CN107498858A - A kind of fiber reinforced thermosetting resin based composites 3D printing method and device - Google Patents

A kind of fiber reinforced thermosetting resin based composites 3D printing method and device Download PDF

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Publication number
CN107498858A
CN107498858A CN201710852259.2A CN201710852259A CN107498858A CN 107498858 A CN107498858 A CN 107498858A CN 201710852259 A CN201710852259 A CN 201710852259A CN 107498858 A CN107498858 A CN 107498858A
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China
Prior art keywords
fiber
printing
thermosetting resin
bean curd
dried bean
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CN201710852259.2A
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Chinese (zh)
Inventor
段玉岗
丁仲秋
明越科
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Xian Jiaotong University
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Xian Jiaotong University
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Priority to CN201710852259.2A priority Critical patent/CN107498858A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing

Abstract

A kind of fiber reinforced thermosetting resin based composites 3D printing method and device, fiber shredded dried bean curd material volume is placed on unwinding device, adjusted by conveying device driving and tenslator, fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber, fiber shredded dried bean curd is exported after being presoaked by thermosetting resin by printing nozzle, be layed in print platform or the fiber aspect that has printed on, then by servo-actuated low-energy electron beam transmitter hardening with radiation, complete printing.The present invention is by directly using fiber shredded dried bean curd to carry out sweat connecting, 3D printing shaping and low energy electron beam irradiation solidify, and during sweat connecting, pass through tension force, temperature control and preimpregnation path clustering, make fibre bundle uniformly compound with resin matrix, then exported by printing nozzle, finally via servo-actuated low-energy electron beam transmitter hardening with radiation, curing rate is fast, efficiency high, curing mechanism are chemical bonding, and component performance is excellent.

