CN107541053A - Ameliorative TUP films - Google Patents

Ameliorative TUP films Download PDF

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Publication number
CN107541053A
CN107541053A CN201710783936.XA CN201710783936A CN107541053A CN 107541053 A CN107541053 A CN 107541053A CN 201710783936 A CN201710783936 A CN 201710783936A CN 107541053 A CN107541053 A CN 107541053A
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CN
China
Prior art keywords
parts
tup
ameliorative
films
stabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710783936.XA
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Chinese (zh)
Inventor
陈维兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rui'an City Hong Plastic Cement Co Ltd
Original Assignee
Rui'an City Hong Plastic Cement Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rui'an City Hong Plastic Cement Co Ltd filed Critical Rui'an City Hong Plastic Cement Co Ltd
Priority to CN201710783936.XA priority Critical patent/CN107541053A/en
Publication of CN107541053A publication Critical patent/CN107541053A/en
Pending legal-status Critical Current

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  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to a kind of film, more particularly to a kind of ameliorative TUP films.The invention provides following technical scheme:A kind of ameliorative TUP films, its processing formula component are configured to by mass fraction:15 parts -25 parts of methyl diphenylene diisocyanate;40 parts -55 parts of adhesive;3 parts -5 parts of dihydric alcohol;1 part -3 parts of polybutylene terephthalate;1 part -3 parts of ion exchange resin;1 part -2 parts of crosslinking agent;1 part of stabilizer.Using above-mentioned technical proposal, there is provided a kind of shrinkage is good, tensile strength is stable, the ameliorative TUP films without glutinous soapy feeling when touching.

Description

Ameliorative TUP films
Technical field
The present invention relates to a kind of film, more particularly to a kind of ameliorative TUP films.
Background technology
TPU film is a kind of thermoplastic elastomer, on the basis of its tangible TPU particulate material, by rolling, being cast, blowing Film is made in the techniques such as film, coating, using extremely wide on sport footwear.It has the five poisonous creatures: scorpion, viper, centipede, house lizard, toad, degradable benefit.
However, more particle be present in the TPU film that traditional formula processes, when being touched with hand, it is very strong to stick soapy feeling.And Less stable in proportioning in heat treatment process is implemented, water resistance and shrinkage are poor, cause the tension of TPU film finished product strong Degree reduces.
The content of the invention
In view of the deficienciess of the prior art, the invention provides a kind of shrinkage is good, tensile strength is stable, touch when without The ameliorative TUP films of glutinous soapy feeling.
To achieve the above object, the invention provides following technical scheme:A kind of ameliorative TUP films, it is characterised in that: Its processing formula component is configured to by mass fraction:15 parts -25 parts of methyl diphenylene diisocyanate;Adhesive 40 parts -55 Part;3 parts -5 parts of dihydric alcohol;1 part -3 parts of polybutylene terephthalate;1 part -3 parts of ion exchange resin;1 part of crosslinking agent- 2 parts;1 part of stabilizer.
Wherein, crosslinking agent is polyalcohol.Stabilizer is lead sulfate tribasic.
Using above-mentioned technical proposal, by adding polybutylene terephthalate in proportioning, promote the TUP processed thin The shrinkage factor increase of film, so as to improve its tensile strength;Ion exchange resin addition can then eliminate particle, while add stabilization Agent, in process hot melt of its proportioning be improved, it is further to eliminate particle and impurity, make the TUP processed thin Film is without glutinous soapy feeling.
Embodiment
The invention provides a kind of ameliorative TUP films, its processing formula component is configured to by mass fraction:Diphenylmethyl 15 parts -25 parts of alkane diisocyanate;40 parts -55 parts of adhesive;3 parts -5 parts of dihydric alcohol;Polybutylene terephthalate 1 - 3 parts of part;1 part -3 parts of ion exchange resin;1 part -2 parts of crosslinking agent;1 part of stabilizer.Wherein crosslinking agent is preferably polyalcohol. Stabilizer is preferably lead sulfate tribasic.Such scheme promotes to process by adding polybutylene terephthalate in proportioning The shrinkage factor increase of the TUP films gone out, so as to improve its tensile strength;Ion exchange resin addition can then eliminate particle, together Shi Tianjia stabilizers, in process hot melt of its proportioning be improved, it is further to eliminate particle and impurity, make processing The TUP films gone out are without glutinous soapy feeling.
Embodiment one:15 parts of methyl diphenylene diisocyanate;40 parts of adhesive;3 parts of dihydric alcohol;Poly terephthalic acid fourth 1 part of diester;1 part of ion exchange resin;1 part of crosslinking agent-;1 part of stabilizer.
Its test structure is as follows:
Embodiment two:25 parts of methyl diphenylene diisocyanate;55 parts of adhesive;5 parts of dihydric alcohol;Polybutylene terephthalate 3 parts;3 parts of ion exchange resin;2 parts of crosslinking agent;1 part of stabilizer.
Its test result is as follows:

