CN107521273A - Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent - Google Patents
Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent Download PDFInfo
- Publication number
- CN107521273A CN107521273A CN201710697326.8A CN201710697326A CN107521273A CN 107521273 A CN107521273 A CN 107521273A CN 201710697326 A CN201710697326 A CN 201710697326A CN 107521273 A CN107521273 A CN 107521273A
- Authority
- CN
- China
- Prior art keywords
- parts
- pumpkin
- softening agent
- side wall
- disk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44B—MACHINES, APPARATUS OR TOOLS FOR ARTISTIC WORK, e.g. FOR SCULPTURING, GUILLOCHING, CARVING, BRANDING, INLAYING
- B44B1/00—Artist's machines or apparatus equipped with tools or work holders moving or able to be controlled three-dimensionally for making single sculptures or models
- B44B1/06—Accessories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44B—MACHINES, APPARATUS OR TOOLS FOR ARTISTIC WORK, e.g. FOR SCULPTURING, GUILLOCHING, CARVING, BRANDING, INLAYING
- B44B1/00—Artist's machines or apparatus equipped with tools or work holders moving or able to be controlled three-dimensionally for making single sculptures or models
Landscapes
- Detergent Compositions (AREA)
Abstract
Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent, including chassis, chassis is provided with annular groove, rotating disc is provided with above chassis, annular ridge is provided with below rotating disc, annular ridge is stuck in annular groove, described rotation disk center is provided with hole, chassis is provided with vertical bar, vertical bar passes through hole, described rotation plate edge is provided with support, cantilever tip is hinged with claw, cutter is placed with claw, described chassis side wall is provided with vertical posts, vertical top end is provided with disk, lower disk surface is provided with a circle LED, disk upper surface is provided with switch and battery pack, switch, battery pack is connected with LED, described disk side wall is provided with box body, box body is built-in with sponge, described box side wall is provided with groove.Beneficial effect：Pumpkin is inserted in vertical bar, opens switch, LED etc. is illuminated, by rotating rotating disc, selects suitable cutter, pumpkin is carved, easy to use.
Description
Technical field：
The present invention relates to crops engraving technology field, and in particular to softening agent and its profit used in a kind of pumpkin engraving process
With the engraving machine of softening agent.
Background technology：
As the improvement of people's living standards, to such as nut, fruit, candy, biscuit, no matter the agricultural byproducts of flowers etc
Still require all very high in appearance in quality, in order to reach preferable decorative appearance, existing way is the side by craft
Formula is carved in agricultural byproducts appearance, is either printed pattern or word using modes such as ink-jets.Manual mode is taken a lot of work expense
When, and formation efficiency is low, is unfavorable for generating on a large scale.The mode of ink-jet etc, easily fades, and pigment itself is poisonous,
It is unfavorable for health.So, it is necessary to research and develop a kind of engraving process of agricultural byproducts.
The content of the invention：
The technical problems to be solved by the invention are the defects of part takes prior art, there is provided a kind of pumpkin of automatic ink-jet
Engraving machine.
The technical problems to be solved by the invention are realized using following technical scheme.
A kind of pumpkin engraving machine, it is characterised in that：Including chassis, chassis is provided with annular groove, is provided with and turns above chassis
Moving plate, rotating disc lower section are provided with annular ridge, and annular ridge is stuck in annular groove, and described rotation disk center is provided with hole, bottom
Disk is provided with vertical bar, and vertical bar passes through hole, and described rotation plate edge is provided with support, and cantilever tip is hinged with claw, claw
On be placed with cutter, described chassis side wall is provided with vertical posts, and vertical top end is provided with disk, and lower disk surface is provided with a circle
LED, disk upper surface are provided with switch and battery pack, switch, and battery pack is connected with LED, and described disk side wall is provided with box
Body, box body are built-in with sponge, and described box side wall is provided with groove.
Described vertical bar is provided with pallet.
Described support is can bending support.
