WO2016112554A1 - Wood-plastic composite decorative panel and manufacturing method thereof - Google Patents

Wood-plastic composite decorative panel and manufacturing method thereof Download PDF

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Publication number
WO2016112554A1
WO2016112554A1 PCT/CN2015/070955 CN2015070955W WO2016112554A1 WO 2016112554 A1 WO2016112554 A1 WO 2016112554A1 CN 2015070955 W CN2015070955 W CN 2015070955W WO 2016112554 A1 WO2016112554 A1 WO 2016112554A1
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WO
WIPO (PCT)
Prior art keywords
wood
plastic composite
core
decorative
plastic
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PCT/CN2015/070955
Other languages
French (fr)
Chinese (zh)
Inventor
王清文
易欣
王小玉
黄浪
宗广功
陈园
谢延军
于伸
Original Assignee
王清文
易欣
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 王清文, 易欣 filed Critical 王清文
Priority to PCT/CN2015/070955 priority Critical patent/WO2016112554A1/en
Priority to CN201580068278.5A priority patent/CN107428133A/en
Publication of WO2016112554A1 publication Critical patent/WO2016112554A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/305Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/78Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/86Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/08Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse

Definitions

  • the invention relates to a decorative board and a manufacturing method thereof, in particular to a wood plastic composite decorative board and a manufacturing method thereof.
  • a method for manufacturing a wood-plastic composite (WPC) decorative sheet based on extrusion, molding or bonding, and the manufactured sheet has a tendency to creep and warp, resulting in furniture and interior decoration using the decorative panel. Defects in component deformation, poor decorative effect, and high density are too heavy to handle.
  • Most of the solid wood decorative panels in the prior art are subject to the specifications of the materials.
  • the wood-based wood-based panels need to be bonded with a large amount of adhesive on the substrate during the manufacturing process.
  • the adhesive layer is easily exposed to the air. On the one hand, the exposed adhesive layer will continue to pollute the environment with the decomposition and volatilization of the adhesive.
  • the invention solves the problem that the wood plastic composite decorative board is easy to creep, easy to warp and easily deform, and affects the decorative effect, and further proposes a wood plastic composite decorative board and a manufacturing method thereof.
  • the technical proposal adopted by the invention is: using a thermoplastic wood-plastic composite material after being melted and co-extruding with a wood core, and manufacturing a decorative board by a decorative process, the method comprising the steps of preparing a wood core; preparing a thermoplastic wood-plastic composite material mother And melting the wood-plastic composite masterbatch by a co-extrusion device that can feed the wood core, and co-extruding the sheet with the wood core; and performing the b-step extrusion of the sheet a step c of the decorative processing; a step d of cooling the shaped sheet; a step e of cutting the sheet; and a step f of closing the end surface of the sheet in the e step.
  • the wood core By feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, the wood core replaces a part of the wood plastic to reduce the overall density of the decorative board, due to the wood core to the wood-plastic
  • the shortcomings of the wood plastics that are easily creepable are greatly weakened, so that the wood-plastic composite decorative board can be used normally under the condition of a certain temperature difference without being affected by the creep of wood plastic; by co-extrusion and after cutting
  • the end face of the plate block is closed, which can solve the problem that the water molecules in the air enter the glue layer or the wood cells, so that the decorative plate has water resistance, avoiding the problems of cracking, warping, deformation, strength drop and mildew decay of the decorative plate.
  • the production of ordinary wood-plastic composite materials is cooled immediately after extrusion of the sheet material, and then subjected to decorative processing after being cooled, and the present invention is carried out on the sheet material extruded in step b.
  • the decorative processing and cooling of the sheet after the step c of the decorative processing is completed, so that the wood-plastic composite has a longer time for the slow knot after the co-extrusion operation.
  • Fig. 1 is a flow chart showing the manufacturing method of the present invention.
  • a method for manufacturing a wood-plastic composite decorative panel comprising the step a of preparing a wood core; preparing a thermoplastic wood-plastic composite master batch and passing the wood-plastic by a co-extrusion device that can feed the wood core a step b of co-extruding the composite masterbatch with the wood core; a step c of decorating the plate extruded in step b; and a step d of cooling and decorating the decorated plate a step e of cutting off the sheet; and a step f of closing the end surface of the sheet of the step e.
  • a method for manufacturing a wood-plastic composite decorative panel includes a step a of preparing a wood core, preparing a thermoplastic wood-plastic composite master batch, and co-extruding through the wood core that can be fed a step b of melt-extruding the wood-plastic composite masterbatch and coextruding the sheet with the wood core; a step c of decorating the sheet extruded by the step b; and a decorative processed sheet a step d of cooling setting; a step e of cutting off the sheet; and a step f of closing the end surface of the sheet in the step e.
  • the technical effect of the embodiment is that the overall density of the decorative panel is reduced by feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, so that the wood core replaces a part of the wood plastic. Due to the pinning of the wood core to the wood plastic, the shortcomings of the wood plastic original creep are greatly weakened, so that the wood plastic composite decorative board can be normally used under the condition of a certain temperature difference without being affected by the wood plastic creep; Co-extrusion and sealing of the cut end face of the sheet can solve the problem of water molecules entering the glue layer or wood cells in the air, so that the decorative board has water resistance and avoids cracking, warping, deformation and strength of the decorative board.
  • step b The extruded sheet is subjected to decorative processing and the sheet is cooled and shaped after the step c of the decorative processing is completed, so that the wood-plastic composite is after the co-extrusion operation Slower crystallization for a longer period of time, promote the crystal uniformity and regularity of the polymer matrix, reduce the internal stress and reduce the possibility of deformation and bending of the wood-plastic composite decorative panel, and improve the comprehensive mechanical properties of the wood-plastic composite decorative panel. And dimensional stability.
  • the wood core processing method in the step a is: firstly, a solid wood rotary cutting veneer is selected, and a vinyl acetate emulsion and an acrylic resin are applied on the surface of the veneer. , an acrylic-polyurethane resin, an isocyanate, a melamine-urea aldehyde, a urea-formaldehyde glue or a phenolic aldehyde glue, and then cross-stacked the composite panels in a warp and weft direction according to the veneer texture, and then applying pressure to the blank sheet and standing to obtain a laminate. The laminate is further subjected to a drying treatment, and the dried laminate is cut to obtain the wood core.
  • the technical effect of the embodiment is that the wood core is manufactured by using the method for manufacturing a laminate, which is advantageous for overcoming the heterogeneity of the mechanical properties of the wood in all directions, and the obtained wood core is not easily deformed or warped.
  • the mechanical properties of the finished decorative panel are more stable, and the decorative panel is not easily warped or deformed.
  • the wood core processing method in the step a further comprises: processing the both ends of the dried laminated wood core by a milling cutter to obtain a mutual fit Finger jointing hoe, and then treating the mutually matching finger joints with melamine-urea aldehyde, urea-formaldehyde glue or phenolic glue, and then applying opposing pressure on both ends of the laminate wood core to splicing the laminate wood core end-to-end, Get the wood core.
  • the wooden core can be made shorter by manufacturing the finger joints which are matched with each other and treating the mutually matching finger joints with polyvinyl acetate emulsion, melamine-urea, urea-formaldehyde or phenolic glue.
  • the material is obtained by long-splicing and splicing, which can realize long-term use of short materials and large-scale use of materials; since the method of co-extrusion of wood core and wood-plastic composite material is adopted, the wood core is enclosed in the wood-plastic composite material, so the external The moisture does not enter the interior of the wood-plastic composite decorative board, so that the water-based adhesive and the emulsion adhesive which are not suitable for the manufacture of the decorative board can be used for the wood-plastic composite decorative board, and the method can help reduce the wood-plastic composite decoration.
  • the manufacturing cost of the board at the same time, the volatile emissions that may be generated by the adhesive of the wood core adhered to the interior of the decorative board are not released into the environment, and the thermosetting resin adhesives which are not suitable for the manufacture of the decorative board are all unsuitable. Can be used to make wood-plastic composite decorative panels.
  • step of coextruding the sheet in step b requires simultaneous feeding of a plurality of narrow strips of wood core by a co-extrusion apparatus.
  • the narrow strips of wood that are fed flat are not in direct contact and separated by a certain distance, and the molten wood-plastic composite masterbatch is coextruded with a plurality of said narrow strips of wood core.
  • the technical effect of the embodiment is that by feeding a plurality of the wood cores in parallel at the same time, each wood core is not directly contacted and separated by a certain distance, so that it is convenient to be in the wood core and wood according to the width after the decorative sheet is manufactured.
  • the wood-plastic composite part between the cores is cut without exposing the wood core of the processed wood-plastic composite decorative board to the air, thereby avoiding cracking, warping, deformation, strength reduction of the wood-plastic composite decorative board, and
  • the problem of mildew decay and other problems can improve the application field of wood-plastic composite decorative panels and simplify the production process of wood-plastic composite decorative panels; since wood is an anisotropic material, parallel feeding of multiple wood cores can balance wood The anisotropy may bring stress to the sheet, which makes the sheet obtained by processing more flat and less deformable.
  • the present embodiment differs from Embodiment 4 in that the co-extrusion apparatus described in the step b includes a wood-plastic extruder, a co-extrusion mold, and a wood core conveying device, and the co-extrusion mold has a mold body and a plurality of a root wood co-feed end, a wood-plastic whole plate discharge end, and the co-extrusion die is mounted on the head of the wood-plastic extruder in step b, so that the plurality of wood cores are fed together
  • the wood plastic whole board discharge end is at Arranging in the same plane and in the same direction, the plurality of wood core co-feeding ends and the wood-plastic whole plate discharge ends are respectively located on two sides of the co-extrusion die, thereby further melting the thermoplastic wood-plastic composite
  • the material masterbatch coats the wood core in a co-extrusion mold to obtain a coextruded sheet material wrapped with a thermoplastic wood-
  • the technical effect of the embodiment is that the wood-plastic extruder, the co-extrusion die and the wood core conveying device are arranged to ensure that the plurality of wood cores are controlled by the wood core transmission at the same time, and maintain a stable rate to ensure the plate material. Quality; by setting multiple wood core co-feed ends and wood-plastic whole plate discharge ends in the same direction on the same plane, it is possible to ensure that the co-extruded sheets are flat.