Claims (3)

  1. A kind of 1. ameliorative TUP films, it is characterised in that:Its processing formula component is configured to by mass fraction:Diphenyl methane 15 parts -25 parts of diisocyanate;40 parts -55 parts of adhesive;3 parts -5 parts of dihydric alcohol;Polybutylene terephthalate 1 part -3 Part;1 part -3 parts of ion exchange resin;1 part -2 parts of crosslinking agent;1 part of stabilizer.
  2. 2. ameliorative TUP films according to claim 1, it is characterised in that:Described crosslinking agent is polyalcohol.
  3. 3. ameliorative TUP films according to claim 1 or 2, it is characterised in that:Described stabilizer is tribasic sulfuric acid Lead.
CN201710783936.XA 2017-09-04 2017-09-04 Ameliorative TUP films Pending CN107541053A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710783936.XA CN107541053A (en) 2017-09-04 2017-09-04 Ameliorative TUP films

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710783936.XA CN107541053A (en) 2017-09-04 2017-09-04 Ameliorative TUP films

Publications (1)

Publication Number Publication Date
CN107541053A true CN107541053A (en) 2018-01-05

Family

ID=60957638

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710783936.XA Pending CN107541053A (en) 2017-09-04 2017-09-04 Ameliorative TUP films

Country Status (1)

Country Link
CN (1) CN107541053A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113106764A (en) * 2020-01-13 2021-07-13 浙江诚迅新材料有限公司 Super-fiber super-soft scratch-resistant wear-resistant surface layer resin and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532471A (en) * 2012-01-01 2012-07-04 于龙洲 Formula of resin special for polyurethane film
JP2012206490A (en) * 2011-03-30 2012-10-25 Shin Etsu Polymer Co Ltd Mold release film
CN102977836A (en) * 2012-11-28 2013-03-20 四川汇利实业有限公司 Environment-friendly adhesive for drug packaging composite membrane and preparation method thereof
KR20150122538A (en) * 2014-04-23 2015-11-02 주식회사 엘지화학 Photo-curable and thermo-curable resin composition, and dry film solder resist

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012206490A (en) * 2011-03-30 2012-10-25 Shin Etsu Polymer Co Ltd Mold release film
CN102532471A (en) * 2012-01-01 2012-07-04 于龙洲 Formula of resin special for polyurethane film
CN102977836A (en) * 2012-11-28 2013-03-20 四川汇利实业有限公司 Environment-friendly adhesive for drug packaging composite membrane and preparation method thereof
KR20150122538A (en) * 2014-04-23 2015-11-02 주식회사 엘지화학 Photo-curable and thermo-curable resin composition, and dry film solder resist

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113106764A (en) * 2020-01-13 2021-07-13 浙江诚迅新材料有限公司 Super-fiber super-soft scratch-resistant wear-resistant surface layer resin and preparation method thereof

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Application publication date: 20180105