikely to deform, be corrosion-resistant, insulation, it is well-pressed, quick-drying washable.Therefore, it washs Synthetic fibre has many uses, and is largely used to manufacture wearing fabric and industry textile fabrics.However, the inflammability of terylene make its application by Limitation.Therefore, exploitation flame retardant polyester fabric has wide application value.
Invention content
The purpose of the present invention is to provide a kind of anti-fire processing method of dacron, with overcome it is in the prior art not Foot.
To achieve the above object, the present invention provides the following technical solutions:
The embodiment of the present application discloses a kind of anti-fire processing method of dacron, including step:
(1), dacron pre-processes, to remove the oil stain and impurity on dacron surface;
(2), dacron is modified, modifying agent includes glycidyl methacrylate and acrylamide, methyl The mass ratio of glycidyl acrylate and acrylamide is (8~12):1;
(3), modified dacron is immersed in flame retardant solution, carries out flame retardant treatment.
Preferably, in the anti-fire processing method of above-mentioned dacron, step (1) includes:Prepare dodecyl sulphur Dacron is immersed in pretreatment fluid by acid sodium aqueous solution, is heated to 80~100 DEG C and is then kept 10~30min, then with third Ketone solution extracts 16~20h, and dacron is fished for out, is dried after being washed with clear water.
Preferably, in the anti-fire processing method of above-mentioned dacron, the quality of sodium dodecyl sulfate aqueous solution Concentration of volume percent is 20g/L.
Preferably, in the anti-fire processing method of above-mentioned dacron, in step (2), Glycidyl methacrylate is sweet The mass ratio of grease and acrylamide is 10:1.
Preferably, in the anti-fire processing method of above-mentioned dacron, step (2) includes:Methacrylic acid is contracted Water glyceride and acrylamide are added in the benzophenone of 5%wt, are stirred, and are configured to modified solution, wherein methyl-prop Olefin(e) acid ethylene oxidic ester and the additive amount of acrylamide entirety are 16%wt, 60min are then irradiated under ultraviolet irradiation condition, most Afterwards 5min is dried under the conditions of 100 DEG C.
Preferably, in the anti-fire processing method of above-mentioned dacron, in step (3), flame retardant solution includes dispersion Bisphenol-A-bis- (diphenyl phosphoesters), borax, mannitol, sulfamic acid and ammonium polyphosphate in water.
Preferably, it in the anti-fire processing method of above-mentioned dacron, in step (3), is dispersed in every 100mL water The bisphenol-As-bis- (diphenyl phosphoesters) of 3 parts by weight, the borax of 0.5 parts by weight, the mannitol of 2.5 parts by weight, 0.5 parts by weight The ammonium polyphosphate of sulfamic acid and 0.5 parts by weight.
Preferably, in the anti-fire processing method of above-mentioned dacron, step (3) includes:By the bis- (hexichol of bisphenol-A- Base phosphate), borax, mannitol, sulfamic acid, ammonium polyphosphate be dispersed in water, be uniformly mixed, flame retardant solution be heated to 50 DEG C, the terylene after graft modification is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure of padding machine 0.2MPa finally dries 10min under the conditions of 100 DEG C, then bakes 30min under the conditions of 200 DEG C.
Compared with the prior art, the advantages of the present invention are as follows:The present invention passes through glycidyl methacrylate and propylene Amide is grafted as modifying agent, can not only improve the flame retardant property of dacron, and it is anti-molten so that dacron has Drop property, and its grafting rate and limit oxygen index are improved significantly.
Description of the drawings
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments described in application, for those of ordinary skill in the art, without creative efforts, Other drawings may also be obtained based on these drawings.
Fig. 1 is shown in the specific embodiment of the invention ...
Specific implementation mode
The present embodiment provides a kind of anti-fire processing methods of dacron, including step:
(1), dacron pre-processes, to remove the oil stain and impurity on dacron surface;
(2), dacron is modified, modifying agent includes glycidyl methacrylate and acrylamide, methyl The mass ratio of glycidyl acrylate and acrylamide is (8~12):1;
(3), modified dacron is immersed in flame retardant solution, carries out flame retardant treatment.
