CN105236564B - A kind of BAF combined stuffing and application - Google Patents
A kind of BAF combined stuffing and application Download PDFInfo
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- CN105236564B CN105236564B CN201510727411.5A CN201510727411A CN105236564B CN 105236564 B CN105236564 B CN 105236564B CN 201510727411 A CN201510727411 A CN 201510727411A CN 105236564 B CN105236564 B CN 105236564B
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- 239000000945 filler Substances 0.000 claims abstract description 30
- 235000009496 Juglans regia Nutrition 0.000 claims abstract description 22
- 235000020234 walnut Nutrition 0.000 claims abstract description 22
- 239000010457 zeolite Substances 0.000 claims abstract description 21
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 238000005273 aeration Methods 0.000 claims description 24
- 244000005700 microbiome Species 0.000 claims description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 230000000694 effects Effects 0.000 claims description 15
- 239000010802 sludge Substances 0.000 claims description 14
- 239000002351 wastewater Substances 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 239000013589 supplement Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 240000007049 Juglans regia Species 0.000 claims 1
- 241000758789 Juglans Species 0.000 abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 8
- 239000007787 solid Substances 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 238000005342 ion exchange Methods 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 19
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003344 environmental pollutant Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005457 optimization Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000035800 maturation Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000108664 Nitrobacteria Species 0.000 description 1
- 241000223785 Paramecium Species 0.000 description 1
- 241000700141 Rotifera Species 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000000703 anti-shock Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000032770 biofilm formation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000004081 cilia Anatomy 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Biological Treatment Of Waste Water (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The invention discloses a kind of BAF combined stuffing, it is made up of walnut shell and zeolite, wherein the volume ratio of walnut shell and zeolite is 2~4:1.The invention also discloses application of the combined stuffing in BAF.BAF combined stuffing of the present invention, it is compared with other fillers, and biofilm speed is fast under equal conditions；Walnut shell and combination of zeolites, which rise, is used as aerating biological filter pool filler, porous, adsorptivity, ion-exchange performance and the stronger supporting role of zeolite can not only be played, and it is used as solid carbon source by the use of walnut shell, without additional carbon, walnut shell also there is certain skeletal support to act on, and be not susceptible to block.It is wide material sources, cheap in addition, walnut shell is as a kind of agricultural solid residue.
Description
Technical field
The invention belongs to water-treatment technology field, and in particular to a kind of BAF combined stuffing, the present invention also relate to
And application of the combined stuffing in BAF.
Background technology
In recent years, because human living standard improves, and agrochemical excessively uses etc. reason, substantial amounts of nitrogenous life
Sewage and industrial wastewater living are discharged into water body, and nitrogen is the principal element for causing body eutrophication, and can be converted into " three cause " thing
Matter nitrite and the health of the serious threat mankind.Therefore economic, efficient denitrogenation of waste water treatment technology is researched and developed, it has also become
The emphasis and focus in Water Pollution Control Engineering field.In numerous denitrogenation technologies, BAF (BAF) collection biological oxidation
With retention suspended solid in one, follow-up secondary sedimentation tank is eliminated, makes handling process simple on the premise for the treatment of effect is ensured
Change, have floor space few, treatment effeciency is high, and effluent quality is good, the advantages that being easy to automatically control.Especially in recent years to the reaction
The research of the nitrification and denitrification function of device turns into focus.
Filler is the place that microorganism inhabites, bred, while play cut again in the process of running as microorganism carrier
The effect of suspended material is stayed, is one of the core of BAF treatment technology, its material composition and surface property will be direct
Attachment, growth, breeding and the activity of filler surface microorganism are influenceed, and then influences microorganism colonization performance and contaminant degradation effect
Rate.The biomembrane that different fillers is formed is different, and different biofilm states cause microbial ecological in system difference occur,
The treatment effeciency of reactor can be had a huge impact.
Study at present more aerating biological filter pool filler mainly active charcoal, burn by primary raw material of flyash and clay
The spherical light porous biological potsherd filling of system, the natural silicate minerals filler such as zeolite and formed by a variety of filler combinations
Compounded mix etc..Activated carbon is expensive as filler, and in activated carbon BAF gas and the aqueous solution to activity
The agitaion of charcoal makes activated carbon bio-filter water outlet color burn and causes its delivery turbidity to increase, and is even greater than turbid into water
Degree；For zeolite as aerating biological filter pool filler, because its is in irregular shape, resistance to water-flow is big, easily blocks, water distribution, gas distribution are not easy
Uniformly.Zeolite surface carries negative electrical charge, is unfavorable for the biofilm formation growth of microorganism during separately as aerating biological filter pool filler；Walnut
Shell is grown as the biofilm time needed for aerating biological filter pool filler, and because microorganism decomposition causes filled column after long-play
Collapse.Therefore, it is required to work out cheap, wide material sources and efficient bio-filter stuffing.
