CN107502808A - A kind of complete pre-alloyed diamond tool tyre case powder - Google Patents

A kind of complete pre-alloyed diamond tool tyre case powder Download PDF

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Publication number
CN107502808A
CN107502808A CN201710630150.4A CN201710630150A CN107502808A CN 107502808 A CN107502808 A CN 107502808A CN 201710630150 A CN201710630150 A CN 201710630150A CN 107502808 A CN107502808 A CN 107502808A
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CN
China
Prior art keywords
powder
diamond tool
complete pre
tyre case
alloyed
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710630150.4A
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Chinese (zh)
Inventor
陈政伟
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Yiwu Tairong Diamond & Tools Co Ltd
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Yiwu Tairong Diamond & Tools Co Ltd
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Priority to CN201710630150.4A priority Critical patent/CN107502808A/en
Publication of CN107502808A publication Critical patent/CN107502808A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • B22F1/0003
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/04Alloys containing less than 50% by weight of each constituent containing tin or lead
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0052Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The present invention relates to a kind of complete pre-alloyed diamond tool tyre case powder, each raw material is respectively the carcass powder by weight percentage:Copper 42 48%, tin 3 8%, iron 26.2 34.7%, chromium 5 7%, nickel 4 7%, titanium carbide 5 9% and rare earth element 0.3 0.8%.Prealloyed carcass powder of the present invention composition based on copper, iron, simultaneously by proportioning addition tin, nickel and tungsten carbide, various ingredients metal, which mutually acts synergistically, reduces sintering temperature, alloy flowability improves, carcass strength and hardness increase after sintering, mechanical performance is improved, strengthens wearability and the hold to diamond;Rare earth element is added in Prealloyed carcass powder composition of the present invention, the reducing metal oxide on surface in sintering process, oxide-film is reduced to the obstacle of atoms permeating, acceleration of sintering process, plays a part of activated sintering and similar pre-oxidation sintering.