Described disk side wall is provided with hole, and vertical top end end face is provided with hole, and vertical top end is inserted with bending bar, bending bar
The other end is inserted in the hole of disk side wall.
Described box side wall is retractable plank, and box body bottom is provided with permeable hole.
Described disk side wall is provided with 2 box bodys, and the sponge in 2 box bodys is respectively immersed with special softening agent and special increasing
Tough dose.
Described special softening agent is mainly prepared including following components:
Glycerine 20-30 parts, alcohol ether glucoside 20-30 parts, surfactant 20-30 parts；Potassium peroxydisulfate 15-25 parts, formaldehyde
20-25 parts, ammonium persulfate 55-60 parts, vegetable oil acid 50-60 parts, maleic anhydride 20-25 parts, catalyst 20-30 parts, fluorobenzene Buddhist nun
Examine 2-8 parts, DMF 13-16 parts, triacetyl glycerine 10-15 parts, Tween-80 10-15 parts, water 60-80 parts,
Chain-transferring agent 3-5 parts, methoxy polyoxyethylene ether 6-12 parts, methacrylic acid or acrylic acid 16-21 parts, acryloxy silane
10-16 parts, amino silane 20-21 parts.
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, the catalyst of 30% deal, Florfenicol, is stirred in reactor, temperature
At 80-100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome for control；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By methoxy polyoxyethylene ether and methacrylic acid or acrylic acid in a solvent or under the conditions of ventilation water removal, heating,
The catalyst action of 70% deal carries out graft esterification, obtains the polymeric monomer of polycarboxylate water-reducer；Second step is by above-mentioned big list
Body and glycerine, alcohol ether glucoside, chain-transferring agent etc. are heating, and are copolymerized in the presence of initiator, obtain molecular weight 10000
~50000 polycarboxylate water-reducer；
The ratio between amount by material is 1：1.02 acryloxy silane is mixed with amino silane after temperature 100~150
Reacted 6~10 hours at DEG C, then cool the temperature to 90~100 DEG C of temperature, then removed under reduced pressure small molecule and unreacted amino
Silane, obtain the intermediate containing tertiary amine structure；
Potassium peroxydisulfate is mixed with the intermediate containing tertiary amine structure, adds toluene and DMP-30, is then protected in nitrogen
Under reacted 3~5 hours in 105~115 DEG C of temperature, then cool the temperature to 50~60 DEG C of vacuum distillations of temperature, molecular weight existed
10000~50000 polycarboxylate water-reducer adds；
Stirring 30 minutes, whipping temp are 80 DEG C, then add formaldehyde, 130 DEG C of ammonium persulfate whipping temp, quick stirring
3 minutes, surfactant is eventually adding, is stirred 1 hour, normal temperature cooling.
Described special toughener is mainly prepared including following components：1000~20000mPas of viscosity diformazan
Dimethyl silicone polymer 100-110 parts of base vinyl silyloxy end-blocking, HMDS 2-3 parts, glycerine 3-5 parts,
Fume colloidal silica 5-10 parts, the poly- diformazan that the dimethyl ethenyl silyloxy that viscosity is 1000~20000mPas blocks
Radical siloxane latting drown 60-70 parts, vegetable oil acid 50-60 parts, maleic anhydride 20-25 parts, catalyst 20-30 parts, Florfenicol 2-8
Part, DMF 13-16 parts, triacetyl glycerine 10-15 parts, Tween-80 10-15 parts, water 60-80 parts, methyl-prop
E pioic acid methyl ester 25-30 parts；Butyl acrylate 26-30 parts；Methacrylic acid 13-20 parts, acrylic acid 6-10 parts, acrylic acid -2- second
The own ester 8-15 parts of base, emulsifying agent 1-4 parts, reagent and additive in polymerization 1-2 parts, initiator 1-2 parts, vinyl polymer 50-60 parts, glue
Glutinous agent 20-30 parts.