  • Embodiment 6 The difference between this embodiment and Embodiment 5 is that the co-extrusion die used in step b further includes a wood core guiding edge, a co-extrusion flow channel, a split flow channel on the mold body, and the wood core a plurality of the wood core guiding ribs are disposed on the inner wall of the feeding end, and the coextrusion flow passage is distributed by a plurality of places circumferentially distributed along the inner wall of the feeding end of the wood core and communicating with the inner wall of the feeding end of the wood core a split flow channel communicating component, the split flow channel is a tapered flow channel, and a corner of the plurality of split flow channels has a corner, and the split flow channel is connected to the wood core feed end on the mold body The profile discharge end on the mold body is wrapped around the coextrusion flow passage.
  • the technical effect of the embodiment is that the wood core guiding rib is provided to help the wood core enter the mold body in a predetermined direction, so that the relative position of the wood core and the coextrusion flow passage does not change during the feeding process, and
  • the wood-plastic composite material that ensures that the wood core is melted inside the co-extrusion mold maintains a stable feed under pressure, and finally ensures that the position of the wood core relative to the outer surface of the wood-plastic composite floor is fixed.
  • the technical effect of the embodiment is that since the plate which has just been co-extruded has the large heat after the co-extrusion of the wood-plastic composite, the plate is still in a high temperature state inside and outside the wood-plastic composite material, and the co-extruded plate is
  • the thermal transfer decorative processing not only makes the decorative processing process save energy without additional heating of the sheet, but also makes the thermal transfer decorative layer obtained by thermal transfer more firmly because of the high temperature hot processing; ordinary thermal transfer
  • the pressure applied to the surface of the object is generally 4 to 6 kg/cm 2 to ensure that the thermal transfer decorative layer adheres firmly to the printed matter, and the phenomenon of pattern deformation and the printing layer is too thin, and the method of the present invention is used.
  • the step of setting the cooling setting after the step of transferring the pattern is completed is advantageous for obtaining a thermoplastic wood-plastic composite shell layer having a uniform thickness, which can make the appearance of the wood-plastic composite floor more smooth and smooth. More stable, the sheet material can obtain a surface having a stable performance.
  • Embodiment 8 The difference between this embodiment and Embodiment 7 is that the thermoplastic wood-plastic composite masterbatch in step b is obtained by the following steps: weigh 30-60 parts of thermoplastics, 40 ⁇ by mass parts. 70 parts of lignocellulosic material, 0-8 parts of reinforcing material, 1-10 parts of coupling agent or interfacial compatibilizer, 0.1-6 parts of lubricant, 0-6 parts of coloring agent, 0.1-3 parts Anti-aging agent, 0 ⁇ 7 parts of heat stabilizer, 0 ⁇ 20 parts of flame retardant, 0 ⁇ 15 parts of mineral filler, put the weighed raw materials into high-speed mixer, control temperature is 25°C ⁇ The thermoplastic wood-plastic composite masterbatch is obtained by mixing at 500 ° C for 5 min to 20 min, and the wood-plastic composite masterbatch directly enters the co-extrusion equipment to participate in co-extrusion.
  • the technical effect of the embodiment is that by using the above method to manufacture a thermoplastic wood-plastic composite masterbatch, a wood-plastic composite material with sufficient mixing, uniform material, good fluidity and stable performance can be obtained with minimum energy consumption, so that The wood-plastic composite decorative board can make the wood-plastic composite decorative board base material uniform in color, small in color difference and stable in performance, and it is not easy to cause warping deformation of wood-plastic composite decorative board due to internal stress of wood-plastic composite material.
  • the wood-plastic composite masterbatch directly enters the co-extrusion equipment to participate in co-extrusion, which helps to reduce operational complexity, reduce worker workload, reduce energy consumption, and improve production efficiency of wood-plastic composite decorative panels.
  • thermoplastic wood-plastic composite masterbatch in step b also needs to be obtained by cooling the wood-plastic composite material mixed by a high-speed mixer. At room temperature, a premix is obtained, and the premix is placed in a twin-screw granulator at a controlled temperature of 145 ° C to 235 ° C, a rotation speed of 30 r / min to 100 r / min, and then obtained by cooling and cutting process. Granular wood-plastic composite masterbatch, the granular wood-plastic composite masterbatch is reserved.
  • the technical effect of the embodiment is that: by adjusting the temperature and the rotation speed of the twin-screw granulator, the above-mentioned thermoplastic wood-plastic composite material is properly melted without destroying the lignocellulosic material.
  • the properties and effects of reinforcing materials, coupling agents or interfacial compatibilizers, lubricants, colorants, anti-aging agents, heat stabilizers, flame retardants and mineral fillers in wood-plastic composite decorative panels are produced by the above method.
  • thermoplastic wood-plastic composite masterbatch and the use of the granular wood-plastic composite masterbatch obtained by the method to manufacture the wood-plastic composite decorative board can better realize the melt extrusion process in the step b, since the granular wood-plastic material will be prepared
  • the process of the composite masterbatch is separated from the other processes in step b, so that the preparation of the masterbatch and the co-extrusion process may not be completed at the same time, thereby making the extrusion process of the wood-plastic composite decorative panel easy to control, so that the co-extrusion
  • the quality of wood-plastic composite decorative board products is more stable and reliable.
  • thermoplastic described in step b is polypropylene, polyethylene, polystyrene, acrylonitrile-butadiene-styrene copolymer and polychlorinated a mixture of one or more of ethylene, or a thermoplastic which is a maleic anhydride graft modified product of one or a mixture of polypropylene, polyethylene, polystyrene, a thermoplastic being a raw material, a recycled material Or a mixture of a raw material and a recycled material;
  • the lignocellulosic material is a mixture of one or more of wood fiber powder, rice husk powder, bamboo fiber powder, hemp fiber powder, cotton fiber powder, and straw fiber powder;
  • the reinforcing material is polyamide fiber, polyester fiber or carbon fiber;
  • the coupling agent is a silane coupling agent, a titanate coupling agent, maleic anhydride, male
  • the technical effect of the embodiment is that the above embodiment solves the problem of compatibility between different plastic components in the waste plastic, and can use an inexpensive mixture, and on the other hand, solves the problem of plastic and lignocellulosic materials.
  • the wood-plastic composite flooring produced by this method is beneficial to the recycling of recycled plastics and biomass waste, thereby helping to reduce the wood-plastic composite floor.
  • the manufacturing cost, and the wood-plastic composite floor produced by the method can be recycled, crushed, melted and put into use after being discarded; using the method to manufacture the wood-plastic composite floor can also make the floor end face closed without using glue
  • the adhesive is melt-bonded with a thermoplastic, thereby avoiding the problem that the adhesive is not resistant to water due to the end face closure, and the adhesive is not safe to release the adhesive.
  • the present embodiment differs from any of Embodiments 1 to 10 in that it further includes a step of dip-coating a paraffin or a water repellent paint on the end surface in a step e of closing the end surface.
  • the technical effect of the embodiment is that the process of dip-coating the paraffin or the waterproof coating on the exposed wooden core is simple and convenient to realize the industrial operation, and the waterproof and moisture-proof of the end portion can be effectively realized, thereby ensuring the quality of the wood-plastic composite decorative panel.
  • a method for manufacturing a wood-plastic composite decorative panel according to the present embodiment is: preparing a wood core having a cross section of 20 mm ⁇ 20 mm by pine shaving; and weighing 38 high density poly by mass parts.
  • Ethylene plastic 62 parts of 40-80 mesh wood fiber powder, 1 part polyester fiber, 3 parts of silane coupling agent, 1 part of polyethylene wax, 1 part of graphite, 1 part of UV absorber UV-9, 1 part of laurel Dibutyltin acid, 1.5 parts of expandable graphite, 5 parts of calcium carbonate powder, the weighed raw materials are placed in a high-speed mixer, the temperature is controlled at 100 ° C, mixed for 15 min to obtain a thermoplastic wood-plastic composite masterbatch, which can be fed through
  • the wood core co-extrusion device melts the wood-plastic composite masterbatch and coextrudes the sheet with the wood core; performs thermal transfer processing on the extruded sheet; and performs thermal transfer processing
  • the plate is cooled and shaped; the plate is cut to length; the end face of the plate is closed.
  • the technical effect of the embodiment is that the preparation of the wood core composite by using the pine wood square and the wood fiber powder of 40-80 mesh is beneficial to improve the creep resistance of the board.
  • a method for manufacturing a wood-plastic composite decorative panel according to the embodiment is: selecting a solid wood rotary-cut veneer, applying a vinyl acetate emulsion on the surface of the veneer, and crossing the veneer texture according to the veneer texture Laminated assembled panels, pressure applied to the blanks and allowed to stand to obtain a laminate, which is dried, and the dried laminate is cut to obtain a laminate having a cross-section of 20 mm ⁇ 20 mm.
  • a wooden core which is processed by a milling head at both ends of the dried laminated wood core to obtain mutually matching finger joints, and then the mutually matching finger joints are treated with melamine-urea, urea-formaldehyde or phenolic glue, and then Applying opposing pressure to both ends of the laminate wood core to make the wood core of the laminate spliced end to end to obtain a wood core; weighing 40 parts of polypropylene plastic and 60 parts of 40-80 mesh wood fiber powder by mass parts.
  • thermoplastic wood-plastic composite masterbatch melting the wood-plastic composite masterbatch by co-extrusion equipment that can feed the wood core, and coextruding the sheet with the wood core; Plate for thermal transfer processing; will be subjected to thermal transfer processing Cooling and shaping plate material; length limitation no longer than 2.4 meters plate, the plate material fixed length truncation; the end face plate for blocking.
  • the technical effect of the embodiment is that the wood-plastic composite decorative board is prepared by adopting the embodiment, so that the creep resistance and the heat deformation resistance of the decorative board are further improved, and the aging test has no penetration and no deformation.