Description

A kind of complete pre-alloyed diamond tool tyre case powder
Technical field
The present invention relates to a kind of metallurgical powder, is particularly used for the complete pre-alloyed Buddha's warrior attendant lapicide for manufacturing diamond tool Have carcass powder, belong to powdered metallurgical material technical field.
Background technology
As industry competition aggravates, the industry such as stone material, ceramics, engineering construction is to reducing cost, carrying efficient requirement day Beneficial strong, domestic and international market rises rapidly to the demand of high-performance diamond instrument.Generally manufacturing the method for diamond tool is First diamond is mixed with metal dust, then by this mixture cold-press moulding, repressurization or be not pressurized sinters into closely solid Caking.Wherein, metal dust holds diamond as cutter carcass binding agent, and the factor such as its material composition and granularity can be to Buddha's warrior attendant Stone cutting performance produces material impact.
Artificial diamond tool is widely used in the drilling of geological drilling and hard brittle material, cutting, grinding, polishing etc. Processing.Need that the diamond tool product with definite shape and mechanical performance is made using carcass material auxiliary.Carcass material Effect be to support and hold diamond, maintain sharp ability, prevent diamond from coming off too early.Traditional carcass material is by list Elemental metal powders or single alloy powder carry out mechanical mixture acquisition, and the carcass sintering temperature that this method obtains is higher, stably The abundant alloying poor, that each composition can not be reached of property and matrix composition is also difficult to uniformly, it is poor to the hold of diamond etc. Many unfavorable factors.
Usually require that metal dust there should be good sintering reaction activity.Good sintering reaction activity means metal Powder can sinter at relatively low temperature to be reached solid density and only needs very short sintering close to solid density, or sintering Time.High sintering temperature can cause following major defect:Sintering mold service life reduction, damnification of diamond grits and higher energy consumption. It should be no more than 850 DEG C to give full play to the superior function of diamond its carcass maximum sintering temperature.Carcass sintering is completed can use To relative density characterize:In general, relative sintered density reaches 98% or more and can be considered as close to solid density.Shadow The primary factor for ringing sintering tyre-e/or performance is the composition of powder.Selection powdered ingredients will be not only considered to sintered body performance, especially It is the requirement of the hold to diamond, toughness and wearability, and takes into account cost factor.Influence the second of tyre-e/or performance Individual key factor is the grain size proportion of powder, and in the case of other conditions identical, the sintering activity of thinner powder is substantially excellent In thicker powder.Another factor is exactly the oxidation on powder surface, and because powder size is thin, surface-active is high, is exposed to It in air, will be easy to aoxidize, so as to form oxide skin(coating) in powder particle surface, and then prevent entering for sintering reaction OK, thus reduce powder sintering reaction activity.
Carcass material uses metal simple-substance powder and part pre-alloyed powder more in the prior art, so being wrapped in carcass powder Contain the various elements of composition carcass, reduced fusing point and easy-sintering, there can be the efficiency for playing diamond.
The content of the invention
It is an object of the invention to each composition proportion and diamond wear resistance ratio are uncoordinated in prior carcass material in order to solve, And matrix composition is uneven, less stable, sintering temperature is higher, it is weaker to diamond hold the defects of and provide a kind of complete Pre-alloyed diamond tool tyre case powder.
To achieve these goals, the present invention uses following technical scheme:
A kind of complete pre-alloyed diamond tool tyre case powder, each raw material is respectively the carcass powder by weight percentage:Copper 42-48%, tin 3-8%, iron 26.2-34.7%, chromium 5-7%, nickel 4-7%, titanium carbide 5-9% and rare earth element 0.3-0.8%. In the technical program, add a small amount of rare earth element can refine carcass crystal grain, activated sintering, improve carcass bending strength, Diamond is held in holding, etc. mechanical performance and is improved the height of protrusion of diamond and is improved the self-sharpening of diamond tool, cutting Efficiency and improve diamond utilization rate, can also in sintering process reducing metal oxide on surface, reduce oxide-film to atom The obstacle of diffusion, activated sintering process is promoted, play a part of fully effectively holding diamond.
Preferably, the titanium carbide granularity is -200 mesh, purity is more than 99%.
Preferably, electrolysis copper ingot purity >=99%.
Preferably, the powder size of iron is -200 mesh, active ingredient percentage by weight >=98.7%, apparent density is 2.0-2.6g/cm3
Preferably, tin slab purity >=99%.
Preferably, chromium >=50%~70% in ferrochrome.
Preferably, the powder size of nickel is -200 mesh, and active ingredient percentage by weight >=98%, apparent density 2.0- 2.6g/cm3
Preferably, the rare earth element is ytterbium or praseodymium.
Preferably, the preparation method of the complete pre-alloyed diamond tool tyre case powder is:First will electrolysis copper ingot and Tin slab carries out high-temperature vacuum melting, 1080-1120 DEG C of temperature, time 15min, adds other each components, is during which sufficiently stirred Uniformly, be allowed to abundant alloying, alloy liquid, which by graphite flows backwards mouth, to carry out atomization and dusts, carried out after powder cooling receipts powder, Drying, obtain complete pre-alloyed diamond tool tyre case powder.
Beneficial effects of the present invention:Compared with prior art, it is an advantage of the invention that:
