CN107513707A - A kind of automobile specified inorganic agent - Google Patents
A kind of automobile specified inorganic agent Download PDFInfo
- Publication number
- CN107513707A CN107513707A CN201710736734.XA CN201710736734A CN107513707A CN 107513707 A CN107513707 A CN 107513707A CN 201710736734 A CN201710736734 A CN 201710736734A CN 107513707 A CN107513707 A CN 107513707A
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- Prior art keywords
- parts
- raw material
- ammonium sulfate
- cyclohexanhexanol
- atmp
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
- C23C22/47—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates containing also phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The invention discloses a kind of automobile specified inorganic agent, it is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane trimethacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene and oxalic acid；The mass fraction of each raw material is respectively：20 22 parts of antioxidant, 8 20 parts of phosphatase 11,68 parts of methyl benzotriazazole, 26 parts of trimethylolpropane trimethacrylate, 37 parts of vinyltrimethoxy silane, 13 parts of ammonium sulfate, 13 parts of ATMP, 24 parts of six phosphate ester of cyclohexanhexanol, 28 parts of dibutyl hydroxy toluene, 8 12 parts of oxalic acid.Inventive formulation is simple and practical, metal works are invaded into phosphating solution, it can deposit to form crystal type phosphate conversion film not soluble in water on surface at normal temperatures, the film layer is microcellular structure, it is firmly combined with matrix, there is good adsorptivity, lubricity, corrosion resistance, do not adhere to molten metal and higher electrical insulating property.
Description
Technical field
The present invention relates to a kind of metal treatment fluid, and in particular to a kind of automobile specified inorganic agent.
Background technology
Vehicle coating process, it generally can be divided into two large divisions：First, metallic surface is handled before application, pre-treatment skill is also
Art；Second, the construction technology of application.Surface treatment mainly includes removing the greasy dirt of workpiece surface, dust, corrosion and repaiied
Removing of old dope layer etc. when mending operation, to improve the surface state of workpiece.Including according to various concrete conditions to workpiece surface
It is machined and is chemically treated, such as phosphatization, oxidation and Passivation Treatment.Phosphatization is the critical process of pretreatment technology, directly
Affect the quality of painting dressing automobiles.
Metal conditioner refers to the general name for the chemical agent that various processing are carried out to metal surface.Treatment of Metal Surface
Include the substrate pretreatments such as oil removing, derusting, phosphatization, antirust, prepared for metal coating techniques, metal protection technology,
Substrate pretreatment quality is prepared to hereafter coating and the use of metal has a great impact, and water soluble anti-rust agent therein is then solvable
The aqueous solution is formed in Xie Shui, metal can prevent rust corrosion after the processing of this aqueous solution.Their anti-rust action can be divided into
Three classes.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of automobile specified inorganic agent.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of automobile specified inorganic agent, its innovative point
It is：It is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane trimethacrylate, vinyl
Trimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene and oxalic acid；It is described
The mass fraction of each raw material is respectively：Antioxidant 20-22 parts, phosphatase 11 8-20 parts, methyl benzotriazazole 6-8 parts, three hydroxyl first
Base propane triacrylate 2-6 parts, vinyltrimethoxy silane 3-7 parts, ammonium sulfate 1-3 parts, ATMP 1-3
Part, six phosphate ester of cyclohexanhexanol 2-4 parts, dibutyl hydroxy toluene 2-8 parts, oxalic acid 8-12 parts.
Further, it is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane tris propylene
Acid esters, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene
And oxalic acid；The mass fraction of each raw material is respectively：20 parts of antioxidant, 8 parts of phosphatase 11,6 parts of methyl benzotriazazole, three
2 parts of hydroxymethyl-propane triacrylate, 3 parts of vinyltrimethoxy silane, 1 part of ammonium sulfate, 1 part of ATMP, ring
2 parts of six phosphate of hexitol, 2 parts of dibutyl hydroxy toluene, 8 parts of oxalic acid.
Further, it is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane tris propylene
Acid esters, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene
And oxalic acid；The mass fraction of each raw material is respectively：22 parts of antioxidant, 20 parts of phosphoric acid, 8 parts of methyl benzotriazazole, three
6 parts of hydroxymethyl-propane triacrylate, 7 parts of vinyltrimethoxy silane, 3 parts of ammonium sulfate, 3 parts of ATMP, ring
4 parts of six phosphate of hexitol, 8 parts of dibutyl hydroxy toluene, 12 parts of oxalic acid.
Further, it is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane tris propylene
Acid esters, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene
And oxalic acid；The mass fraction of each raw material is respectively：21 parts of antioxidant, 9 parts of phosphatase 11,7 parts of methyl benzotriazazole, three
4 parts of hydroxymethyl-propane triacrylate, 5 parts of vinyltrimethoxy silane, 2 parts of ammonium sulfate, 2 parts of ATMP, ring
3 parts of six phosphate of hexitol, 5 parts of dibutyl hydroxy toluene, 10 parts of oxalic acid.
