CN107499015A - A kind of electrochemical aluminum foil - Google Patents

A kind of electrochemical aluminum foil Download PDF

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Publication number
CN107499015A
CN107499015A CN201710764680.8A CN201710764680A CN107499015A CN 107499015 A CN107499015 A CN 107499015A CN 201710764680 A CN201710764680 A CN 201710764680A CN 107499015 A CN107499015 A CN 107499015A
Authority
CN
China
Prior art keywords
chromatograph
sealant
aluminium lamination
layer
aluminum foil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710764680.8A
Other languages
Chinese (zh)
Inventor
马艳超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhengzhou Huamei Color Printing Paper Products Co Ltd
Original Assignee
Zhengzhou Huamei Color Printing Paper Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou Huamei Color Printing Paper Products Co Ltd filed Critical Zhengzhou Huamei Color Printing Paper Products Co Ltd
Priority to CN201710764680.8A priority Critical patent/CN107499015A/en
Publication of CN107499015A publication Critical patent/CN107499015A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0358Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/107Ceramic
    • B32B2264/108Carbon, e.g. graphite particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/406Bright, glossy, shiny surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/416Reflective

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of electrochemical aluminum foil, belongs to printing technology, including pet layer, peel ply, sealant, chromatograph, aluminium lamination and the adhesive-layer set gradually from top to bottom;The sealant is film made of high density polyethylene (HDPE);The present invention has sets sealant between peel ply and chromatograph; sealant forms fine and close protective layer in chromatograph periphery; avoid pigment in corrosive substance and chromatograph in the oxygen rainwater in air react colourless generation or the material of other colors and the pigment that avoids in chromatograph destroy after corrosive substance in oxygen or rainwater in air can travel further into aluminium lamination, by the metallic aluminium oxidation in aluminium lamination so that the advantages of pattern tarnishes.

