CN107513329A - A kind of fireproof coating based on poly- carborane methylsiloxane - Google Patents
A kind of fireproof coating based on poly- carborane methylsiloxane Download PDFInfo
- Publication number
- CN107513329A CN107513329A CN201610426930.2A CN201610426930A CN107513329A CN 107513329 A CN107513329 A CN 107513329A CN 201610426930 A CN201610426930 A CN 201610426930A CN 107513329 A CN107513329 A CN 107513329A
- Authority
- CN
- China
- Prior art keywords
- parts
- carborane
- methylsiloxane
- poly
- fireproof coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of fireproof coating based on poly- carborane methylsiloxane, the key component of following mass parts is included in its raw material：It is double（2,3 epoxycyclopentyls）15 25 parts of ether resin, 15 30 parts of metal hydroxides, 5 12 parts of ethanol, 7 10 parts of calcium carbonate, 15 25 parts of talcum powder, poly- 6 12 parts of carborane methylsiloxane, 58 parts of glass sand, 58 parts of resin.The present invention is with double（2,3 epoxycyclopentyls）Ether resin and metal hydroxides add poly- carborane methylsiloxane, make fireproof coating in addition to fire retardant property as being combined in complex, additionally it is possible to maintain resistance to combustion, flame proof and the fire resistance property such as fire-retardant, can effectively protect surrounding combustible material.
Description
Technical field
The present invention relates to a kind of fireproof coating, and in particular to a kind of fire prevention of poly-organic acid system of fire prevention indoors applies
Material.
Background technology
At present, fire prevention measure both domestic and external from principle for be divided into Dredging Method and blocking cut-off process, and blocking cut-off process be divided into it is outer
Envelope, screen method, spraying process.Fire proofing material is coated in body surface as one kind, has heat-insulated, anti-flaming, anti-flaming function
Material is used widely, and using the development that can effectively delay the intensity of a fire in construction material, prevents propagation of flame.
Application publication number CN103923545A patent application discloses a kind of fireproof coating, fireproof coating proportioning, double cyanogen
Amine, silicate, pentaerythrite, titanium dioxide, chlorinated paraffin, APP, acrylic emulsion, remaining is auxiliary agent, the fireproof coating
Nontoxic, nonirritant, in coating, caking property is good, attractive in appearance and good flame retardation effect.Existing fireproof coating exists anti-toward contact
The shortcomings of fiery time is short, and protection domain limits to.The fire-proof and thermal-insulation effect for further improving fireproof coating is still art technology
The direction that personnel make great efforts.
The content of the invention
The technical problems to be solved by the invention are to provide one kind for above-mentioned prior art to be based on poly- carborane methyl silicon
The fireproof coating of oxygen alkane, it has good fireproofing flame-resistant characteristic.
Technical scheme is used by the present invention solves the above problems：A kind of fire prevention based on poly- carborane methylsiloxane
Coating, the key component of following mass parts is included in its raw material：
It is double（2,3- epoxycyclopentyls）Ether resin 15-25 parts,
Metal hydroxides 15-30 parts,
Ethanol 5-12 parts,
Calcium carbonate 7-10 parts,
Talcum powder 15-25 parts,
Poly- carborane methylsiloxane 6-12 parts,
Glass sand 5-8 parts,
Resin 5-8 parts.
Metal hydroxides of the present invention is magnesium hydroxide, aluminium hydroxide.
The particle diameter of talcum powder of the present invention is 100~350nm.
Glass sand of the present invention can be replaced with glass fibre.
Fireproof coating of the present invention also includes pigment, water, thickener, defoamer.
Fireproof coating of the present invention also includes levelling agent, curing agent.
Compared with prior art, the advantage of the invention is that：The present invention is with double（2,3- epoxycyclopentyls）Ether resin and gold
Belong to hydroxide as complex composition, metal hydroxides is homogeneously dispersed in double（2,3- epoxycyclopentyls）Gone forward side by side in ether resin
Row reaction, reinforcement are double（2,3- epoxycyclopentyls）The performance of ether resin, poly- carborane methylsiloxane is added, makes fireproof coating
In addition to fire retardant property, additionally it is possible to maintain resistance to combustion, flame proof and the fire resistance property such as fire-retardant, can effectively protect inflammable around
Material.
Embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
Based on the fireproof coating of poly- carborane methylsiloxane, the component of following mass parts is included in its raw material：
It is double（2,3- epoxycyclopentyls）20 parts of ether resin,
15 parts of magnesium hydroxide,
10 parts of ethanol,
10 parts of calcium carbonate,
15 parts of talcum powder,
Poly- 12 parts of carborane methylsiloxane,
5 parts of glass sand,
5 parts of resin.
Will be double（2,3- epoxycyclopentyls）Ether resin and magnesium hydroxide first mix, and are heated to 75-125 DEG C, are incubated 30-
240min, then add ethanol, calcium carbonate, talcum powder, poly- carborane methylsiloxane, glass sand, resin and add, temperature is adjusted
To 60-85 DEG C, 50-120min is incubated, produces fireproof coating.
Embodiment 2
Based on the fireproof coating of poly- carborane methylsiloxane, the component of following mass parts is included in its raw material：
It is double（2,3- epoxycyclopentyls）25 parts of ether resin,
30 parts of magnesium hydroxide,
5 parts of ethanol,
10 parts of calcium carbonate,
15 parts of talcum powder,
Poly- 8 parts of carborane methylsiloxane,
8 parts of glass fibre,
6 parts of resin,
3 parts of levelling agent,
2 parts of defoamer.
Will be double（2,3- epoxycyclopentyls）Ether resin and magnesium hydroxide first mix, and are heated to 75-125 DEG C, are incubated 30-
240min, then add ethanol, calcium carbonate, talcum powder, poly- carborane methylsiloxane, glass fibre, resin, levelling agent and disappear
Infusion is added, and temperature is adjusted into 60-85 DEG C, 50-120min is incubated, produces fireproof coating.
Embodiment 3
Based on the fireproof coating of poly- carborane methylsiloxane, the component of following mass parts is included in its raw material：
It is double（2,3- epoxycyclopentyls）15 parts of ether resin,
25 parts of aluminium hydroxide,
5 parts of ethanol,
7 parts of calcium carbonate,
25 parts of talcum powder,
Poly- 12 parts of carborane methylsiloxane,
5 parts of glass sand,
8 parts of resin,
8 parts of water,
2 parts of thickener.
Will be double（2,3- epoxycyclopentyls）Ether resin and aluminium hydroxide and water first mix, and are heated to 75-125 DEG C, insulation
30-240min, then addition ethanol, calcium carbonate, talcum powder, poly- carborane methylsiloxane, glass sand, resin and thickener add
Enter, temperature is adjusted to 60-85 DEG C, 50-120min is incubated, produces fireproof coating.
Claims (6)
- A kind of 1. fireproof coating based on poly- carborane methylsiloxane, it is characterised in that：Following mass parts are included in its raw material Key component：It is double（2,3- epoxycyclopentyls）Ether resin 15-25 parts,Metal hydroxides 15-30 parts,Ethanol 5-12 parts,Calcium carbonate 7-10 parts,Talcum powder 15-25 parts,Poly- carborane methylsiloxane 6-12 parts,Glass sand 5-8 parts,Resin 5-8 parts.
- 2. the fireproof coating according to claim 1 based on poly- carborane methylsiloxane, it is characterised in that：The metal Hydroxide is magnesium hydroxide, aluminium hydroxide.
- 3. the fireproof coating according to claim 1 based on poly- carborane methylsiloxane, it is characterised in that：The talcum The particle diameter of powder is 100~350nm.
- 4. the fireproof coating according to claim 1 based on poly- carborane methylsiloxane, it is characterised in that：The glass Sand can be replaced with glass fibre.
- 5. the fireproof coating according to claim 1 based on poly- carborane methylsiloxane, it is characterised in that：Also include face Material, water, thickener, defoamer.
- 6. the fireproof coating according to claim 1 based on poly- carborane methylsiloxane, it is characterised in that：Also include stream Flat agent, curing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610426930.2A CN107513329A (en) | 2016-06-17 | 2016-06-17 | A kind of fireproof coating based on poly- carborane methylsiloxane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610426930.2A CN107513329A (en) | 2016-06-17 | 2016-06-17 | A kind of fireproof coating based on poly- carborane methylsiloxane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107513329A true CN107513329A (en) | 2017-12-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610426930.2A Pending CN107513329A (en) | 2016-06-17 | 2016-06-17 | A kind of fireproof coating based on poly- carborane methylsiloxane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107513329A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109400846A (en) * | 2018-10-27 | 2019-03-01 | 濮阳天健生物科技有限公司 | A kind of chemical reaction kettle composite insulation boards and preparation method thereof |
-
2016
- 2016-06-17 CN CN201610426930.2A patent/CN107513329A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109400846A (en) * | 2018-10-27 | 2019-03-01 | 濮阳天健生物科技有限公司 | A kind of chemical reaction kettle composite insulation boards and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171226 |