CN107502159A - A kind of preparation method of efficient short oil-ity alcohol acid resin corrosive enamel - Google Patents
A kind of preparation method of efficient short oil-ity alcohol acid resin corrosive enamel Download PDFInfo
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- CN107502159A CN107502159A CN201711001692.1A CN201711001692A CN107502159A CN 107502159 A CN107502159 A CN 107502159A CN 201711001692 A CN201711001692 A CN 201711001692A CN 107502159 A CN107502159 A CN 107502159A
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- acid resin
- alcohol acid
- short oil
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a kind of preparation method of efficient short oil-ity alcohol acid resin corrosive enamel; using dryness short oil-ity alcohol acid resin and the β acyl groups camptothecine of 20 (s) O, 3 β acetoxyl groups, 5 androstene 17 as film forming matter; using ortho-xylene as solvent; the manganese salt of the polyether-modified Dimethicone Copolyol body of talcum powder, bentonite, dispersant polyethylene glycol 200, levelling agent and drier aphthenic acids is added, high-speed stirred produces efficient short oil-ity alcohol acid resin corrosive enamel.The enamel paint has higher decay resistance and ageing-resistant performance, can be applied to the heavy antisepsis engineering in the fields such as petrochemical equipment, pipeline, offshore oil platform, terminal facilities, ship.
Description
Technical field
The present invention relates to enamel paint field, more particularly, to a kind of preparation side of efficient short oil-ity alcohol acid resin corrosive enamel
Method.
Background technology
Because the equipment such as petrochemical equipment, pipeline, offshore oil platform, ship are corroded by atmospheric environment, particularly ship
Oceangoing ship equipment underwater position is because easily ftracture in the corrosive mediums such as long period of soaking sodium chloride by foaming, the method handled at present
It is to add the heavy metal compounds such as substantial amounts of lead orthoplumbate in paint formulation, but this kind of corrosion-inhibiting coating constantly has these heavy
Metallic lead plasma separates out, and serious Marine Pollution, river and soil environment, serious shadow is caused to global ecological environment and human body
Ring.But due to currently without suitable substitute technology, therefore, it is significant to find suitable substitute technology.
Alkyd resin is formed by polyalcohol, phthalic anhydride and aliphatic acid or oil (fatty acid triglyceride) condensation polymerization
Oil modified polyester resin.Many hydrogen bonds in alkyd resin macromolecular be present, intermolecular force is big, can be with many compounds
Crosslinking film forming is carried out, so having using alkyd resin as the alkyd resin antifouling paint that film forming matter is made into preferably corrosion-resistant
Property, the characteristic such as permeability resistance, wearability and preferable adhesive force, it is but many with the variable factor of alkyd resin crosslinking film forming,
At present because the monomer of selection matches with alkyd resin incorrect, the rigidity of crosslinking is also poor, and therefore, decay resistance is not very
Height, it can not meet the needs of actual adverse circumstances.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of simple, easy to manufacture, a kind of efficient short oil alcohol of equipment
The preparation method of acid resin corrosive enamel.
In order to solve the above technical problems, the present invention adopts the following technical scheme that:With dryness short oil-ity alcohol acid resin and 20
(s)-O-3 beta-acetoxyl group-5s-the β of androstene-17-acyl group camptothecine is film forming matter, using ortho-xylene as solvent, adds cunning
The polyether-modified Dimethicone Copolyol body of stone flour, bentonite, dispersant polyethylene glycol 200, levelling agent and drier cycloalkanes
It is prepared by the manganese salt of acid.
A kind of preparation method of above-mentioned efficient short oil-ity alcohol acid resin corrosive enamel, with dryness short oil-ity alcohol acid resin and
20 (the s)-O-3 beta-acetoxyl group-5s-β of androstene-17-acyl group camptothecine is film forming matter, using ortho-xylene as solvent, is added
The polyether-modified Dimethicone Copolyol body of talcum powder, bentonite, dispersant polyethylene glycol 200, levelling agent and drier ring
The manganese salt of alkanoic acid, stir and produce in retort high speed.
A kind of preparation method of above-mentioned efficient short oil-ity alcohol acid resin corrosive enamel, including procedure below:
By the dryness short oil-ity alcohol acid resin of 10~30 parts by weight, 20 (s)-O-3 beta-acetoxyl group-5s-hero of 15~30 parts by weight
- 17 β of steroid alkene-acyl group camptothecine and the ortho-xylene solvent of 40~60 parts by weight are together added in retort and stirred, followed by
Continue the talcum powder of 5~20 parts by weight, the bentonite of 5~15 parts by weight, the dispersant polyethylene glycol 200 of 1~10 parts by weight, 1
The manganese salt of the polyether-modified Dimethicone Copolyol body of levelling agent of~8 parts by weight, the drier aphthenic acids of 1~6 parts by weight
Together put the stirring of retort high speed into and produce within 1 hour a kind of efficient short oil-ity alcohol acid resin corrosive enamel.
Experiment is found, with dryness short oil-ity alcohol acid resin and 20 (the s)-O-3 beta-acetoxyl group-5s-β of androstene-17-acyl group
Camptothecine is film forming matter, using ortho-xylene as solvent, adds talcum powder, bentonite, dispersant polyethylene glycol 200, levelling
Short oil-ity alcohol acid resin anti-corrosion magnetic prepared by the manganese salt of the polyether-modified Dimethicone Copolyol body of agent and drier aphthenic acids
Paint, be sprayed in tinplate sheet, test when being soaked 100 hours in 3.5% sodium chloride solution it is non-foaming, do not ftracture, do not take off
Fall;Tested on electrochemical operation, bare area is 1 square centimeter, and AC impedance is in 500 k Ω .cm2Left and right, therefore, system
Standby short oil-ity alcohol acid resin corrosive enamel has higher Corrosion Protection, more than current short oil-ity alcohol acid resin anti-corrosion magnetic
Paint, and equipment is simple, it is easy to make.