The content of the invention
It is an object of the invention to provide a kind of BAF combined stuffing, and the combined stuffing biofilm speed is fast, most preferably
Nitrogen removal performance is good under run parameter, and wide material sources, and price is inexpensive.
It is a further object to provide a kind of application of combinations thereof filler in BAF.
The technical solution adopted in the present invention is a kind of BAF combined stuffing, to be made up of walnut shell and zeolite,
Wherein the volume ratio of walnut shell and zeolite is 2~4:1.
The features of the present invention also resides in,
The average grain diameter of walnut shell and zeolite is 4~6mm.
Another technical scheme of the present invention is application of the combinations thereof filler in BAF, tool
Body is implemented according to following steps
Step 1, the static biofilm stage
It is 2~4 by volume by walnut shell and zeolite that average grain diameter is 4~6mm:1 it is well mixed after load aeration life
Thing filter tank, and activated sludge is injected in filter tank and carry out stewing exposure, makes sludge activity recovery, sludge dosage using fill filter tank as
Standard, intake with small water after seed sludge, and be passed through air and carry out aeration agitation, every 24 hours molten by filter tank 1/3 upper strata
Liquid takes out, and supplements simulated wastewater, daily periodic monitor reactor effluent quality, that is, monitors pH, DO, COD and NH4 +- N, and
The upgrowth situation of microorganism on micro- Microscopic observation filler；Continuous cultivation stage is entered after 7 days；
Step 2, continuous cultivation stage
Discharge fails the suspension microorganism of effective biofilm, with simulated wastewater continuum micromeehanics and is passed through air, keeps biological filter
The hydraulic detention time in pond is 12h, dissolved oxygen concentration is kept during biofilm in 4mg/L, before dissolved oxygen concentration meets to require
Put, reduce aeration quantity as far as possible, the reactor effluent quality of timing detection daily, that is, monitor pH, DO, COD and NH4 +- N, and observe
The upgrowth situation of microorganism on filler；If effluent quality fluctuates smaller, COD and NH4 +- N clearances tend towards stability, under the microscope
It can be observed to contain more campanularian in water outlet, illustrate through domestication culture after a while, biomembrane has been formed and just gradually life
It is long ripe, there is stronger anti-load impact ability, determine biofilm success；
Step 3, the BAF operation phase
After biofilm success, pH value 7.5~8.5, inlet COD concentration 300mg/L, NH4 +Under the conditions of-N concentration is 30mg/L
Operation, daily periodic monitor reactor effluent quality, that is, monitor pH, dissolved oxygen, COD, NH4 +-N、NO2 -- N and NO3 -- N water quality refers to
Mark.
The features of the present invention also resides in,
Aeration quantity is 9L/h in step 1, and using intermittent aeration, 1h is stood to cultivate microorganism after being aerated 3h.
Aeration quantity is 9~12L/h, 0.03~0.06m of hydraulic load in step 33/(m2H), gas-water ratio is 3~12:1.
The invention has the advantages that BAF combined stuffing of the present invention, it is compared with other fillers, equal bar
Biofilm speed is fast under part；Walnut shell and combination of zeolites, which rise, is used as aerating biological filter pool filler, can not only play the more of zeolite
Permeability, adsorptivity, ion-exchange performance and stronger supporting role, and by the use of walnut shell as solid carbon source, without outer
Add carbon source, walnut shell also there is certain skeletal support to act on, be not susceptible to block.In addition, walnut shell is as a kind of agricultural solid
Body discarded object, it is wide material sources, cheap.
Brief description of the drawings
COD change curves during Fig. 1 is start-up；
NH4 during Fig. 2 is start-up+- N change curves；
Fig. 3 is the influence curve of BAF operation phase hydraulic load；
Fig. 4 is the influence curve of BAF operation phase gas-water ratio.
Embodiment
The present invention is described in detail with reference to the accompanying drawings and detailed description.
A kind of BAF combined stuffing of the present invention, be made up of walnut shell and zeolite, wherein walnut shell and zeolite
Volume ratio is 2~4:1.
