CN107523260A - The double cured silicone compounds of two-component - Google Patents
The double cured silicone compounds of two-component Download PDFInfo
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- CN107523260A CN107523260A CN201710804361.5A CN201710804361A CN107523260A CN 107523260 A CN107523260 A CN 107523260A CN 201710804361 A CN201710804361 A CN 201710804361A CN 107523260 A CN107523260 A CN 107523260A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention proposes a kind of double cured silicone compounds of two-component, is made up of component A and B component, the component A includes the polydimethylsiloxane containing vinyl, the methyl polysiloxane and crosslinking agent of hydrosilyl group-containing；B component includes hydroxyl endblocked polydimethylsiloxane, platinum catalyst；The weight of component A and B component ratio is 1:1 to 10:1.The dual vulcanizing silicone rubber composite of two-component proposed by the present invention, can there can be good bonding force to base material with short vulcanization into silicone elastomer, realize cohesional failure, adhesive strength >=1.0MPA in a heated condition；Also there is the curingprocess rate for being equal to double component room temperature vulcanization silicon rubber and quick formation bonding force under normal temperature moist conditions.And the ratio of component A and B component variable in certain scope can adjust curingprocess rate, ratio can be adjusted according to curstomer's site working condition requirement to adapt to customer demand.
Description
Technical field
The invention belongs to bonding agent field, and in particular to a kind of organic silicon composite.
Background technology
Silicon rubber is divided into condensed type and add-on type according to vulcanization reaction mechanism；Condensed type silicon rubber is given birth to according to vulcanization reaction
It is divided into many kinds such as depickling type, de-oxime type, dealcoholized type, de- amine type, de amide type and deacetone into species.Add-on type silicon
Rubber generates during vulcanization reaction without small-molecule substance.Condensed type silicon rubber be divided into again single-component room-temperature-vulsilicone silicone rubber and
Double component room temperature vulcanization silicon rubber；The cure time of single-component room-temperature-vulsilicone silicone rubber depend on vulcanizing system, temperature, humidity and
The thickness of silastic-layer, the temperature and humidity of environment is improved, sulfidation can be accelerated；And double component room temperature vulcanization silicon rubber
Vulcanization reaction while having begun to whole system while two components mix, cure time depend on crosslinking agent and catalysis
The activity of agent, and deep cure can be realized；Addition-type silicon rubber is generally two-component heating vulcanization type；Compared to two-component room
Temperature vulcanizable silicone rubber, the quick and complete vulcanization at high temperature of dual composition addition type silicon rubber, and quickly form good bonding force.
The addition of silicon rubber in the industry double is always difficult point admittedly, is all one-component although many patents were write, this area
The addition storage stability for knowing one-component is always problem, and the one-component addition glue of typically energy room temperature storage is needed higher
At a temperature of could realize solidification, can the one-component addition glue of normal temperature cure generally require low-temperature storage, and two-component addition silica gel,
The problem of normal temperature storage, normal temperature cure can be realized, and storage stability is not present.Such as patent CN105348813A proposes one
The single-component organic silicon of the wettable-heat cure of kind, but under normal temperature moist conditions, its rapid deep zone solidification relatively difficult to achieve, and it is stored up
Stability is deposited to cause anxiety.
The content of the invention
For the weak point of this area, the present invention proposes a kind of double cured silicone compounds of two-component.
To realize that the technical scheme of the purpose of the present invention is：
A kind of double cured silicone compounds of two-component, are made up of, it is characterised in that the component A component A and B component
Methyl polysiloxane and crosslinking agent including the polydimethylsiloxane containing vinyl, hydrosilyl group-containing；B component includes hydroxyl
Base end-blocking dimethyl silicone polymer, platinum catalyst；The weight of component A and B component ratio is 1:1 to 10:1.
Two-component composition is because A, B component are separated, and the problem of in the absence of storage stability, Storage period is substantially all
More than 1 year.
Further, the component A includes by weight：
The B component includes by weight：
Wherein, the crosslinking agent is methyl tributanoximo silane, vinyl tributyl ketoximyl silane, the diacetylmonoxime of phenyl three
Base silane, four butanone oximino silanes, MTMS, vinyltrimethoxy silane, MTES, second
One or more in alkenyl triethoxysilane, tetraethoxysilane.