Description

A kind of fiber reinforced thermosetting resin based composites 3D printing method and device
Technical field
The invention mainly relates to novel hot setting composite 3D printing technique field, and in particular to a kind of fiber reinforcement heat Thermosetting resin based composites 3D printing method and device.
Background technology
Composite element have high ratio modulus, high specific strength, endurance, corrosion-resistant, damping property is good, designability can etc. Many advantages, in alternative metals, energy-saving and emission-reduction and the special effect that uniqueness is played with many aspects such as materials.
The traditional moulding process of composite is very more, such as manual laying forming, resin transfer molding, fiber twine It is uneven around the requirements such as shaping etc., the precision of each process forming composite component, size, structural strength or spread in performance, It is difficult to equilibrium.
3D printing technique is a kind of based on mathematical model, and linear silk material by using metal dust or plastics etc. can The material of bonding, in a manner of successively printing or successively selectively bond, to construct the quick increases material manufacturing technology of entity.In recent years Come, both at home and abroad the successive 3D printing method and device for successfully working out fiber-reinforced thermoplastic resin based composites, but by It is equal in the poor-performing of thermoplastic resin matrix, the rigidity of shaped component, tensile strength, compressive strength, interlaminar shear strength etc. Can not meet automobile, Aero-Space field large high-strength composite element requirement.Epoxy resin be it is a kind of it is corrosion-resistant, Insulating properties and the good thermoset macromolecule material of adhesive property, but due to its solidification after, material is crisp, impact resistance, anti- Cracking behavior limits its further application and development than relatively low.Using fiber reinforcement made of epoxy resin as matrix material Thermosetting resin based composites, both advantages are combined, make up respective defect, it is compound compared with fiber-reinforced thermoplastic resin matrix The performance of material is increased dramatically.
The method that the traditional curing technology of composite uses heat cure more, and the method for heat cure needs HTHP Closed environment, cycle length, the geomery of autoclave again limits the geomery of shaped component, therefore is directed to large-scale composite material The solidification of component is extremely difficult, and cost is high.In recent years, there is a kind of emerging hardening with radiation technology --- electronic beam curing Technology.Electron beam curing technology refer to using electron accelerator accelerate caused by high-power electron beam as radiation source, pass through induce it is special Polymerization crosslinking reaction occurs for different liquid oligomer, is a kind of new non-heated non-pressurised so as to realize quick-setting technology Rapid solidification techniques.Low-energy electron beam curing technology refers to that beam energy is less than 300KeV Electron beam curing technology.It is low Although energy is merely capable of penetrating the thickness of composite material of solidification hundreds of or even tens microns, but its equipment is simple, amount of radiation Small, shielding is easy, many advantages such as simple operation.
Exist in the traditional moulding process of composite relatively low automaticity, low precision, size shape limitation, structure it is strong The performance such as degree the problems such as can not meeting to require, the closed loop for needing HTHP again be present in the traditional curing technology of composite The problems such as border, cycle length, the geomery of autoclave limit, and cost is high, in summary content, can not realize and grow fibre to continuity The 3D printing of dimension enhancing thermosetting resin based composites.
The content of the invention
To solve the problems of the prior art, it is an object of the invention to provide a kind of fiber reinforced thermosetting resin base to answer Condensation material 3D printing method and device, convey fiber shredded dried bean curd side, side preimpregnation, side printing, the solidification of side low energy electron beam irradiation, in fact The quick preparation of existing fiber reinforced thermosetting resin based composite material component.
To achieve the above object, the present invention adopts the following technical scheme that:
A kind of fiber reinforced thermosetting resin based composites 3D printing device, including unwinding device, conveying device, tension force Control device, resin storage tank, sweat connecting hybrid chamber, low-energy electron beam transmitter and print platform, wherein, resin storage tank is built with warm Thermosetting resin, printing nozzle is provided with sweat connecting hybrid chamber, conveying device is arranged on unwinding device and mixed with sweat connecting Between chamber, resin storage tank is connected with sweat connecting hybrid chamber;Fiber shredded dried bean curd material volume is placed on unwinding device, is driven by conveying device The regulation of dynamic and tenslator, fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber, fiber shredded dried bean curd is by thermosetting Exported after resin prepreg by printing nozzle, be layed in print platform or the fiber aspect that has printed on, then by servo-actuated low energy electricity Beamlet transmitter hardening with radiation, complete printing.
Further improve of the invention is that conveying device includes the conveying that two identicals are used for gripping fibers shredded dried bean curd beam Mechanism, and tenslator is arranged between two conveying mechanisms.
Further improve of the invention is that sweat connecting hybrid chamber is with vertical direction in 30 °~60 ° settings.
Further improve of the invention is, part connection printing is connected through a screw thread at sweat connecting hybrid chamber lower part outlet Nozzle.
Further improve of the invention is, traction guide roller is fixed with threaded connector.
Further improve of the invention is that sweat connecting hybrid chamber top connects resin storage tank by pipeline.
Further improve of the invention is, is set on sweat connecting mixing cavity wall some for about bundle fiber shredded dried bean curd beam And fiber shredded dried bean curd beam is set to be in guide wheel of the broken line form by sweat connecting hybrid chamber.
Further improve of the invention is that low-energy electron beam transmitter is perpendicular to print platform;Fiber shredded dried bean curd is that carbon is fine One or both of dimension, glass fibre, and quantity is one or more.
A kind of fiber reinforced thermosetting resin based composites 3D printing method, thermosetting resin is in air pressure thrust Under, by resin storage tank enter sweat connecting hybrid chamber in, fiber shredded dried bean curd material volume is placed on unwinding device, by conveying device drive with And tenslator regulation, fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber;Fiber in sweat connecting hybrid chamber After shredded dried bean curd is uniformly presoaked by thermosetting resin, then exported by printing nozzle, the fiber for being layed in print platform or having printed In aspect, then by low-energy electron beam transmitter hardening with radiation, complete printing.
Of the invention further improve be, printing nozzle by fiber shredded dried bean curd beam is moulding exported into circular cross-section tow after again Be rolled into square-section tow by drawing guiding, be layed in print platform or the fiber aspect that has printed on.
Compared with prior art, the device have the advantages that:The present invention is by setting sweat connecting hybrid chamber and low Energy electron beam emitter, fiber shredded dried bean curd material volume are placed on unwinding device, pass through conveying device driving and tenslator is adjusted Section, fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber, and fiber shredded dried bean curd quilt can the preimpregnation of electronic beam curing thermosetting resin Exported afterwards by printing nozzle, be layed in print platform or the fiber aspect that has printed on, then launch by servo-actuated low-energy electron beam Device hardening with radiation, complete printing.Whole device collection preimpregnation of the present invention, printing, solidifies in one, traditional composite of breakthrough Moulding process, the confinement of curing mode, using 3D printing technique advantage, its shaped component size, shape can be with travel mechanism Expand and infinitely extend, precision improves with the raising of the positioning precision of travel mechanism, utilizes low-energy electron beam curing technology again Immediately solidification, the quick preparation of comprehensive achievable high-performance fiber enhancing thermosetting resin based composite material component.