The average grain diameter of walnut shell and zeolite is 4~6mm.
Application of the combinations thereof filler in BAF, specifically implements according to following steps：
Step 1, the static biofilm stage
It is 2~4 by volume by walnut shell and zeolite that average grain diameter is 4~6mm:1 it is well mixed after load aeration life
Thing filter tank, and activated sludge is injected in filter tank and carry out stewing exposure, makes sludge activity recovery, sludge dosage using fill filter tank as
Standard, intake with small water after seed sludge, and be passed through air and carry out aeration agitation, aeration quantity 9L/h, using intermittent aeration,
1h is stood to cultivate microorganism after aeration 3h so that the good microorganism of adhesion property can fully grow, adhere to and fix on filler
It is grown on filling carrier；In filter tank 1/3 upper solution is taken out, and supplements simulated wastewater within every 24 hours, timing daily is supervised
Reactor effluent quality is surveyed, that is, monitors pH, DO, COD and NH4 +- N, and the growth shape of microorganism on filler is observed under the microscope
Condition；Continuous cultivation stage is entered after 7 days；
Step 2, continuous cultivation stage
Discharge fails the suspension microorganism of effective biofilm, with simulated wastewater continuum micromeehanics and is passed through air, keeps biological filter
The hydraulic detention time in pond is 12h, dissolved oxygen concentration is kept during biofilm in 4mg/L, before dissolved oxygen concentration meets to require
Put, reduce aeration quantity as far as possible, so can not only reduce and filter material surface is washed away, also help the attachment and life of microorganism
It is long, the reactor effluent quality of timing detection daily, that is, monitor pH, DO, COD and NH4 +- N, and observe the life of microorganism on filler
Long situation；If effluent quality fluctuates smaller, COD and NH4 +- N clearances tend towards stability, and can be observed to contain in water outlet under the microscope
There is more campanularian, illustrate that, through domestication culture after a while, biomembrane has formed and has just been grown into maturation, there is stronger resist
Load impact ability, determine biofilm success；
Step 3, the BAF operation phase
After biofilm success, pH value 7.5~8.5, inlet COD concentration 300mg/L, NH4 +- N concentration is 30mg/L, aeration quantity
For 9~12L/h, 0.03~0.06m of hydraulic load3/(m2H), gas-water ratio is 3~12:Run under the conditions of 1, daily periodic monitor
Reactor effluent quality, that is, monitor pH, dissolved oxygen, COD, NH4 +-N、NO2 -- N and NO3 -- N water quality index.
Embodiment 1
It is 3 by volume by walnut shell and zeolite:It is applied to after 1 mixing in BAF.
1. BAF start-up operational effect
(1) COD concentration and its clearance during start-up
From figure 1 it appears that BAF is during start-up, continuum micromeehanics initial stages, COD clearances are
60% or so, when successive reaction proceeds to the 5th day, COD clearances have brought up to 90% rapidly by the 61.5% of the previous day.Enter
COD maintains higher clearance (61.5% when water organic concentration (COD) is in the range of 218.4mg/L~353.9mg/L
~94%).It can also be seen that in addition to indivedual days special circumstances, COD clearances are overall in rising trend with the time, and are starting
In the later stage, even if inlet COD concentration fluctuation is larger, but it also has higher clearance.This explanation is through domestication after a while
Culture, biomembrane have formed and have just been grown into maturation.And because the specific surface area of Discussion of Biological Aerated Filter Medium is big, make its list
Biomass is high on bit surface area, and stronger buffer capacity can be shown when applied load varies widely, and reactor resists
Load impact ability is stronger.
(2) NH during starting4 +- N concentration and its clearance
As shown in Figure 2：Continuum micromeehanics initial stages, ammonia nitrogen removal frank increase with the time it is very fast, within two days, ammonia nitrogen removal frank by
73.7% has brought up to 85.96%, then when influent ammonium concentration changes in the range of 35.4mg/L~53.5mg/L, ammonia nitrogen
Clearance is held at more than 60%, can reach 86.5%.
With also occurring obvious fluctuation as the removal of organic matter, on the whole BAF has very well to ammonia nitrogen
Removal effect.It can also be seen that when influent ammonium concentration is maintained at 50 ± 3mg/L, water outlet ammonia nitrogen is in 10mg/L or so.
