CN107502215A - A kind of TPO waterproof rolls with heat insulating function and preparation method thereof - Google Patents
A kind of TPO waterproof rolls with heat insulating function and preparation method thereof Download PDFInfo
- Publication number
- CN107502215A CN107502215A CN201710795532.2A CN201710795532A CN107502215A CN 107502215 A CN107502215 A CN 107502215A CN 201710795532 A CN201710795532 A CN 201710795532A CN 107502215 A CN107502215 A CN 107502215A
- Authority
- CN
- China
- Prior art keywords
- tpo
- layer
- waterproof rolls
- heat insulating
- blanket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000010410 layer Substances 0.000 claims abstract description 116
- 239000004831 Hot glue Substances 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000000835 fiber Substances 0.000 claims description 20
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- 239000003292 glue Substances 0.000 claims description 17
- 238000004026 adhesive bonding Methods 0.000 claims description 14
- 230000004888 barrier function Effects 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- 229920002943 EPDM rubber Polymers 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 239000012943 hotmelt Substances 0.000 claims description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 238000013329 compounding Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000005304 joining Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 9
- 239000003963 antioxidant agent Substances 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 7
- 239000004814 polyurethane Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- -1 Attagel Chemical compound 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000004595 color masterbatch Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005439 thermosphere Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/045—Presence of homo or copolymers of ethene in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/005—Presence of polyester in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of TPO waterproof rolls with heat insulating function and preparation method thereof.The TPO waterproof rolls include TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer, lower hot melt adhesive layer and the separating film layer being arranged in order.Also disclose that a kind of preparation method of the TPO waterproof rolls with heat insulating function simultaneously.The present invention combines the heat insulating function of viscous blanket and TPO water-proof function together, obtained TPO waterproof rolls are reasonable in design, and structure is novel, convenient construction, operating expenses can be saved and construction speed can be greatly speeded up, suitable for being promoted the use of a large area on single-ply roofing system.
Description
Technical field
The present invention relates to a kind of TPO waterproof rolls with heat insulating function and preparation method thereof.
Background technology
At present, single-ply roofing system China is newly-built and reconstruction heavy construction in using increasingly wider, single-layer roof is main
Using TPO material, this is a kind of waterproof material of superior performance.In order to heat-insulated, generally constructed again below TPO coiled materials one layer every
Thermosphere, to reach the energy-saving effect of requirement of engineering.
Because heat-barrier material and waterproof material are only merely single function material, step-by-step construction, after heat-barrier material of having constructed,
One layer of cement mortar is coated above as protective layer, be easily damaged during subsequent construction, and it is loaded down with trivial details to construct, the engineering time is longer,
Expense is also high.
The content of the invention
It is an object of the invention to provide a kind of TPO waterproof rolls with heat insulating function and preparation method thereof.
The technical solution used in the present invention is：
A kind of TPO waterproof rolls with heat insulating function, including the TPO material layer, upper hot melt adhesive layer, heat-insulated being arranged in order
Viscous blanket layer, lower hot melt adhesive layer and separating film layer.
Further, the thickness ratio of TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer, lower hot melt adhesive layer and separating film layer
For (1.0~1.5)：(0.3~0.5)：(2.0~4.0)：(0.3~0.5)：(0.02~0.03).
Further, TPO material layer is that homogeneous TPO waterproof rolls layer or grid cloth strengthen TPO waterproof roll layers.
Further, upper hot melt adhesive layer and lower hot melt adhesive layer are polyurethane-hot melt glue-line, EVA hot-melt adhesive layer, butyl heat
One of which in melt layer or reaction joining type hot melt adhesive layer.
Further, heat-insulated viscous blanket layer is that alumina silicate fibre glues blanket layer.
Further, separating film layer is PE separating film layers or PET separating film layers.
