CN107529522A - Floating stuffing for sewage disposal and preparation method thereof - Google Patents

Floating stuffing for sewage disposal and preparation method thereof Download PDF

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Publication number
CN107529522A
CN107529522A CN201710946659.XA CN201710946659A CN107529522A CN 107529522 A CN107529522 A CN 107529522A CN 201710946659 A CN201710946659 A CN 201710946659A CN 107529522 A CN107529522 A CN 107529522A
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China
Prior art keywords
hemivertebra
floating stuffing
filler
preparation
nitrobacteria
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CN201710946659.XA
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CN107529522B (en
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龚云霄
李泽世
刘锐
谭亮
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Chong Qing Hao Garden Environmental Protection Technology Co Ltd
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Chong Qing Hao Garden Environmental Protection Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)

Abstract

The present invention provides a kind of floating stuffing for sewage disposal and preparation method thereof, and preparation method includes:(1) it is by mass fraction:Activated carbon powder 4~10, ground rubber 8~11, diatomite 1~3, maleic anhydride 1~7, cumyl peroxide 0.3~0.9, biology enzyme 0.5~2 are well mixed, then add high density polyethylene (HDPE) 75~80, high-speed stirred;(2) said mixture material is added to modeling in floating stuffing mould;(3) floating stuffing produced is shaped, cooling, machine drilling, cuts gear;(4) filamentary fibers carrier is finally added at center.The present invention is by adding enhancement composition and progress hydrophilic modifying to biology enzyme, promote catalytic action, the nitrification of nitrobacteria of biology enzyme, improve the hydrophilicity of filler and the nitrification ability of nitrobacteria, so that microorganism is easily adsorbed on filler, microorganism is significantly improved to the capacity of decomposition of water pollutant and the removal ability of ammonia nitrogen.