At the 20th day to the 26th day, influent ammonium concentration changed greatly, but ammonia nitrogen removal frank is relatively stable, in 74.4%~79.7% scope
Interior, for this explanation through domestication culture after a while, biomembrane, which has been formed, is grown into maturation, there is certain anti-shock loading energy
Power.
2. BAF startup optimization microscopy result
In initial start stage, reactor fluctuation of service, effluent quality is poor, can be observed have grass in water outlet under the microscope
The microorganisms such as worm, wheel animalcule, tired branch worm are carried out, paramecium represents that system loading is low, and dissolved oxygen is low；It is considerable with the operation of reactor
Observe with the presence of a large amount of campanularians in water outlet, the front end peristoma of its polypide is by ciliated band (cilium that can be stirred by two circles forms), worm
Body is in typical bell-shaped, therefore claims campanularian, belongs to protozoan.Either single or colony species, in wastewater biological
Very abundant is grown in the aeration tank and filter tank for the treatment of plant, the flocculation reaction of activated sludge can be promoted, and can largely prey on free
Bacterium and use clarification of water.The a large amount of of campanularian occur being the ripe performance of Activated Sludge Growth, represent that treatment effect is good.
3. the optimization of BAF operational factor
(1) hydraulic load
In pH value 7.5~8.5, inlet COD concentration 300mg/L, NH4+- N concentration is under 30mg/L service condition.Water
Power load is from 0.03m3/(m2H) it is changed to 0.06m3/(m2To COD, NH4 when h)+The influence situation of-N clearances.Waterpower is born
The influence of lotus is as shown in Figure 3.
As seen from Figure 3, COD clearances and ammonia nitrogen removal frank are first raised with the increase of hydraulic load and then reduced.Work as water
Power load is by 0.03m3/(m2H) 0.04m is risen to3/(m2When h), COD average removal rates are increased to by 56.20%
83.16%, when hydraulic load continues to increase to 0.06m3/(m2When h), COD average removal rates decline again, are reduced to
74%, therefore water conservancy load is 0.04m3/(m2When h)), COD clearance highests.Equally, NH4 +- N clearances are also with hydraulic load
0.04m3/(m2It is maximum when h), now, ammonia nitrogen removal frank 81.26%, when hydraulic load is reduced to 0.03m3/(m2H) or
Increase to 0.06m3/(m2H) ammonia nitrogen removal frank is respectively reduced to 72.50% and 75.01%.
As a result show：In the case where ensureing enough hydraulic detention times, BAF has certain water resistant power to bear
Lotus impact capacity, when hydraulic load value is 0.03~0.06m3/(m2When h)), BAF reactor can guarantee that higher
Organic matter, ammonia nitrogen removal frank it is horizontal.
When hydraulic load is less than or greater than 0.03~0.06m3/(m2When h)), COD clearances and ammonia nitrogen removal frank have
Declined.Because keeping certain gas-water ratio, hydraulic load is too high, and the haptoreaction time of microorganism and substrate is reduced, and is unfavorable for
The removal of pollutant；Meanwhile higher filtering velocity also increases excessively stream speed and the hydraulic shear between filtering layer, make biomembrane be more easy to by
Elution, so that the removal efficiency of pollutant declines.And increase hydraulic load means to reduce hydraulic detention time simultaneously
(HRT) unfavorable status will be in being carbonized in the competition of heterotroph by, growing slower nitrobacteria nitrite bacteria, overall
Activity decrease, so as to reduce the nitrification ability of whole reactor.
(2) gas-water ratio
PH be 7.5~8.5, hydraulic load 0.04m3/(m2H), inlet COD concentration 300mg/L, N H4 +- N is dense
Spend under the service condition for 30mg/L, gas-water ratio is respectively 3:1、6:1、12:To COD, NH in the case of 14 +The shadow of-N clearances
Ring, the influence result of different gas-water ratios is as shown in Figure 4.
As seen from Figure 4, with the gradual increase of gas-water ratio, BAF is to COD, NH4 +- N removal ability
Gradually increase.When gas-water ratio is by 3:1 brings up to 6:When 1, COD, NH4 +- N clearance is respectively by 66.71%, 76.17% increase
To 79.85%, 80.6%, increase is relatively obvious.When gas-water ratio is by 6:1 brings up to 12:When 1, COD, NH4 +- N clearance
Increase but unobvious, COD clearance value addeds are less than 1%.