The dimethyl silicone polymer that 1 1000~20000mPas of viscosity dimethyl ethenyl silyloxy is blocked, six
Methyl disilazane, glycerine, fume colloidal silica mixing are mediated 1~3 hour after room temperature, then heat to 150~200 DEG C and pinch
Close 2~6 hours, add what the dimethyl ethenyl silyloxy that 100 parts by weight viscosity are 1000~20000mPas blocked
Dimethyl silicone polymer latting drown, obtains base rubber；
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, catalyst, Florfenicol, is stirred in reactor, temperature control is in 80-
100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By base rubber and methyl methacrylate, butyl acrylate, methacrylic acid and acrylic acid are put into baking oven and dried, so
Extruded by double screw extruder, water cooling, biodegradable master batch is made after cutting；
By acrylic acid-2-ethyl caproite, emulsifying agent, reagent and additive in polymerization, initiator, it is well mixed with the water of 50% deal, so
Extruded by double screw extruder, water cooling, degradable master batch is made after cutting；
Vinyl polymer and adhesive are added into obtained degradable master batch, is mixed into the water of 50% deal, mixing
Uniformly, 300 DEG C of high-temperature stirrings, 10 minutes, heating, cooling are stopped, you can.
Beneficial effect：Pumpkin is inserted in vertical bar, opens switch, LED etc. is illuminated, by rotating rotating disc, choosing
Suitable cutter is selected, pumpkin is carved, on the one hand, cutter is directly placed on rotating disc, without using can be by be hinged
Place, cutter bending is packed up, in use, directly selecting, on the other hand by pallet, can be easy to carve by pumpkin turn,
During engraving, the harder position of pumpkin, engraving is to insert cutter in the sponge of softening agent, softening agent is stained with cutter, can be had
Effect goes out pleasantly surprised softening engraving to pumpkin firmly, pumpkin soft portion position, cutter is inserted in toughener, and after engraving, sculptured surface can be risen
To toughening effect, the integrality of carving, easy to use, positive effect are preserved.
Brief description of the drawings：
Fig. 1 is the structural representation of embodiment 1 of the engraving machine of the present invention；
Fig. 2 is the structural representation of embodiment 2 of the engraving machine of the present invention.
Embodiment：
In order that the technological means that the present invention realizes, creation characteristic, reached purpose are easy to understand with effect, tied below
Specific embodiment is closed, the present invention is expanded on further.
Specific embodiment 1：
A kind of pumpkin engraving machine, including chassis 1, chassis are provided with annular groove 2, rotating disc 3 are provided with above chassis, rotate
Annular ridge 4 is provided with below disk, annular ridge is stuck in annular groove, and described rotation disk center is provided with hole 5, and chassis is provided with
Vertical bar 6, vertical bar pass through hole, and described rotation plate edge is provided with support 7, and cantilever tip is hinged with claw 8, placed on claw
There is cutter 9, described chassis side wall is provided with vertical posts 10, and vertical top end is provided with disk 11, and lower disk surface is provided with a circle LED
Lamp 12, disk upper surface are provided with switch 13 and battery pack 14, switch, and battery pack is connected with LED, and described disk side wall is provided with
Box body 15, box body are built-in with sponge 16, and described box side wall is provided with groove 19.
Vertical bar is provided with pallet 17.
Support is can bending support.
Box side wall is retractable plank, and box body bottom is provided with permeable hole 18.
Disk side wall is provided with 2 box bodys, and the sponge in 2 box bodys is respectively immersed with special softening agent and special toughener.
Special softening agent is mainly prepared including following components:
20 parts of glycerine, 20 parts of alcohol ether glucoside, 20 parts of surfactant；15 parts of potassium peroxydisulfate, 20 parts of formaldehyde, ammonium persulfate
55 parts, 50 parts of vegetable oil acid, 20 parts of maleic anhydride, 20 parts of catalyst, 2 parts of Florfenicol, 13 parts of DMF, three
10 parts of acetoglyceride, 10 parts of Tween-80,60 parts of water, 3 parts of chain-transferring agent, 6 parts of methoxy polyoxyethylene ether, methacrylic acid
Or 16 parts of acrylic acid, 10 parts of acryloxy silane, 20 parts of amino silane.