First, Prealloyed carcass powder of the present invention composition based on copper, tin, while by proportioning addition iron powder, chromium powder, nickel powder and Carbonized titanium powder, the method for this " ingot and powder " " mixed smelting ", considerably reduces the temperature of melting powder, carries to greatest extent High production efficiency, significantly saves the energy, carcass strength and toughness increase after sintering, improves mechanical performance,
Second, Prealloyed carcass powder of the present invention adds rare earth element in forming, the reducing metal surface oxidation in sintering process Thing, compatibility of the alloy to diamond surface is improved, add hold of the alloy carcass to diamond.
3rd, the uniformity and stability of sintering metal carcass are significantly improved, significantly reduces the mixing time of powder, Follow-up tool production efficiency is significantly improved, the energy consumption of tool production is greatly saved,
Improve the stability of instrument quality.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention, after the present invention has been read, various equivalences of the those skilled in the art to the present invention The modification of form falls within the application appended claims limited range.
Titanium carbide granularity is -200 mesh, and purity is more than 99%.
It is electrolysed copper ingot purity >=99%.
The powder size of iron is -200 mesh, active ingredient percentage by weight >=98.7%, apparent density 2.0-2.6g/ cm3
Tin slab purity >=99%.
Chromium >=50%~70% in ferrochrome.
The powder size of nickel is -200 mesh, active ingredient percentage by weight >=98%, apparent density 2.0-2.6g/cm3
Embodiment 1
A kind of complete pre-alloyed diamond tool tyre case powder, each raw material is respectively the carcass powder by weight percentage:Copper 42%th, tin 8%, iron 26.2%, chromium 7%, nickel 7%, titanium carbide 9% and rare earth element 0.8%.
The rare earth element is ytterbium or praseodymium.
The preparation method of the complete pre-alloyed diamond tool tyre case powder is:First will electrolysis copper ingot and tin slab progress height Warm vacuum melting, 1080 DEG C of temperature, time 15min, adds other each components, during which stirs, and is allowed to fully close Aurification, alloy liquid carry out atomization by graphite refluence mouth and dusted, and receipts powder, drying are carried out after powder cooling, obtains complete pre- conjunction The diamond tool tyre case powder of aurification.
Embodiment 2
A kind of complete pre-alloyed diamond tool tyre case powder, each raw material is respectively the carcass powder by weight percentage:Copper 45%th, tin 5%, iron 32.5%, chromium 6%, nickel 5%, titanium carbide 6% and rare earth element 0.5%.
The rare earth element is ytterbium or praseodymium.
The preparation method of the complete pre-alloyed diamond tool tyre case powder is:First will electrolysis copper ingot and tin slab progress height Warm vacuum melting, 1100 DEG C of temperature, time 15min, adds other each components, during which stirs, and is allowed to fully close Aurification, alloy liquid carry out atomization by graphite refluence mouth and dusted, and receipts powder, drying are carried out after powder cooling, obtains complete pre- conjunction The diamond tool tyre case powder of aurification.
Embodiment 3
A kind of complete pre-alloyed diamond tool tyre case powder, each raw material is respectively the carcass powder by weight percentage:Copper 48%th, tin 3%, iron 34.7%, chromium 5%, nickel 4%, titanium carbide 5% and rare earth element 0.3%.
The rare earth element is ytterbium or praseodymium.
The preparation method of the complete pre-alloyed diamond tool tyre case powder is:First will electrolysis copper ingot and tin slab progress height Warm vacuum melting, 1120 DEG C of temperature, time 15min, adds other each components, during which stirs, and is allowed to fully close Aurification, alloy liquid carry out atomization by graphite refluence mouth and dusted, and receipts powder, drying are carried out after powder cooling, obtains complete pre- conjunction The diamond tool tyre case powder of aurification.
Full Prealloyed carcass powder prepared by the embodiment of the present invention 2 is placed in the graphite that size is 30mm × 12mm × 6mm In mould, pressure 10MPa, sintered 3 minutes in different temperature, determine the relative density of agglomerate, the results are shown in Table 1.
The relative density of table 1, sintered powder
Sintering temperature 750℃ 810℃ 820℃ 830℃ 850℃ 870℃
Relative density (%) 97.8 99.1 99.4 99.2 97.8 97.8
The above results show that the powder can obtain higher sintered density at a relatively low sintering temperature, and optimization sintering temperature is 810~830 DEG C, relative density no longer improves after sintering temperature is more than 830 DEG C.
Measuring Mechanical Properties:
Determination of Hardness:Prealloyed carcass powder prepared by the embodiment of the present invention 2 is placed in the stone that size is 30mm × 12mm × 6mm In black mould, pressure 10MPa, sintered 3 minutes in different temperature, determine the HRB hardness of agglomerate, as a result see table 2.
The hardness of the sintered powder of table 2
Sintering temperature 750℃ 810℃ 820℃ 830℃ 850℃ 870℃
Hardness (HRB) 35.5 51.5 53.4 52.5 48.3 48.1
From table 2, powder hardness when sintering for 820 DEG C reaches maximum, and optimization sintering temperature is 810~830 DEG C, this As a result it is consistent with the agglomerate relative density variation with temperature rule of table 1.
Anti-reflecting bending strength determining:Prealloyed carcass powder prepared by the embodiment of the present invention 2 is placed in 30mm × 12mm × 6mm's Agglomerate is placed directly on two bearings for being separated by 25.4mm, is exerted a force therebetween, until sample fracture, as a result sees table 3.
The bending strength of the sintered powder of table 3
From table 3, when sintering temperature is 810~830 DEG C, bending strength reaches more than 403MPa, illustrates that the powder has Good sintering process, higher bending strength can be obtained in wider sintering range.

Claims (9)

1. a kind of complete pre-alloyed diamond tool tyre case powder, it is characterised in that the carcass powder is each by weight percentage Raw material is respectively:Copper 42-48%, tin 3-8%, iron 26.2-34.7%, chromium 5-7%, nickel 4-7%, titanium carbide 5-9% and rare earth Element 0.3-0.8%.
A kind of 2. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that the carbonization Titanium granularity is -200 mesh, and purity is more than 99%.
A kind of 3. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that electrolysis copper ingot Purity >=99%.
A kind of 4. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that the powder of iron Granularity is -200 mesh, active ingredient percentage by weight >=98.7%, apparent density 2.0-2.6g/cm3
A kind of 5. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that tin slab purity >=99%.
A kind of 6. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that ferrochrome Middle chromium >=50%~70%.
A kind of 7. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that the powder of nickel Granularity is -200 mesh, active ingredient percentage by weight >=98%, apparent density 2.0-2.6g/cm3
A kind of 8. complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that the rare earth Element is ytterbium or praseodymium.
9. a kind of complete pre-alloyed diamond tool tyre case powder according to claim 1, it is characterised in that described complete pre- The preparation method of the diamond tool tyre case powder of alloying is:Copper ingot first will be electrolysed and tin slab carries out high-temperature vacuum melting, temperature 1080-1120 DEG C, time 15min, other each components are added, are during which stirred, be allowed to abundant alloying, aluminium alloy Body carries out atomization by graphite refluence mouth and dusted, and receipts powder, drying are carried out after powder cooling, obtains complete pre-alloyed diamond Tool tyre case powder.
CN201710630150.4A 2017-07-28 2017-07-28 A kind of complete pre-alloyed diamond tool tyre case powder Pending CN107502808A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113524052A (en) * 2021-07-28 2021-10-22 惠州捷姆复合材料有限公司 Metal bond sintered diamond grinding wheel and preparation method thereof
CN116079048A (en) * 2023-03-09 2023-05-09 东莞市华冠新材料科技有限公司 Grinding body capable of improving wear resistance and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01255631A (en) * 1988-04-06 1989-10-12 Isamu Kikuchi Sintered alloy material and its manufacture
JPH111736A (en) * 1997-06-09 1999-01-06 Chuetsu Gokin Chuko Kk Brass alloy material for heating device
CN101407045A (en) * 2008-11-25 2009-04-15 北京科技大学 Diamond grinding block and preparation thereof
CN103266258A (en) * 2013-05-20 2013-08-28 江苏锋泰钻石工具制造有限公司 Rare earth prealloyed powder and preparation method thereof
CN105441815A (en) * 2015-03-13 2016-03-30 泉州天智合金材料科技有限公司 Preparation method for modified superfine low-oxygen water-atomized alloy powder used for diamond tool

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01255631A (en) * 1988-04-06 1989-10-12 Isamu Kikuchi Sintered alloy material and its manufacture
JPH111736A (en) * 1997-06-09 1999-01-06 Chuetsu Gokin Chuko Kk Brass alloy material for heating device
CN101407045A (en) * 2008-11-25 2009-04-15 北京科技大学 Diamond grinding block and preparation thereof
CN103266258A (en) * 2013-05-20 2013-08-28 江苏锋泰钻石工具制造有限公司 Rare earth prealloyed powder and preparation method thereof
CN105441815A (en) * 2015-03-13 2016-03-30 泉州天智合金材料科技有限公司 Preparation method for modified superfine low-oxygen water-atomized alloy powder used for diamond tool

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113524052A (en) * 2021-07-28 2021-10-22 惠州捷姆复合材料有限公司 Metal bond sintered diamond grinding wheel and preparation method thereof
CN113524052B (en) * 2021-07-28 2022-03-04 惠州捷姆复合材料有限公司 Metal bond sintered diamond grinding wheel and preparation method thereof
CN116079048A (en) * 2023-03-09 2023-05-09 东莞市华冠新材料科技有限公司 Grinding body capable of improving wear resistance and preparation method thereof

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