CN107523215A - A kind of ANTI-FOULING PAINT FOR FISHING NET and preparation method thereof - Google Patents
A kind of ANTI-FOULING PAINT FOR FISHING NET and preparation method thereof Download PDFInfo
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- CN107523215A CN107523215A CN201710827043.0A CN201710827043A CN107523215A CN 107523215 A CN107523215 A CN 107523215A CN 201710827043 A CN201710827043 A CN 201710827043A CN 107523215 A CN107523215 A CN 107523215A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
- C09D171/03—Polyepihalohydrins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of ANTI-FOULING PAINT FOR FISHING NET and preparation method thereof, it is characterized in, the antifouling paint is mixed by composite resin material, rosin, plasticizer, anti-fouling agent, anti-settling agent and solvent；Its preparation method is to prepare to disclosure satisfy that there is good adhesion and flexible composite resin material on fishing net first, then composite resin material, rosin, plasticizer, anti-fouling agent, anti-settling agent and solvent are added in disperse mill by weight and carry out scattered milled processed, processing time is 1~2 hour, and antifouling paint is made；The antifouling composition has good anti-halobios adhersion performance on the cultivation fishing gear such as net cage, cylinder mould, and antifouling composition preparation technology is easy, workable, has preferable industrial prospect.
Description
Technical field：
The present invention relates to antifouling paint technical field, specifically a kind of ANTI-FOULING PAINT FOR FISHING NET and preparation method thereof；It is applied to
The fishing nets such as net cage, cylinder mould.
Background technology：
Biodeterioration is produced to marine aquaculture industry in worldwide and had a strong impact on.Fishing net only soaks in the seawater
In 1~2 week, it will make to adhere to some macroscopic fouling organisms on fishing net, and degree can be with fishing net in the seawater
Usage time change.And attachment of the fouling organism on netting cage can bring a series of harm, such as reduce dictyosome
Product, reduce Netcom's permeability, increase net load, obstruction current oxygen and the exchange of nutrition, nourish disease, even resulting in aquaculture organism
Death etc..
Based on above-mentioned fouling organism sclerozone come harm, therefore be badly in need of effective anti-pollution measure to solve the above problems.
And fishing net anti-pollution measure at this stage mainly includes the removal of machinery, the design of cylinder mould, the use of antifouling paint, biological competition
Utilize.Because the use that netpen designs and biological competition utilize has certain limitation, therefore mechanical removal and antifouling paint
Use be measure relatively conventional at this stage.Wherein mechanical removal needs to expend substantial amounts of manpower and material resources, and can be to cultivation
Certain influence is carried out in biozone.Therefore antifouling phase, effect was longer and industrial for the antifouling paint suitable for netting cage is at this stage
Change achievable antifouling means.
For the fishing nets such as net cage, it is mainly made up of materials such as hdpe fiber and nylon.At present, market
On make breeding net case, customization net, rope etc. 80% above is polyethylene and nylon material fishing net.Due to polyethylene kind, nylon-type
The strong pliability and strong-hydrophobicity that material has, therefore also needed for antifouling paint with stronger pliability and online good
Good adhesion property.Although there has been more research in the antifouling field of fishing net, adhesiveness of these antifouling paints on fishing net
Energy and pliability are simultaneously bad, very easy under the effects such as construction, seawater immersion and alluvion to come off from network, therefore it is anti-
Biological attachment performance receives important influence.
The content of the invention：
The purpose of the present invention is to overcome the shortcomings of above-mentioned prior art, and provides a kind of ANTI-FOULING PAINT FOR FISHING NET.
Another object of the present invention is to provide a kind of preparation method of ANTI-FOULING PAINT FOR FISHING NET.
Present invention mainly solves existing ANTI-FOULING PAINT FOR FISHING NET in adhesive force deficiency on etting and the problem of poor toughness.
The technical scheme is that：A kind of ANTI-FOULING PAINT FOR FISHING NET, it is characterized in that, the original matched by following weight
Material is made, and 5~40 parts of composite resin material, 6~20 parts of rosin, 2~5 parts of plasticizer, 10~30 parts of anti-fouling agent, anti-settling agent 3~
10 parts, 10~30 parts of solvent.
Further, described composite resin material is chlorinated polyether resin, acrylic resin, chlorosulfonated polyethylene resin, ring
Mixing, dissolving, reaction are made in proportion for two or three in oxygen tree fat, polyurethane, chlorinated rubber.
Further, described composite resin material matches two or three in raw material by following weight and mixed in proportion
Close, dissolve, reaction is made；5~25 parts of chlorinated polyether resin, 5~20 parts of acrylic resin, 5~15 parts of chlorosulfonated polyethylene resin, ring
5~18 parts of oxygen tree fat, 5~15 parts of polyurethane, 3~20 parts of chlorinated rubber, two of which or three kinds are mixed in proportion, are added molten
Agent 40~100 DEG C heating for dissolving, add 0.1~0.3 part of initiator, be warming up to 90~120 DEG C, then under agitation to
The acrylic monomer of 3~10 parts of parts by weight is added dropwise in the solution, is added dropwise 1.5~2.5 hours, is incubated 0.5~1 hour, cooling
Discharging, composite resin material is made.
Further, described solvent is the one or more in hydro carbons or alcohol ethers solvent；Described solvent and resin
Weight ratio is 3~10：1；Described acrylic ester monomer is EMA, methoxyethyl methacrylate, first
Base cyclohexyl acrylate, Isobutyl methacrylate, Tert-butyl Methacrylate, EHMA, methyl acrylate,
One kind in cyclohexyl acrylate, tert-butyl acrylate, Isooctyl acrylate monomer, methoxyethyl acrylate；Described initiator
For one kind in azodiisobutyronitrile, AMBN, benzoyl peroxide.
Further, described hydro carbons and alcohol ethers solvent are dimethylbenzene, n-butanol, cyclohexanol, dihydroxypropane single-ether, vinegar
One kind in acid butyl ester.
Further, described plasticizer is one in tricresyl phosphate, dibutyl phthalate, chlorinated paraffin
Kind.
Further, described anti-fouling agent be cuprous oxide, cuprous sulfocyanide, Seanine211, BIT,
At least one of copper pyrithione, Bravo, ZPT.
Further, described solvent is dimethylbenzene, dihydroxypropane single-ether, butyl acetate, cyclohexanone, methyl-isobutyl first
One kind in ketone.
Further, described anti-settling agent is one kind in organobentonite, Tissuemat E, polyamide wax.
A kind of preparation method of ANTI-FOULING PAINT FOR FISHING NET of the present invention, it is characterized in that：By described composite resin material,
Rosin, plasticizer, anti-fouling agent, anti-settling agent and solvent are added in disperse mill by weight carries out scattered milled processed, place
It is 1 hour~2 hours to manage the time.
Compared with the prior art a kind of ANTI-FOULING PAINT FOR FISHING NET of the present invention and preparation method thereof has prominent essence
Property feature and marked improvement, 1, by resin material compound, dissolve and react in proportion, obtain can have on fishing net it is good
Good adhesive force and flexible composite resin material, reach the purpose used on fishing net；2nd, preparation method is simple, is easy to grasp
Make, be cost-effective, being easy to implement industrialization.
Embodiment：
Following examples are the further explanations to the present invention, but the invention is not restricted to this；Illustrated embodiment is only used for explaining this
Invention, is not intended to limit the scope of the present invention.
Embodiment 1, the antifouling paint formula of the present embodiment and technological process are as follows：
The preparation of composite resin material：Accurately weigh 15 parts of chlorinated polyether resin, 10 parts of acrylic resin, chlorosulfonated polyethylene resin 5
Part, mixing, add at 100 parts, 80 DEG C of xylene solvent and dissolve, 0.1 part of azodiisobutyronitrile is added under stirring, mixing is equal
It is even；120 DEG C are heated to, 5 parts of Isobutyl methacrylates are then added dropwise in 2 hours in the case where stirring spare part, it is small to be then incubated 0.5
When, cooling, discharging, obtain composite resin material；
Accurately weigh 15 parts of composite resin material, 10 parts of rosin, 2 parts of chlorinated paraffin, 10 parts of cuprous sulfocyanide, butyl acetate
30 parts, 10 parts of organobentonite；Above-mentioned raw materials are mixed, it is fully dispersed, after disperseing, using grinding distribution machine by coating
It is fully ground 2 hours, that is, antifouling paint is made.
Embodiment 2, the antifouling paint formula of the present embodiment and technological process are as follows：
The preparation of composite resin material：15 parts of chlorinated polyether resin, 5 parts of acrylic resin accurately are weighed, is mixed, adds xylene solvent
Dissolved at 200 parts, 40 DEG C, stir lower 0.2 part of AMBN of addition, be well mixed；90 DEG C are heated to, then in stirring bar
5 parts of methoxyethyl acrylates are added dropwise in lower 2 hours in part, are then incubated 0.5 hour, cooling, discharging, obtain compound resin material
Material；
Accurately weigh 40 parts of composite resin material, 20 parts of rosin, 5 parts of chlorinated paraffin, 10 parts of cuprous oxide, 5 parts of Bravo, diformazan
25 parts of benzene, 10 parts of polyamide wax；Above-mentioned raw materials are mixed, it is fully dispersed, after disperseing, coating is filled using grinding distribution machine
Divide grinding 1 hour, that is, antifouling paint is made.
Embodiment 3, the antifouling paint formula of the present embodiment and technological process are as follows：
The preparation of composite resin material：15 parts of acrylic resin, 5 parts of epoxy resin, 5 parts of chlorinated polyether resin are weighed, is mixed, adds two
Dissolved at 125 parts, 90 DEG C of toluene solvant, stir lower 0.3 part of azodiisobutyronitrile of addition, be well mixed；100 DEG C are heated to, so
5 parts of Tert-butyl Methacrylates are added dropwise in 2.5 hours under agitation afterwards, are then incubated 1 hour, cooling, discharging, are prepared into
To composite resin material；
Weigh 25 parts of composite resin material, 10 parts of rosin, 5 parts of tricresyl phosphate, 30 parts of Seanine211, butyl acetate 30
Part, 3 parts of Tissuemat E；Above-mentioned raw materials are mixed, it is fully dispersed, after disperseing, coating is fully ground using grinding distribution machine
Mill 1 hour, that is, be made antifouling paint.
Embodiment 4；The antifouling paint formula of the present embodiment and technological process are as follows：
The preparation of composite resin material：It is mixed to weigh 5 parts of acrylic resin, 10 parts of chlorosulfonated polyethylene resin, 10 parts of chlorinated rubber
Close, add at 150 parts, 100 DEG C of dihydroxypropane single-ether solvent and dissolve, stir lower 0.2 part of benzoyl peroxide of addition, mixing is equal
It is even；Then it is heated to that 10 parts of methyl acrylates are added dropwise in 110 DEG C, 2 hours under agitation, is then incubated 0.7 hour, it is cold
But, discharge, composite resin material is prepared；
Weigh 25 parts of composite resin material, 15 parts of rosin, 3 parts of dibutyl phthalate, 10 parts of Seanine211, pyridine sulphur
5 parts of ketone copper, 30 parts of butyl acetate, 5 parts of organobentonite；Above-mentioned raw materials are mixed, it is fully dispersed, after disperseing, using grinding
Coating is fully ground 1 hour by mill dispersion machine, that is, antifouling paint is made.
Embodiment 5；The antifouling paint formula of the present embodiment and technological process are as follows：
The preparation of composite resin material：10 parts of 5 parts of epoxy resin, polyurethane mixing are weighed, add 45 parts of butyl acetate solvent,
Dissolved at 100 DEG C, stir lower 0.2 part of benzoyl peroxide of addition, be well mixed；Then 100 DEG C are heated under agitation,
Then 3 parts of EMAs are added dropwise in 1.5 hours under agitation, are then incubated 0.6 hour, cooling, discharging, prepare
Obtain composite resin material；
Weigh 5 parts of composite resin material, 6 parts of rosin, 3 parts of dibutyl phthalate, 10 parts of BIT, propane diols
Single 10 parts of ether, 5 parts of organobentonite；Above-mentioned raw materials are mixed, it is fully dispersed, will using grinding distribution machine after disperseing
Coating is fully ground 1 hour, that is, antifouling paint is made.
The antifouling paint of the present invention carries out application by the way of dip-coating, and for the adhesive rate of coating after dip-coating is done solid work
Calculated：
Adhesive rate：Quality before fishing net dip-coating is m0, the quality after dip-coating is done solid work is m,
The adhesive rate of antifouling paint=（M~m0）/ m0
Adhesion property result such as table 1 of each embodiment of antifouling paint of the present invention on polythene fishing net：
It can be drawn by result above, the antifouling paint prepared by the present invention can preferably stick attachment on fishing net.
Evaluated by field lacing film, the antifouling paint that the present invention prepares not only reveals good in polyethylene mesh sheet upper table
Adhesive force and pliability, while there is good antibiont adhesive ability.Concrete outcome such as table 2 below：
Claims (10)
1. a kind of ANTI-FOULING PAINT FOR FISHING NET, it is characterised in that the raw material matched by following weight is made, composite resin material 5~40
Part, 6~20 parts of rosin, 2~5 parts of plasticizer, 10~30 parts of anti-fouling agent, 3~10 parts of anti-settling agent, 10~30 parts of solvent.
2. ANTI-FOULING PAINT FOR FISHING NET according to claim 1, it is characterised in that described composite resin material is chlorine ether tree
Mix in proportion for two or three in fat, acrylic resin, chlorosulfonated polyethylene resin, epoxy resin, polyurethane, chlorinated rubber
Close, dissolve, reaction is made.
3. ANTI-FOULING PAINT FOR FISHING NET according to claim 2, it is characterised in that described composite resin material is by following weight
Mixing, dissolving, reaction are made in proportion for two or three in proportioning raw material；5~25 parts of chlorinated polyether resin, acrylic resin 5~
20 parts, 5~15 parts of chlorosulfonated polyethylene resin, 5~18 parts of epoxy resin, 5~15 parts of polyurethane, 3~20 parts of chlorinated rubber, will
Two of which or three kinds mix in proportion, add solvent in 40~100 DEG C of heating for dissolving, add 0.1~0.3 part of initiator, rise
Then the acrylic monomer of 3~10 parts of parts by weight is added dropwise to 90~120 DEG C in temperature into the solution under agitation, be added dropwise
1.5~2.5 hours, 0.5~1 hour is incubated, cooling discharge, composite resin material is made.
4. ANTI-FOULING PAINT FOR FISHING NET according to claim 3, it is characterised in that described solvent is hydro carbons or alcohol ethers solvent
In one or more；Described solvent is 3~10 with weight resin ratio：1；Described acrylic ester monomer is metering system
The tertiary fourth of acetoacetic ester, methoxyethyl methacrylate, cyclohexyl methacrylate, Isobutyl methacrylate, methacrylic acid
Ester, EHMA, methyl acrylate, cyclohexyl acrylate, tert-butyl acrylate, Isooctyl acrylate monomer, acrylic acid
One kind in methoxy acrylate；Described initiator is one in azodiisobutyronitrile, AMBN, benzoyl peroxide
Kind.
5. ANTI-FOULING PAINT FOR FISHING NET according to claim 4, it is characterised in that described hydro carbons and alcohol ethers solvent are diformazan
One kind in benzene, n-butanol, cyclohexanol, dihydroxypropane single-ether, butyl acetate.
6. ANTI-FOULING PAINT FOR FISHING NET according to claim 1, it is characterised in that described plasticizer be tricresyl phosphate,
One kind in dibutyl phthalate, chlorinated paraffin.
7. ANTI-FOULING PAINT FOR FISHING NET according to claim 1, it is characterised in that described anti-fouling agent is cuprous oxide, sulphur cyanogen
At least one of sour cuprous, Seanine211, BIT, copper pyrithione, Bravo, ZPT.
8. ANTI-FOULING PAINT FOR FISHING NET according to claim 1, it is characterised in that described solvent is dimethylbenzene, propane diols list
One kind in ether, butyl acetate, cyclohexanone, hexone.
9. ANTI-FOULING PAINT FOR FISHING NET according to claim 1, it is characterised in that described anti-settling agent is organobentonite, gathered
One kind in ethylene waxes, polyamide wax.
10. the preparation method of any one ANTI-FOULING PAINT FOR FISHING NET in claim 1-9, it is characterized in that：By described compound resin
Material, rosin, plasticizer, anti-fouling agent, anti-settling agent and solvent are added in disperse mill by weight to be carried out at scattered grinding
Reason, processing time are 1 hour~2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710827043.0A CN107523215B (en) | 2017-09-14 | 2017-09-14 | Fishing net antifouling paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710827043.0A CN107523215B (en) | 2017-09-14 | 2017-09-14 | Fishing net antifouling paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN107523215A true CN107523215A (en) | 2017-12-29 |
| CN107523215B CN107523215B (en) | 2020-02-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710827043.0A Active CN107523215B (en) | 2017-09-14 | 2017-09-14 | Fishing net antifouling paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795243A (en) * | 2018-07-02 | 2018-11-13 | 界首市汇珠渔具有限公司 | A method of addition hydrophobically modified cuprous oxide prepares fishing net with antifouling anticorrosive paint |
| CN108977077A (en) * | 2018-05-04 | 2018-12-11 | 无锡市海轮涂料有限公司 | A kind of low copper environment-friendly high-efficiency self-polishing antifouling paint and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580569A (en) * | 2009-06-22 | 2009-11-18 | 中国海洋石油总公司 | Chemically modified chlorinated polyether resin and anticorrosive coating thereof |
-
2017
- 2017-09-14 CN CN201710827043.0A patent/CN107523215B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580569A (en) * | 2009-06-22 | 2009-11-18 | 中国海洋石油总公司 | Chemically modified chlorinated polyether resin and anticorrosive coating thereof |
Non-Patent Citations (1)
| Title |
|---|
| 马星等: "聚乙烯类渔网防污涂料的制备与性能评价", 《涂料工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977077A (en) * | 2018-05-04 | 2018-12-11 | 无锡市海轮涂料有限公司 | A kind of low copper environment-friendly high-efficiency self-polishing antifouling paint and preparation method thereof |
| CN108795243A (en) * | 2018-07-02 | 2018-11-13 | 界首市汇珠渔具有限公司 | A method of addition hydrophobically modified cuprous oxide prepares fishing net with antifouling anticorrosive paint |
| CN108795243B (en) * | 2018-07-02 | 2020-08-18 | 界首市汇珠渔具有限公司 | Method for preparing antifouling and anticorrosive paint for fishing net by adding hydrophobically modified cuprous oxide |
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| Publication number | Publication date |
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| CN107523215B (en) | 2020-02-07 |
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