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, the catalyst of 30% deal, Florfenicol, is stirred in reactor, temperature
At 80-100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome for control；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By methoxy polyoxyethylene ether and methacrylic acid or acrylic acid in a solvent or under the conditions of ventilation water removal, heating,
The catalyst action of 70% deal carries out graft esterification, obtains the polymeric monomer of polycarboxylate water-reducer；Second step is by above-mentioned big list
Body and glycerine, alcohol ether glucoside, chain-transferring agent etc. are heating, and are copolymerized in the presence of initiator, obtain molecular weight 10000
~50000 polycarboxylate water-reducer；
The ratio between amount by material is 1：1.02 acryloxy silane is mixed with amino silane after temperature 100~150
Reacted 6~10 hours at DEG C, then cool the temperature to 90~100 DEG C of temperature, then removed under reduced pressure small molecule and unreacted amino
Silane, obtain the intermediate containing tertiary amine structure；
Potassium peroxydisulfate is mixed with the intermediate containing tertiary amine structure, adds toluene and DMP-30, is then protected in nitrogen
Under reacted 3~5 hours in 105~115 DEG C of temperature, then cool the temperature to 50~60 DEG C of vacuum distillations of temperature, molecular weight existed
10000~50000 polycarboxylate water-reducer adds；
Stirring 30 minutes, whipping temp are 80 DEG C, then add formaldehyde, 130 DEG C of ammonium persulfate whipping temp, quick stirring
3 minutes, surfactant is eventually adding, is stirred 1 hour, normal temperature cooling.
Special toughener is mainly prepared including following components：1000~20000mPas of viscosity dimethylvinylsiloxy
100 parts of the dimethyl silicone polymer of base silyloxy end-blocking, 2 parts of HMDS, 3 parts of glycerine, fume colloidal silica 5
Part, 60 parts of the dimethyl silicone polymer latting drown that the dimethyl ethenyl silyloxy that viscosity is 1000~20000mPas blocks,
50 parts of vegetable oil acid, 20 parts of maleic anhydride, 20 parts of catalyst, 2 parts of Florfenicol, 13 parts of DMF, three acetic acid are sweet
10 parts of grease, 10 parts of Tween-80,60 parts of water, 25 parts of methyl methacrylate；26 parts of butyl acrylate；Methacrylic acid 13-20
Part, 6 parts of acrylic acid, 8 parts of acrylic acid-2-ethyl caproite, 1 part of emulsifying agent, 1 part of reagent and additive in polymerization, 1 part of initiator, vinyl
50 parts of polymer, 20 parts of adhesive.
The dimethyl silicone polymer that 1 1000~20000mPas of viscosity dimethyl ethenyl silyloxy is blocked, six
Methyl disilazane, glycerine, fume colloidal silica mixing are mediated 1~3 hour after room temperature, then heat to 150~200 DEG C and pinch
Close 2~6 hours, add what the dimethyl ethenyl silyloxy that 100 parts by weight viscosity are 1000~20000mPas blocked
Dimethyl silicone polymer latting drown, obtains base rubber；
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, catalyst, Florfenicol, is stirred in reactor, temperature control is in 80-
100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By base rubber and methyl methacrylate, butyl acrylate, methacrylic acid and acrylic acid are put into baking oven and dried, so
Extruded by double screw extruder, water cooling, biodegradable master batch is made after cutting；
By acrylic acid-2-ethyl caproite, emulsifying agent, reagent and additive in polymerization, initiator, it is well mixed with the water of 50% deal, so
Extruded by double screw extruder, water cooling, degradable master batch is made after cutting；
Vinyl polymer and adhesive are added into obtained degradable master batch, is mixed into the water of 50% deal, mixing
Uniformly, 300 DEG C of high-temperature stirrings, 10 minutes, heating, cooling are stopped, you can.