Wherein, the moisture-curable catalyst is organotin, organic titanium, the one or more in organo-bismuth class catalyst；
Wherein described organic tin catalyst is selected from dibutyl tin laurate, dibutyltin diacetate, in silane-modified dibutyl tin
One or more, the organic titanium class catalyst be selected from tetraisopropyl titanate, tetrabutyl titanate, the tert-butyl ester of metatitanic acid four, two
One or more kinds of mixing in isopropoxy ethyl diacetoacetate titanium, two isobutoxy ethyl diacetoacetate titaniums
Thing, the organo-bismuth class catalyst include bismuth neodecanoate, Bi (OOCR1)3、Bi[OOCCH(C2H5)C4H9]3With Bi (CpH2p- 1COO)3In one or more, wherein p=5~11, R1For in line style or branched C1~C20 alkane, phenyl ring or biphenyl group
One kind.
Wherein, the coupling agent is amino silicane coupling agent, acryloxy silane coupling agent, epoxy radicals silicone hydride coupling
Agent, glycidyl ether oxygen propyl trimethoxy silicane, glycidoxypropyltrietandysilane andysilane, NCO propyl group three
One or more in methoxy silane, NCO triethoxysilane and its oligomer, preferably secondary amino group coupling agent and
Its oligomer；The inhibitor is acetylene alcohol or propiolic alcohol inhibitor.
This area seldom uses the crosslinking agent of mentioned kind, and is used cooperatively the crosslinking coupling agent with nitrogen with above-mentioned crosslinking agent
Even more grope repeatedly through inventor and determine, so as to realize the double solidification functions of two-component.
Wherein, the catalyst made from platonic is vinylsiloxane platinum complex or chloroplatinic acid；The filler be reinforcement and/or
Half reinforced filling, the one or more in aerosil, calcium carbonate, silicon powder, aluminum oxide, carbon black.
Preferably, the viscosity of the dimethyl silicone polymer containing vinyl is 1000mPas~200 at 25 DEG C
000mPa·s；The viscosity of the methyl polysiloxane of the hydrosilyl group-containing is 100mPas~20000mPas at 25 DEG C；Institute
The viscosity for stating hydroxyl endblocked polydimethylsiloxane is 1000mPas~20000mPas at 25 DEG C.
It is highly preferred that the component A includes by weight：
The B component includes by weight：
Double applications of the cured silicone compound as bonding agent of two-component of the present invention.
The double cured silicone compounds of described two-component are under the conditions of heating or room temperature condition, relative humidity 30~70%
Realize solidification.
For example, the bonding applied to one or both of stainless steel, aluminium alloy, PVC, the bar of coating adhesive solidify afterwards
Part is 10~40 DEG C of temperature, relative humidity 30~70%.
The beneficial effects of the present invention are：
The dual vulcanizing silicone rubber composite of two-component proposed by the present invention, in a heated condition can be with short vulcanization into silicon rubber
Glue elastomer, can have good bonding force, adhesive strength >=1.0MPA to base material；Also have under normal temperature moist conditions equivalent
Curingprocess rate and quick formation bonding force in double component room temperature vulcanization silicon rubber.And the ratio of component A and B component can be
It is variable in certain scope to adjust curingprocess rate, ratio can be adjusted according to curstomer's site working condition requirement to adapt to client's need
Ask.
Embodiment
Following examples are used to illustrate the present invention, but should not be taken to limit the scope of the present invention.
In embodiment, unless otherwise instructed, means used are this area conventional technical means.
Embodiment 1：
Component A is 10000mPas by 100 parts of viscosity, and contents of ethylene is 0.15% ethenyl blocking poly dimethyl
Siloxanes, 10 parts of viscosity are 1000mPas, and hydrogen content is the methyl polysiloxane of 0.2% hydrosilyl group-containing, 50 parts of lightweight carbon
Sour calcium, 8 parts of MTMSs, 1 part of double (3- trimethoxy-silylpropyls) amine.
B component is by hydroxyl endblocked polydimethylsiloxane, 10 parts of carbon blacks that 100 parts of viscosity are 3000mPas, 0.5 part of second
Alkynyl cyclohexanol, 4 parts of platinum contents are in the 2000ppm silica complex compound of chloroplatinic acid tetramethyl divinyl two, 0.5 part of moisture.
