CN105906969A - Flexible insulation polypropylene cable material - Google Patents

Flexible insulation polypropylene cable material Download PDF

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Publication number
CN105906969A
CN105906969A CN201610291816.3A CN201610291816A CN105906969A CN 105906969 A CN105906969 A CN 105906969A CN 201610291816 A CN201610291816 A CN 201610291816A CN 105906969 A CN105906969 A CN 105906969A
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CN
China
Prior art keywords
parts
flexible insulation
cable material
polypropylene cable
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610291816.3A
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Chinese (zh)
Inventor
李会玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Jun Hetiancheng Science And Technology Ltd
Original Assignee
Chengdu Jun Hetiancheng Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Jun Hetiancheng Science And Technology Ltd filed Critical Chengdu Jun Hetiancheng Science And Technology Ltd
Priority to CN201610291816.3A priority Critical patent/CN105906969A/en
Publication of CN105906969A publication Critical patent/CN105906969A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A flexible insulation polypropylene cable material comprises the following raw materials in parts by weight: 62 parts of polypropenyl chloride resin with the polymerization degree of 500, 20 parts of a plasticizer, 6 parts of propenyl acetate copolymer and 1 part of stearic acid. The cable material has the advantages that the material feels soft, the content of the plasticizer is low, and the plasticizer cannot separate out when the material soaks in hot water at the temperature of 70 DEG C.

Description

A kind of flexible insulation polypropylene cable material
Technical field
The present invention relates to composite cable field of material technology, specifically refer to a kind of flexible insulation polypropylene cable material.
Background technology
The fields such as polychloroprene is a kind of general-purpose plastics, has the strong points such as low cost, easy to process, excellent in mechanical performance, corrosion-resistant and insulating properties are excellent, is widely used in building, light industry, chemical industry, electrical equipment, electric wire.Polychloroprene can produce the hardest polychloroprene electric wire by the content of regulation plasticizer, also the softest polychloroprene electric wire can be produced, but agent content increase is moulded in increase can increase plasticizer extraction risk, in order to reduce this potential risk, it is necessary to control the consumption of plasticizer.
If reducing the addition of plasticizer, so flexibility of material is difficult to embody, if and add plasticizer in a large number, so can increase plasticizer extraction risk as aforementioned, the problem the most how finding rational equilibrium point between the addition and the hardness of material of plasticizer suffers from industry for a long time, and is showed no all useful enlightenment having and being addressed this technical problem in disclosed patent up to now and non-patent literature.Make substantial amounts of experiment for this applicant, finally found a way to resolve the problem, and define technical scheme described below.
Summary of the invention
It is an object of the invention to provide a kind of flexible insulation polypropylene cable material, have soft, plasticizer loading is low and soaks in 70C hot water, the feature that plasticizer does not separates out.
The present invention is achieved through the following technical solutions: a kind of flexible insulation polypropylene cable material, represents with weight portion, and raw material consists of: the degree of polymerization is the polychloroprene resin 62 parts of 500, rate accelerating material 20 parts, acetate propylene copolymer 6 parts, stearic acid 1 part.
In order to preferably realize the present invention, further, described plasticizer is o-phthalic acid dibutyl ester.
In order to preferably realize the present invention, further, representing with weight portion, raw material components also includes dynamic chlorinated polypropylene 11 parts, calcium carbonate 12 parts.
In order to preferably realize the present invention, further, representing with weight portion, raw material components also includes 4 parts of calcium zinc stabilizers, and calcium zinc stabilizer is the compounding mixture containing nano calcium oxide and nano zine oxide.
In order to preferably realize the present invention, further, described acetate propylene copolymer be acetate propylene content be the copolymer of propylene and the acetic acid of 35%.
In order to preferably realize the present invention, further, described stearic acid be fusing point be the stearic acid of 80 DEG C.
The present invention compared with prior art, has the following advantages and beneficial effect:
Cable material in the present invention, have soft, plasticizer loading is low and in 70C hot water soak, the feature that plasticizer does not separates out.
Detailed description of the invention
The present invention is expanded on further, it should be appreciated that embodiment is merely to illustrate the present invention rather than limits the scope of the invention below in conjunction with specific embodiment.
Embodiment:
Cable material of the present invention, represents with weight portion, and the component of raw material is as follows:
The degree of polymerization is the polychloroprene resin 62 parts of 500, rate accelerating material 20 parts, acetate propylene copolymer 6 parts, stearic acid 1 part.
Wherein, described plasticizer is o-phthalic acid dibutyl ester.Representing with weight portion, raw material components also includes dynamic chlorinated polypropylene 11 parts, 12 parts, 4 parts calcium zinc stabilizers of calcium carbonate, and calcium zinc stabilizer is the compounding mixture containing nano calcium oxide and nano zine oxide;Described acetate propylene copolymer be acetate propylene content be the copolymer of propylene and the acetic acid of 35%;Described stearic acid be fusing point be the stearic acid of 80 DEG C.
Test performance is carried out as follows through the cable material measured by embodiment:
ShoreA is 85, and hot strength (Mpa) is 13.9, and elongation at break (%) is without plasticizer extraction after 510,70 DEG C of hot-water soak 12h.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: these embodiments can carry out under without departing from the principle of the present invention and objective multiple change, revise, replace and modification, the scope of the present invention is limited by claim and equivalent thereof.