A kind of preparation method of the TPO waterproof rolls with heat insulating function, comprises the following steps：
1) take PE barrier films or the PET barrier films of one side painting silicone oil standby；
2) ethylene propylene diene rubber, acrylic resin, filler, Masterbatch and auxiliary agent mixing are taken, is then extruded in an extruder,
It is standby to obtain TPO sheet materials；
3) alumina silicate fibre is glued blanket and puts glue spreader into, carry out front-back two-sided gluing by PUR after the melting of melten gel device,
The alumina silicate fibre for obtaining gluing glues blanket；
4) the TPO sheet materials that the barrier film and step 2) prepared step 1) prepares glue blanket with the alumina silicate fibre of gluing respectively
Obverse and reverse carried out in double roller compounding machine it is compound, obtain being arranged in order TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer,
The TPO waterproof rolls of lower hot melt adhesive layer and separating film layer.
Further, in step 2), ethylene propylene diene rubber, acrylic resin, filler, the mass ratio of Masterbatch and auxiliary agent are
(30~40)：(50~60)：(5~15)：(0.1~1)：(0.1~1).
Further, in step 2), the screw temperature set of extruder is：160 DEG C~180 DEG C of feeding section, fluxing zone 180
DEG C~200 DEG C, 190 DEG C~220 DEG C of metering section, 180 DEG C~200 DEG C of die temperature；40~50 revs/min of screw speed.
Further, in step 3), alumina silicate fibre glues thermal conductivity factor≤0.025w/mK of blanket.
The beneficial effects of the invention are as follows：
The present invention combines the heat insulating function of viscous blanket and TPO water-proof function together, and obtained TPO waterproof rolls design is closed
Reason, structure is novel, convenient construction, can save operating expenses and can greatly speed up construction speed, suitable in single-layer roof
Promoted the use of a large area in system.
Brief description of the drawings
Fig. 1 is the TPO waterproof roll cross section structure schematic diagrams of the present invention.
Embodiment
A kind of TPO waterproof rolls with heat insulating function, including the TPO material layer, upper hot melt adhesive layer, heat-insulated being arranged in order
Viscous blanket layer, lower hot melt adhesive layer and separating film layer.
Further, the thickness ratio of TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer, lower hot melt adhesive layer and separating film layer
For (1.0~1.5)：(0.3~0.5)：(2.0~4.0)：(0.3~0.5)：(0.02~0.03).
Further, TPO material layer is that homogeneous TPO waterproof rolls layer or grid cloth strengthen TPO waterproof roll layers.It is preferred that
, described grid cloth enhancing TPO waterproof rolls layer is that polyester fiber grid cloth strengthens TPO waterproof roll layers.
Further, upper hot melt adhesive layer and lower hot melt adhesive layer are phase same material, are selected from polyurethane-hot melt glue-line, EVA heat
One of which in melt layer, butyl hot-melt glue-line or reaction joining type hot melt adhesive layer.
Further, heat-insulated viscous blanket layer is that alumina silicate fibre glues blanket layer.
Further, separating film layer is PE separating film layers or PET separating film layers.
A kind of preparation method of the TPO waterproof rolls with heat insulating function, comprises the following steps：
1) take PE barrier films or the PET barrier films of one side painting silicone oil standby；
2) ethylene propylene diene rubber, acrylic resin, filler, Masterbatch and auxiliary agent mixing are taken, is then extruded in an extruder,
It is standby to obtain TPO sheet materials；
3) alumina silicate fibre is glued blanket and puts glue spreader into, carry out front-back two-sided gluing by PUR after the melting of melten gel device,
The alumina silicate fibre for obtaining gluing glues blanket；
4) the TPO sheet materials that the barrier film and step 2) prepared step 1) prepares glue blanket with the alumina silicate fibre of gluing respectively
Obverse and reverse carried out in double roller compounding machine it is compound, obtain being arranged in order TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer,
The TPO waterproof rolls of lower hot melt adhesive layer and separating film layer.