As a result show：BAF has higher oxygen utilization and conversion capability.In gas-water ratio 6:It can obtain when 1
Good oxidation effect so that aerobic bacteria can well grow, and reactor shows stable treatment effect.With aeration quantity
Increase, liquid less turbulence caused by air bubbling increase, be advantageous to oxygen in gas phase into water and filler surface transmission, reaction
The concentration of oxygen improves in system, the oxygen of abundance is provided for aerobic microbiological, therefore pollutants removal rate increases and carried with aeration quantity
It is high.But if aeration quantity is excessive, the concentration of oxygen is limited by equilbrium solubility in reaction system, and dissolved oxygen does not increase not only, mistake
Strong turbulent flow causes coming off for biomembrane in the parsing and filler of oxygen in water on the contrary, reduces the dense of immobilized microorganism
Degree, is unfavorable for the removal of pollutant.And aeration quantity is excessive can also increase power consumption.
Embodiment 2
It is 2 by volume by walnut shell and zeolite:1 it is well mixed be used as aerating biological filter pool filler, it is same by embodiment 1
Mode startup optimization, monitoring result shows that now BAF success biofilm needs 23 days, COD and NH4 +- N removal
Rate is respectively 73.3%~87.5% and 63.2%~77.4%.
Embodiment 3
It is 4 by volume by walnut shell and zeolite:1 it is well mixed be used as aerating biological filter pool filler, it is same by embodiment 1
Mode startup optimization, monitoring result shows, now BAF success biofilm needs 27 days, COD and NH4 +- N removal
Rate respectively reaches 71.8%~89.6% and 65.1%~80.6%.
BAF combined stuffing of the present invention, it is compared with other fillers, and biofilm speed is fast under equal conditions, biofilm
Success only about needs more than 20 days；To pollutant (COD, N H4 +- N) removal effect is good,
And filler is common agricultural discarded object, wide material sources are cheap, are adapted to a large amount of use.
Claims (1)
1. application of a kind of combined stuffing in BAF, it is characterised in that specifically implement according to following steps：
Step 1, the static biofilm stage
It is 3~4 by volume by walnut shell and zeolite that average grain diameter is 4~6mm:1 it is well mixed after load aeration and biological filter
Pond, and activated sludge is injected in filter tank and carries out stewing exposure, make sludge activity recovery, sludge dosage is defined to fill filter tank, connects
Intake after kind sludge with small water, and be passed through air and carry out aeration agitation, taken in filter tank 1/3 upper solution within every 24 hours
Go out, and supplement simulated wastewater, daily periodic monitor reactor effluent quality, that is, monitor pH, DO, COD and NH4 +- N, and micro-
The upgrowth situation of microorganism on Microscopic observation filler, enters continuous cultivation stage after 7 days；
Aeration quantity is 9L/h in step 1, and using intermittent aeration, 1h is stood to cultivate microorganism after being aerated 3h；
Step 2, continuous cultivation stage
Discharge fails the suspension microorganism of effective biofilm, with simulated wastewater continuum micromeehanics and is passed through air, keeps biofilter
Hydraulic detention time is 12h, and dissolved oxygen concentration is kept during biofilm in 4mg/L, on the premise of dissolved oxygen concentration meets to require,
Aeration quantity is reduced as far as possible, the reactor effluent quality of timing detection daily, that is, monitors pH, DO, COD and NH4 +- N, and observe filler
The upgrowth situation of upper microorganism；If effluent quality fluctuates smaller, COD and NH4 +- N clearances tend towards stability, considerable under the microscope
Observe and contain more campanularian in water outlet, illustrate to have been formed and just gradually grown into through domestication culture after a while, biomembrane
It is ripe, there is stronger anti-load impact ability, determine biofilm success；
Step 3, the BAF operation phase
After biofilm success, pH value 7.5~8.5, inlet COD concentration 300mg/L, NH4 +- N concentration is run under the conditions of being 30mg/L,
Daily periodic monitor reactor effluent quality, that is, monitor pH, dissolved oxygen, COD, NH4 +-N、NO2 -- N and NO3 -- N water quality index；