Description

A kind of electrochemical aluminum foil
Technical field
The invention belongs to printing technology, and in particular to a kind of electrochemical aluminum foil.
Background technology
Electrochemical aluminum foil is that one kind is added with layer of metal paper tinsel and manufactured thermoprint in film chip base through coating and vacuum evaporation Material, its packaged form are roll type.It is more using gold and silver color, it has as ornament materials that electrochemical aluminum foil, which can replace metal foil, There is the features such as magnificent attractive in appearance, bright in colour, sparkling and crystal-clear brilliant, easy to use, suitable in paper, plastics, leather, fabric, coating Thermoprint on the materials such as material, lucite;The printed matter produced in a manner of gold stamping is because its metal-like is strong, prominent design is led Topic, it is wear-resisting the advantages that and be widely used.
Because gold stamping mode using the mode of HTHP carries out thermoprint, this require peel ply can quickly from Separated on pet layer and adhesive-layer can quickly be bonded in print and scald on thing;After electrochemical aluminum foil, which is printed, to scald in print boiling hot thing, by It is exposed in atmosphere in chromatograph, cause the color of chromatograph thin out and the gloss of pattern disappears by exposing to the weather for a long time and drenching with rain Lose, lose original magnificent and gloss so as to cause to print boiling hot thing and lose Packaging Value.
The content of the invention
It is an object of the invention to:Exist for above-mentioned electrochemical aluminum foil and exposed for a long time in atmosphere and expose to the weather and drench with rain Cause the color of chromatograph thin out and the problem of the gloss of pattern disappears, the present invention provides a kind of electrochemical aluminum foil.
The technical solution adopted by the present invention is as follows:
A kind of electrochemical aluminum foil, including pet layer, peel ply, sealant, chromatograph, the aluminium lamination and viscous set gradually from top to bottom Glue-line;The sealant is film made of high density polyethylene (HDPE).
Preferably, adjacent in the sealant, chromatograph, aluminium lamination and adhesive-layer is connected by PVC crosslinking agents between the two Connect.
Preferably, CNT is added in the aluminium lamination, the wall thickness of CNT is 10~15nm.
Preferably, the mass ratio of the CNT and aluminium is 1:150~200.
Preferably, the thickness of the adhesive-layer is between 15nm~28nm.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
1. setting sealant between peel ply and chromatograph, sealant forms fine and close protective layer in chromatograph periphery, avoids Pigment reacts that generation is colourless or other colors in the corrosive substance and chromatograph in oxygen or rainwater in air The corrosive substance in oxygen or rainwater after material and the pigment avoided in chromatograph destroy in air can further enter Enter aluminium lamination, the metallic aluminium in aluminium lamination is aoxidized, so that pattern tarnishes.
2. adjacent in sealant, chromatograph, aluminium lamination and adhesive-layer is connected by PVC crosslinking agents between the two, due to PVC adds sealant, color together with being mixed well with the CNT in sealant, chromatograph, aluminium lamination and adhesive-layer Fastness in layer, aluminium lamination and adhesive-layer between adjacent two layers, avoids the generation of delamination.
3. CNT is added in aluminium lamination, on the one hand can be with aluminium lamination both sides because CNT has many apertures PVC crosslinking agents be attached together, on the other hand can provide movable passageway for aluminium atom, it is anti-on aluminium lamination so as to change light Firing angle degree so that pattern radiates brilliant light, more gorgeous.
4. because the color of CNT is black, cause so being largely added to and the light that irradiation comes being absorbed in aluminium lamination Intensity of reflected light weakens, so the mass ratio of CNT and aluminium is 1:Volume reflection influence when 150~200 both on light is small or can So that the reflection angle of light changes.
5. it is longer easily to be bonded at the times that are more firm and needing on the boiling hot thing of print for electrochemical aluminum foil when the thickness of adhesive-layer is thicker Cause the sensitivity of adhesive-layer and peel ply to heat asynchronous, so as to influence hot stamping effects.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention;
Wherein:1-PET layers;2- peel plies;3- sealants;4- chromatographs;5- aluminium laminations;6- adhesive-layers.
Embodiment
All features disclosed in this specification, or disclosed all methods or during the step of, except mutually exclusive Feature and/or step beyond, can combine in any way.The present invention is elaborated below in conjunction with the accompanying drawings.
Embodiment one
The technical scheme of the present embodiment is:A kind of electrochemical aluminum foil, including pet layer 1, the peel ply set gradually from top to bottom 2nd, sealant 3, chromatograph 4, aluminium lamination 5 and adhesive-layer 6;The sealant 3 is film made of high density polyethylene (HDPE).The sealant 3rd, adjacent in chromatograph 4, aluminium lamination 5 and adhesive-layer 6 is connected by PVC crosslinking agents between the two.Carbon is added in the aluminium lamination 5 to receive Mitron, the wall thickness of CNT is 10~15nm.The mass ratio of the CNT and aluminium is 1:150~200.The adhesive-layer 6 thickness is between 15nm~28nm.
As shown in figure 1, setting sealant 3 between peel ply 2 and chromatograph 4, sealant 3 forms fine and close in the periphery of chromatograph 4 Protective layer, avoid corrosive substance in oxygen or rainwater in air and pigment in chromatograph 4 and react generation nothing The corrosivity in oxygen or rainwater after color or the material of other colors and the pigment avoided in chromatograph 4 destroy in air Material can travel further into aluminium lamination 5, the metallic aluminium in aluminium lamination 5 be aoxidized, so that pattern tarnishes.
Adjacent in sealant 3, chromatograph 4, aluminium lamination 5 and adhesive-layer 6 is connected by PVC crosslinking agents between the two, by Together with PVC can mix well with the CNT in sealant 3, chromatograph 4, aluminium lamination 5 and adhesive-layer 6, add close Fastness in sealing 3, chromatograph 4, aluminium lamination 5 and adhesive-layer 6 between adjacent two layers, avoids the generation of delamination.
CNT is added in aluminium lamination 5, on the one hand can be with the both sides of aluminium lamination 5 because CNT has many apertures PVC crosslinking agents be attached together, on the other hand movable passageway can be provided for aluminium atom, so as to change light on aluminium lamination 5 Reflection angle so that pattern radiates brilliant light, more gorgeous.
Because the color of CNT is black, cause so being largely added to and the light that irradiation comes being absorbed in aluminium lamination 5 Intensity of reflected light weakens, so the mass ratio of CNT and aluminium is 1:Volume reflection influence when 150~200 both on light is small or can So that the reflection angle of light changes.
When the thickness of adhesive-layer 6 is thicker, electrochemical aluminum foil, which is bonded at print and scalds the times that are more firm on thing and needing, longer easily leads Cause adhesive-layer 6 asynchronous with sensitivity of the peel ply 2 to heat, so as to influence hot stamping effects.