Further, in step 2), ethylene propylene diene rubber, acrylic resin, filler, the mass ratio of Masterbatch and auxiliary agent are
(30~40)：(50~60)：(5~15)：(0.1~1)：(0.1~1).
Further, filler is selected from aluminum oxide, aluminium borate, magnesia, magnesium hydroxide, sodium antimonate, antimony trioxide, sulfuric acid
It is barium, barium titanate, barium metaborate, boron oxide, zinc sulphide, Firebrake ZB, calcium carbonate, calcium hydroxide, calcium sulfate, afwillite, white
Carbon black, apatite, feldspar, float stone, lardite, zeolite, sepiolite, silica gel, clay, Attagel, bentonite, diatomite, kaolin,
At least one of montmorillonite, talcum powder, mica powder.
Further, auxiliary agent is at least one of antioxidant, light stabilizer.
Further, described antioxidant is Hinered phenols antioxidant, phosphite ester kind antioxidant, thio esters antioxygen
At least one of agent, composite antioxidant.
Further, described light stabilizer is benzophenone, benzotriazole, salicylic acid esters, triazines, taken
For at least one of vinyl cyanide, hindered amine light stabilizer.
Further, in step 2), the screw temperature set of extruder is：160 DEG C~180 DEG C of feeding section, fluxing zone 180
DEG C~200 DEG C, 190 DEG C~220 DEG C of metering section, 180 DEG C~200 DEG C of die temperature；40~50 revs/min of screw speed.
Further, in step 3), alumina silicate fibre glues thermal conductivity factor≤0.025w/mK of blanket；Preferably, step 3)
In, the thermal conductivity factor that alumina silicate fibre glues blanket is 0.02w/mK.
Present disclosure is described in further detail below by way of specific embodiment.
Embodiment：
Accompanying drawing 1 for the present invention TPO waterproof roll cross section structure schematic diagrams, in Fig. 1,1- separating film layers, PUR under 2-
Layer, the heat-insulated viscous blanket layer of 3-, the upper hot melt adhesive layers of 4-, 5-TPO material layers.The TPO waterproof rolls of the present invention are entered to advance with reference to accompanying drawing 1
The explanation of one step.The TPO waterproof rolls are arranged in order TPO material layer (5), upper hot melt adhesive layer (4), heat-insulated viscous blanket from top to bottom
Layer (3), lower hot melt adhesive layer (2) and separating film layer (1)；The TPO material layer (5), heat-insulated viscous blanket layer (3) and separating film layer (1)
It is gluing using PUR respectively and be pressed in one；At least side of the hot melt adhesive layer contacted with separating film layer is provided with certain
The overlapping part of width.
The specific preparation method of TPO waterproof rolls of the present invention is as follows：
First step：Take PE barrier films or the PET barrier films of one side painting silicone oil standby；
Second step：Take the mass parts of ethylene propylene diene rubber 35, the mass parts of acrylic resin 57, the mass parts of talcum powder 8, color masterbatch
0.1 mass parts of grain, the mass parts of antioxidant 0.1, it is sent into batch mixer and is premixed, is then fed into barrel, the screw rod temperature of extruder
Degree setting：160 DEG C~180 DEG C of feeding section, 180 DEG C~200 DEG C of fluxing zone, 190 DEG C~220 DEG C of metering section, 180 DEG C of die temperature
~200 DEG C, the TPO sheet materials of 40~50 revs/min of screw speed, on this condition extrusion calendaring thickness 2mm are standby；
Third step：Take polyurethane hot melt to put melten gel device into, heating melting, take alumina silicate fibre to glue blanket and put gluing into
Machine, carry out double spread；The TPO coiled materials and the alumina silicate of gluing that the barrier film and second step that first step is prepared again prepare
The tow sides that fiber glues blanket are compound in the progress of double roller compounding machine respectively；Obtain by be arranged in order TPO material layer (5), upper heat
What melt layer (4), heat-insulated viscous blanket layer (3), lower hot melt adhesive layer (2) and separating film layer (1) were combined into one has heat insulating function
TPO waterproof rolls.