Beneficial effects of the present invention are as follows：Inventive formulation is simple and practical, metal works is invaded into phosphating solution, at normal temperatures
It can deposit to form crystal type phosphate conversion film not soluble in water on surface, the film layer is microcellular structure, and jail is combined with matrix
Gu with good adsorptivity, lubricity, corrosion resistance, molten metal and higher electrical insulating property are not adhered to.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of automobile specified inorganic agent, is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trihydroxy methyl
Propane triacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, two fourths
Base hydroxy-methylbenzene and oxalic acid；The mass fraction of each raw material is respectively：Antioxidant 20-22 parts, phosphatase 11 8-20 parts, methyl
BTA 6-8 parts, trimethylolpropane trimethacrylate 2-6 parts, vinyltrimethoxy silane 3-7 parts, ammonium sulfate 1-3
Part, ATMP 1-3 parts, six phosphate ester of cyclohexanhexanol 2-4 parts, dibutyl hydroxy toluene 2-8 parts, oxalic acid 8-12 parts.
Embodiment 1
A kind of automobile specified inorganic agent, is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane
Triacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxyl
Base toluene and oxalic acid；The mass fraction of each raw material is respectively：20 parts of antioxidant, 8 parts of phosphatase 11, methyl benzotriazazole 6
Part, 2 parts of trimethylolpropane trimethacrylate, 3 parts of vinyltrimethoxy silane, 1 part of ammonium sulfate, ATMP 1
Part, 2 parts of six phosphate ester of cyclohexanhexanol, 2 parts of dibutyl hydroxy toluene, 8 parts of oxalic acid.
Embodiment 2
A kind of automobile specified inorganic agent, is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane
Triacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxyl
Base toluene and oxalic acid；The mass fraction of each raw material is respectively：22 parts of antioxidant, 20 parts of phosphoric acid, methyl benzotriazazole 8
Part, 6 parts of trimethylolpropane trimethacrylate, 7 parts of vinyltrimethoxy silane, 3 parts of ammonium sulfate, ATMP 3
Part, 4 parts of six phosphate ester of cyclohexanhexanol, 8 parts of dibutyl hydroxy toluene, 12 parts of oxalic acid.
Embodiment 3
A kind of automobile specified inorganic agent, is made up of following raw material：Antioxidant, phosphoric acid, methyl benzotriazazole, trimethylolpropane
Triacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, six phosphate ester of cyclohexanhexanol, dibutyl hydroxyl
Base toluene and oxalic acid；The mass fraction of each raw material is respectively：21 parts of antioxidant, 9 parts of phosphatase 11, methyl benzotriazazole 7
Part, 4 parts of trimethylolpropane trimethacrylate, 5 parts of vinyltrimethoxy silane, 2 parts of ammonium sulfate, ATMP 2
Part, 3 parts of six phosphate ester of cyclohexanhexanol, 5 parts of dibutyl hydroxy toluene, 10 parts of oxalic acid.
Inventive formulation is simple and practical, and metal works are invaded into phosphating solution, can deposit to be formed not on surface at normal temperatures
Be dissolved in the crystal type phosphate conversion film of water, the film layer is microcellular structure, is firmly combined with matrix, have good adsorptivity,
Lubricity, corrosion resistance, molten metal and higher electrical insulating property are not adhered to.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (4)
- A kind of 1. automobile specified inorganic agent, it is characterised in that：It is made up of following raw material：Antioxidant, phosphoric acid, the nitrogen of methyl benzo three Azoles, trimethylolpropane trimethacrylate, vinyltrimethoxy silane, ammonium sulfate, ATMP, inositol six Phosphate, dibutyl hydroxy toluene and oxalic acid；The mass fraction of each raw material is respectively：Antioxidant 20-22 parts, phosphoric acid 18-20 parts, methyl benzotriazazole 6-8 parts, trimethylolpropane trimethacrylate 2-6 parts, vinyltrimethoxy silane 3-7 Part, ammonium sulfate 1-3 parts, ATMP 1-3 parts, six phosphate ester of cyclohexanhexanol 2-4 parts, dibutyl hydroxy toluene 2-8 parts, Oxalic acid 8-12 parts.
- A kind of 2. automobile specified inorganic agent according to claim 1, it is characterised in that：It is made up of following raw material：Antioxidant, Phosphoric acid, methyl benzotriazazole, trimethylolpropane trimethacrylate, vinyltrimethoxy silane, ammonium sulfate, amino front three Pitch phosphonic acids, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene and oxalic acid；The mass fraction of each raw material is respectively：It is anti- 20 parts of oxygen agent, 8 parts of phosphatase 11,6 parts of methyl benzotriazazole, 2 parts of trimethylolpropane trimethacrylate, vinyl trimethoxy 3 parts of silane, 1 part of ammonium sulfate, 1 part of ATMP, 2 parts of six phosphate ester of cyclohexanhexanol, 2 parts of dibutyl hydroxy toluene, grass 8 parts of acid.