Contrasted using pumpkin engraving：
As can be seen that the harder position of pumpkin, during engraving, cutter is inserted in the sponge of softening agent, softening is stained with cutter
Agent, it can effectively go out pleasantly surprised softening engraving firmly to pumpkin, pumpkin soft portion position, cutter be inserted in toughener, can be to carving after engraving
Toughening effect is played in facet, preserves the integrality of carving, easy to use, positive effect.
Embodiment 2：On the basis of the structure of embodiment 1, disk side wall is provided with hole 21, and vertical top end end face is provided with hole
22, vertical top end is inserted with bending bar 20, and the bending bar other end is inserted in the hole of disk side wall.
Special softening agent is mainly prepared including following components:
30 parts of glycerine, 30 parts of alcohol ether glucoside, 30 parts of surfactant；25 parts of potassium peroxydisulfate, 25 parts of formaldehyde, ammonium persulfate
60 parts, 60 parts of vegetable oil acid, 25 parts of maleic anhydride, 30 parts of catalyst, 8 parts of Florfenicol, 16 parts of DMF, three
15 parts of acetoglyceride, 15 parts of Tween-80,80 parts of water, 5 parts of chain-transferring agent, 12 parts of methoxy polyoxyethylene ether, methacrylic acid
Or 21 parts of acrylic acid, 16 parts of acryloxy silane, 21 parts of amino silane.
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, the catalyst of 30% deal, Florfenicol, is stirred in reactor, temperature
At 80-100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome for control；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By methoxy polyoxyethylene ether and methacrylic acid or acrylic acid in a solvent or under the conditions of ventilation water removal, heating,
The catalyst action of 70% deal carries out graft esterification, obtains the polymeric monomer of polycarboxylate water-reducer；Second step is by above-mentioned big list
Body and glycerine, alcohol ether glucoside, chain-transferring agent etc. are heating, and are copolymerized in the presence of initiator, obtain molecular weight 10000
~50000 polycarboxylate water-reducer；
The ratio between amount by material is 1：1.02 acryloxy silane is mixed with amino silane after temperature 100~150
Reacted 6~10 hours at DEG C, then cool the temperature to 90~100 DEG C of temperature, then removed under reduced pressure small molecule and unreacted amino
Silane, obtain the intermediate containing tertiary amine structure；
Potassium peroxydisulfate is mixed with the intermediate containing tertiary amine structure, adds toluene and DMP-30, is then protected in nitrogen
Under reacted 3~5 hours in 105~115 DEG C of temperature, then cool the temperature to 50~60 DEG C of vacuum distillations of temperature, molecular weight existed
10000~50000 polycarboxylate water-reducer adds；
Stirring 30 minutes, whipping temp are 80 DEG C, then add formaldehyde, 130 DEG C of ammonium persulfate whipping temp, quick stirring
3 minutes, surfactant is eventually adding, is stirred 1 hour, normal temperature cooling.
Special toughener is mainly prepared including following components：1000~20000mPas of viscosity dimethylvinylsiloxy
110 parts of the dimethyl silicone polymer of base silyloxy end-blocking, 3 parts of HMDS, 5 parts of glycerine, fume colloidal silica 10
Part, 70 parts of the dimethyl silicone polymer latting drown that the dimethyl ethenyl silyloxy that viscosity is 1000~20000mPas blocks,
60 parts of vegetable oil acid, 25 parts of maleic anhydride, 30 parts of catalyst, 8 parts of Florfenicol, 16 parts of DMF, three acetic acid are sweet
15 parts of grease, 15 parts of Tween-80,80 parts of water, 30 parts of methyl methacrylate；30 parts of butyl acrylate；20 parts of methacrylic acid,
10 parts of acrylic acid, 15 parts of acrylic acid-2-ethyl caproite, 4 parts of emulsifying agent, 2 parts of reagent and additive in polymerization, 2 parts of initiator, vinyl gathers
60 parts of compound, 30 parts of adhesive.