The present invention is used as modifying agent by glycidyl methacrylate and acrylamide and is grafted, and can not only carry The flame retardant property of high dacron, and make dacron that there is anti-dropping, and also its grafting rate and limit oxygen index obtain It significantly improves.
Those skilled in the art can use for reference present disclosure, be suitably modified technological parameter realization.In particular, it should be pointed out that All similar substitutions and modifications are apparent to those skilled in the art, they are considered as being included in this hair It is bright.The present invention application be described by preferred embodiment, related personnel obviously can not depart from the content of present invention, Application as described herein is modified or is suitably changed and combined in spirit and scope, to realize and apply the technology of the present invention.
For a further understanding of the present invention, the following describes the present invention in detail with reference to examples.
Embodiment 1
The pretreatment of dacron:The sodium dodecyl sulfate aqueous solution that quality concentration of volume percent is 20g/L is prepared, Dacron is immersed in pretreatment fluid, the input amount of dacron is 50g/L, is heated to 90 DEG C and then keeps 30min, then 20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water, dacron can be thus removed The oil stain and impurity on surface, obtain pretreated dacron.
Graft modification:By glycidyl methacrylate and acrylamide according to mass ratio 10:1 is added to 5%wt's It in benzophenone, is stirred, is configured to modified solution.Wherein glycidyl methacrylate and acrylamide are whole adds Dosage is 16%wt.Then 60min is irradiated under ultraviolet irradiation condition, then dries 5min under the conditions of 100 DEG C.
Flame retardant treatment:Prepare flame retardant solution, by 3g bisphenol-As-bis- (diphenyl phosphoesters), 0.5g boraxs, 2.5g mannitol, 0.5g sulfamic acids, 0.5g ammonium polyphosphate are dispersed in 100mL water, are uniformly mixed.Flame retardant solution is heated to 50 DEG C, will be grafted Modified terylene is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure 0.2MPa of padding machine.Most 10min is dried under the conditions of 100 DEG C afterwards, then 30min is baked under the conditions of 200 DEG C.
To treated, dacron is tested, and performance parameter is shown in ginseng table 1.
Embodiment 2
The pretreatment of dacron:The sodium dodecyl sulfate aqueous solution that quality concentration of volume percent is 20g/L is prepared, Dacron is immersed in pretreatment fluid, the input amount of dacron is 50g/L, is heated to 90 DEG C and then keeps 30min, then 20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water, dacron can be thus removed The oil stain and impurity on surface, obtain pretreated dacron.
Graft modification:By glycidyl methacrylate and acrylamide according to mass ratio 8:1 is added to the two of 5%wt It in Benzophenone, is stirred, is configured to modified solution.The wherein addition of glycidyl methacrylate and acrylamide entirety Amount is 15%wt.Then 60min is irradiated under ultraviolet irradiation condition, then dries 5min under the conditions of 100 DEG C.
Flame retardant treatment:Prepare flame retardant solution, by 3g bisphenol-As-bis- (diphenyl phosphoesters), 0.5g boraxs, 2.5g mannitol, 0.5g sulfamic acids, 0.5g ammonium polyphosphate are dispersed in 100mL water, are uniformly mixed.Flame retardant solution is heated to 50 DEG C, will be grafted Modified terylene is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure 0.2MPa of padding machine.Most 10min is dried under the conditions of 100 DEG C afterwards, then 30min is baked under the conditions of 200 DEG C.
To treated, dacron is tested, and performance parameter is shown in ginseng table 1.
Embodiment 3
The pretreatment of dacron:The sodium dodecyl sulfate aqueous solution that quality concentration of volume percent is 20g/L is prepared, Dacron is immersed in pretreatment fluid, the input amount of dacron is 50g/L, is heated to 90 DEG C and then keeps 30min, then 20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water, dacron can be thus removed The oil stain and impurity on surface, obtain pretreated dacron.
Graft modification:By glycidyl methacrylate and acrylamide according to mass ratio 12:1 is added to 5%wt's It in benzophenone, is stirred, is configured to modified solution.Wherein glycidyl methacrylate and acrylamide are whole adds Dosage is 18%wt.Then 60min is irradiated under ultraviolet irradiation condition, then dries 5min under the conditions of 100 DEG C.