Aeration quantity is 9~12L/h, 0.03~0.06m of hydraulic load in step 33/(m2H), gas-water ratio is 3~12:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510727411.5A CN105236564B (en) | 2015-10-30 | 2015-10-30 | A kind of BAF combined stuffing and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510727411.5A CN105236564B (en) | 2015-10-30 | 2015-10-30 | A kind of BAF combined stuffing and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105236564A CN105236564A (en) | 2016-01-13 |
| CN105236564B true CN105236564B (en) | 2018-03-23 |
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| CN107162168A (en) * | 2017-05-04 | 2017-09-15 | 浙江省农业科学院 | A kind of biological aerated filter based on microbial augmentation |
| CN108328737B (en) * | 2017-11-30 | 2020-10-20 | 河海大学 | Micro-ecological substrate for strengthening treatment of aquaculture wastewater based on artificial wetland, preparation method and application thereof |
| CN109489568B (en) * | 2018-09-30 | 2019-10-08 | 南京大学 | A kind of auxiliary device and measuring method of on-line determination Wastewater treatment filling material biofilm thickness |
| CN109928492A (en) * | 2019-04-18 | 2019-06-25 | 南京清元景和环境科技有限公司 | The preparation method of modified activated carbon biologic packing material for biofilter |
| CN112340836B (en) * | 2020-11-06 | 2022-12-27 | 江西挺进环保科技股份有限公司 | A2O + MBBR processing system based on low-cost suspended packing |
| CN113772808A (en) * | 2021-10-11 | 2021-12-10 | 合肥学院 | Method for hanging EPP filler on membrane in biological trickling filter |
| CN114538714B (en) * | 2022-03-08 | 2023-05-16 | 青海洁神环境科技股份有限公司 | Sewage treatment method by utilizing MBBR to cooperate with BBR |
| CN116177771B (en) * | 2022-11-16 | 2023-11-07 | 中国科学院生态环境研究中心 | Sewage treatment method and device |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100994781B1 (en) * | 2010-04-20 | 2010-11-17 | 주식회사 성일엔텍 | Filling material having bottom ash of constructed wetland for the treatment of polluted water and preparation methods thereof |
| CN102616921A (en) * | 2012-04-09 | 2012-08-01 | 河海大学 | Composite ecological fillers and preparation method thereof |
| CN102718311A (en) * | 2012-07-06 | 2012-10-10 | 江苏蓝星环保科技有限公司 | Method for deeply treating wastewater containing ammonia nitrogen |
| CN103172169A (en) * | 2013-04-08 | 2013-06-26 | 上海电力学院 | Urban sewage treatment method with lytag material as filler |
| CN103395942A (en) * | 2013-08-09 | 2013-11-20 | 湖北理工学院 | Method and device for realizing lasting and stable accumulation of nitrite nitrogen under low-temperature condition |
| CN103613188A (en) * | 2013-12-02 | 2014-03-05 | 上海理工大学 | Outside cycle continuous biological aerated filter for composite fillers |
| CN104512960A (en) * | 2013-09-26 | 2015-04-15 | 中国石油化工股份有限公司 | Wastewater biological treatment integrated device and wastewater processing method |
-
2015
- 2015-10-30 CN CN201510727411.5A patent/CN105236564B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100994781B1 (en) * | 2010-04-20 | 2010-11-17 | 주식회사 성일엔텍 | Filling material having bottom ash of constructed wetland for the treatment of polluted water and preparation methods thereof |
| CN102616921A (en) * | 2012-04-09 | 2012-08-01 | 河海大学 | Composite ecological fillers and preparation method thereof |
| CN102718311A (en) * | 2012-07-06 | 2012-10-10 | 江苏蓝星环保科技有限公司 | Method for deeply treating wastewater containing ammonia nitrogen |
| CN103172169A (en) * | 2013-04-08 | 2013-06-26 | 上海电力学院 | Urban sewage treatment method with lytag material as filler |
| CN103395942A (en) * | 2013-08-09 | 2013-11-20 | 湖北理工学院 | Method and device for realizing lasting and stable accumulation of nitrite nitrogen under low-temperature condition |
| CN104512960A (en) * | 2013-09-26 | 2015-04-15 | 中国石油化工股份有限公司 | Wastewater biological treatment integrated device and wastewater processing method |
| CN103613188A (en) * | 2013-12-02 | 2014-03-05 | 上海理工大学 | Outside cycle continuous biological aerated filter for composite fillers |
Non-Patent Citations (2)
| Title |
|---|
| 曝气生物滤池脱氮工艺与过程;刘剑;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20060415(第4期);正文第15-16页、19-23页 * |
| 核桃壳填料曝气生物滤池去除废水中氨氮的研究;贾丽娟;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20120915(第9期);正文第12页、17-21页、第33页 * |
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