Description

Floating stuffing for sewage disposal and preparation method thereof
Technical field
The invention belongs to sanitary sewage disposal field, and in particular to a kind of floating stuffing and its preparation for sewage disposal Method.
Background technology
In biomembrance process, the filler place inhabited of being rely as microorganism is one of key technology of wastewater treatment, its Performance directly affects treatment effect and investment cost.Since the 1970s, researcher just using improve filler as Breach, constantly promote the development of biomembrance process.At present, domestic conventional filler is honeycomb filler, soft-filler, semi-soft filled out Material and the fixed filler such as floating stuffing, but often to run into blocking, conglomeration, gas distribution water distribution in use uneven etc. for these fillers Problem, it have impact on biological treatment effect.And above-mentioned filler is both needed to be arranged on auxiliary stand, cause filler installation, replacing etc. all It is more inconvenient, make construction investment and the relative raising of operational and administrative expenses.The exploitation of floating stuffing is current both at home and abroad for filling out above The deficiency of material, the new research trends triggered by organism fluidization bed process.This filler proportion close to water, without Fixed support, Quan can be suspended in water in pond with aeration agitation, simultaneously pond is even fluidizing, and energy consumption is relatively low, is before one kind has development very much The filler on way.Filler product in the market has a lot, but in actual applications there is it is certain the problem of, such as specific surface area Small, hydrophilicity is poor, and biofilm and startup cycle are long, biomembrane is easy to fall off etc..Many companies try hard to from the improvement in structure and answered Hydridization improves the specific surface area of filler, improves treatment effect, subject matter is that filling-material structure is more complicated, and cost is higher, and raw Production efficiency can decline.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of floating stuffing for sewage disposal and preparation method thereof The problem of being proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:The preparation method of floating stuffing, including following step Suddenly:(1) it is by mass fraction:Activated carbon powder 4~10, ground rubber 8~11, diatomite 1~3, maleic anhydride 1~7, peroxide It is well mixed to change diisopropylbenzene (DIPB) 0.3~0.9, biology enzyme 0.5~2, then adds high density polyethylene (HDPE) 75~80, high-speed stirred; (2) said mixture material is added to modeling in floating stuffing mould;(3) floating stuffing produced is shaped, cooling, machinery is worn Hole, cut gear;(4) filamentary fibers carrier is finally added at its center.
Further, the biology enzyme in the composition is to enter the formula of composition for the enzymatic of nitrobacteria, passes through urging for enzyme Change acts on, and improves the hydrophilicity of filler and the nitrification ability of nitrobacteria.
Prepared by the present invention (enters composition to the enhancement composition of biology enzyme by adding in particular for the enzymatic of nitrobacteria Formula) and carry out hydrophilic modifying, promote catalytic action, the nitrification of nitrobacteria of biology enzyme, improve the hydrophilic of filler Performance and the nitrification ability of nitrobacteria so that microorganism is easily adsorbed on filler, significantly improves microorganism to being polluted in water The capacity of decomposition of thing and the removal ability of ammonia nitrogen.
The present invention also provides a kind of floating stuffing for sewage disposal, as the floating stuffing described in claim 1 or 2 Preparation method is prepared, and the floating stuffing includes the first hemivertebra and the second hemivertebra, and the second hemivertebra is set in standing upside down, In being arranged symmetrically up and down, first hemivertebra and the second hemivertebra are hollow, described for first hemivertebra and the second hemivertebra The 3rd hemivertebra is provided with first hemivertebra, the exterior contour of the 3rd hemivertebra and the in-profile of the first hemivertebra match Close, the 4th hemivertebra, the exterior contour of the 4th hemivertebra and the inside of the second hemivertebra are provided with second hemivertebra Match profiles are closed, and the 4th hemivertebra is set in standing upside down, and the 3rd hemivertebra and the 4th hemivertebra are in be arranged symmetrically up and down, 3rd hemivertebra and the 4th hemivertebra are hollow, and filamentary fibers carrier is provided with the 3rd hemivertebra and the 4th hemivertebra, First hemivertebra is connected by polyethylene flat plate and tooth profile slice with the 3rd hemivertebra, and second hemivertebra passes through poly- second Alkene flat plate and tooth profile slice are connected with the 4th hemivertebra, and the polyethylene flat plate and tooth profile slice are in circumferentially arranged for interval.
Biology enzyme in the composition is to enter the formula of composition for the enzymatic of nitrobacteria, by the catalytic action of enzyme, Improve the hydrophilicity of filler and the nitrification ability of nitrobacteria.
Flat plate and tooth profile slice are in arranged for interval, and tooth form can have repetition dissection to the bubble in aeration, make in water Dissolved oxygen concentration improves, so as to enhance the mass transfer between microorganism, organism and dissolved oxygen three.Flat plate and tooth profile slice are in Arranged for interval, both ensured to the repetition dissection in aeration, it is ensured that water passes through performance, raising processing speed.
Further, the floating stuffing global density is 0.95~0.97g/cm3, and its density and aqueous phase are worked as after biofilm, its A diameter of 50~the 80cm of median plane, a diameter of 30~50cm in top and bottom, filler not easily run off.
Compared with existing domestic customary filler, the beneficial effects of the invention are as follows:Biology enzyme and silicon are added in floating stuffing Algae essence soil, nitrifier digestion power can be improved by the catalytic action of enzyme, diatomite can improve porosity, and tooth profile slice can be to holding Bubble in device repeats to cut, and improves dissolution oxygen utilization rate, and the thread fiber carrier in center can expand microorganism growing environment.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
In figure, the 1, first hemivertebra;2nd, the second hemivertebra;3rd, the 3rd hemivertebra;4th, the 4th hemivertebra;5th, flat plate;6、 Tooth profile slice;7th, filamentary fibers carrier.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Conjunction is specifically illustrating, and the present invention is expanded on further.
The present invention provides following technical scheme:The preparation method of floating stuffing, comprises the following steps:(1) by mass fraction For:Activated carbon powder 4~10, ground rubber 8~11, diatomite 1~3, maleic anhydride 1~7, cumyl peroxide 0.3~ 0.9th, biology enzyme 0.5~2 is well mixed, then adds high density polyethylene (HDPE) 75~80, high-speed stirred;(2) by said mixture Material is added to modeling in floating stuffing mould;(3) floating stuffing produced is shaped, cooling, machine drilling, cuts gear;(4) Finally filamentary fibers carrier 7 is added at its center.
As specific embodiment, the biology enzyme in the composition is to enter the formula of composition for the enzymatic of nitrobacteria, is led to The catalytic action of enzyme is crossed, improves the hydrophilicity of filler and the nitrification ability of nitrobacteria.
Prepared by the present invention (enters composition to the enhancement composition of biology enzyme by adding in particular for the enzymatic of nitrobacteria Formula) and carry out hydrophilic modifying, promote catalytic action, the nitrification of nitrobacteria of biology enzyme, improve the hydrophilic of filler Performance and the nitrification ability of nitrobacteria so that microorganism is easily adsorbed on filler, significantly improves microorganism to being polluted in water The capacity of decomposition of thing and the removal ability of ammonia nitrogen.
As shown in figure 1, the present invention also provides a kind of floating stuffing for sewage disposal, as described in claim 1 or 2 The preparation method of floating stuffing is prepared, and the floating stuffing includes the first hemivertebra 1 and the second hemivertebra 2, the second half vertebras Body 2 is set in standing upside down, and the hemivertebra 2 of the first hemivertebra 1 and second in being arranged symmetrically up and down, first hemivertebra 1 and the Two hemivertebras 2 are hollow, are provided with the 3rd hemivertebra 3 in first hemivertebra 1, the exterior contour of the 3rd hemivertebra 3 and the The in-profile of one hemivertebra 1 is engaged, and the 4th hemivertebra 4 is provided with second hemivertebra 2, the 4th hemivertebra 4 Exterior contour is engaged with the in-profile of the second hemivertebra 2, and the 4th hemivertebra 4 is set in standing upside down, the 3rd half vertebra The hemivertebra 4 of body 3 and the 4th in being arranged symmetrically up and down, and the 3rd hemivertebra 3 and the 4th hemivertebra 4 are hollow, the 3rd half vertebra Filamentary fibers carrier 7 is provided with the hemivertebra 4 of body 3 and the 4th, first hemivertebra 1 passes through polyethylene flat plate 5 and tooth profile slice 6 It is connected with the 3rd hemivertebra 3, second hemivertebra 2 is connected by polyethylene flat plate 5 and tooth profile slice 6 with the 4th hemivertebra 4, The polyethylene flat plate 5 and tooth profile slice 6 are in circumferentially arranged for interval.
Biology enzyme in the composition is to enter the formula of composition for the enzymatic of nitrobacteria, by the catalytic action of enzyme, Improve the hydrophilicity of filler and the nitrification ability of nitrobacteria.
Flat plate 5 and tooth profile slice 6 are in arranged for interval, and tooth form can have repetition dissection to the bubble in aeration, make in water Dissolved oxygen concentration improve, so as to enhance the mass transfer between microorganism, organism and dissolved oxygen three.Flat plate 5 and tooth form Piece 6 is in arranged for interval, has both been ensured to the repetition dissection in aeration, it is ensured that water passes through performance, raising processing speed.
As specific embodiment, the floating stuffing global density is 0.95~0.97g/cm3, its density and water after biofilm Quite, a diameter of 50~80cm of its median plane, a diameter of 30~50cm in top and bottom, filler not easily run off.
Compared with existing domestic customary filler, the beneficial effects of the invention are as follows:Biology enzyme and silicon are added in floating stuffing Algae essence soil, can improve nitrifier digestion power, diatomite can improve porosity, and tooth profile slice 6 can be right by the catalytic action of enzyme Bubble in container repeats to cut, and improves dissolution oxygen utilization rate, and the thread fiber carrier 7 in center can expand microorganism growing environment.
Embodiments of the present invention are these are only, are not intended to limit the scope of the invention, it is every to utilize the present invention The equivalent structure that specification and accompanying drawing content are made, other related technical areas are directly or indirectly used in, similarly at this Within the scope of patent protection of invention.

Claims (4)

1. the preparation method of floating stuffing, it is characterised in that comprise the following steps:(1) it is by mass fraction:Activated carbon powder 4~ 10th, ground rubber 8~11, diatomite 1~3, maleic anhydride 1~7, cumyl peroxide 0.3~0.9, biology enzyme 0.5~ 2 is well mixed, then adds high density polyethylene (HDPE) 75~80, high-speed stirred;(2) said mixture material is added to floating stuffing Modeling in mould;(3) floating stuffing produced is shaped, cooling, machine drilling, cuts gear;(4) it is last to add at its center Upper filamentary fibers carrier.
2. the preparation method of floating stuffing as claimed in claim 1, it is characterised in that the biology enzyme in the composition is to be directed to The enzymatic of nitrobacteria enters the formula of composition, by the catalytic action of enzyme, improves the hydrophilicity of filler and the nitre of nitrobacteria Change ability.
3. the floating stuffing for sewage disposal, it is characterised in that as the preparation side of the floating stuffing described in claim 1 or 2 Method is prepared, and the floating stuffing includes the first hemivertebra and the second hemivertebra, and the second hemivertebra is set in standing upside down, and described the In being arranged symmetrically up and down, first hemivertebra and the second hemivertebra are hollow for one hemivertebra and the second hemivertebra, and described the first half The 3rd hemivertebra is provided with centrum, the exterior contour of the 3rd hemivertebra is engaged with the in-profile of the first hemivertebra, institute State in the second hemivertebra and be provided with the 4th hemivertebra, the in-profile phase of the exterior contour and the second hemivertebra of the 4th hemivertebra Coordinating, the 4th hemivertebra is set in standing upside down, and the 3rd hemivertebra and the 4th hemivertebra in being arranged symmetrically up and down, and described the Three hemivertebras and the 4th hemivertebra are hollow, are provided with filamentary fibers carrier in the 3rd hemivertebra and the 4th hemivertebra, and described the One hemivertebra is connected by polyethylene flat plate and tooth profile slice with the 3rd hemivertebra, and second hemivertebra passes through polyethylene flat board Piece and tooth profile slice are connected with the 4th hemivertebra, and the polyethylene flat plate and tooth profile slice are in circumferentially arranged for interval.
4. it is used for the floating stuffing of sewage disposal as claimed in claim 3, it is characterised in that the floating stuffing global density For 0.95~0.97g/cm3, its density and aqueous phase are worked as after biofilm, a diameter of 50~80cm of its median plane, top and bottom a diameter of 30 ~50cm, filler not easily run off.
CN201710946659.XA 2017-10-12 2017-10-12 Floating stuffing for sewage disposal Active CN107529522B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503037A (en) * 2018-01-25 2018-09-07 天津城建大学 The preparation and its application of biomembrane carrier
CN108543512A (en) * 2018-04-27 2018-09-18 和县伊迈炭业有限责任公司 The charcoal pretreating process of bio-filter stuffing is prepared using charcoal powder
CN115196742A (en) * 2022-08-16 2022-10-18 合肥工业大学 Sewage treatment filler with selectivity on microorganism species

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006175388A (en) * 2004-12-24 2006-07-06 Tom Tom Club:Kk Spherical filter medium
CN201077799Y (en) * 2007-08-21 2008-06-25 四川立新瑞德环保科技发展有限责任公司 Biology suspending stuffing
CN104609567A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Preparation method of suspended packing bioreactor and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006175388A (en) * 2004-12-24 2006-07-06 Tom Tom Club:Kk Spherical filter medium
CN201077799Y (en) * 2007-08-21 2008-06-25 四川立新瑞德环保科技发展有限责任公司 Biology suspending stuffing
CN104609567A (en) * 2013-11-05 2015-05-13 中国石油化工股份有限公司 Preparation method of suspended packing bioreactor and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503037A (en) * 2018-01-25 2018-09-07 天津城建大学 The preparation and its application of biomembrane carrier
CN108503037B (en) * 2018-01-25 2021-02-26 高频美特利环境科技(北京)有限公司 Preparation and application of novel biofilm carrier
CN108543512A (en) * 2018-04-27 2018-09-18 和县伊迈炭业有限责任公司 The charcoal pretreating process of bio-filter stuffing is prepared using charcoal powder
CN115196742A (en) * 2022-08-16 2022-10-18 合肥工业大学 Sewage treatment filler with selectivity on microorganism species

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