  • the wood core By feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, the wood core replaces a part of the wood plastic to reduce the overall density of the decorative board, due to the wood core to the wood-plastic
  • the shortcomings of the wood plastics that are easily creepable are greatly weakened, so that the wood-plastic composite decorative board can be used normally under the condition of a certain temperature difference without being affected by the creep of wood plastic; by co-extrusion and after cutting
  • the end face of the plate block is closed, which can solve the problem that the water molecules in the air enter the glue layer or the wood cells, so that the decorative plate has water resistance, avoiding the problems of cracking, warping, deformation, strength drop and mildew decay of the decorative plate.
  • the production of ordinary wood-plastic composite materials is cooled immediately after extrusion of the sheet material, and then subjected to decorative processing after being cooled, and the present invention is carried out on the sheet material extruded in step b.
  • the decorative processing and cooling of the sheet after the step c of the decorative processing is completed, so that the wood-plastic composite has a longer time for the slow knot after the co-extrusion operation.
  • DETAILED DESCRIPTION OF THE INVENTION 1 The relevant performance indicators of 2-13 products are shown in Table 1.

Abstract

A wood-plastic composite (WPC) decorative panel and manufacturing method thereof, the WPC decorative panel comprising: a shell layer composed of a thermoplastic WPC material and a core layer composed of a panel-shaped wood core. The core layer composed of the panel-shaped wood core is covered by the thermoplastic WPC shell layer, and a decorative layer printed by a thermal transfer technique is disposed on outside of the shell layer. The manufacturing method of the WPC decorative panel comprises: a, preparing the wood core; b, preparing thermoplastic WPC source materials, melting the WPC source materials by a co-extrusion device capable of receiving the wood core, and coextruding the melted source materials and the wood core to form a panel material comprising the wood core as an inside of the panel material and the thermoplastic WPC material as an outside of the panel material; c, performing a decorative processing on the extruded panel material; d, cooling and shaping the decorative processed panel material; e, cutting the cooled and shaped panel material; and f, sealing an end surface of the panel material. The WPC decorative panel manufactured by the method is resistant to creep, and has a good overall mechanical property and structural stability.

Description

一种木塑复合装饰板及其制造方法Wood plastic composite decorative board and manufacturing method thereof 技术领域Technical field
本发明涉及一种装饰板及其制造方法,具体涉及一种木塑复合装饰板及其制造方法。The invention relates to a decorative board and a manufacturing method thereof, in particular to a wood plastic composite decorative board and a manufacturing method thereof.
背景技术Background technique
现有技术中基于挤塑、模压或粘接等手段制造木塑复合材(WPC)装饰板材的方法,制造出的板材存在容易发生蠕变、翘曲而导致使用该装饰板的家具和室内装修部件变形、装饰效果不佳、密度大过于沉重而不便搬运等不足。现有技术中的实木装饰板又大都受制于材料的规格,以实木为基材的人造板在制造过程中需要在基材上使用大量的胶黏剂进行粘接,这些经粘接加工的地板其胶层容易暴露在空气中,一方面暴露的胶层会随着胶黏剂的分解和挥发持续的对环境造成污染,另一方面当空气中的水分子进入胶层或木材后极易使家具面板发生开裂、翘曲、变形、强度下降以及霉变腐朽等缺陷。以怎样一种新的方法制造出可以解决上述问题的装饰板,是现有技术中的难题。In the prior art, a method for manufacturing a wood-plastic composite (WPC) decorative sheet based on extrusion, molding or bonding, and the manufactured sheet has a tendency to creep and warp, resulting in furniture and interior decoration using the decorative panel. Defects in component deformation, poor decorative effect, and high density are too heavy to handle. Most of the solid wood decorative panels in the prior art are subject to the specifications of the materials. The wood-based wood-based panels need to be bonded with a large amount of adhesive on the substrate during the manufacturing process. The adhesive layer is easily exposed to the air. On the one hand, the exposed adhesive layer will continue to pollute the environment with the decomposition and volatilization of the adhesive. On the other hand, when the water molecules in the air enter the adhesive layer or the wood, it is easy to make The furniture panel is cracked, warped, deformed, reduced in strength, and mildewed and decayed. It is a problem in the prior art to create a decorative panel that solves the above problems in a new way.
技术问题technical problem
本发明为解决木塑复合材装饰板易蠕变、易翘曲、易变形而影响装饰效果的问题,进而提出一种木塑复合装饰板及其制造方法。The invention solves the problem that the wood plastic composite decorative board is easy to creep, easy to warp and easily deform, and affects the decorative effect, and further proposes a wood plastic composite decorative board and a manufacturing method thereof.
问题的解决方案Problem solution
技术解决方案Technical solution
本发明采取的技术方案是:采用将热塑性木塑复合材经熔融后与木芯共挤,并经装饰处理制造出装饰板,该方法包括制备木芯的步骤a;制备热塑性木塑复合材料母料并通过可以进给所述木芯的共挤设备将所述木塑复合材料母料熔融,并与所述木芯共同挤出板材的步骤b;对经b步骤挤出的所述板材进行装饰加工的步骤c;将经装饰加工的板材进行冷却定型的步骤d;将板材截断的步骤e;以及将e步骤所述板材的端面进行封闭的步骤f。The technical proposal adopted by the invention is: using a thermoplastic wood-plastic composite material after being melted and co-extruding with a wood core, and manufacturing a decorative board by a decorative process, the method comprising the steps of preparing a wood core; preparing a thermoplastic wood-plastic composite material mother And melting the wood-plastic composite masterbatch by a co-extrusion device that can feed the wood core, and co-extruding the sheet with the wood core; and performing the b-step extrusion of the sheet a step c of the decorative processing; a step d of cooling the shaped sheet; a step e of cutting the sheet; and a step f of closing the end surface of the sheet in the e step.
发明的有益效果 Advantageous effects of the invention
有益效果Beneficial effect
通过在共挤设备中进给木芯并将木塑复合材料母料与所述木芯共同挤出板材,使木芯替代一部分木塑而使装饰板整体密度降低,由于木芯对木塑的牵制而使木塑原本易蠕变的缺点被大大弱化,使木塑复合装饰板可以在具有一定温差的条件下正常使用而不受木塑蠕变的影响;通过共挤并对裁切后的板材块端面进行封闭,可以解决空气中的水分子进入胶层或木材细胞的问题,从而使装饰板具有耐水性能,避免了装饰板开裂、翘曲、变形、强度下降以及霉变腐朽等问题的产生;正常情况为了使操作方便,普通木塑复合材料的生产都是在板材挤出后马上进行冷却,待冷却后再进行装饰加工,而本发明因对b步骤挤出的所述板材上进行装饰加工并在完成装饰加工的步骤c后才对板材进行冷却定型,使得木塑复合材在共挤出的操作之后有更长的时间进行缓慢的结晶,促进聚合物基体的结晶均匀性和规整度,减小内应力并降低木塑复合装饰板变形和弯曲的可能,有利于提高木塑复合装饰板的综合力学性能和尺寸稳定性。By feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, the wood core replaces a part of the wood plastic to reduce the overall density of the decorative board, due to the wood core to the wood-plastic The shortcomings of the wood plastics that are easily creepable are greatly weakened, so that the wood-plastic composite decorative board can be used normally under the condition of a certain temperature difference without being affected by the creep of wood plastic; by co-extrusion and after cutting The end face of the plate block is closed, which can solve the problem that the water molecules in the air enter the glue layer or the wood cells, so that the decorative plate has water resistance, avoiding the problems of cracking, warping, deformation, strength drop and mildew decay of the decorative plate. Normally, in order to facilitate the operation, the production of ordinary wood-plastic composite materials is cooled immediately after extrusion of the sheet material, and then subjected to decorative processing after being cooled, and the present invention is carried out on the sheet material extruded in step b. The decorative processing and cooling of the sheet after the step c of the decorative processing is completed, so that the wood-plastic composite has a longer time for the slow knot after the co-extrusion operation. Promote the uniformity and regularity of the crystalline polymer matrix, to reduce the internal stress and may decrease decorative wood-plastic composite plate is deformed and bent, help to improve the mechanical properties and dimensional stability of wood-plastic composite trim panel.
对附图的简要说明Brief description of the drawing
附图说明DRAWINGS
图1是本发明的制造方法流程示意图。BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing the manufacturing method of the present invention.
实施该发明的最佳实施例BEST MODE FOR CARRYING OUT THE INVENTION
本发明的最佳实施方式BEST MODE FOR CARRYING OUT THE INVENTION
本实施方式所述一种木塑复合装饰板的制造方法,包括制备木芯的步骤a;制备热塑性木塑复合材料母料并通过可以进给所述木芯的共挤设备将所述木塑复合材料母料熔体,并与所述木芯共同挤出板材的步骤b;对经b步骤挤出的所述板材进行装饰加工的步骤c;将经装饰加工的板材进行冷却定型的步骤d;将板材截断的步骤e;以及将e步骤所述板材的端面进行封闭的步骤f。A method for manufacturing a wood-plastic composite decorative panel according to the embodiment, comprising the step a of preparing a wood core; preparing a thermoplastic wood-plastic composite master batch and passing the wood-plastic by a co-extrusion device that can feed the wood core a step b of co-extruding the composite masterbatch with the wood core; a step c of decorating the plate extruded in step b; and a step d of cooling and decorating the decorated plate a step e of cutting off the sheet; and a step f of closing the end surface of the sheet of the step e.
发明实施例Invention embodiment
本发明的实施方式Embodiments of the invention
具体实施方式1:本实施方式所述一种木塑复合装饰板的制造方法,包括制备木芯的步骤a;制备热塑性木塑复合材料母料并通过可以进给所述木芯的共挤设 备将所述木塑复合材料母料熔体,并与所述木芯共同挤出板材的步骤b;对经b步骤挤出的所述板材进行装饰加工的步骤c;将经装饰加工的板材进行冷却定型的步骤d;将板材截断的步骤e;以及将e步骤所述板材的端面进行封闭的步骤f。DETAILED DESCRIPTION OF THE INVENTION A method for manufacturing a wood-plastic composite decorative panel according to the present embodiment includes a step a of preparing a wood core, preparing a thermoplastic wood-plastic composite master batch, and co-extruding through the wood core that can be fed a step b of melt-extruding the wood-plastic composite masterbatch and coextruding the sheet with the wood core; a step c of decorating the sheet extruded by the step b; and a decorative processed sheet a step d of cooling setting; a step e of cutting off the sheet; and a step f of closing the end surface of the sheet in the step e.
本实施方式的技术效果是:通过在共挤设备中进给木芯并将木塑复合材料母料与所述木芯共同挤出板材,使木芯替代一部分木塑而使装饰板整体密度降低,由于木芯对木塑的牵制而使木塑原本易蠕变的缺点被大大弱化,使木塑复合装饰板可以在具有一定温差的条件下正常使用而不受木塑蠕变的影响;通过共挤并对裁切后的板材块端面进行封闭,可以解决空气中的水分子进入胶层或木材细胞的问题,从而使装饰板具有耐水性能,避免了装饰板开裂、翘曲、变形、强度下降以及霉变腐朽等问题的产生;正常情况为了使操作方便,普通木塑复合材料的生产都是在板材挤出后马上进行冷却,待冷却后再进行装饰加工,而本发明因对b步骤挤出的所述板材上进行装饰加工并在完成装饰加工的步骤c后才对板材进行冷却定型,使得木塑复合材在共挤出的操作之后有更长的时间进行缓慢的结晶,促进聚合物基体的结晶均匀性和规整度,减小内应力并降低木塑复合装饰板变形和弯曲的可能,有利于提高木塑复合装饰板的综合力学性能和尺寸稳定性。The technical effect of the embodiment is that the overall density of the decorative panel is reduced by feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, so that the wood core replaces a part of the wood plastic. Due to the pinning of the wood core to the wood plastic, the shortcomings of the wood plastic original creep are greatly weakened, so that the wood plastic composite decorative board can be normally used under the condition of a certain temperature difference without being affected by the wood plastic creep; Co-extrusion and sealing of the cut end face of the sheet can solve the problem of water molecules entering the glue layer or wood cells in the air, so that the decorative board has water resistance and avoids cracking, warping, deformation and strength of the decorative board. The problem of falling and mildew decay; normal situation In order to facilitate the operation, the production of ordinary wood-plastic composite materials is cooled immediately after the sheet is extruded, and then subjected to decorative processing after being cooled, and the present invention is directed to step b. The extruded sheet is subjected to decorative processing and the sheet is cooled and shaped after the step c of the decorative processing is completed, so that the wood-plastic composite is after the co-extrusion operation Slower crystallization for a longer period of time, promote the crystal uniformity and regularity of the polymer matrix, reduce the internal stress and reduce the possibility of deformation and bending of the wood-plastic composite decorative panel, and improve the comprehensive mechanical properties of the wood-plastic composite decorative panel. And dimensional stability.
具体实施方式2:本实施方式与具体实施方式1的区别在于步骤a中所述木芯加工方法为,首先选取实木旋切单板,在所述单板表面施聚醋酸乙烯脂乳液、丙烯酸树脂、丙烯酸-聚氨酯树脂、异氰酸酯、三聚氰胺-脲醛、脲醛胶或酚醛胶,然后按单板纹理以经纬向交叉层叠的组配坯板,之后对所述坯板施加压力并静置,获得层压板,再对所述层压板进行干燥处理,将经干燥处理的层压板裁切获得所述木芯。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 2: The difference between this embodiment and the specific embodiment 1 is that the wood core processing method in the step a is: firstly, a solid wood rotary cutting veneer is selected, and a vinyl acetate emulsion and an acrylic resin are applied on the surface of the veneer. , an acrylic-polyurethane resin, an isocyanate, a melamine-urea aldehyde, a urea-formaldehyde glue or a phenolic aldehyde glue, and then cross-stacked the composite panels in a warp and weft direction according to the veneer texture, and then applying pressure to the blank sheet and standing to obtain a laminate. The laminate is further subjected to a drying treatment, and the dried laminate is cut to obtain the wood core.
本实施方式的技术效果是:通过使用所述制造层压板的方法制造木芯,有利于克服木材各方向上力学性质的不均一性,可以使制得的木芯不容易发生变形或者翘曲,使最终制造出的装饰板内部力学性能更稳定,使装饰板不易翘曲、变形。The technical effect of the embodiment is that the wood core is manufactured by using the method for manufacturing a laminate, which is advantageous for overcoming the heterogeneity of the mechanical properties of the wood in all directions, and the obtained wood core is not easily deformed or warped. The mechanical properties of the finished decorative panel are more stable, and the decorative panel is not easily warped or deformed.
具体实施方式3:本实施方式与具体实施方式2的区别在于步骤a中所述木芯加工方法还包括,将经干燥处理后的层压板木芯两端以铣刀头加工获得相互吻合 的指接榫头,再以三聚氰胺-脲醛、脲醛胶或酚醛胶处理所述相互吻合的指接榫头,然后在所述层压板木芯两端施加相向的压力使所述层压板木芯首尾拼接,获得木芯。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 3: The difference between this embodiment and the specific embodiment 2 is that the wood core processing method in the step a further comprises: processing the both ends of the dried laminated wood core by a milling cutter to obtain a mutual fit Finger jointing hoe, and then treating the mutually matching finger joints with melamine-urea aldehyde, urea-formaldehyde glue or phenolic glue, and then applying opposing pressure on both ends of the laminate wood core to splicing the laminate wood core end-to-end, Get the wood core.
本实施方式的技术效果是:通过制造相互吻合的指接榫头并以聚醋酸乙烯脂乳液、三聚氰胺-脲醛、脲醛胶或酚醛胶处理所述相互吻合的指接榫头,使木芯可以由较短小的材料接长拼接而得到,可以实现短材长用和小材大用;由于采用了木芯与木塑复合材共挤的方法,使木芯被封闭在木塑复合材料之中,因此外部的水分不会进入木塑复合装饰板内部而使原本不适合用于制造装饰板的水基胶粘剂、乳液胶粘剂均能用于制作木塑复合装饰板,采用该方法有助于降低木塑复合装饰板的制造成本;同时由于木芯被封闭而装饰板内部粘接木芯的胶黏剂可能产生的挥发性释放物不会释放到环境中,原本不适合用于制造装饰板的热固性树脂胶粘剂均能用于制作木塑复合装饰板。The technical effect of the embodiment is that the wooden core can be made shorter by manufacturing the finger joints which are matched with each other and treating the mutually matching finger joints with polyvinyl acetate emulsion, melamine-urea, urea-formaldehyde or phenolic glue. The material is obtained by long-splicing and splicing, which can realize long-term use of short materials and large-scale use of materials; since the method of co-extrusion of wood core and wood-plastic composite material is adopted, the wood core is enclosed in the wood-plastic composite material, so the external The moisture does not enter the interior of the wood-plastic composite decorative board, so that the water-based adhesive and the emulsion adhesive which are not suitable for the manufacture of the decorative board can be used for the wood-plastic composite decorative board, and the method can help reduce the wood-plastic composite decoration. The manufacturing cost of the board; at the same time, the volatile emissions that may be generated by the adhesive of the wood core adhered to the interior of the decorative board are not released into the environment, and the thermosetting resin adhesives which are not suitable for the manufacture of the decorative board are all unsuitable. Can be used to make wood-plastic composite decorative panels.
具体实施方式4:本实施方式与具体实施方式1-3中任一项的区别在于步骤b中共同挤出板材的步骤需通过共挤设备将多根窄条木芯同时平行进给,所述平行进给的窄条木芯之间不直接接触并相隔一定的距离,以熔融的木塑复合材料母料与多根所述窄条木芯共同挤出。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 4: The difference between this embodiment and any one of Embodiments 1 to 3 is that the step of coextruding the sheet in step b requires simultaneous feeding of a plurality of narrow strips of wood core by a co-extrusion apparatus. The narrow strips of wood that are fed flat are not in direct contact and separated by a certain distance, and the molten wood-plastic composite masterbatch is coextruded with a plurality of said narrow strips of wood core.
本实施方式的技术效果是:通过同时平行进给多根所述木芯,使每根木芯不直接接触并相隔一定的距离,因此便于在装饰板材制造完成之后可以依据宽度需要在木芯与木芯之间的木塑复合材部分进行裁切,而不至于使加工后的木塑复合装饰板的木芯暴露于空气中,可以避免木塑复合装饰板开裂、翘曲、变形、强度下降以及霉变腐朽等问题的产生,可以提高木塑复合装饰板的应用领域并简化木塑复合装饰板的生产工艺;由于木材是具有各向异性的材料,将多根木芯进行平行进给可以平衡木材的各向异性可能带给板材的应力,而使得加工获得的板材更平整而不易变形。The technical effect of the embodiment is that by feeding a plurality of the wood cores in parallel at the same time, each wood core is not directly contacted and separated by a certain distance, so that it is convenient to be in the wood core and wood according to the width after the decorative sheet is manufactured. The wood-plastic composite part between the cores is cut without exposing the wood core of the processed wood-plastic composite decorative board to the air, thereby avoiding cracking, warping, deformation, strength reduction of the wood-plastic composite decorative board, and The problem of mildew decay and other problems can improve the application field of wood-plastic composite decorative panels and simplify the production process of wood-plastic composite decorative panels; since wood is an anisotropic material, parallel feeding of multiple wood cores can balance wood The anisotropy may bring stress to the sheet, which makes the sheet obtained by processing more flat and less deformable.
具体实施方式5:本实施方式与具体实施方式4的区别在于步骤b所述的共挤设备包括木塑挤出机、共挤模具和木芯传送装置,所述共挤模具具有模具本体、多根木芯共同进料端、木塑整板出料端,在步骤b中将所述共挤模具安装在所述木塑挤出机的机头上,使所述多根木芯共同进料端和所述木塑整板出料端处于 同一平面上并沿同一方向设置,使所述多根木芯共同进料端和所述木塑整板出料端分别位于所述共挤模具的两侧,进而使熔融的所述热塑性木塑复合材料母料在共挤模具内对木芯进行包覆,获得由热塑性木塑复合材料包裹且具有多根木芯的共同挤出板材。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 5: The present embodiment differs from Embodiment 4 in that the co-extrusion apparatus described in the step b includes a wood-plastic extruder, a co-extrusion mold, and a wood core conveying device, and the co-extrusion mold has a mold body and a plurality of a root wood co-feed end, a wood-plastic whole plate discharge end, and the co-extrusion die is mounted on the head of the wood-plastic extruder in step b, so that the plurality of wood cores are fed together The wood plastic whole board discharge end is at Arranging in the same plane and in the same direction, the plurality of wood core co-feeding ends and the wood-plastic whole plate discharge ends are respectively located on two sides of the co-extrusion die, thereby further melting the thermoplastic wood-plastic composite The material masterbatch coats the wood core in a co-extrusion mold to obtain a coextruded sheet material wrapped with a thermoplastic wood-plastic composite material and having a plurality of wood cores.
本实施方式的技术效果是:通过设置木塑挤出机、共挤模具和木芯传送装置使多根木芯同时进给时受木芯传动装置的控制,而保持稳定的速率,以确保板材的品质;通过在同一平面上沿同一方向设置多根木芯共同进料端和木塑整板出料端,可以保证共挤出的板材平整。The technical effect of the embodiment is that the wood-plastic extruder, the co-extrusion die and the wood core conveying device are arranged to ensure that the plurality of wood cores are controlled by the wood core transmission at the same time, and maintain a stable rate to ensure the plate material. Quality; by setting multiple wood core co-feed ends and wood-plastic whole plate discharge ends in the same direction on the same plane, it is possible to ensure that the co-extruded sheets are flat.
具体实施方式6:本实施方式与具体实施方式5的区别在于步骤b所使用的共挤模具还包括所述模具本体上的木芯导向棱、共挤流道、分流流道,所述木芯进料端内壁上设有多个所述木芯导向棱,所述共挤流道由沿所述木芯进料端内壁周向分布并与所述木芯进料端内壁连通的多个所述分流流道连通组成,所述分流流道为锥形流道,且多个分流流道的交汇处存在拐角,所述分流流道与所述模具本体上的所述木芯进料端连通,所述模具本体上的所述型材出料端包覆在所述共挤流道的四周。Embodiment 6: The difference between this embodiment and Embodiment 5 is that the co-extrusion die used in step b further includes a wood core guiding edge, a co-extrusion flow channel, a split flow channel on the mold body, and the wood core a plurality of the wood core guiding ribs are disposed on the inner wall of the feeding end, and the coextrusion flow passage is distributed by a plurality of places circumferentially distributed along the inner wall of the feeding end of the wood core and communicating with the inner wall of the feeding end of the wood core a split flow channel communicating component, the split flow channel is a tapered flow channel, and a corner of the plurality of split flow channels has a corner, and the split flow channel is connected to the wood core feed end on the mold body The profile discharge end on the mold body is wrapped around the coextrusion flow passage.
本实施方式的技术效果是:通过设置木芯导向棱,有助于木芯按照既定的方向进入模具本体,使进给过程中木芯与所述共挤流道的相对位置不发生变化,能确保木芯在共挤模具内部熔融的木塑复合材料在压力作用下保持稳定的进给,最终确保木芯相对于木塑复合地板各外表面的位置固定不变。The technical effect of the embodiment is that the wood core guiding rib is provided to help the wood core enter the mold body in a predetermined direction, so that the relative position of the wood core and the coextrusion flow passage does not change during the feeding process, and The wood-plastic composite material that ensures that the wood core is melted inside the co-extrusion mold maintains a stable feed under pressure, and finally ensures that the position of the wood core relative to the outer surface of the wood-plastic composite floor is fixed.
具体实施方式7:本实施方式与具体实施方式1~6中任一项的区别在于步骤c所述的装饰加工处于所述板材熔融共挤之后,利用熔融挤出后板材表面具有的高温,通过热转印设备将热转印装饰层粘附到所述板材外表面实现图案的热转印,热转印速度参数与所述板材挤出的速度参数保持一致,所述转印图案的步骤设置在冷却定型的步骤之前。BEST MODE FOR CARRYING OUT THE INVENTION 7: The difference between this embodiment and any one of Embodiments 1 to 6 is that the decorative processing described in the step c is after the molten co-extrusion of the sheet material, and the high temperature of the surface of the sheet after melt extrusion is passed. The thermal transfer device adheres the thermal transfer decorative layer to the outer surface of the plate to realize thermal transfer of the pattern, and the thermal transfer speed parameter is consistent with the speed parameter of the plate extrusion, and the step of setting the transfer pattern Before the step of cooling the setting.
本实施方式的技术效果是:由于刚被共挤出的板材本身还具有木塑熔融共挤之后的较大热量,在木塑复合材内外依然处于高温的状态之下,对共挤出的板材进行热转印装饰加工,不仅可以使装饰加工过程无需额外对板材加热而节约能源,更因为高温的热加工而使经热转印获得的热转印装饰层粘贴更牢固;普通 的热转印在物体表面施加的压力一般在4~6kg/cm2才能保证热转印装饰层与被印物粘附牢固,且容易出现花纹变形和印层过薄的现象,采用本发明的方法由于所述板材还未完全冷却固化,则仅需在转印图案的过程使用0.1~5kg/cm2的压力就能使热转印装饰层与所述板材粘附得牢固且均匀,获得较好的性能;此外,在转印图案的步骤完成之后方设置冷却定型的步骤有利于获得厚度均匀的热塑性木塑复合材料壳层,能使木塑复合地板表观效果更平整、性能更稳定,可以使板材获得具有稳定性能的表面。The technical effect of the embodiment is that since the plate which has just been co-extruded has the large heat after the co-extrusion of the wood-plastic composite, the plate is still in a high temperature state inside and outside the wood-plastic composite material, and the co-extruded plate is The thermal transfer decorative processing not only makes the decorative processing process save energy without additional heating of the sheet, but also makes the thermal transfer decorative layer obtained by thermal transfer more firmly because of the high temperature hot processing; ordinary thermal transfer The pressure applied to the surface of the object is generally 4 to 6 kg/cm 2 to ensure that the thermal transfer decorative layer adheres firmly to the printed matter, and the phenomenon of pattern deformation and the printing layer is too thin, and the method of the present invention is used. If the plate has not been completely cooled and solidified, it is only necessary to use a pressure of 0.1 to 5 kg/cm 2 in the process of transferring the pattern to make the thermal transfer decorative layer adhere to the plate firmly and uniformly, and obtain better performance; In addition, the step of setting the cooling setting after the step of transferring the pattern is completed is advantageous for obtaining a thermoplastic wood-plastic composite shell layer having a uniform thickness, which can make the appearance of the wood-plastic composite floor more smooth and smooth. More stable, the sheet material can obtain a surface having a stable performance.
具体实施方式8:本实施方式与具体实施方式7的区别在于步骤b中所述热塑性木塑复合材料母料由以下步骤制得:按质量份数称取30~60份的热塑性塑料、40~70份的木质纤维材料、0~8份的增强材料、1~10份的偶联剂或界面相容剂、0.1~6份的润滑剂、0~6份的着色剂、0.1~3份的抗老化剂、0~7份的热稳定剂、0~20份的阻燃剂、0~15份的矿物质填料,将称取好的原料放入高速混合机中,控制温度为25℃~130℃,混合5min~20min,得到所述热塑性木塑复合材料母料,所述木塑复合材料母料直接进入共挤设备参与共挤。Embodiment 8: The difference between this embodiment and Embodiment 7 is that the thermoplastic wood-plastic composite masterbatch in step b is obtained by the following steps: weigh 30-60 parts of thermoplastics, 40~ by mass parts. 70 parts of lignocellulosic material, 0-8 parts of reinforcing material, 1-10 parts of coupling agent or interfacial compatibilizer, 0.1-6 parts of lubricant, 0-6 parts of coloring agent, 0.1-3 parts Anti-aging agent, 0~7 parts of heat stabilizer, 0~20 parts of flame retardant, 0~15 parts of mineral filler, put the weighed raw materials into high-speed mixer, control temperature is 25°C~ The thermoplastic wood-plastic composite masterbatch is obtained by mixing at 500 ° C for 5 min to 20 min, and the wood-plastic composite masterbatch directly enters the co-extrusion equipment to participate in co-extrusion.
本实施方式的技术效果是:通过采用上述方法制造热塑性木塑复合材料母料,能在能耗最小的情况下获得混合充分、材质均匀、流动性好、性能稳定的木塑复合材料,以这样的木塑复合材料制造木塑复合装饰板可以使木塑复合装饰板基材的色泽均一、色差小、性能稳定而不易由于木塑复合材料的内应力而发生木塑复合装饰板的翘曲变形;所述木塑复合材料母料直接进入共挤设备参与共挤,有助于降低操作复杂性,减少工人的工作量,降低能耗,提高木塑复合装饰板的生产效率。The technical effect of the embodiment is that by using the above method to manufacture a thermoplastic wood-plastic composite masterbatch, a wood-plastic composite material with sufficient mixing, uniform material, good fluidity and stable performance can be obtained with minimum energy consumption, so that The wood-plastic composite decorative board can make the wood-plastic composite decorative board base material uniform in color, small in color difference and stable in performance, and it is not easy to cause warping deformation of wood-plastic composite decorative board due to internal stress of wood-plastic composite material. The wood-plastic composite masterbatch directly enters the co-extrusion equipment to participate in co-extrusion, which helps to reduce operational complexity, reduce worker workload, reduce energy consumption, and improve production efficiency of wood-plastic composite decorative panels.
具体实施方式9:本实施方式与具体实施方式8的区别在于步骤b中所述热塑性木塑复合材料母料还需要经以下步骤制得:将经高速混合机混合的所述木塑复合材料冷却至室温,得到预混料,再将所述预混料放入双螺杆造粒机中,控制温度为145℃~235℃,转速为30r/min~100r/min,再经冷却和切割过程得到颗粒状木塑复合材料母料,所述颗粒状木塑复合材料母料留做备用。BEST MODE FOR CARRYING OUT THE INVENTION 9: The difference between this embodiment and Embodiment 8 is that the thermoplastic wood-plastic composite masterbatch in step b also needs to be obtained by cooling the wood-plastic composite material mixed by a high-speed mixer. At room temperature, a premix is obtained, and the premix is placed in a twin-screw granulator at a controlled temperature of 145 ° C to 235 ° C, a rotation speed of 30 r / min to 100 r / min, and then obtained by cooling and cutting process. Granular wood-plastic composite masterbatch, the granular wood-plastic composite masterbatch is reserved.
本实施方式的技术效果是:通过对双螺杆造粒机温度和转速的调节,使经过配比的上述热塑性木塑复合材料获得了适当的熔融,但又不会破坏木质纤维材料 、增强材料、偶联剂或界面相容剂、润滑剂、着色剂、抗老化剂、热稳定剂、阻燃剂及矿物质填料在木塑复合装饰板中的性状和作用,采用上述方法制造热塑性木塑复合材料母料,并使用以该方法获得的颗粒状木塑复合材料母料制造木塑复合装饰板能更好的实现步骤b中的熔融挤出过程,由于将制备颗粒状木塑复合材料母料的过程与步骤b中的其他过程分离,使母料的制备与共挤出过程可以不在同一时间完成,进而使木塑复合装饰板的挤出工艺过程易于控制,使共挤出的木塑复合装饰板产品质量更稳定可靠。The technical effect of the embodiment is that: by adjusting the temperature and the rotation speed of the twin-screw granulator, the above-mentioned thermoplastic wood-plastic composite material is properly melted without destroying the lignocellulosic material. The properties and effects of reinforcing materials, coupling agents or interfacial compatibilizers, lubricants, colorants, anti-aging agents, heat stabilizers, flame retardants and mineral fillers in wood-plastic composite decorative panels are produced by the above method. The thermoplastic wood-plastic composite masterbatch and the use of the granular wood-plastic composite masterbatch obtained by the method to manufacture the wood-plastic composite decorative board can better realize the melt extrusion process in the step b, since the granular wood-plastic material will be prepared The process of the composite masterbatch is separated from the other processes in step b, so that the preparation of the masterbatch and the co-extrusion process may not be completed at the same time, thereby making the extrusion process of the wood-plastic composite decorative panel easy to control, so that the co-extrusion The quality of wood-plastic composite decorative board products is more stable and reliable.
具体实施方式10:本实施方式与具体实施方式8的区别在于在于步骤b中所述的热塑性塑料是聚丙烯、聚乙烯、聚苯乙烯、丙烯腈-丁二烯-苯乙烯共聚物和聚氯乙烯中一种或几种的混合物,或者热塑性塑料是聚丙烯、聚乙烯、聚苯乙烯中的一种或几种的混合物的马来酸酐接枝改性产物,热塑性塑料为原生料、再生料或者原生料与再生料的混合物;所述的木质纤维材料是木纤维粉、稻壳粉、竹纤维粉、麻纤维粉、棉纤维粉和秸秆纤维粉中的一种或者几种的混合物;所述的增强材料是聚酰胺纤维、聚酯纤维或碳纤维;所述的偶联剂为硅烷类偶联剂、钛酸酯类偶联剂、马来酸酐、马来酸酐接枝聚烯烃和异氰酸酯中的一种或几种的混合物;所述的润滑剂为聚乙烯蜡、聚丙烯蜡、石蜡、硬脂酸、硬脂酸锌和硬脂酸钙中的一种或几种的混合物;所述的着色剂为氧化铁、二氧化钛、炭黑、酞青蓝和酞青绿中的一种或几种的混合物;所述的抗老化剂为紫外线吸收剂UV-9、紫外线吸收剂UV-P、紫外线吸收剂UV-326、紫外线吸收剂UV327、紫外线吸收剂UV328、紫外线吸收剂UV329、紫外线吸收剂UV531、抗氧剂四[β-(3,5-二叔丁基-4-羟基苯基)丙酸]季戊四醇酯、β-(3,5-二叔丁基-4-羟基苯基)丙酸正十八烷醇酯、抗氧剂2,6-二叔丁基-4-甲基苯酚、抗氧剂2,2,-亚甲基-双(4-甲基-6-叔丁基苯酚)、抗氧剂三(2,4-二叔丁基苯基)亚磷酸酯和4,4,-硫代双(3-甲基-6-叔丁基苯酚中的一种或几种的混合物;所述的热稳定剂是二月桂酸二丁基锡、二月桂酸二辛基锡、马来酸二烷基锡、双(马来酸单丁酯)二丁基锡、马来酸二辛基锡、二辛基锡双(巯基乙酸异丁酯)或二辛基锡双(巯基乙酸异辛酯);所述的阻燃剂为聚磷酸铵、硼酸或偏硼酸、八硼酸钠、硼酸锌和可膨胀石墨中的一种或几种的混合物;所述的矿物质填料为碳酸钙粉、硅酸钙粉、滑石 粉和热粉煤灰中的一种或几种的混合物。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 10: This embodiment differs from Embodiment 8 in that the thermoplastic described in step b is polypropylene, polyethylene, polystyrene, acrylonitrile-butadiene-styrene copolymer and polychlorinated a mixture of one or more of ethylene, or a thermoplastic which is a maleic anhydride graft modified product of one or a mixture of polypropylene, polyethylene, polystyrene, a thermoplastic being a raw material, a recycled material Or a mixture of a raw material and a recycled material; the lignocellulosic material is a mixture of one or more of wood fiber powder, rice husk powder, bamboo fiber powder, hemp fiber powder, cotton fiber powder, and straw fiber powder; The reinforcing material is polyamide fiber, polyester fiber or carbon fiber; the coupling agent is a silane coupling agent, a titanate coupling agent, maleic anhydride, maleic anhydride grafted polyolefin and isocyanate a mixture of one or more of the following; the lubricant is a mixture of one or more of polyethylene wax, polypropylene wax, paraffin wax, stearic acid, zinc stearate, and calcium stearate; Colorant for oxidation a mixture of one or more of titanium dioxide, carbon black, indigo blue, and indigo green; the anti-aging agent is UV absorber UV-9, UV absorber UV-P, UV absorber UV-326, UV absorber UV327, UV absorber UV328, UV absorber UV329, UV absorber UV531, antioxidant tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate] pentaerythritol ester, β -(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid n-octadecyl ester, antioxidant 2,6-di-tert-butyl-4-methylphenol, antioxidant 2,2 ,-methylene-bis(4-methyl-6-tert-butylphenol), antioxidant tris(2,4-di-tert-butylphenyl)phosphite, and 4,4,-thiobis ( a mixture of one or more of 3-methyl-6-tert-butylphenol; the heat stabilizer is dibutyltin dilaurate, dioctyltin dilaurate, dialkyltin maleate, bis ( Monobutyl maleate) dibutyltin, dioctyltin maleate, dioctyltin bis(isobutyl thioglycolate) or dioctyltin bis(isooctyl thioglycolate); the flame retardant is ammonium polyphosphate, boric acid Or metaboric acid, sodium octaborate, zinc borate And a mixture of one or more of expandable graphite; the mineral filler is calcium carbonate powder, calcium silicate powder, talc a mixture of one or more of powder and hot fly ash.
本实施方式的技术效果是:采用上述实施方式一方面解决了废旧塑料中不同塑料成分之间的相容性问题而可以使用廉价的混合料,另一方面则同时解决了塑料与木质纤维材料之间的相容性问题而获得高性能的木塑复合材料,使用该方法制造的木塑复合地板有利于实现对回收塑料和生物质废弃物的再生利用,进而有助于降低木塑复合地板的制造成本,且以该方法生产的木塑复合地板在废弃后还可以经回收、粉碎、熔融而再投入使用;使用该方法制造木塑复合地板还可以使所述地板端面进行封闭时不使用胶黏剂,而使用热塑性塑料熔融粘接,进而避免了因端面封闭而带来的胶黏剂不耐水而开胶、胶黏剂释放污染物而不安全等问题。The technical effect of the embodiment is that the above embodiment solves the problem of compatibility between different plastic components in the waste plastic, and can use an inexpensive mixture, and on the other hand, solves the problem of plastic and lignocellulosic materials. A high-performance wood-plastic composite material with compatibility problems. The wood-plastic composite flooring produced by this method is beneficial to the recycling of recycled plastics and biomass waste, thereby helping to reduce the wood-plastic composite floor. The manufacturing cost, and the wood-plastic composite floor produced by the method can be recycled, crushed, melted and put into use after being discarded; using the method to manufacture the wood-plastic composite floor can also make the floor end face closed without using glue The adhesive is melt-bonded with a thermoplastic, thereby avoiding the problem that the adhesive is not resistant to water due to the end face closure, and the adhesive is not safe to release the adhesive.
具体实施方式11:本实施方式与具体实施方式1~10中任一项的区别在于还包括在对端面进行封闭的步骤e中在端面浸涂石蜡或者防水涂料的步骤。BEST MODE FOR CARRYING OUT THE INVENTION 11: The present embodiment differs from any of Embodiments 1 to 10 in that it further includes a step of dip-coating a paraffin or a water repellent paint on the end surface in a step e of closing the end surface.
本实施方式的技术效果是:在外露的木芯部分浸涂石蜡或者防水涂料工艺简单方便实现工业化操作,能够有效的实现端部的防水防潮,进而保证木塑复合装饰板的品质。The technical effect of the embodiment is that the process of dip-coating the paraffin or the waterproof coating on the exposed wooden core is simple and convenient to realize the industrial operation, and the waterproof and moisture-proof of the end portion can be effectively realized, thereby ensuring the quality of the wood-plastic composite decorative panel.
具体实施方式12:本实施方式所述一种木塑复合装饰板的制造方法为:以松木经刨削加工制备截面为20mm×20mm规格木芯;以按质量份数称取38份高密度聚乙烯塑料、62份40~80目的木纤维粉、1份聚酯纤维、3份硅烷类偶联剂、1份聚乙烯蜡、1份石墨、1份紫外线吸收剂UV-9、1份二月桂酸二丁基锡、1.5份可膨胀石墨、5份碳酸钙粉,将称取好的原料放入高速混合机中,控制温度为100℃,混合15min获得热塑性木塑复合材料母料,通过可以进给所述木芯的共挤设备将所述木塑复合材料母料熔体,并与所述木芯共同挤出板材;对挤出的所述板材进行热转印加工;将经热转印加工的板材进行冷却定型;将板材进行定长截断;将所述板材的端面进行封闭。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 12: A method for manufacturing a wood-plastic composite decorative panel according to the present embodiment is: preparing a wood core having a cross section of 20 mm×20 mm by pine shaving; and weighing 38 high density poly by mass parts. Ethylene plastic, 62 parts of 40-80 mesh wood fiber powder, 1 part polyester fiber, 3 parts of silane coupling agent, 1 part of polyethylene wax, 1 part of graphite, 1 part of UV absorber UV-9, 1 part of laurel Dibutyltin acid, 1.5 parts of expandable graphite, 5 parts of calcium carbonate powder, the weighed raw materials are placed in a high-speed mixer, the temperature is controlled at 100 ° C, mixed for 15 min to obtain a thermoplastic wood-plastic composite masterbatch, which can be fed through The wood core co-extrusion device melts the wood-plastic composite masterbatch and coextrudes the sheet with the wood core; performs thermal transfer processing on the extruded sheet; and performs thermal transfer processing The plate is cooled and shaped; the plate is cut to length; the end face of the plate is closed.
本实施方式的技术效果是:通过使用松木木方制备规格木芯并以40~80目的木纤维粉进行木塑复合材料的制备有利于提高板材的抗蠕变性能。The technical effect of the embodiment is that the preparation of the wood core composite by using the pine wood square and the wood fiber powder of 40-80 mesh is beneficial to improve the creep resistance of the board.
具体实施方式13:本实施方式所述一种木塑复合装饰板的制造方法为:选取实木旋切单板,在所述单板表面施聚醋酸乙烯脂乳液,按单板纹理以经纬向交叉 层叠的组配坯板,对所述坯板施加压力并静置,获得层压板,对所述层压板进行干燥处理,将经干燥处理的层压板裁切获得截面为20mm×20mm规格的层压板木芯,将经干燥处理后的层压板木芯两端以铣刀头加工获得相互吻合的指接榫头,再以三聚氰胺-脲醛、脲醛胶或酚醛胶处理所述相互吻合的指接榫头,然后在所述层压板木芯两端施加相向的压力使所述层压板木芯首尾拼接,制得木芯;以按质量份数称取40份聚丙烯塑料、60份40~80目的木纤维粉、4份偶联剂或界面相容剂、1.5份润滑剂、1份抗老化剂、1份热稳定剂,将称取好的原料放入高速混合机中,控制温度为105℃,混合20min获得热塑性木塑复合材料母料,通过可以进给所述木芯的共挤设备将所述木塑复合材料母料熔体,并与所述木芯共同挤出板材;对挤出的所述板材进行热转印加工;将经热转印加工的板材进行冷却定型;限制板材的长度不长于2.4米,将板材进行定长截断;将所述板材的端面进行封闭。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 13: A method for manufacturing a wood-plastic composite decorative panel according to the embodiment is: selecting a solid wood rotary-cut veneer, applying a vinyl acetate emulsion on the surface of the veneer, and crossing the veneer texture according to the veneer texture Laminated assembled panels, pressure applied to the blanks and allowed to stand to obtain a laminate, which is dried, and the dried laminate is cut to obtain a laminate having a cross-section of 20 mm×20 mm. a wooden core, which is processed by a milling head at both ends of the dried laminated wood core to obtain mutually matching finger joints, and then the mutually matching finger joints are treated with melamine-urea, urea-formaldehyde or phenolic glue, and then Applying opposing pressure to both ends of the laminate wood core to make the wood core of the laminate spliced end to end to obtain a wood core; weighing 40 parts of polypropylene plastic and 60 parts of 40-80 mesh wood fiber powder by mass parts. 4 parts of coupling agent or interfacial compatibilizer, 1.5 parts of lubricant, 1 part of anti-aging agent, 1 part of heat stabilizer, put the weighed raw materials into high-speed mixer, control temperature is 105 ° C, mix for 20 min Obtaining a thermoplastic wood-plastic composite masterbatch, melting the wood-plastic composite masterbatch by co-extrusion equipment that can feed the wood core, and coextruding the sheet with the wood core; Plate for thermal transfer processing; will be subjected to thermal transfer processing Cooling and shaping plate material; length limitation no longer than 2.4 meters plate, the plate material fixed length truncation; the end face plate for blocking.
本实施方式的技术效果是:通过采用本实施方式制备木塑复合装饰板,使装饰板的抗蠕变性能、抗热变形能力都得到进一步改善,经老化测试无渗透无变形现象。The technical effect of the embodiment is that the wood-plastic composite decorative board is prepared by adopting the embodiment, so that the creep resistance and the heat deformation resistance of the decorative board are further improved, and the aging test has no penetration and no deformation.
工业实用性Industrial applicability
通过在共挤设备中进给木芯并将木塑复合材料母料与所述木芯共同挤出板材,使木芯替代一部分木塑而使装饰板整体密度降低,由于木芯对木塑的牵制而使木塑原本易蠕变的缺点被大大弱化,使木塑复合装饰板可以在具有一定温差的条件下正常使用而不受木塑蠕变的影响;通过共挤并对裁切后的板材块端面进行封闭,可以解决空气中的水分子进入胶层或木材细胞的问题,从而使装饰板具有耐水性能,避免了装饰板开裂、翘曲、变形、强度下降以及霉变腐朽等问题的产生;正常情况为了使操作方便,普通木塑复合材料的生产都是在板材挤出后马上进行冷却,待冷却后再进行装饰加工,而本发明因对b步骤挤出的所述板材上进行装饰加工并在完成装饰加工的步骤c后才对板材进行冷却定型,使得木塑复合材在共挤出的操作之后有更长的时间进行缓慢的结晶,促进聚合物基体的结晶均匀性和规整度,减小内应力并降低木塑复合装饰板变形和弯曲的可能,有利于提高木塑复合装饰板的综合力学性能和尺寸稳定性。具体实施方式1 2-13产品的相关性能指标见表1。By feeding the wood core in the co-extrusion device and coextruding the wood-plastic composite masterbatch with the wood core, the wood core replaces a part of the wood plastic to reduce the overall density of the decorative board, due to the wood core to the wood-plastic The shortcomings of the wood plastics that are easily creepable are greatly weakened, so that the wood-plastic composite decorative board can be used normally under the condition of a certain temperature difference without being affected by the creep of wood plastic; by co-extrusion and after cutting The end face of the plate block is closed, which can solve the problem that the water molecules in the air enter the glue layer or the wood cells, so that the decorative plate has water resistance, avoiding the problems of cracking, warping, deformation, strength drop and mildew decay of the decorative plate. Normally, in order to facilitate the operation, the production of ordinary wood-plastic composite materials is cooled immediately after extrusion of the sheet material, and then subjected to decorative processing after being cooled, and the present invention is carried out on the sheet material extruded in step b. The decorative processing and cooling of the sheet after the step c of the decorative processing is completed, so that the wood-plastic composite has a longer time for the slow knot after the co-extrusion operation. Promote the uniformity and regularity of the crystalline polymer matrix, to reduce the internal stress and may decrease decorative wood-plastic composite plate is deformed and bent, help to improve the mechanical properties and dimensional stability of wood-plastic composite trim panel. DETAILED DESCRIPTION OF THE INVENTION 1 The relevant performance indicators of 2-13 products are shown in Table 1.
表1具体实施方式12-13产品相关性能指标Table 1 Specific implementation mode 12-13 product related performance indicators
材料material 抗弯强度(MPa)Bending strength (MPa) 弯曲弹性模量(GPa)Flexural modulus of elasticity (GPa) 弯曲极限载荷(N)Bending ultimate load (N) 蠕变恢复率(%)Creep recovery rate (%)
普通木塑板Ordinary wood-plastic board 22-2522-25 3~53~5 130~190130~190 7575
具体实施方式12DETAILED DESCRIPTION 12 80~9580~95 12~1512~15 400~650400~650 85.585.5
具体实施方式13DETAILED DESCRIPTION 13 85~10085~100 16~2116~21 700~850700~850 9090
注:上述普通木塑板未经过与木芯共挤,不含木芯。Note: The above ordinary wood-plastic board has not been co-extruded with the wood core and does not contain wood core.
最后应说明的是:以上各实施方式仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施方式对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施方式所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。 It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, and are not intended to be limiting; although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that The technical solutions described in the foregoing embodiments may be modified, or some or all of the technical features may be equivalently replaced; and the modifications or substitutions do not deviate from the technical solutions of the embodiments of the present invention. range.

Claims (10)

  1. 一种木塑复合装饰板的制造方法,其特征在于,包括:步骤a,制备木芯;步骤b,制备热塑性木塑复合材料母料,并通过可以进给所述木芯的共挤设备将所述木塑复合材料母料熔融,将熔融的所述母料与所述木芯共同挤出成木芯在内木塑在外的板材;步骤c,对经b步骤挤出的所述板材进行装饰加工;步骤d,将经装饰加工的板材进行冷却定型;步骤e,将经冷却定型的板材截断;步骤f,将e步骤所述板材的端面进行封闭。A method for manufacturing a wood-plastic composite decorative panel, comprising: step a, preparing a wood core; step b, preparing a thermoplastic wood-plastic composite masterbatch, and passing through a co-extrusion device that can feed the wood core The wood-plastic composite masterbatch is melted, and the molten masterbatch and the wood core are co-extruded into a wood core-external wood-plastic sheet; in step c, the sheet extruded through the step b is performed. The decorative processing; in step d, the decorative processed sheet is cooled and shaped; in step e, the cooled shaped sheet is cut off; and in step f, the end surface of the sheet in step e is closed.