Further, constrained by printing nozzle, it is moulding to be exported into circular cross-section tow, then be rolled into by traction guiding The laying printing of square-section tow, circular cross-section tow bring can any angle, the advantage of free routing laying, then suppress Rectangular section tow is easy to position again, between eliminating tow, the gap of interlayer.
The present invention by directly using fiber shredded dried bean curd to carry out sweat connecting, consolidate by 3D printing shaping and low energy electron beam irradiation Change, instead of and prepare composite material prepreg in advance, then laid, the old three-wave-length method of last hot-press solidifying, it is fine It is selectively extensive to tie up tow, also compound multiple fiber, plurality of specifications can carry out conveying printing, sweat connecting mistake in one simultaneously Cheng Zhong, by tension force, temperature control and preimpregnation path clustering, make fibre bundle uniformly compound with resin matrix, Ran Houtong Printing nozzle output is crossed, finally via servo-actuated low-energy electron beam transmitter hardening with radiation, curing rate is fast, efficiency high, curing Manage to be chemically bonded, component performance is excellent.
Brief description of the drawings
Fig. 1 is the principle schematic of the device of the present invention;
In figure:1 is unwinding device, and 2 be conveying device, and 3 be tenslator, and 4 be resin storage tank, and 5 mix for sweat connecting Chamber is closed, 6 be printing nozzle, and 7 be traction guide roller, and 8 be low-energy electron beam transmitter, and 9 be print platform.
Embodiment
The present invention is described further below in conjunction with accompanying drawing.Low-energy electron beam transmitter launches low-energy electron in the present invention Beam energy is 80Kev~300Kev, and line is less than or equal to 25mA.Heat reactive resin is can electronic beam curing thermosetting resin.
Referring to Fig. 1, a kind of fiber reinforced thermosetting resin based composites 3D printing device of the invention includes unreeling dress Put 1, conveying device 2, tenslator 3, resin storage tank 4, sweat connecting hybrid chamber 5, printing nozzle 6, traction guide roller 7, low Energy electron beam emitter 8 and print platform 9, wherein, the conveying device 2 is used for gripping fibers shredded dried bean curd beam including two identicals Conveying mechanism, be separately positioned on after unwinding device 1 and sweat connecting hybrid chamber 5 before, tenslator 3 is arranged on this Between two conveying mechanisms, sweat connecting hybrid chamber 5, in 30 °~60 ° placements, its underpart exit, is connected with vertical direction by screw thread Printing nozzle 6 is connect, while traction guide roller 7 is fixed with threaded connector, the top of sweat connecting hybrid chamber 5 is connected by pipeline Resin storage tank 4, resin storage tank 4 are fixed together by connector with electron beam emitter 8, perpendicular to print platform 9, poured into downwards again Thermosetting resin and transmitting low-energy electron beam, in fiber transmission channel, fiber shredded dried bean curd material volume is placed on unwinding device 1, by defeated Device 2 is sent to drive, tenslator 3 is adjusted, and fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber 5;Resin transfer In passage, thermosetting resin is entered in sweat connecting hybrid chamber 5 under air pressure thrust by resin storage tank 4, sweat connecting mixing In chamber 5, fiber shredded dried bean curd by can electronic beam curing thermosetting resin matrix uniformly preimpregnation after, exported from printing nozzle 6, via traction After guide roller 7 acts on, be layed in print platform 9 or the fiber aspect that has printed on, then by servo-actuated low-energy electron beam transmitter 8 Hardening with radiation, above-mentioned each part are integrated on Multi-degree-of-freedom moving mechanism, to provide three-dimensional motion needed for printing.
Fiber shredded dried bean curd is the flexible hydrodynamic form silk material that carbon fiber, glass fibre etc. have continuity long fibre feature in the present invention In one or more, one or more, in sweat connecting hybrid chamber 5, preimpregnation can after electronic beam curing thermosetting resin, by Resin is sticky in itself, by moulding constraint, is combined into the output printing of one circular cross-section tow.
Heretofore described unwinding device 1, conveying device 2, tenslator 3, printing nozzle 6, traction guide roller 7 with The Multi-degree-of-freedom moving mechanism for being integrated with above-mentioned all parts forms cooperative control system, and unwinding device 1 unreels speed, conveying The translational speed of the transfer rate of device 2, the Tensity size of tenslator 3, printing nozzle 6 and traction guide roller 7, and The translational speed of travel mechanism is mutually coordinated.
Sweat connecting hybrid chamber 5 includes internal fiber resin hybrid chamber and peripheral temperature control device in the present invention, in hybrid chamber Fixation is connected through a screw thread, is limited according to cavity size, is arranged symmetrically 4 or multiple guide wheels, about bundle fiber shredded dried bean curd beam is oriented to, and is made Fiber shredded dried bean curd beam preimpregnation path be reciprocal broken line form, and for angle between 30 °~150 °, it is in integrally Z-shaped to presoak route between broken line Type, with the wellability of tow after increased fiber and resin compounded, cavity temperature is controlled according to resin formula, resin viscosity and tow Wellability requires determination, and control interval is 40 DEG C~100 DEG C.
In the present invention launching electronics beam energy of low-energy electron beam transmitter 8 be 80Kev~300Kev it is adjustable, line be 0~ 25mA is adjustable;Low-energy electron beam emitting head can move with fibre bundle, instant hardening with radiation, also can print completion in individual layer Afterwards, whole face carries out hardening with radiation.
Continuity long fiber reinforcement thermosetting resin based composites low-energy electron beam solidification 3D side based on said apparatus Method is:Thermosetting resin is entered in sweat connecting hybrid chamber 5, fiber shredded dried bean curd material volume is put under air pressure thrust by resin storage tank 4 In on unwinding device 1, being driven by conveying device 2 and tenslator 3 is adjusted, fiber shredded dried bean curd beam is delivered into hot melt Presoak in hybrid chamber 5;After fiber shredded dried bean curd is uniformly presoaked by thermosetting resin in sweat connecting hybrid chamber 5, by printing nozzle 6 about Beam, it is moulding into circular cross-section tow export, then by traction guide roller 7 be pressed into square-section tow be layed in print platform 9 or In the fiber aspect printed, then by the hardening with radiation of low-energy electron beam transmitter 8, complete printing.Circular cross-section tow band is come Can any angle, the advantage of free routing laying, be then pressed into square-section tow and be easy to position again, eliminate tow it Between, the gap of interlayer.
After exemplar is integrally printed and irradiates completion, the last handling process such as microwave, infrared, heating can be carried out as needed To lift curing degree and improve performance.
The present invention use can electronic beam curing thermosetting resin matrix it is corrosion-resistant, high temperature resistant, insulating properties, adhesive property are excellent Different, intensity is high, and 3D printing technique technique strong applicability can both meet small complex forming parts, and and can meets large-scale composite wood Expect prepared by component, precision is high, arbitrarily the free degree can print, and low-energy electron beam, again with the energy is saved, equipment is simple, radiation Measure small, shielding is easy, the advantage such as simple operation, comprehensive achievable fiber reinforced thermosetting resin based composite material component it is quick Prepare, be particularly suitable for use in automobile, the field such as Aero-Space.