Component A is 1.1 with B component weight ratio:1, volume ratio 1:1 is used in mixed way.
Mixture heats 10min at 100 DEG C, forms silicone elastomer and is bonded simultaneously, to materials such as aluminium alloy and PVC
Matter has cohesion bond failure, adhesive strength 1.3MPA.
Under the conditions of 23 DEG C of normal temperature, relative humidity 50%, the surface drying time of mixture exists in 20~30min, gel resin time
40~60min (the gel resin time refers to that whole colloid has been fully cured from the inside to surface, in the absence of liquid or the colloid of paste).
Two aluminum alloy base materials use gained silicone elastomer to be bonded, and are passed through under the conditions of 23 DEG C of normal temperature, relative humidity 50%
30min is crossed, survey adhesive strength is 1.2MPA.
Storage stability test：Room temperature storage 12 months, change is not observed.
Embodiment 2
Component A is 20000mPas by 100 parts of viscosity, and contents of ethylene is 0.10% ethenyl blocking poly dimethyl
Siloxanes, 20 parts of viscosity are 5000mPas, and hydrogen content is the methyl polysiloxane of 0.15% hydrosilyl group-containing, and 100 parts aoxidize
Aluminium powder, 6 parts of ethyl trimethoxy silanes, 1 part of N- n-butyl amine base propyl trimethoxy silicane.
Hydroxyl endblocked polydimethylsiloxane, 50 part powdered whitings of the B component by 100 parts of viscosity for 5000mPas,
0.4 part of 2- acetylene -1- alcohol, 8 parts of platinum contents are in the 2000ppm silica complex compound of chloroplatinic acid tetramethyl divinyl two, 1 part of water
Point.
Component A is 2.3 with B component weight ratio:1, volume ratio 2:1 is used in mixed way.
Mixture heats 5min at 120 DEG C, forms silicone elastomer, and to metal materials such as aluminium alloy, stainless steels
With cohesion bond failure, aluminium alloy adhesive strength 1.0MPA.
Under the conditions of 23 DEG C of normal temperature, relative humidity 50%, the surface drying time of mixture exists in 40~60min, gel resin time
40~60min, cohesion bond failure (vulcanization is moisture-curable) is formed to rust steel after vulcanizing 120min, stainless steel bonding
Adhesive strength 1.2MPA.
Storage stability test：Room temperature storage 12 months.
Adhesive strength refers to lap shear strength, is tested according to national standard GB7124-86 methods.Above example failure mode
It is cohesional failure, experimental test condition is 23 DEG C of room temperature.
Comparative example：
Other non-amine coupling agents are used in formula, adhesive property can be affected.Here is that inventor is done to having a competition
An example in testing.
Component A is 10000mPas by 100 parts of viscosity, and contents of ethylene is 0.15% ethenyl blocking poly dimethyl
Siloxanes, 50 parts of viscosity are 1000mPas, and hydrogen content is the methyl polysiloxane of 0.2% hydrosilyl group-containing, 50 parts of lightweight carbon
Sour calcium, 8 parts of MTMSs, 1 part of 200s (chelating titanate coupling agent).
B component is by hydroxyl endblocked polydimethylsiloxane, 10 parts of carbon blacks that 100 parts of viscosity are 3000mPas, 0.5 part of second
Alkynyl cyclohexanol, 4 parts of platinum contents are in the 2000ppm silica complex compound of chloroplatinic acid tetramethyl divinyl two, 0.5 part of moisture.
Component A is 1.1 with B component weight ratio:1, volume ratio 1:1 is used in mixed way.
100 DEG C of solidification 10min, are≤0.1 to stainless steel adhesive strength, failure mode is interfacial failure.
Although above the present invention has made detailed description, on the basis of the present invention, some can be made to it and repaiied
Change or improve, this will be apparent to those skilled in the art.Therefore, institute without departing from theon the basis of the spirit of the present invention
The these modifications or improvements done, belong to the scope of protection of present invention.
Claims (10)
1. a kind of double cured silicone compounds of two-component, are made up of, it is characterised in that the component A bag component A and B component
Include the methyl polysiloxane and crosslinking agent of the polydimethylsiloxane containing vinyl, hydrosilyl group-containing；B component includes hydroxyl
Block dimethyl silicone polymer, platinum catalyst；The weight of component A and B component ratio is 1:1 to 10:1.