The dimethyl silicone polymer that 1 1000~20000mPas of viscosity dimethyl ethenyl silyloxy is blocked, six
Methyl disilazane, glycerine, fume colloidal silica mixing are mediated 1~3 hour after room temperature, then heat to 150~200 DEG C and pinch
Close 2~6 hours, add what the dimethyl ethenyl silyloxy that 100 parts by weight viscosity are 1000~20000mPas blocked
Dimethyl silicone polymer latting drown, obtains base rubber；
Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, split under vacuum 0.1MPa
Solution, obtains crude monomer；
Maleic anhydride is added in crude monomer, catalyst, Florfenicol, is stirred in reactor, temperature control is in 80-
100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome；
Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtained
Solvent；
By base rubber and methyl methacrylate, butyl acrylate, methacrylic acid and acrylic acid are put into baking oven and dried, so
Extruded by double screw extruder, water cooling, biodegradable master batch is made after cutting；
By acrylic acid-2-ethyl caproite, emulsifying agent, reagent and additive in polymerization, initiator, it is well mixed with the water of 50% deal, so
Extruded by double screw extruder, water cooling, degradable master batch is made after cutting；
Vinyl polymer and adhesive are added into obtained degradable master batch, is mixed into the water of 50% deal, mixing
Uniformly, 300 DEG C of high-temperature stirrings, 10 minutes, heating, cooling are stopped, you can.
Contrasted using pumpkin engraving：
As can be seen that the harder position of pumpkin, during engraving, cutter is inserted in the sponge of softening agent, softening is stained with cutter
Agent, it can effectively go out pleasantly surprised softening engraving firmly to pumpkin, pumpkin soft portion position, cutter be inserted in toughener, can be to carving after engraving
Toughening effect is played in facet, preserves the integrality of carving, easy to use, positive effect.
The general principle of the present invention, principal character and advantages of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (8)
- A kind of 1. softening agent used in pumpkin engraving process, it is characterised in that：Glycerine 20-30 parts, alcohol ether glucoside 20-30 parts, table Face activating agent 20-30 parts；Potassium peroxydisulfate 15-25 parts, formaldehyde 20-25 parts, ammonium persulfate 55-60 parts, vegetable oil acid 50-60 parts, Maleic anhydride 20-25 parts, catalyst 20-30 parts, Florfenicol 2-8 parts, DMF 13-16 parts, three triacetins Ester 10-15 parts, Tween-80 10-15 parts, water 60-80 parts, chain-transferring agent 3-5 parts, methoxy polyoxyethylene ether 6-12 parts, methyl Acrylic acid or acrylic acid 16-21 parts, acryloxy silane 10-16 parts, amino silane 20-21 parts.
- 2. according to softening agent used in a kind of pumpkin engraving process described in claim 1, it is characterised in that：Preparation method bag Include：Take vegetable oil acid to add in the water of 70% deal, be heated to 190 DEG C -200 DEG C, cracked, obtained under vacuum 0.1MPa To crude monomer；Maleic anhydride is added in crude monomer, the catalyst of 30% deal, Florfenicol, is stirred in reactor, temperature control At 80-100 DEG C, vacuum is that the product that cut is 70-80 DEG C is collected under 0.1MPa, obtains essence monome；Essence monome, DMF, triacetyl glycerine, Tween-80 are mixed with the water of 30% deal, obtain solvent；By methoxy polyoxyethylene ether and methacrylic acid or acrylic acid in a solvent or under the conditions of ventilation water removal, heating, 70% The catalyst action of deal carries out graft esterification, obtains the polymeric monomer of polycarboxylate water-reducer；Second step by above-mentioned polymeric monomer with Glycerine, alcohol ether glucoside, chain-transferring agent etc. are heating, and are copolymerized in the presence of initiator, obtain molecular weight 10000~ 50000 polycarboxylate water-reducer；The ratio between amount by material is 1：1.02 acryloxy silane is mixed with amino silane after at 100~150 DEG C of temperature Reaction 6~10 hours, then cools the temperature to 90~100 DEG C of temperature, then removed under reduced pressure small molecule and unreacted amino silane, Obtain the intermediate containing tertiary amine structure；Potassium peroxydisulfate is mixed with the intermediate containing tertiary amine structure, adds toluene and DMP-30, then under nitrogen protection in 105~115 DEG C of temperature is reacted 3~5 hours, 50~60 DEG C of vacuum distillations of temperature is then cooled the temperature to, by molecular weight 10000 ~50000 polycarboxylate water-reducer adds；Stirring 30 minutes, whipping temp are 80 DEG C, then add formaldehyde, 130 DEG C of ammonium persulfate whipping temp, quick 3 points of stirring Clock, surfactant is eventually adding, stirred 1 hour, normal temperature cooling.
