CN107503139A - A kind of spinning sizing agent - Google Patents

A kind of spinning sizing agent Download PDF

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Publication number
CN107503139A
CN107503139A CN201710658842.XA CN201710658842A CN107503139A CN 107503139 A CN107503139 A CN 107503139A CN 201710658842 A CN201710658842 A CN 201710658842A CN 107503139 A CN107503139 A CN 107503139A
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CN
China
Prior art keywords
parts
slurry
sizing agent
spinning sizing
silicon oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710658842.XA
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Chinese (zh)
Inventor
仲伟德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Xiangjia Textile Science & Tech Co Ltd
Original Assignee
Nantong Xiangjia Textile Science & Tech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Xiangjia Textile Science & Tech Co Ltd filed Critical Nantong Xiangjia Textile Science & Tech Co Ltd
Priority to CN201710658842.XA priority Critical patent/CN107503139A/en
Publication of CN107503139A publication Critical patent/CN107503139A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/07—Cellulose esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D06M15/51—Unsaturated polymerisable polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to a kind of spinning sizing agent, fraction proportioning by weight is made up of following components：12 28 parts of nano SiO 2 modified starch；34 parts of anti wrinkling agent；26 parts of modified silicon oil defoamer；18 parts of terylene；36 parts of polyvinyl ester；11 18 parts of acetate fiber；12 17 parts of vinylacetate；7 12 parts of acrylic acid；7 15 parts of butyl acrylate；Water-based 6 10 parts of copolyether ester；27 parts of pentaerythritol stearate；10 15 parts of albumen slurry；4 12 parts of polyvinyl alcohol；7 10 parts of acetic acid.The advantage of the invention is that：The spinning sizing agent of the present invention, with functional, simple production process, the stability of viscosity, it is nontoxic to human body and environment, it is energy-saving and environment-friendly and cost is low, from modified silicon oil defoamer as defoamer, caused foam in sizing process can effectively be eliminated, slurry is more fully contacted with fabric, improve starching efficiency, save slurry.

Description

A kind of spinning sizing agent
Technical field
The present invention relates to field of textiles, more particularly to a kind of spinning sizing agent.
Background technology
Slurry makes sliver surface be coated with serous coat that is smooth, wear-resisting, flexible and having some strength, makes twining for sliver surface It is close to the trunk of sliver around fiber, reduces the coefficient of friction on sliver surface, while be that fraction slurries penetrate into yarn interior, increase is fine The viscous tensile strength paid power, improve yarn between dimension, to adapt to the hightension in weaving process, middle beating, reduce broken end and carry High efficiency.Slurry mainly has three major types at present:Starch (including converted starch), polyvinyl alcohol (PVA), acrylic compounds (including acid Salt, amide-type, esters), that is developing also has water-dispersible polyester slurry.However, in production slurry, use slurry In material, desizing processes, unavoidably environment is polluted, and turn into one of larger pollution sources of textile industry.Form sediment Powder is with a long history for warp sizing, because starch is a kind of aftergrowth, aboundresources source is wide, cheap, to hydrophilic Property fiber（Such as linen-cotton, viscose rayon）With good adhesion property, therefore dosage is most in three major types slurry, and most accords with The slurry of cyclization guaranteed request.But some defects in performance also be present, serous coat is crisp and hard, and degree of stretching is small, stability is poor, using right Starch conversion, it is set to improve serous coat pliability, adherence, permeability, wearability, it is degradable, environment, human body will not be caused Evil influences.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of spinning sizing agent for making slurry more fully be contacted with fabric.
In order to solve the above technical problems, the technical scheme is that：A kind of spinning sizing agent, its innovative point are：By weight Amount fraction proportioning is made up of following components：
Nano SiO 2 modified starch 12-28 parts；
Anti wrinkling agent 3-4 parts；
Modified silicon oil defoamer 2-6 parts；
Terylene 1-8 parts；
Polyvinyl ester 3-6 parts；
Acetate fiber 11-18 parts；
Vinylacetate 12-17 parts；
Acrylic acid 7-12 parts；
Butyl acrylate 7-15 parts；
Water-based copolyether ester 6-10 parts；
Pentaerythritol stearate 2-7 parts；
Albumen slurry 10-15 parts；
Polyvinyl alcohol 4-12 parts；
Acetic acid 7-10 parts.
Further, the polyacrylate of 5 parts by weight is included.
The advantage of the invention is that：The spinning sizing agent of the present invention, has functional a, simple production process, viscosity it is steady It is qualitative, it is nontoxic to human body and environment, and also cost is low, and it is energy-saving and environment-friendly, from modified silicon oil defoamer as defoaming Agent, caused foam in sizing process can be effectively eliminated, slurry is more fully contacted with fabric, improve starching efficiency, Save slurry.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among described scope of embodiments.
Embodiment 1
The spinning sizing agent of present invention fraction proportioning by weight is made up of following components：
12 parts of nano SiO 2 modified starch；
3 parts of anti wrinkling agent；
2 parts of modified silicon oil defoamer；
1 part of terylene；
3 parts of polyvinyl ester；
11 parts of acetate fiber；
12 parts of vinylacetate；
7 parts of acrylic acid；
7 parts of butyl acrylate；
Water-based 6 parts of copolyether ester；
2 parts of pentaerythritol stearate；
10 parts of albumen slurry；
4 parts of polyvinyl alcohol；
7 parts of acetic acid；
5 parts of polyacrylate.
Embodiment 2
The spinning sizing agent of present invention fraction proportioning by weight is made up of following components：
28 parts of nano SiO 2 modified starch；
4 parts of anti wrinkling agent；
6 parts of modified silicon oil defoamer；
8 parts of terylene；
6 parts of polyvinyl ester；
18 parts of acetate fiber；
17 parts of vinylacetate；
12 parts of acrylic acid；
15 parts of butyl acrylate；
Water-based 10 parts of copolyether ester；
7 parts of pentaerythritol stearate；
15 parts of albumen slurry；
12 parts of polyvinyl alcohol；
10 parts of acetic acid；
5 parts of polyacrylate.
Embodiment 3
The spinning sizing agent of present invention fraction proportioning by weight is made up of following components：
21 parts of nano SiO 2 modified starch；
3 parts of anti wrinkling agent；
4 parts of modified silicon oil defoamer；
5 parts of terylene；
4 parts of polyvinyl ester；
15 parts of acetate fiber；
16 parts of vinylacetate；
9 parts of acrylic acid；
11 parts of butyl acrylate；
Water-based 8 parts of copolyether ester；
5 parts of pentaerythritol stearate；
13 parts of albumen slurry；
8 parts of polyvinyl alcohol；
8 parts of acetic acid；
5 parts of polyacrylate.
The spinning sizing agent of the present invention, has functional, simple production process, the stability of viscosity, to human body and environment It is nontoxic, and cost is low, it is energy-saving and environment-friendly, from modified silicon oil defoamer as defoamer, can effectively eliminate Caused foam, makes slurry more fully be contacted with fabric in sizing process, improves starching efficiency, saves slurry.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention By appended claims and its equivalent thereof.

Claims (2)

  1. A kind of 1. spinning sizing agent, it is characterised in that：Fraction proportioning by weight is made up of following components：
    Nano SiO 2 modified starch 12-28 parts；
    Anti wrinkling agent 3-4 parts；
    Modified silicon oil defoamer 2-6 parts；
    Terylene 1-8 parts；
    Polyvinyl ester 3-6 parts；
    Acetate fiber 11-18 parts；
    Vinylacetate 12-17 parts；
    Acrylic acid 7-12 parts；
    Butyl acrylate 7-15 parts；
    Water-based copolyether ester 6-10 parts；
    Pentaerythritol stearate 2-7 parts；
    Albumen slurry 10-15 parts；
    Polyvinyl alcohol 4-12 parts；
    Acetic acid 7-10 parts.
  2. 2. spinning sizing agent according to claim 1, it is characterised in that：Also include the polyacrylate of 5 parts by weight.
CN201710658842.XA 2017-08-04 2017-08-04 A kind of spinning sizing agent Pending CN107503139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710658842.XA CN107503139A (en) 2017-08-04 2017-08-04 A kind of spinning sizing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710658842.XA CN107503139A (en) 2017-08-04 2017-08-04 A kind of spinning sizing agent

Publications (1)

Publication Number Publication Date
CN107503139A true CN107503139A (en) 2017-12-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710658842.XA Pending CN107503139A (en) 2017-08-04 2017-08-04 A kind of spinning sizing agent

Country Status (1)

Country Link
CN (1) CN107503139A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110424159A (en) * 2019-07-10 2019-11-08 南通缘喜纺织品有限公司 A kind of spinning sizing agent and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110424159A (en) * 2019-07-10 2019-11-08 南通缘喜纺织品有限公司 A kind of spinning sizing agent and preparation method thereof

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Application publication date: 20171222

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