2. the double cured silicone compounds of two-component according to claim 1, it is characterised in that the component A is by weight
Part includes：
The B component includes by weight：
3. the double cured silicone compounds of two-component according to claim 1, it is characterised in that the crosslinking agent is methyl
Tributanoximo silane, vinyl tributyl ketoximyl silane, phenyl tributanoximo silane, four butanone oximino silanes, methyl three
Methoxy silane, vinyltrimethoxy silane, MTES, VTES, tetraethoxy-silicane
One or more in alkane.
4. the double cured silicone compounds of two-component according to claim 2, it is characterised in that the moisture-curable catalysis
Agent is organotin, organic titanium, the one or more in organo-bismuth class catalyst；Wherein described organic tin catalyst is selected from February
Dilaurylate, dibutyltin diacetate, the one or more in silane-modified dibutyl tin, the organic titanium class catalyst
Selected from tetraisopropyl titanate, tetrabutyl titanate, the tert-butyl ester of metatitanic acid four, diisopropoxy ethyl diacetoacetate titanium, two isobutyls
One or more kinds of mixtures in epoxide ethyl diacetoacetate titanium, the organo-bismuth class catalyst include neodecanoic acid
Bismuth, Bi (OOCR1)3、Bi[OOCCH(C2H5)C4H9]3With Bi (CpH2p-1COO)3In one or more, wherein p=5~11, R1
For one kind in line style or branched C1~C20 alkane, phenyl ring or biphenyl group.
5. the double cured silicone compounds of two-component according to claim 2, it is characterised in that the coupling agent is amino
Silane coupler, acryloxy silane coupling agent, epoxy silane coupling, glycidyl ether oxygen propyl trimethoxy silicon
Alkane, glycidoxypropyltrietandysilane andysilane, NCO propyl trimethoxy silicane, NCO triethoxy
One or more in silane and its oligomer, preferably secondary amino group coupling agent and its oligomer；The inhibitor be acetylene alcohol or
Propiolic alcohol inhibitor.
6. the double cured silicone compounds of two-component according to claim 2, it is characterised in that the catalyst made from platonic is
Vinylsiloxane platinum complex or chloroplatinic acid；The filler is reinforcement and/or half reinforced filling, selected from aerosil,
One or more in calcium carbonate, silicon powder, aluminum oxide, carbon black.
7. the double cured silicone compounds of two-component according to any one of claim 1~6, it is characterised in that described to contain
The viscosity for having the dimethyl silicone polymer of vinyl is 1000mPas~200000mPas at 25 DEG C；The hydrosilyl group-containing
The viscosity of methyl polysiloxane be 100mPas~20000mPas at 25 DEG C；The hydroxy-end capped polydimethylsiloxanes
The viscosity of alkane is 1000mPas~20000mPas at 25 DEG C.
8. the double cured silicone compounds of two-component according to any one of claim 1~6, it is characterised in that the A groups
Part includes by weight：
The B component includes by weight：
9. double applications of the cured silicone compound as bonding agent of two-component described in any one of claim 1~8.
10. application according to claim 9, it is characterised in that the double cured silicone compounds of described two-component are adding
Solidification is realized under the conditions of heat or room temperature condition, relative humidity 30~70%.