- 3. a kind of pumpkin engraving process utilizes the engraving machine of above-mentioned softening agent, it is characterised in that：Including chassis, chassis is provided with annular groove, and rotating disc is provided with above chassis, annular ridge, ring are provided with below rotating disc Shape fin is stuck in annular groove, and described rotation disk center is provided with hole, and chassis is provided with vertical bar, and vertical bar passes through hole, institute The rotation plate edge stated is provided with support, and cantilever tip is hinged with claw, and cutter is placed with claw, and described chassis side wall is provided with Vertical posts, vertical top end are provided with disk, and lower disk surface is provided with a circle LED, and disk upper surface is provided with switch and battery pack, Switch, battery pack are connected with LED, and described disk side wall is provided with box body, and box body is built-in with sponge, and described box side wall is set There is groove.
- 4. engraving machine of the process using above-mentioned softening agent is carved according to a kind of pumpkin described in claim 3, it is characterised in that： Described vertical bar is provided with pallet.
- 5. engraving machine of the process using above-mentioned softening agent is carved according to a kind of pumpkin described in claim 3, it is characterised in that： Described support is can bending support.
- 6. engraving machine of the process using above-mentioned softening agent is carved according to a kind of pumpkin described in claim 3, it is characterised in that： Described disk side wall is provided with hole, and vertical top end end face is provided with hole, and vertical top end is inserted with bending bar, and the bending bar other end is inserted In the hole of disk side wall.
- 7. engraving machine of the process using above-mentioned softening agent is carved according to a kind of pumpkin described in claim 3, it is characterised in that： Described box side wall is retractable plank, and box body bottom is provided with permeable hole.
- 8. engraving machine of the process using above-mentioned softening agent is carved according to a kind of pumpkin described in claim 3, it is characterised in that： Described disk side wall is provided with 2 box bodys, and the sponge in 2 box bodys is respectively immersed with special softening agent and special toughener.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710697326.8A CN107521273B (en) | 2017-08-15 | 2017-08-15 | Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710697326.8A CN107521273B (en) | 2017-08-15 | 2017-08-15 | Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107521273A true CN107521273A (en) | 2017-12-29 |
| CN107521273B CN107521273B (en) | 2019-03-01 |
Family
ID=60681159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710697326.8A Active CN107521273B (en) | 2017-08-15 | 2017-08-15 | Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107521273B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3534920A1 (en) * | 1985-09-30 | 1987-05-21 | Rodenstock Optik G | Device for engraving workpieces, in particular spectacle lenses |
| CN104493934A (en) * | 2014-12-10 | 2015-04-08 | 界首市祥雨竹编专业合作社 | Bamboo weaving softening agent and preparation technique thereof |
| CN104526810A (en) * | 2014-12-19 | 2015-04-22 | 赵俊辉 | Bamboo weaving softener and preparation method thereof |
| CN104890075A (en) * | 2015-06-19 | 2015-09-09 | 陈新棠 | Softener for bamboo product |
| CN106427335A (en) * | 2016-11-04 | 2017-02-22 | 苏州亨达尔工业材料有限公司 | Carved sample observation device for carving machine assisting |
| CN106494143A (en) * | 2016-12-09 | 2017-03-15 | 兴业县金达木材有限公司 | A kind of artificial woodcarving workbench |