Four steps：The TPO waterproof rolls with heat insulating function being combined into one carry out air-cooled cooling and shaping, cutting,
Batch, detect, packaging and storage.
In embodiment, antioxidant used is irgasfos 168 and antioxidant 1010 with mass ratio 1:The compounding antioxygen of 1 combination
Agent, the thermal conductivity factor that alumina silicate fibre glues blanket is 0.02w/mK, the TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer,
The thickness ratio of lower hot melt adhesive layer and separating film layer is 1.0:0.4:3:0.4:0.02.
A kind of TPO waterproof rolls with heat insulating function of the present invention, reasonable in design, structure is novel, by the heat-insulated work(of viscous blanket
It can be combined together with TPO water-proof function, facilitate construction, save operating expenses and construction speed can be greatly speeded up, fit
For being promoted the use of a large area on single-ply roofing system.TPO waterproof rolls of the present invention are by extrusion, gluing, laying isolation
Film layer, compound one-shot forming, preparation method is simple and convenient, suitable for large-scale production application.
Claims (10)
- A kind of 1. TPO waterproof rolls with heat insulating function, it is characterised in that：Including TPO material layer, the upper hot melt being arranged in order Glue-line, heat-insulated viscous blanket layer, lower hot melt adhesive layer and separating film layer.
- A kind of 2. TPO waterproof rolls with heat insulating function according to claim 1, it is characterised in that：TPO material layer, Upper hot melt adhesive layer, heat-insulated viscous blanket layer, the thickness ratio of lower hot melt adhesive layer and separating film layer are (1.0~1.5)：(0.3~0.5)： (2.0~4.0)：(0.3~0.5)：(0.02~0.03).
- A kind of 3. TPO waterproof rolls with heat insulating function according to claim 2, it is characterised in that：TPO material layer is Homogeneous TPO waterproof rolls layer or grid cloth enhancing TPO waterproof roll layers.
- A kind of 4. TPO waterproof rolls with heat insulating function according to claim 2, it is characterised in that：Upper hot melt adhesive layer It is in polyurethane-hot melt glue-line, EVA hot-melt adhesive layer, butyl hot-melt glue-line or reaction joining type hot melt adhesive layer with lower hot melt adhesive layer One of which.
- A kind of 5. TPO waterproof rolls with heat insulating function according to claim 2, it is characterised in that：Heat-insulated viscous blanket layer Blanket layer is glued for alumina silicate fibre.
- A kind of 6. TPO waterproof rolls with heat insulating function according to claim 2, it is characterised in that：Separating film layer is PE separating film layers or PET separating film layers.
- A kind of 7. preparation method of the TPO waterproof rolls with heat insulating function, it is characterised in that：Comprise the following steps：1) take PE barrier films or the PET barrier films of one side painting silicone oil standby；2) ethylene propylene diene rubber, acrylic resin, filler, Masterbatch and auxiliary agent mixing are taken, then extrudes, obtains in an extruder TPO sheet materials are standby；3) alumina silicate fibre is glued blanket and puts glue spreader into, carried out front-back two-sided gluing, obtain by PUR after the melting of melten gel device The alumina silicate fibre of gluing glues blanket；4) the TPO sheet materials that the barrier film and step 2) prepared step 1) prepares are gluing blanket just with the alumina silicate fibre of gluing respectively Face and reverse side are compound in the progress of double roller compounding machine, obtain being arranged in order TPO material layer, upper hot melt adhesive layer, heat-insulated viscous blanket layer, lower heat The TPO waterproof rolls of melt layer and separating film layer.
- A kind of 8. preparation method of TPO waterproof rolls with heat insulating function according to claim 7, it is characterised in that： In step 2), ethylene propylene diene rubber, acrylic resin, filler, the mass ratio of Masterbatch and auxiliary agent are (30~40)：(50~ 60)：(5~15)：(0.1~1)：(0.1~1).