- A kind of 3. automobile specified inorganic agent according to claim 1, it is characterised in that：It is made up of following raw material：Antioxidant, Phosphoric acid, methyl benzotriazazole, trimethylolpropane trimethacrylate, vinyltrimethoxy silane, ammonium sulfate, amino front three Pitch phosphonic acids, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene and oxalic acid；The mass fraction of each raw material is respectively：It is anti- 22 parts of oxygen agent, 20 parts of phosphoric acid, 8 parts of methyl benzotriazazole, 6 parts of trimethylolpropane trimethacrylate, vinyl trimethoxy 7 parts of silane, 3 parts of ammonium sulfate, 3 parts of ATMP, 4 parts of six phosphate ester of cyclohexanhexanol, 8 parts of dibutyl hydroxy toluene, grass 12 parts of acid.
- A kind of 4. automobile specified inorganic agent according to claim 1, it is characterised in that：It is made up of following raw material：Antioxidant, Phosphoric acid, methyl benzotriazazole, trimethylolpropane trimethacrylate, vinyltrimethoxy silane, ammonium sulfate, amino front three Pitch phosphonic acids, six phosphate ester of cyclohexanhexanol, dibutyl hydroxy toluene and oxalic acid；The mass fraction of each raw material is respectively：It is anti- 21 parts of oxygen agent, 9 parts of phosphatase 11,7 parts of methyl benzotriazazole, 4 parts of trimethylolpropane trimethacrylate, vinyl trimethoxy 5 parts of silane, 2 parts of ammonium sulfate, 2 parts of ATMP, 3 parts of six phosphate ester of cyclohexanhexanol, 5 parts of dibutyl hydroxy toluene, grass 10 parts of acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710736734.XA CN107513707A (en) | 2017-08-24 | 2017-08-24 | A kind of automobile specified inorganic agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710736734.XA CN107513707A (en) | 2017-08-24 | 2017-08-24 | A kind of automobile specified inorganic agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107513707A true CN107513707A (en) | 2017-12-26 |
Family
ID=60724103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710736734.XA Pending CN107513707A (en) | 2017-08-24 | 2017-08-24 | A kind of automobile specified inorganic agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107513707A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002698A (en) * | 2010-11-29 | 2011-04-06 | 湘潭大学 | Anti-rust treating agent for nickel-plated battery steel shell and using method thereof |
| CN102011112A (en) * | 2010-12-15 | 2011-04-13 | 济南德锡科技有限公司 | Zinc and zinc alloy plating black passivation solution and preparation method thereof |
| CN102131911A (en) * | 2008-09-07 | 2011-07-20 | 朗姆研究公司 | Cleaning solution formulations for substrates |
| CN103205738A (en) * | 2013-03-19 | 2013-07-17 | 武汉钢实硅钢浩源润滑油有限公司 | Non-chrome purified liquid |
| CN103668249A (en) * | 2013-12-01 | 2014-03-26 | 刘芳圃 | Derusting and pickling pretreatment fluid for copper electroless plating of steel substrate |
| CN104195536A (en) * | 2014-07-01 | 2014-12-10 | 国家电网公司 | Rust inactivation promoting conversion agent |
| CN104862680A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Anti-oxidation metal surface treatment agent |
| CN106756970A (en) * | 2016-11-30 | 2017-05-31 | 马鞍山德鸿生物技术有限公司 | A kind of water-based antirust agent, preparation method and applications for steel protection |
-
2017
- 2017-08-24 CN CN201710736734.XA patent/CN107513707A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102131911A (en) * | 2008-09-07 | 2011-07-20 | 朗姆研究公司 | Cleaning solution formulations for substrates |
| CN102002698A (en) * | 2010-11-29 | 2011-04-06 | 湘潭大学 | Anti-rust treating agent for nickel-plated battery steel shell and using method thereof |
| CN102011112A (en) * | 2010-12-15 | 2011-04-13 | 济南德锡科技有限公司 | Zinc and zinc alloy plating black passivation solution and preparation method thereof |
| CN103205738A (en) * | 2013-03-19 | 2013-07-17 | 武汉钢实硅钢浩源润滑油有限公司 | Non-chrome purified liquid |
| CN103668249A (en) * | 2013-12-01 | 2014-03-26 | 刘芳圃 | Derusting and pickling pretreatment fluid for copper electroless plating of steel substrate |
| CN104195536A (en) * | 2014-07-01 | 2014-12-10 | 国家电网公司 | Rust inactivation promoting conversion agent |
| CN104862680A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Anti-oxidation metal surface treatment agent |
| CN106756970A (en) * | 2016-11-30 | 2017-05-31 | 马鞍山德鸿生物技术有限公司 | A kind of water-based antirust agent, preparation method and applications for steel protection |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171226 |
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| WD01 | Invention patent application deemed withdrawn after publication |