-
2017
- 2017-08-15 CN CN201710697326.8A patent/CN107521273B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3534920A1 (en) * | 1985-09-30 | 1987-05-21 | Rodenstock Optik G | Device for engraving workpieces, in particular spectacle lenses |
| CN104493934A (en) * | 2014-12-10 | 2015-04-08 | 界首市祥雨竹编专业合作社 | Bamboo weaving softening agent and preparation technique thereof |
| CN104526810A (en) * | 2014-12-19 | 2015-04-22 | 赵俊辉 | Bamboo weaving softener and preparation method thereof |
| CN104890075A (en) * | 2015-06-19 | 2015-09-09 | 陈新棠 | Softener for bamboo product |
| CN106427335A (en) * | 2016-11-04 | 2017-02-22 | 苏州亨达尔工业材料有限公司 | Carved sample observation device for carving machine assisting |
| CN106494143A (en) * | 2016-12-09 | 2017-03-15 | 兴业县金达木材有限公司 | A kind of artificial woodcarving workbench |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107521273B (en) | 2019-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102516893B (en) | Adherent composition and method of temporarily fixing member therewith | |
| JP2017031249A (en) | Resin composition for model material, resin composition for support material, optically shaped article and method for manufacturing optically shaped article | |
| CN103254857A (en) | Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof | |
| CN108314981B (en) | Environment-friendly thermoplastic resin water-based adhesive | |
| CN104559829A (en) | Sticky rice wet glue added with emulsion stabilizer and preparation method thereof | |
| CN113512322B (en) | Environment-friendly water-based varnish for photovoltaic glass glaze and preparation method thereof | |
| CN107487122A (en) | A kind of pumpkin engraving process toughening agent and its engraving machine using toughener | |
| CN102167948A (en) | UV (ultraviolet) photo-cured acrylic resin composition | |
| CN106381090A (en) | Mildew-resistant and environment-friendly glutinous rice wet glue and production method thereof | |
| CN107521273A (en) | Softening agent used in a kind of pumpkin engraving process and its engraving machine using softening agent | |
| CN113583600A (en) | High-temperature-resistant pressure-sensitive adhesive, preparation process and application thereof | |
| CN111849405B (en) | Water-based high-gloss vacuum suction plastic and preparation method thereof | |
| CN112175555A (en) | Polar hot melt adhesive and preparation method thereof | |
| CN107599712A (en) | A kind of pumpkin engraving machine | |
| CN104194695A (en) | Grafted nano ambary fiber crystal whisker modified urea formaldehyde resin adhesive and preparation method thereof | |
| CN107858129A (en) | A kind of preparation method of solvent borne acrylic's ester pressure-sensitive | |
| CN109370506A (en) | A kind of ultraviolet light solidfication water polyurethane binder and preparation method thereof | |
| CN110591010A (en) | Water-resistant styrene-free artificial stone resin and preparation method thereof | |
| CN106398584A (en) | Rose aroma type glutinous-rice wet adhesive and preparation method thereof | |
| CN101787102A (en) | Method for preparing white latex by utilizing polystyrene waste | |
| CN111320726A (en) | Waterborne polyurethane-polyvinyl acetate emulsion, preparation method thereof, waterborne vacuum plastic absorbing material comprising waterborne polyurethane-polyvinyl acetate emulsion and preparation method thereof | |
| KR100761972B1 (en) | Vinyl acetate emulsion adhesive and method of manufacturing the same | |
| CN109266261A (en) | A kind of student's environmentally protective glue and preparation method thereof | |
| JPH0216322B2 (en) | ||
| TW202112741A (en) | 2-cyanoacrylate compound and adhesive composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |