CN107502190A - A kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof - Google Patents
A kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof Download PDFInfo
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- CN107502190A CN107502190A CN201710862500.XA CN201710862500A CN107502190A CN 107502190 A CN107502190 A CN 107502190A CN 201710862500 A CN201710862500 A CN 201710862500A CN 107502190 A CN107502190 A CN 107502190A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof, belongs to bridge floor and China Democratic National Construction Association's water-repellent paint technical field.The coating includes 45 50 parts of pitches, 2 10 parts of tackifier, 10 40 parts of fillers, 45 50 parts of solvents, 0.6 1 parts of emulsifying agents, 20 30 parts of rubber powders, 10 20 parts of stabilizers, 0.6 1 parts of age resisters, 45 50 parts of water.Softening point of the present invention is not easy to crack compared with high and low temperature, adhesive strength is high, pliability improves, top layer is not easy the factors such as ponding, self-cleaning ability be strong so that waterproof coating service life and follow-up top layer cleaning up cost cost substantially reduce, while are also beneficial to bonding with upper layer of material；Process flow is simple, workable；It is not required to transformation existing equipment to can be used, equipment and the cost of raw material are cheap, remarkable in economical benefits, are adapted to industrialized production.The present invention will play a great role in fields such as traffic, China Democratic National Construction Associations, wide market.
Description
Technical field
The present invention relates to a kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof, belongs to bridge floor and China Democratic National Construction Association's waterproof applies
Expect technical field.
Background technology
Using water-repellent paint come to prevent the infiltration of building and leak be just to have begun to late 1950s use
A kind of waterproof method.The mid-50, petroleum emulsification pitch being prepared by emulsifying agent of lime, this coating is mostly extemporaneous preparation,
Performance is unstable, and application effect is bad, then develops water-repellent paint that lime paste emulsified asphalt etc. is primary raw material etc. again and is
Row product, develop bentonite emulsified asphalt water-proof paint and water-based asbestos bitumen water-repellent paint etc. the 1970s again, this
A little coating are once promoted the use of a large area in waterproofing work, but these coating or because of poor quality, and waterproof layer service life is short,
Or because environmental pollution does not reach relevant criterion requirement, workmen's health is had a strong impact on, dosage is more and more at present
It is few.At the same time, occur solvent-borne type chloroprene rubber asphalt waterproofing coating in middle 1960s, water occur the end of the seventies
, there is emulsion type the beginning of the eighties in newborn type reclaimed rubber asphalt waterproofing paint（That is cationic）Chloroprene rubber asphalt waterproofing coating, water
Newborn type styrene butadiene rubber modified asphalt water-repellent paint, SBS rubber asphalts solvent-type waterproofing paint, butyl rubber asphalt solvent type waterproof
Coating, NBR latex asphalt waterproofing paint etc..The country mainly uses cationic system modified emulsifying asphalt water-repellent paint, institute at present
The modifying agent used is SBS, SBR, CR etc., can adjust addition according to different use demands respectively.
Although the water-repellent paint being modified to emulsified asphalt has many types, while has carried out substantial amounts of research both at home and abroad,
Modified emulsifying asphalt class water-repellent paint can run into the problem of some are peculiar in actual use at present, be mainly reflected in：（1）
It is relatively low with the adhesion strength of cement basic layer, it is easy to fall off so as to cause；（2）Softening point is relatively low, after construction, in the higher ring of temperature
Tire is easily glued under border；（3）Low-temperature stability is poor, easily cracked, causes waterproof hidden danger.According to JC/T975-2005《Road
Bridge water-repellent paint》、《Road Engineering Quality Checking And Evaluation standard》Construction quality can not be completely secured to carry out coherent detection,
Its adhesion strength and stability can not meet to require, greatly shorten the service life of the buildings such as bridge.
Meanwhile existing modified emulsifying asphalt waterproof coating because surface smoothness is high, surface energy is larger, self-cleaning ability is poor etc. because
Element causes waterproof coating easily to pollute, easily assemble water droplet, so as to greatly reduce actual waterproof effect, adds subsequent construction and brings
Waterproof coating top layer cleaning etc. needed for expense, make so as to hinder existing being widely applied for modified emulsifying asphalt water-repellent paint
With.
So for water-repellent paint defect set forth above, new hydrophobic type Emulsificated asphalt water-proof painting material is developed.
The content of the invention
The present invention is intended to provide a kind of hydrophobic type Emulsificated asphalt water-proof painting material and preparation method thereof, to meet China Democratic National Construction Association, bridge floor
The requirement of waterproof also reduces engineering cost simultaneously, has far-reaching society and economic benefit.
It is logical by the inspiration of natural plant surface such as lotus leaf, taro leaves and insect surfaces such as butterfly's wing etc., the present invention
A kind of high and low temperature is stable, adhesion strength is high, film self-cleaning property for prepared by crossing the means such as addition filler, solvent volatilization technique
It is strong and be not easy to assemble water droplet, be easy to waterproof uses in terms of bridge floor and China Democratic National Construction Association hydrophobic type Emulsificated asphalt water-proof painting material and its preparation side
Method.
The invention provides a kind of hydrophobic type Emulsificated asphalt water-proof painting material, include the component of following parts by weight：45-50 parts
Pitch, 2-10 parts tackifier, the filler of 10-40 parts, the solvent of 45-50 parts, the emulsifying agent of 0.6-1 parts, the rubber of 20-30 parts
Powder, the stabilizer of 10-20 parts, 0.6-1 age resister, the water of 45-50 parts.
In such scheme, the pitch is one kind in domestic 90# pitches, shell 90# pitches or SK90# pitches.
In such scheme, the tackifier are polyvinyl alcohol, polyacrylamide, polyvinylpyrrolidone, polyacrylate
One kind in copolymer emulsion or butadiene rubber.
In such scheme, the filler is hydrophobic nano SiO2, micron order CaCO3, titanium dioxide, one in talcum powder etc.
Kind or several mixing, proportioning is 10~30 parts during four kinds of material mixings：0~15 part：0~20 part：0~25 part.
In such scheme, the solvent is absolute methanol（Analyze pure）, ethanol（Analyze pure）Or acetone（Analyze pure）In
It is a kind of.
In such scheme, the emulsifying agent is DTAC, hexadecyltrimethylammonium chloride, 18
One kind in alkyl trimethyl ammonium chloride.
In such scheme, the rubber powder is styrene butadiene rubber powder or rubber powder of waste tire.
In such scheme, the stabilizer is chloroprene rubber powder or butyronitrile powder.
In such scheme, the age resister is the one of tert-butyl group anisole, BHT or phosphorous acid esters
Kind.
The invention provides a kind of preparation method of hydrophobic type Emulsificated asphalt water-proof painting material, the preparation method specific steps
For：Each component is weighed by formula, tackifier, emulsifying agent, polymer, stabilizer, water is well mixed at 60~65 DEG C, and pitch adds
Heat is to 130~135 DEG C, by above-mentioned two parts in proportion at the uniform velocity after colloid mill high speed shear uniformly mixing, and add in proportion
Enter filler, solvent, age resister to disperse to produce at a high speed in 1500~2500r/min.
Beneficial effects of the present invention
（1）Hydrophobic type Emulsificated asphalt water-proof painting material provided by the invention belongs to the higher waterproof of new hydrophobic type, cost performance and applied
Material.The water-repellent paint substantially improve conventional rubber elastomer modified emulsifying asphalt water-repellent paint softening point is low, low temperature is easy to crack,
The shortcomings of adhesion strength is low, pliability is poor, easy ponding, resistance to soiling difference；The adhesion strength of waterproof coating and basic unit is improved, is improved
The performances such as the ageing-resistant and resistance to greasy dirt of film, improve the actual effect and service life of waterproof coating, reduce because of film
The unnecessary cost increase that cleaning tape of getting dirty is come, improves the adhesion strength and using effect with upper layer of material.
（2）The invention provides the preparation method of above-mentioned coating, and it is produced, construction technology is prevented with existing modified emulsifying asphalt
Water paint is completely the same, it is not necessary to carries out equipment investment and production and site operation can be achieved；It is cost-effective.
Embodiment
The present invention is further illustrated below by embodiment, but is not limited to following examples.
Embodiment 1：
By each component proportion by weight, by 2 parts of polyvinyl alcohol, 0.6 part of DTAC, 20 parts of SBR powder, CR powder
10 parts, 45 parts of water it is well mixed at 60 DEG C, 45 parts of 90# pitches are heated to 135 DEG C, and above-mentioned two parts are at the uniform velocity passed through into glue in proportion
Body mill high speed shear uniformly after mixing, adds hydrophobic nano SiO210 parts of filler, micron order CaCO35 parts of filler, absolute methanol
0.6 part of 45 parts, tert-butyl group anisole obtained hydrophobic type Emulsificated asphalt water-proof painting material after 1800r/min is scattered at a high speed.
Embodiment 2
By each component proportion by weight, by 2 parts of polyvinyl alcohol, 0.6 part of DTAC, 25 parts of SBR powder, CR powder
10 parts, 45 parts of water it is well mixed at 65 DEG C, 45 parts of 90# pitches are heated to 135 DEG C, and above-mentioned two parts are at the uniform velocity passed through into glue in proportion
Body mill high speed shear uniformly after mixing, adds hydrophobic nano SiO210 parts of filler, micron order CaCO38 parts of filler, absolute methanol
0.6 part of 45 parts, tert-butyl group anisole obtained hydrophobic type Emulsificated asphalt water-proof painting material after 2500r/min is scattered at a high speed.
Embodiment 3
By each component proportion by weight, by 2 parts of polyacrylamide, 0.8 part of DTAC, 25 parts of SBR powder, CR
15 parts of powder, 45 parts of water are well mixed at 65 DEG C, and 50 parts of 90# pitches are heated to 130 DEG C, and above-mentioned two parts are at the uniform velocity passed through in proportion
Colloid mill high speed shear uniformly after mixing, adds hydrophobic nano SiO215 parts of filler, micron order CaCO310 parts of filler, without water beetle
Hydrophobic type Emulsificated asphalt water-proof painting material is made after 2200r/min is scattered at a high speed in 45 parts of alcohol, 0.6 part of tert-butyl group anisole.
Embodiment 4
By each component proportion by weight, by 2.5 parts of polyacrylamide, 1 part of OTAC, 28 parts of SBR powder, CR
15 parts of powder, 45 parts of water are well mixed at 62 DEG C, and 48 parts of 90# pitches are heated to 135 DEG C, and above-mentioned two parts are at the uniform velocity passed through in proportion
Colloid mill high speed shear uniformly after mixing, adds hydrophobic nano SiO218 parts of filler, micron order CaCO310 parts of filler, without water beetle
Hydrophobic type Emulsificated asphalt water-proof painting material is made after 2000r/min is scattered at a high speed in 45 parts of alcohol, 0.6 part of tert-butyl group anisole.
Embodiment 5
By each component proportion by weight, by 2.5 parts of polyvinylpyrrolidone, 1 part of OTAC, SBR powder 28
Part, 15 parts of CR powder, 50 parts of water are well mixed at 65 DEG C, and 50 parts of 90# pitches are heated to 133 DEG C, and above-mentioned two parts are even in proportion
Speed adds hydrophobic nano SiO after colloid mill high speed shear uniformly mixing220 parts of filler, micron order CaCO310 parts of filler,
50 parts of absolute ethyl alcohol, 0.6 part of tert-butyl group anisole are made hydrophobic type emulsified asphalt waterproof after 1900r/min is scattered at a high speed and applied
Material.
Embodiment 6
By each component proportion by weight, by 3 parts of polyvinylpyrrolidone, 1 part of OTAC, 28 parts of SBR powder,
20 parts of CR powder, 50 parts of water are well mixed at 65 DEG C, and 50 parts of 90# pitches are heated to 134 DEG C, and above-mentioned two parts are at the uniform velocity passed through in proportion
After crossing the uniform mixing of colloid mill high speed shear, hydrophobic nano SiO is added220 parts of filler, 15 parts of titanium dioxide filler, absolute ethyl alcohol
0.6 part of 50 parts, tert-butyl group anisole obtained hydrophobic type Emulsificated asphalt water-proof painting material after 1500r/min is scattered at a high speed.
Embodiment 7
By each component proportion by weight, by 3 parts of polyvinylpyrrolidone, 1 part of OTAC, 28 parts of SBR powder,
20 parts of CR powder, 50 parts of water are well mixed at 60 DEG C, and 50 parts of 90# pitches are heated to 135 DEG C, and above-mentioned two parts are at the uniform velocity passed through in proportion
After crossing the uniform mixing of colloid mill high speed shear, hydrophobic nano SiO is added222 parts of filler, 15 parts of titanium dioxide, absolute ethyl alcohol 50
Hydrophobic type Emulsificated asphalt water-proof painting material is made after 2500r/min is scattered at a high speed in part, 0.6 part of tert-butyl group anisole.
Embodiment 8
By each component proportion by weight, by 3 parts of Polyacrylate Emulsion, 0.8 part of hexadecyltrimethylammonium chloride, SBR
28 parts of powder, 20 parts of CR powder, 50 parts of water are well mixed at 65 DEG C, and 50 parts of 90# pitches are heated to 135 DEG C, by above-mentioned two parts press than
Example at the uniform velocity after colloid mill high speed shear uniformly mixing, adds hydrophobic nano SiO2It is 22 parts of filler, 15 parts of talcum powder, anhydrous
Hydrophobic type Emulsificated asphalt water-proof painting material is made after 2400r/min is scattered at a high speed in 50 parts of ethanol, 0.6 part of tert-butyl group anisole.
Embodiment 9
By each component proportion by weight, by 3 parts of Polyacrylate Emulsion, 0.8 part of hexadecyltrimethylammonium chloride, SBR
28 parts of powder, 20 parts of CR powder, 50 parts of water are well mixed at 62 DEG C, and 50 parts of 90# pitches are heated to 130 DEG C, by above-mentioned two parts press than
Example at the uniform velocity after colloid mill high speed shear uniformly mixing, adds hydrophobic nano SiO2It is 22 parts of filler, 20 parts of talcum powder, anhydrous
Hydrophobic type Emulsificated asphalt water-proof painting material is made after 1850r/min is scattered at a high speed in 50 parts of methanol, 0.6 part of tert-butyl group anisole.
Performance detection：
Hydrophobic type Emulsificated asphalt water-proof painting material obtained by the present invention and existing pure Emulsificated asphalt water-proof painting material, modified emulsifying are dripped
Blue or green water-repellent paint（It is purchased in market, Taiyuan City Jinyuan District Jin Yuan Building Materials Factories）It is compared：
Pure Emulsificated asphalt water-proof painting material by the aqueous solution of pitch and emulsifying agent colloid mill effect under be made, its solid content be 50 ±
2%；
Modified emulsifying asphalt water-repellent paint is that outer ginseng modifying agent styrene-butadiene latex is uniformly dispersed after emulsified asphalt is made by aforesaid way
It is made, solid content is 50 ± 2%.
Detect foundation：The test of adhesive strength, tensile strength, elongation at break, impermeability, resistance to acids and bases technical indicator
Method foundation《Aqueous emulsion asphalt waterproofing paint》JC/T408-2005.Contact-angle measurement uses deionized water, and liquid volume is 5 μ
L, with the measurement of TY-82 contact measurements instrument in the static contact angle of coating surface, its technical indicator contrast such as following table：
Three kinds of water-repellent paint performance comparison tables
A kind of hydrophobic type Emulsificated asphalt water-proof painting material provided by the invention proves by experiment and site operation：The water-repellent paint glues
Knotting strength, tensile strength, elongation at break etc. substantially increase, and suitable for many waterproofing works such as bridge deck water-proof, civil buildings, prolong
The service life of building has been grown, has saved maintenance of works cost, economic benefit is all good, is current preferably water-repellent paint choosing
Select.A kind of hydrophobic type Emulsificated asphalt water-proof painting material production process control and process route and existing modification simultaneously of the present invention
Emulsificated asphalt water-proof painting material is consistent, is not required to the correlative investments such as equipment and technical training.The present invention will be sent out in fields such as traffic, China Democratic National Construction Associations
Great function is waved, wide market, there is good society and economic benefit.
Claims (10)
- A kind of 1. hydrophobic type Emulsificated asphalt water-proof painting material, it is characterised in that：Include the component of following parts by weight：45-50 parts drip Green grass or young crops, 2-10 parts tackifier, 10-40 parts filler, 45-50 parts solvent, 0.6-1 parts emulsifying agent, 20-30 parts rubber powder, 10-20 parts are steady Determine agent, 0.6-1 parts age resister, 45-50 part water.
- 2. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The pitch is domestic 90# One kind in pitch, shell 90# pitches or SK90# pitches.
- 3. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The tackifier are polyethylene One kind in alcohol, polyacrylamide, polyvinylpyrrolidone, Polyacrylate Emulsion or butadiene rubber.
- 4. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The filler is received for hydrophobicity Rice SiO2, micron order CaCO3, titanium dioxide, one or more of mixing in talcum powder, during four kinds of material mixings proportioning for 10~ 30 parts：0~15 part：0~20 part：0~25 part.
- 5. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The solvent is without water beetle One kind in alcohol, ethanol or acetone.
- 6. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The emulsifying agent is dodecane One kind in base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride or OTAC.
- 7. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The rubber powder is butylbenzene rubber Rubber powder or rubber powder of waste tire.
- 8. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The stabilizer is neoprene rubber Rubber powder or butyronitrile powder.
- 9. hydrophobic type Emulsificated asphalt water-proof painting material according to claim 1, it is characterised in that：The age resister is tertiary fourth One kind in base anisole, BHT or phosphorous acid esters.
- 10. a kind of preparation method of the hydrophobic type Emulsificated asphalt water-proof painting material described in any one of claim 1 ~ 9, the preparation side Method concretely comprises the following steps：Each component is weighed by formula, by tackifier, emulsifying agent, polymer, stabilizer, water in 60~65 DEG C of mixing Uniformly, pitch is heated to 130~135 DEG C, and above-mentioned two parts are at the uniform velocity uniformly mixed by colloid mill high speed shear in proportion, and Filler, solvent, age resister is proportionally added into disperse to produce at a high speed in 1500~2500r/min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108252530A (en) * | 2018-01-23 | 2018-07-06 | 厦门防水博士建筑工程有限公司 | A kind of parapet percolating water repairs technique |
| CN108343164A (en) * | 2018-01-31 | 2018-07-31 | 刘志宏 | A kind of expansion joint percolating water repairerment technique |
| CN109251668A (en) * | 2018-08-30 | 2019-01-22 | 内蒙古万创新型建材有限公司 | Rubber asphalt fast filming water-repellent paint |
| CN110128945A (en) * | 2018-03-13 | 2019-08-16 | 西牛皮防水科技有限公司 | Rubber Modified Asphalt Waterproof Coating and its preparation method and application |
| CN111253863A (en) * | 2020-03-12 | 2020-06-09 | 洛阳腾飞市政工程有限公司 | Hydrophobic pavement coating material and preparation method thereof |
| CN111440539A (en) * | 2020-05-29 | 2020-07-24 | 樊雪梅 | Modified asphalt waterproof coating |
| WO2023045553A1 (en) * | 2021-09-26 | 2023-03-30 | 江苏凯伦建材股份有限公司 | Highly water-resistant environmentally-friendly waterproof sealant, preparation method therefor and application thereof |
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| CN105086476A (en) * | 2014-05-08 | 2015-11-25 | 重庆市化工研究院 | Composite emulsion modified emulsified asphalt and preparation method therefor |
| CN105694494A (en) * | 2016-03-30 | 2016-06-22 | 徐州卧牛山新型防水材料有限公司 | Emulsified asphalt and preparation method thereof, and water-based substrate treating agent for asphalt waterproof coiled materials and preparation method thereof |
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| CN1613939A (en) * | 2004-09-16 | 2005-05-11 | 王耀波 | Waterproof sealing compound for asphalt road surface, production and applied constructing process |
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| CN105086476A (en) * | 2014-05-08 | 2015-11-25 | 重庆市化工研究院 | Composite emulsion modified emulsified asphalt and preparation method therefor |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108252530A (en) * | 2018-01-23 | 2018-07-06 | 厦门防水博士建筑工程有限公司 | A kind of parapet percolating water repairs technique |
| CN108343164A (en) * | 2018-01-31 | 2018-07-31 | 刘志宏 | A kind of expansion joint percolating water repairerment technique |
| CN110128945A (en) * | 2018-03-13 | 2019-08-16 | 西牛皮防水科技有限公司 | Rubber Modified Asphalt Waterproof Coating and its preparation method and application |
| CN110128946A (en) * | 2018-03-13 | 2019-08-16 | 西牛皮防水科技有限公司 | Bi-component Rubber Modified Asphalt Waterproof Coating and its preparation method and application |
| CN109251668A (en) * | 2018-08-30 | 2019-01-22 | 内蒙古万创新型建材有限公司 | Rubber asphalt fast filming water-repellent paint |
| CN111253863A (en) * | 2020-03-12 | 2020-06-09 | 洛阳腾飞市政工程有限公司 | Hydrophobic pavement coating material and preparation method thereof |
| CN111440539A (en) * | 2020-05-29 | 2020-07-24 | 樊雪梅 | Modified asphalt waterproof coating |
| WO2023045553A1 (en) * | 2021-09-26 | 2023-03-30 | 江苏凯伦建材股份有限公司 | Highly water-resistant environmentally-friendly waterproof sealant, preparation method therefor and application thereof |
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Application publication date: 20171222 |