- A kind of 9. preparation method of TPO waterproof rolls with heat insulating function according to claim 7, it is characterised in that： In step 2), the screw temperature set of extruder is：160 DEG C~180 DEG C of feeding section, 180 DEG C~200 DEG C of fluxing zone, metering section 190 DEG C~220 DEG C, 180 DEG C~200 DEG C of die temperature；40~50 revs/min of screw speed.
- A kind of 10. preparation method of TPO waterproof rolls with heat insulating function according to claim 7, it is characterised in that： In step 3), alumina silicate fibre glues thermal conductivity factor≤0.025w/mK of blanket.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710795532.2A CN107502215A (en) | 2017-09-06 | 2017-09-06 | A kind of TPO waterproof rolls with heat insulating function and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710795532.2A CN107502215A (en) | 2017-09-06 | 2017-09-06 | A kind of TPO waterproof rolls with heat insulating function and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502215A true CN107502215A (en) | 2017-12-22 |
Family
ID=60695961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710795532.2A Pending CN107502215A (en) | 2017-09-06 | 2017-09-06 | A kind of TPO waterproof rolls with heat insulating function and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502215A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108952205A (en) * | 2018-09-04 | 2018-12-07 | 上海市房地产科学研究院（上海市住宅修缮工程质量检测中心） | A kind of thermal-insulating waterproof composite sheet material and preparation method suitable for roofing transformation |
| CN110576661A (en) * | 2019-09-02 | 2019-12-17 | 杭州金凯包装材料有限公司 | coiled material with good heat insulation, water resistance and corrosion resistance |
| CN112852358A (en) * | 2019-11-12 | 2021-05-28 | 诚泰工业科技股份有限公司 | Formula of environment-friendly waterproof hot melt adhesive, film sheet thereof and production process |
| CN112982845A (en) * | 2021-05-20 | 2021-06-18 | 中铁建工集团有限公司 | Construction method of metal roof system for improving wind resistance |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07247795A (en) * | 1994-03-03 | 1995-09-26 | Daiken Sangyo Kk | Coating method and structure of tunnel waterproof sheet for spraying heat-insulating material |
| CN101788096A (en) * | 2010-01-22 | 2010-07-28 | 刘礼龙 | Nano heat insulating blanket and production method thereof |
| CN202117239U (en) * | 2011-05-20 | 2012-01-18 | 深圳市卓宝科技股份有限公司 | Self-adhesion waterproof material for roofing |
| CN205395315U (en) * | 2016-03-04 | 2016-07-27 | 兰溪市天信新型建材有限公司 | Special twins base waterproofing membrane is construct to underground |
-
2017
- 2017-09-06 CN CN201710795532.2A patent/CN107502215A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07247795A (en) * | 1994-03-03 | 1995-09-26 | Daiken Sangyo Kk | Coating method and structure of tunnel waterproof sheet for spraying heat-insulating material |
| CN101788096A (en) * | 2010-01-22 | 2010-07-28 | 刘礼龙 | Nano heat insulating blanket and production method thereof |
| CN202117239U (en) * | 2011-05-20 | 2012-01-18 | 深圳市卓宝科技股份有限公司 | Self-adhesion waterproof material for roofing |
| CN205395315U (en) * | 2016-03-04 | 2016-07-27 | 兰溪市天信新型建材有限公司 | Special twins base waterproofing membrane is construct to underground |
Non-Patent Citations (1)
| Title |
|---|
| 邓钫印: "《建筑工程防水材料手册》", 30 September 1994, 中国建筑工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108952205A (en) * | 2018-09-04 | 2018-12-07 | 上海市房地产科学研究院（上海市住宅修缮工程质量检测中心） | A kind of thermal-insulating waterproof composite sheet material and preparation method suitable for roofing transformation |
| CN110576661A (en) * | 2019-09-02 | 2019-12-17 | 杭州金凯包装材料有限公司 | coiled material with good heat insulation, water resistance and corrosion resistance |