Claims (7)

1. a flexible insulation polypropylene cable material, it is characterised in that: representing with weight portion, raw material consists of: the degree of polymerization is polychloroprene resin 60-65 part of 500, plasticizer 15-25 part, acetate propylene copolymer 4-8 part, stearic acid 0.5-1.5 part.
A kind of flexible insulation polypropylene cable material the most according to claim 1, it is characterised in that: representing with weight portion, concrete raw material consists of: the degree of polymerization is the polychloroprene resin 62 parts of 500, rate accelerating material 20 parts, acetate propylene copolymer 6 parts, stearic acid 1 part.
A kind of flexible insulation polypropylene cable material the most according to claim 1, it is characterised in that: described plasticizer is o-phthalic acid dibutyl ester.
A kind of flexible insulation polypropylene cable material the most according to claim 1 and 2, it is characterised in that: representing with weight portion, raw material components also includes dynamic chlorinated polypropylene 11 parts, calcium carbonate 12 parts.
A kind of flexible insulation polypropylene cable material the most according to claim 1 and 2, it is characterised in that: representing with weight portion, raw material components also includes 4 parts of calcium zinc stabilizers, and calcium zinc stabilizer is the compounding mixture containing nano calcium oxide and nano zine oxide.
A kind of flexible insulation polypropylene cable material the most according to claim 1 and 2, it is characterised in that: described acetate propylene copolymer be acetate propylene content be the copolymer of propylene and the acetic acid of 35%.
A kind of flexible insulation polypropylene cable material the most according to claim 1 and 2, it is characterised in that: described stearic acid be fusing point be the stearic acid of 80 DEG C.
CN201610291816.3A 2016-05-05 2016-05-05 Flexible insulation polypropylene cable material Pending CN105906969A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610291816.3A CN105906969A (en) 2016-05-05 2016-05-05 Flexible insulation polypropylene cable material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610291816.3A CN105906969A (en) 2016-05-05 2016-05-05 Flexible insulation polypropylene cable material

Publications (1)

Publication Number Publication Date
CN105906969A true CN105906969A (en) 2016-08-31

Family

ID=56752418

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610291816.3A Pending CN105906969A (en) 2016-05-05 2016-05-05 Flexible insulation polypropylene cable material

Country Status (1)

Country Link
CN (1) CN105906969A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673509A (en) * 2016-12-09 2017-05-17 广西北海浩邦新能源科技有限公司 Heat insulating material with good flame retardant property

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746564A (en) * 2012-06-04 2012-10-24 安徽扬天塑业科技有限公司 Modified electric cable material with characteristics of high temperature resistance and corrosion resistance, and preparation method thereof
CN103351556A (en) * 2013-07-22 2013-10-16 常熟市辛庄镇前进五金厂 Soft polyvinyl chloride electric cable material
CN104962065A (en) * 2015-07-14 2015-10-07 常州市盈顺电子有限公司 Epichlorohydrin rubber aging-resisting and wear-resisting cable material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746564A (en) * 2012-06-04 2012-10-24 安徽扬天塑业科技有限公司 Modified electric cable material with characteristics of high temperature resistance and corrosion resistance, and preparation method thereof
CN103351556A (en) * 2013-07-22 2013-10-16 常熟市辛庄镇前进五金厂 Soft polyvinyl chloride electric cable material
CN104962065A (en) * 2015-07-14 2015-10-07 常州市盈顺电子有限公司 Epichlorohydrin rubber aging-resisting and wear-resisting cable material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673509A (en) * 2016-12-09 2017-05-17 广西北海浩邦新能源科技有限公司 Heat insulating material with good flame retardant property

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Application publication date: 20160831

RJ01 Rejection of invention patent application after publication