  2. 如权利要求1所述的木塑复合装饰板的制造方法,其特征在于:步骤c所述的装饰加工处于所述板材熔融共挤之后,通过热转印设备将热转印装饰层粘附到所述板材外表面实现图案的热转印,向所述板材外表面转印图案的过程中热转印装饰层与所述板材间的压力为0.1~5kg/cm2,热转印速度参数与所述板材挤出的速度参数保持一致,所述转印图案的步骤设置在冷却定型的步骤之前。The method for manufacturing a wood-plastic composite decorative panel according to claim 1, wherein the decorative processing described in the step c is performed after the sheet is melt-co-extruded, and the thermal transfer decorative layer is adhered to the thermal transfer device. The outer surface of the plate realizes thermal transfer of the pattern, and the pressure between the thermal transfer decorative layer and the plate in the process of transferring the pattern to the outer surface of the plate is 0.1-5 kg/cm 2 , and the thermal transfer speed parameter and The speed parameters of the sheet extrusion are kept consistent, and the step of transferring the pattern is set before the step of cooling the setting.
  3. 如权利要求1所述的木塑复合装饰板的制造方法,其特征在于:步骤a中所述木芯加工方法为,首先选取实木旋切单板,在所述单板表面施聚醋酸乙烯脂乳液、丙烯酸树脂、丙烯酸-聚氨酯树脂、异氰酸酯、三聚氰胺-脲醛、脲醛胶或酚醛胶,然后按单板纹理以经纬向交叉层叠的组配坯板,之后对所述坯板施加压力并静置,获得层压板,再对所述层压板进行干燥处理,将经干燥处理的层压板裁切获得所述木芯。The method for manufacturing a wood-plastic composite decorative panel according to claim 1, wherein the wood core processing method in the step a is: first selecting a solid wood rotary cutting veneer, and applying vinyl acetate on the surface of the veneer An emulsion, an acrylic resin, an acrylic-urethane resin, an isocyanate, a melamine-urea aldehyde, a urea-formaldehyde sol, or a phenolic aldehyde, and then the laminated panels are cross-laminated in a warp and weft direction according to the veneer texture, after which the pressure is applied to the blank and allowed to stand. A laminate is obtained, and the laminate is further subjected to a drying treatment, and the dried laminate is cut to obtain the wood core.
  4. 如权利要求1、2或3所述的木塑复合装饰板的制造方法,其特征在于:步骤b中共同挤出板材的步骤需通过共挤设备将多根木芯同时平行进给,所述平行进给的木芯与木芯不直接接触并相隔一定的距离,以熔融的木塑复合材料母料与多根所述木芯共同挤出。The method for manufacturing a wood-plastic composite decorative panel according to claim 1, 2 or 3, wherein the step of coextruding the sheet in step b requires simultaneous feeding of a plurality of wood cores in parallel by a co-extrusion apparatus, said parallel The fed wood core and the wood core are not in direct contact with each other and separated by a certain distance, and the molten wood-plastic composite masterbatch is coextruded with a plurality of the wood cores.
  5. 如权利要求4所述的木塑复合装饰板的制造方法,其特征在于:步骤b所述的共挤设备包括木塑挤出机、共挤模具和木芯传送装置,所述共挤模具具有模具本体、多根木芯共同进料端、木塑整板出 料端,在步骤b中将所述共挤模具安装在所述木塑挤出机的机头上,使所述多根木芯共同进料端和所述木塑整板出料端处于同一平面上并沿同一方向设置,使所述多根木芯共同进料端和所述木塑整板出料端分别位于所述共挤模具的两侧,进而使熔融的所述热塑性木塑复合材料母料在共挤模具内对木芯进行包覆,获得由热塑性木塑复合材料包裹且具有多根木芯的共同挤出板材。The method of manufacturing a wood-plastic composite decorative panel according to claim 4, wherein the co-extrusion device according to step b comprises a wood-plastic extruder, a co-extrusion die, and a wood core conveying device, wherein the co-extrusion die has Mold body, multiple wood core common feeding end, wood plastic whole board At the material end, the co-extrusion die is installed on the head of the wood-plastic extruder in step b, so that the plurality of wood core co-feed ends and the wood-plastic whole plate discharge end are in the same plane And disposed in the same direction, wherein the plurality of wood core co-feeding ends and the wood-plastic whole plate discharge ends are respectively located on two sides of the co-extrusion die, thereby further melting the thermoplastic wood-plastic composite material mother The wood core is coated in a co-extrusion mold to obtain a coextruded sheet wrapped with a thermoplastic wood-plastic composite material and having a plurality of wood cores.
  6. 如权利要求5所述的木塑复合装饰板的制造方法,其特征在于:步骤b所使用的共挤模具还包括所述模具本体上的木芯导向棱、共挤流道、分流流道,所述木芯进料端内壁上设有多个所述木芯导向棱,所述共挤流道由沿所述木芯进料端内壁周向分布并与所述木芯进料端内壁连通的多个所述分流流道连通组成,所述分流流道为锥形流道,且多个分流流道的交汇处存在拐角,所述分流流道与所述模具本体上的所述木芯进料端连通,所述模具本体上的所述型材出料端包覆在所述共挤流道的四周。The method for manufacturing a wood-plastic composite decorative panel according to claim 5, wherein the co-extrusion die used in step b further comprises a wood core guiding rib, a co-extruded flow channel, and a split flow channel on the mold body. The inner wall of the wood core feeding end is provided with a plurality of the wood core guiding edges, and the coextrusion flow channel is circumferentially distributed along the inner wall of the feeding end of the wood core and communicates with the inner wall of the feeding end of the wood core a plurality of the split flow passages are connected to each other, the split flow passage is a tapered flow passage, and a corner exists at an intersection of the plurality of split flow passages, the split flow passage and the wooden core on the mold body The feed end is in communication, and the profile discharge end on the mold body is wrapped around the coextrusion flow passage.
  7. 如权利要求4所述的木塑复合装饰板的制造方法,其特征在于:步骤b中所述热塑性木塑复合材料母料由以下步骤制得:按质量份数称取30~60份的热塑性塑料、40~70份的木质纤维材料、0~8份的增强材料、1~10份的偶联剂或界面相容剂、0.1~6份的润滑剂、0~6份的着色剂、0.1~3份的抗老化剂、0~7份的热稳定剂、0~20份的阻燃剂、0~15份的矿物质填料,将称取好的原料放入高速混合机中,控制温度为25℃~130℃,混合5min~20min,得到所述热塑性木塑复合材料母料。The method for manufacturing a wood-plastic composite decorative panel according to claim 4, wherein the thermoplastic wood-plastic composite masterbatch in the step b is obtained by the following steps: weighing 30 to 60 parts of thermoplastics by mass parts. Plastic, 40 to 70 parts of lignocellulosic material, 0 to 8 parts of reinforcing material, 1 to 10 parts of coupling agent or interfacial compatibilizer, 0.1 to 6 parts of lubricant, 0 to 6 parts of coloring agent, 0.1 ~3 parts of anti-aging agent, 0~7 parts of heat stabilizer, 0~20 parts of flame retardant, 0~15 parts of mineral filler, put the weighed raw materials into high-speed mixer, control temperature The thermoplastic wood-plastic composite masterbatch is obtained by mixing at 25 ° C to 130 ° C for 5 min to 20 min.
  8. 如权利要求7所述的木塑复合装饰板的制造方法,其特征在于:步骤b中所述热塑性木塑复合材料母料还需要经以下步骤制得:将经高速混合机混合的所述木塑复合材料冷却至室温,得到预混料,再将所述预混料放入双螺杆造粒机中,控制温度为145℃~235℃,转速为30r/min~100r/min,再经冷却和切割过程得到颗粒状木塑复合材料母料。 The method for manufacturing a wood-plastic composite decorative panel according to claim 7, wherein the thermoplastic wood-plastic composite masterbatch in step b is further prepared by the step of mixing the wood by a high-speed mixer. The plastic composite is cooled to room temperature to obtain a premix, and the premix is placed in a twin-screw granulator at a temperature of 145 ° C to 235 ° C, a rotation speed of 30 r / min to 100 r / min, and then cooled. And the cutting process results in a granular wood-plastic composite masterbatch.
  9. 一种木塑复合装饰板,由热塑性木塑复合材料经熔融挤出工艺制成板材,其特征在于:包括热塑性木塑复合材构成的壳层和由板状木芯构成的核层,所述板状木芯构成的核层被所述热塑性木塑复合材料壳层包覆,所述板状木芯构成的核层端部具有与所述壳层连接的封闭层,所述壳层外具有经热转印技术印制得的装饰层。A wood-plastic composite decorative board, which is formed from a thermoplastic wood-plastic composite material by a melt extrusion process, and is characterized in that: a shell layer composed of a thermoplastic wood-plastic composite material and a core layer composed of a plate-shaped wood core, a core layer composed of a plate-like wood core is covered by the thermoplastic wood-plastic composite shell layer, and the core layer end portion of the plate-shaped wood core has a sealing layer connected to the shell layer, and the shell layer has a shell layer outside A decorative layer printed by thermal transfer technology.
  10. 如权利要求9所述的一种木塑复合装饰板,其特征在于:所述板状木芯为实木旋切单板经胶合层压而成,所述壳层包覆由多根木芯构成的多个核层,所述多根木芯相互平行且不直接接触,所述木芯与木芯之间相隔一定的距离。 A wood-plastic composite decorative board according to claim 9, wherein the plate-shaped wood core is a solid wood rotary-cut veneer which is laminated by a glue, and the shell layer is covered by a plurality of wood cores. a plurality of core layers, the plurality of wood cores being parallel to each other and not in direct contact, and the wood core and the wood core are separated by a certain distance.
PCT/CN2015/070955 2015-01-17 2015-01-17 Wood-plastic composite decorative panel and manufacturing method thereof WO2016112554A1 (en)

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