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| CN201710804361.5A CN107523260B (en) | 2017-09-08 | 2017-09-08 | Two-component dual-cure silicone compound |
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| CN201710804361.5A CN107523260B (en) | 2017-09-08 | 2017-09-08 | Two-component dual-cure silicone compound |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109777347A (en) * | 2018-12-29 | 2019-05-21 | 山东华夏神舟新材料有限公司 | Double component room temperature vulcanization fluorine silicone sealant and preparation method thereof |
| CN110041877A (en) * | 2019-03-14 | 2019-07-23 | 湖北航聚科技有限公司 | A kind of good bonding agent of thermal matching and preparation method thereof |
| CN110054999A (en) * | 2019-02-11 | 2019-07-26 | 斯迪克新型材料（江苏）有限公司 | The preparation method of anti-residue glue heat-conducting double-sided adhesive tape |
| CN110172328A (en) * | 2019-05-30 | 2019-08-27 | 北京诚和龙盛工程技术有限公司 | A kind of Self-leveling insulation and moisture sealing agent |
| CN112210341A (en) * | 2020-09-18 | 2021-01-12 | 山东东岳有机硅材料股份有限公司 | Double-vulcanization system building sealant and preparation method thereof |
| CN114341272A (en) * | 2019-09-09 | 2022-04-12 | 信越化学工业株式会社 | Addition curing type liquid silicon rubber composition for air bag and air bag |
| CN114921219A (en) * | 2022-04-18 | 2022-08-19 | 浙江润禾有机硅新材料有限公司 | Novel two-component organic silicon adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408947A (en) * | 2013-07-26 | 2013-11-27 | 中科院广州化学有限公司 | Dual-cured high-performance LED packaging material and preparation method thereof |
| CN105348813A (en) * | 2015-12-04 | 2016-02-24 | 厦门安耐伟业新材料有限公司 | One-component organic silicon composition applicable to moisture-heat dual-curing and preparation method thereof |
| CN105348809A (en) * | 2015-12-17 | 2016-02-24 | 刘爱华 | Novel organic siloxane polymer material for electronic packaging |
| CN105950100A (en) * | 2016-05-31 | 2016-09-21 | 江苏创景科技有限公司 | {0><}0{>Organosilicon pouring sealant with high curing speed and low wiredrawing capability and preparation method thereof<0} |
-
2017
- 2017-09-08 CN CN201710804361.5A patent/CN107523260B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408947A (en) * | 2013-07-26 | 2013-11-27 | 中科院广州化学有限公司 | Dual-cured high-performance LED packaging material and preparation method thereof |
| CN105348813A (en) * | 2015-12-04 | 2016-02-24 | 厦门安耐伟业新材料有限公司 | One-component organic silicon composition applicable to moisture-heat dual-curing and preparation method thereof |
| CN105348809A (en) * | 2015-12-17 | 2016-02-24 | 刘爱华 | Novel organic siloxane polymer material for electronic packaging |
| CN105950100A (en) * | 2016-05-31 | 2016-09-21 | 江苏创景科技有限公司 | {0><}0{>Organosilicon pouring sealant with high curing speed and low wiredrawing capability and preparation method thereof<0} |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109777347A (en) * | 2018-12-29 | 2019-05-21 | 山东华夏神舟新材料有限公司 | Double component room temperature vulcanization fluorine silicone sealant and preparation method thereof |
| CN110054999A (en) * | 2019-02-11 | 2019-07-26 | 斯迪克新型材料（江苏）有限公司 | The preparation method of anti-residue glue heat-conducting double-sided adhesive tape |
| CN110054999B (en) * | 2019-02-11 | 2021-08-13 | 斯迪克新型材料（江苏）有限公司 | Preparation method of anti-adhesive-residue heat-conducting double-sided adhesive tape |
| CN110041877A (en) * | 2019-03-14 | 2019-07-23 | 湖北航聚科技有限公司 | A kind of good bonding agent of thermal matching and preparation method thereof |
| CN110172328A (en) * | 2019-05-30 | 2019-08-27 | 北京诚和龙盛工程技术有限公司 | A kind of Self-leveling insulation and moisture sealing agent |
| CN114341272A (en) * | 2019-09-09 | 2022-04-12 | 信越化学工业株式会社 | Addition curing type liquid silicon rubber composition for air bag and air bag |
| CN114341272B (en) * | 2019-09-09 | 2023-10-20 | 信越化学工业株式会社 | Addition-curable liquid silicone rubber composition for air bags and air bag |
| CN112210341A (en) * | 2020-09-18 | 2021-01-12 | 山东东岳有机硅材料股份有限公司 | Double-vulcanization system building sealant and preparation method thereof |
| CN112210341B (en) * | 2020-09-18 | 2022-07-26 | 山东东岳有机硅材料股份有限公司 | Double-vulcanization system building sealant and preparation method thereof |
| CN114921219A (en) * | 2022-04-18 | 2022-08-19 | 浙江润禾有机硅新材料有限公司 | Novel two-component organic silicon adhesive and preparation method thereof |
| CN114921219B (en) * | 2022-04-18 | 2023-08-15 | 小禾电子材料(德清)有限公司 | Double-component organic silica gel adhesive and preparation method thereof |
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| CN107523260B (en) | 2021-05-25 |
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