Claims (5)

1. a kind of electrochemical aluminum foil, it is characterised in that including the pet layer (1), peel ply (2), sealant set gradually from top to bottom (3), chromatograph (4), aluminium lamination (5) and adhesive-layer (6);The sealant (3) is film made of high density polyethylene (HDPE).
2. a kind of electrochemical aluminum foil according to claim 1, it is characterised in that the sealant (3), chromatograph (4), aluminium lamination (5) it is adjacent with adhesive-layer (6) to be connected between the two by PVC crosslinking agents.
3. a kind of electrochemical aluminum foil according to claim 1, it is characterised in that CNT, carbon are added in the aluminium lamination (5) The wall thickness of nanotube is 10~15nm.
4. a kind of electrochemical aluminum foil according to claim 3, it is characterised in that the mass ratio of the CNT and aluminium is 1: 150~200.
A kind of 5. electrochemical aluminum foil according to claim 1, it is characterised in that the thickness of the adhesive-layer (6) be 15nm~ Between 28nm.
CN201710764680.8A 2017-08-30 2017-08-30 A kind of electrochemical aluminum foil Pending CN107499015A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710764680.8A CN107499015A (en) 2017-08-30 2017-08-30 A kind of electrochemical aluminum foil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710764680.8A CN107499015A (en) 2017-08-30 2017-08-30 A kind of electrochemical aluminum foil

Publications (1)

Publication Number Publication Date
CN107499015A true CN107499015A (en) 2017-12-22

Family

ID=60693174

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710764680.8A Pending CN107499015A (en) 2017-08-30 2017-08-30 A kind of electrochemical aluminum foil

Country Status (1)

Country Link
CN (1) CN107499015A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101642974A (en) * 2009-09-09 2010-02-10 刘小弟 Composite membrane
CN101879819A (en) * 2010-06-13 2010-11-10 高邮市卫星卷烟材料有限公司 Production method of hot stamping foil
CN103087555A (en) * 2012-12-11 2013-05-08 中钞油墨有限公司 Microstructure metallic pigment with anti-fake function and preparation method of microstructure metallic pigment
US20130196170A1 (en) * 2009-06-02 2013-08-01 Integran Technologies, Inc. Structural metal-clad polymer article
KR20140122104A (en) * 2013-04-09 2014-10-17 주식회사 마프로 Window film
CN205553484U (en) * 2016-04-12 2016-09-07 南京恒业包装材料有限公司 Electrochemical aluminum
CN205601424U (en) * 2016-04-25 2016-09-28 浙江恒丰包装有限公司 Radium -shine electrochemical aluminium stamping foil
CN106245384A (en) * 2016-09-21 2016-12-21 东莞市联洲知识产权运营管理有限公司 A kind of concentrator based on nanometer gold and the application on silk fabric thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130196170A1 (en) * 2009-06-02 2013-08-01 Integran Technologies, Inc. Structural metal-clad polymer article
CN101642974A (en) * 2009-09-09 2010-02-10 刘小弟 Composite membrane
CN101879819A (en) * 2010-06-13 2010-11-10 高邮市卫星卷烟材料有限公司 Production method of hot stamping foil
CN103087555A (en) * 2012-12-11 2013-05-08 中钞油墨有限公司 Microstructure metallic pigment with anti-fake function and preparation method of microstructure metallic pigment
KR20140122104A (en) * 2013-04-09 2014-10-17 주식회사 마프로 Window film
CN205553484U (en) * 2016-04-12 2016-09-07 南京恒业包装材料有限公司 Electrochemical aluminum
CN205601424U (en) * 2016-04-25 2016-09-28 浙江恒丰包装有限公司 Radium -shine electrochemical aluminium stamping foil
CN106245384A (en) * 2016-09-21 2016-12-21 东莞市联洲知识产权运营管理有限公司 A kind of concentrator based on nanometer gold and the application on silk fabric thereof

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SE01 Entry into force of request for substantive examination
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Application publication date: 20171222

RJ01 Rejection of invention patent application after publication