Flame retardant treatment:Prepare flame retardant solution, by 3g bisphenol-As-bis- (diphenyl phosphoesters), 0.5g boraxs, 2.5g mannitol, 0.5g sulfamic acids, 0.5g ammonium polyphosphate are dispersed in 100mL water, are uniformly mixed.Flame retardant solution is heated to 50 DEG C, will be grafted Modified terylene is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure 0.2MPa of padding machine.Most 10min is dried under the conditions of 100 DEG C afterwards, then 30min is baked under the conditions of 200 DEG C.
To treated, dacron is tested, and performance parameter is shown in ginseng table 1.
Comparative example 1
The pretreatment of dacron:The sodium dodecyl sulfate aqueous solution that quality concentration of volume percent is 20g/L is prepared, Dacron is immersed in pretreatment fluid, the input amount of dacron is 50g/L, is heated to 90 DEG C and then keeps 30min, then 20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water, dacron can be thus removed The oil stain and impurity on surface, obtain pretreated dacron.
Graft modification:Glycidyl methacrylate is added in the benzophenone of 5%wt, is stirred, is prepared At modified solution.Wherein the additive amount of glycidyl methacrylate is 14%wt.Then it is irradiated under ultraviolet irradiation condition Then 60min dries 5min under the conditions of 100 DEG C.
Flame retardant treatment:Prepare flame retardant solution, by 3g bisphenol-As-bis- (diphenyl phosphoesters), 0.5g boraxs, 2.5g mannitol, 0.5g sulfamic acids, 0.5g ammonium polyphosphate are dispersed in 100mL water, are uniformly mixed.Flame retardant solution is heated to 50 DEG C, will be grafted Modified terylene is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure 0.2MPa of padding machine.Most 10min is dried under the conditions of 100 DEG C afterwards, then 30min is baked under the conditions of 200 DEG C.
To treated, dacron is tested, and performance parameter is shown in ginseng table 1.
Comparative example 2
The pretreatment of dacron:The sodium dodecyl sulfate aqueous solution that quality concentration of volume percent is 20g/L is prepared, Dacron is immersed in pretreatment fluid, the input amount of dacron is 50g/L, is heated to 90 DEG C and then keeps 30min, then 20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water, dacron can be thus removed The oil stain and impurity on surface, obtain pretreated dacron.
Graft modification:Acrylamide is added in the benzophenone of 5%wt, is stirred, modified solution is configured to.Its The additive amount of middle glycidyl methacrylate and acrylamide entirety is 16%wt.Then it is irradiated under ultraviolet irradiation condition Then 60min dries 5min under the conditions of 100 DEG C.
Flame retardant treatment:Prepare flame retardant solution, by 3g bisphenol-As-bis- (diphenyl phosphoesters), 0.5g boraxs, 2.5g mannitol, 0.5g sulfamic acids, 0.5g ammonium polyphosphate are dispersed in 100mL water, are uniformly mixed.Flame retardant solution is heated to 50 DEG C, will be grafted Modified terylene is immersed in 30min in flame retardant solution, is then rolled in padding machine, the double rod pressure 0.2MPa of padding machine.Most 10min is dried under the conditions of 100 DEG C afterwards, then 30min is baked under the conditions of 200 DEG C.
To treated, dacron is tested, and performance parameter is shown in ginseng table 1.
Table 1
As shown in Table 1, it is used as modifying agent by glycidyl methacrylate and acrylamide to be grafted, not only may be used To improve the flame retardant property of dacron, and make dacron that there is anti-dropping, and its grafting rate and limit oxygen index It is apparently higher than comparative example 1 and comparative example 2, in addition, inventor is found surprisingly that by a large amount of experiment, according to the item of embodiment 1 Part is modified dacron, can generate the fabric of excellent combination property, and modifying agent grafting rate and limit oxygen index obtain To being obviously improved.