| CN112852358A (en) * | 2019-11-12 | 2021-05-28 | 诚泰工业科技股份有限公司 | Formula of environment-friendly waterproof hot melt adhesive, film sheet thereof and production process |
| CN112982845A (en) * | 2021-05-20 | 2021-06-18 | 中铁建工集团有限公司 | Construction method of metal roof system for improving wind resistance |
| CN112982845B (en) * | 2021-05-20 | 2021-08-20 | 中铁建工集团有限公司 | Construction method of metal roof system for improving wind resistance |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107502215A (en) | A kind of TPO waterproof rolls with heat insulating function and preparation method thereof | |
| CN103772894B (en) | A kind of Wood plastic composite and preparation method thereof | |
| KR101463721B1 (en) | Multi-Plate Complex Sheet with Waterproof, Root Barrier and Adhesive Condition and Construction Method Thereof | |
| SE441375C (en) | HEAT-INSULATING AND WATER TENT, BITUMINO'S DISC | |
| KR101484093B1 (en) | Integral Type Color Sheet for Waterproof and Root Barrier Using PVC Sheet and Adhesive and the Construction Method Thereof | |
| CN101550729A (en) | Asphalt modified thermoplastic polyolefin water-proof coiled material and preparation method thereof | |
| US20140363645A1 (en) | Multilayered product for joint utilization of smc, bmc and pet waste | |
| CN108239319A (en) | Continuous fiber reinforced thermoplastic resin prepreg tape and grid and preparation method thereof | |
| CN103291068A (en) | High-strength, high-tenacity and high-hardness plastic building template and producing method thereof | |
| CN102444056A (en) | Five-layer resolvable or degradable environmental friendly paper and production method thereof | |
| CN105238347B (en) | A kind of self-adhesive, FPF high-polymer self-adhesion waterproof coiled materials and manufacturing process | |
| CN107910087A (en) | Radiation protection hard material and preparation method and application | |
| RU2607653C2 (en) | Composite profile and preparation method thereof | |
| CN101486326A (en) | Double-layer shock-absorbing damping plate for automobile and production method thereof | |
| WO2016112554A1 (en) | Wood-plastic composite decorative panel and manufacturing method thereof | |
| CN106894611A (en) | A kind of stone-plastic plate and preparation method thereof | |
| CN103832027B (en) | It is a kind of by rubber, plastic foil, chemical fabric composite waterproof sheet product | |
| CN100567445C (en) | The manufacture method of a kind of thermoplastic polyolefin water-proof coiled material and substrate thereof | |
| CN106009270A (en) | Novel foamed wood-plastic wallboard and preparation method thereof | |
| CN207362130U (en) | A kind of TPO waterproof rolls with heat insulating function | |
| CN109971074B (en) | Multilayer co-extrusion composite hollow glass warm edge spacing bar and preparation method thereof | |
| CN115074048B (en) | Thermosensitive discoloring body reverse-adhesion type TPO (thermoplastic polyolefin) macromolecular waterproof coiled material and preparation method thereof | |
| CN101544090A (en) | Dynamic-vulcanization thermoplastic polyolefine waterproof roll material and preparation method thereof | |
| CN202163067U (en) | Five-layer decomposable or degradable environment-friendly paper | |
| CN1246556C (en) | Waterproof thermal insulative foaming coiled materials |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 513059 Jin Bei Road No. 5, South District of Qingyuan Huaqiao Industrial Park, Qingyuan, Qingyuan, Guangdong Applicant after: DAYU JIUDING NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 513059 Jin Bei Road No. 5, South District of Qingyuan Huaqiao Industrial Park, Qingyuan, Qingyuan, Guangdong Applicant before: GUANGDONG DAYU JIUDING WATERPROOF TECHNOLOGY Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171222 |
|
| WD01 | Invention patent application deemed withdrawn after publication |