Brief description of the drawings
Fig. 1 is a kind of AC impedance figure of efficient short oil-ity alcohol acid resin corrosive enamel in embodiment 1.
Embodiment
Embodiment 1
First, the processing of tinplate sheet
Tinplate sheet is polished with the alumina powder of 1.0 μm, 0.3 μm successively on polishing cloth, is then placed in 5% hydrochloric acid
6 min of ultrasound, place into deionized water and are cleaned by ultrasonic 5 min, be finally putting into absolute ethyl alcohol after 6 min of ultrasound dry it is standby
With.
2nd, the preparation of short oil-ity alcohol acid resin corrosive enamel
By the dryness short oil-ity alcohol acid resin of 15 parts by weight, 20 (s)-O-3 beta-acetoxyl group-5s-androstene -17 of 20 parts by weight
β-acyl group camptothecine and the ortho-xylene solvent of 50 parts by weight are together added in retort and stirred, and are further continued for 15 parts by weight
Talcum powder, the bentonite of 15 parts by weight, the dispersant polyethylene glycol 200 of 2 parts by weight, the levelling agent of 2 parts by weight it is polyether-modified
Dimethicone Copolyol body, 1 parts by weight drier aphthenic acids manganese salt together add retort high speed stir 1 hour
Produce;
3rd, the antiseptic property test of short oil-ity alcohol acid resin corrosive enamel
<1>The short oil-ity alcohol acid resin corrosive enamel of preparation is used into solvent volume ratio as 3:2 dimethylbenzene and butyl acetate mixes
Bonding solvent dilutes, and is then sprayed in standby tinplate sheet, is soaked in after 24 hours in 3.5% sodium chloride solution, soaks
100 hours, it is no foaming, without cracking, without obscission.
<2>Take step<1>It is coated with the tinplate sheet of the short oil-ity alcohol acid resin corrosive enamel of preparation, tinplate sheet film
Bare area be 1 square centimeter, electrochemical AC impedance test is carried out in 3.5% sodium chloride solution, AC impedance connects
Nearly 500 k Ω .cm2Left and right.
Therefore, the short oil-ity alcohol acid resin corrosive enamel has higher antiseptic property.
Claims (1)
- A kind of 1. preparation method of efficient short oil-ity alcohol acid resin corrosive enamel, it is characterised in that the composition of film forming agent is 10~ The dryness short oil-ity alcohol acid resin of 30 parts by weight, 20 (s)-O-3 beta-acetoxyl group-5s-β of androstene-17-of 15~30 parts by weight Acyl group camptothecine;Specifically carried out by following operation:By the dryness short oil-ity alcohol acid resin of 10~30 parts by weight, 20 (s)-O-3 beta-acetoxyl group-5s-hero of 15~30 parts by weight - 17 β of steroid alkene-acyl group camptothecine and the ortho-xylene solvent of 40~60 parts by weight are together added in retort and stirred, followed by Continue the talcum powder of 5~20 parts by weight, the bentonite of 5~15 parts by weight, the dispersant polyethylene glycol 200 of 1~10 parts by weight, 1 The manganese salt of the polyether-modified Dimethicone Copolyol body of levelling agent of~8 parts by weight, the drier aphthenic acids of 1~6 parts by weight Together put the stirring of retort high speed into and produce within 1 hour a kind of efficient short oil-ity alcohol acid resin corrosive enamel.
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CN201711001692.1A CN107502159A (en) | 2017-10-24 | 2017-10-24 | A kind of preparation method of efficient short oil-ity alcohol acid resin corrosive enamel |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110229595A (en) * | 2019-07-12 | 2019-09-13 | 广西民族大学 | A kind of preparation method of the abietyl short oil-ity alcohol acid resin corrosive enamel of high pitting potential |
CN110330873A (en) * | 2019-07-12 | 2019-10-15 | 广西民族大学 | A kind of preparation method of the alkyd resin corrosive enamel of high pitting potential |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102746360A (en) * | 2012-06-19 | 2012-10-24 | 广西民族大学 | Synthesis and application of four new conjugates of camptothecin-steroid |
CN102863881A (en) * | 2012-09-14 | 2013-01-09 | 黄宣斐 | Steel-surface environment-friendly anticorrosive paint and preparation method thereof |
-
2017
- 2017-10-24 CN CN201711001692.1A patent/CN107502159A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102746360A (en) * | 2012-06-19 | 2012-10-24 | 广西民族大学 | Synthesis and application of four new conjugates of camptothecin-steroid |
CN102863881A (en) * | 2012-09-14 | 2013-01-09 | 黄宣斐 | Steel-surface environment-friendly anticorrosive paint and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110229595A (en) * | 2019-07-12 | 2019-09-13 | 广西民族大学 | A kind of preparation method of the abietyl short oil-ity alcohol acid resin corrosive enamel of high pitting potential |
CN110330873A (en) * | 2019-07-12 | 2019-10-15 | 广西民族大学 | A kind of preparation method of the alkyd resin corrosive enamel of high pitting potential |
CN110330873B (en) * | 2019-07-12 | 2021-04-23 | 广西民族大学 | Preparation method of alkyd resin anticorrosive enamel with high pitting potential |
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Application publication date: 20171222 |