Here, it should also be noted that, in order to avoid having obscured the present invention because of unnecessary details, in the accompanying drawings only It shows the structure and/or processing step closely related with scheme according to the present invention, and is omitted little with relationship of the present invention Other details.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that including a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (8)

1. a kind of anti-fire processing method of dacron, which is characterized in that including step:
(1), dacron pre-processes, to remove the oil stain and impurity on dacron surface;
(2), dacron is modified, modifying agent includes glycidyl methacrylate and acrylamide, metering system The mass ratio of acid glycidyl ester and acrylamide is (8~12):1;
(3), modified dacron is immersed in flame retardant solution, carries out flame retardant treatment.
2. the anti-fire processing method of dacron according to claim 1, which is characterized in that step (1) includes:It prepares Dacron is immersed in pretreatment fluid by sodium dodecyl sulfate aqueous solution, be heated to 80~100 DEG C then keep 10~ 30min, then 16~20h is extracted with acetone soln, dacron is fished for out, is dried after being washed with clear water.
3. the anti-fire processing method of dacron according to claim 2, which is characterized in that dodecyl sodium sulfate water The quality concentration of volume percent of solution is 20g/L.
4. the anti-fire processing method of dacron according to claim 1, which is characterized in that in step (2), methyl-prop The mass ratio of olefin(e) acid ethylene oxidic ester and acrylamide is 10:1.
5. the anti-fire processing method of dacron according to claim 4, which is characterized in that step (2) includes:By first Base glycidyl acrylate and acrylamide are added in the benzophenone of 5%wt, are stirred, and are configured to modified solution, Wherein the additive amount of glycidyl methacrylate and acrylamide entirety is 16%wt, then the spoke under ultraviolet irradiation condition According to 60min, finally 5min is dried under the conditions of 100 DEG C.
6. the anti-fire processing method of dacron according to claim 1, which is characterized in that fire-retardant molten in step (3) Liquid includes bisphenol-A-bis- (diphenyl phosphoesters), borax, mannitol, sulfamic acid and the ammonium polyphosphate being dispersed in water.
7. the anti-fire processing method of dacron according to claim 6, which is characterized in that in step (3), often Be dispersed in 100mL water the bisphenol-As-bis- (diphenyl phosphoesters) of 3 parts by weight, the borax of 0.5 parts by weight, 2.5 parts by weight it is sweet Reveal alcohol, 0.5 parts by weight sulfamic acid and 0.5 parts by weight ammonium polyphosphate.
8. the anti-fire processing method of dacron according to claim 7, which is characterized in that step (3) includes:It will be double Phenol A- bis- (diphenyl phosphoesters), borax, mannitol, sulfamic acid, ammonium polyphosphate are dispersed in water, and are uniformly mixed, will be fire-retardant Solution is heated to 50 DEG C, and the terylene after graft modification is immersed in 30min in flame retardant solution, is then rolled in padding machine, The double rod pressure 0.2MPa of padding machine, finally dry 10min, then bake 30min under the conditions of 200 DEG C under the conditions of 100 DEG C.
CN201810166172.4A 2018-02-28 2018-02-28 The anti-fire processing method of dacron Pending CN108385389A (en)

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CN111188193A (en) * 2018-11-15 2020-05-22 北京服装学院 Flame-retardant anti-dripping polyester fabric and preparation method thereof
CN111559127A (en) * 2020-06-03 2020-08-21 席梦思床褥家具(苏州)有限公司 Medium flame-retardant copper ion fiber composite fabric and manufacturing method thereof
CN113463392A (en) * 2021-06-15 2021-10-01 吴江市南麻恒兴丝织厂 Preparation method of biomass particle modified four-side elastic fabric

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CN111188193A (en) * 2018-11-15 2020-05-22 北京服装学院 Flame-retardant anti-dripping polyester fabric and preparation method thereof
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CN111559127A (en) * 2020-06-03 2020-08-21 席梦思床褥家具(苏州)有限公司 Medium flame-retardant copper ion fiber composite fabric and manufacturing method thereof
CN113463392A (en) * 2021-06-15 2021-10-01 吴江市南麻恒兴丝织厂 Preparation method of biomass particle modified four-side elastic fabric

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Application publication date: 20180810