Claims (10)

  1. A kind of 1. fiber reinforced thermosetting resin based composites 3D printing device, it is characterised in that including unwinding device (1), Conveying device (2), tenslator (3), resin storage tank (4), sweat connecting hybrid chamber (5), low-energy electron beam transmitter (8) and Print platform (9), wherein, resin storage tank (4) is provided with printing nozzle built with thermosetting resin, sweat connecting hybrid chamber on (5) (6), conveying device (2) is arranged between unwinding device (1) and sweat connecting hybrid chamber (5), and resin storage tank (4) mixes with sweat connecting Chamber (5) is closed to be connected;Fiber shredded dried bean curd material volume is placed on unwinding device (1), is filled by conveying device (2) driving and tension force (3) regulation is put, fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber (5), after fiber shredded dried bean curd is presoaked by thermosetting resin Exported, be layed in print platform (9) or the fiber aspect printed by printing nozzle (6), then by servo-actuated low-energy electron beam Transmitter (8) hardening with radiation, complete printing.
  2. 2. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In conveying device (2) includes the conveying mechanism that two identicals are used for gripping fibers shredded dried bean curd beam, and tenslator (3) It is arranged between two conveying mechanisms.
  3. 3. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In sweat connecting hybrid chamber (5) is with vertical direction in 30 °~60 ° settings.
  4. 4. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In, be connected through a screw thread at sweat connecting hybrid chamber (5) lower part outlet part connection printing nozzle (6).
  5. 5. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 4, its feature exist In, be fixed with threaded connector traction guide roller (7).
  6. 6. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In sweat connecting hybrid chamber (5) top connects resin storage tank (4) by pipeline.
  7. 7. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In being set on sweat connecting hybrid chamber (5) inwall and some be used to about bundle fiber shredded dried bean curd beam and make fiber shredded dried bean curd beam be in broken line form Pass through the guide wheel of sweat connecting hybrid chamber (5).
  8. 8. a kind of fiber reinforced thermosetting resin based composites 3D printing device according to claim 1, its feature exist In low-energy electron beam transmitter (8) is perpendicular to print platform (9), low-energy electron beam transmitter (8) transmitting low-energy electron beam energy For 80Kev~300Kev, line is less than or equal to 25mA;Fiber shredded dried bean curd is carbon fiber, one or both of glass fibre, and Quantity is one or more.
  9. A kind of 9. fiber reinforced thermosetting resin based composites 3D printing based on any one described device in claim 5 Method, it is characterised in that thermosetting resin enters sweat connecting hybrid chamber (5) under air pressure thrust, by resin storage tank (4) In, fiber shredded dried bean curd material volume is placed on unwinding device (1), is adjusted by conveying device (2) driving and tenslator (3), Fiber shredded dried bean curd beam is delivered into sweat connecting hybrid chamber (5);Fiber shredded dried bean curd is by thermosetting tree in sweat connecting hybrid chamber (5) Fat uniformly after preimpregnation, is then exported by printing nozzle (6), is layed in print platform (9) or the fiber aspect printed, then By low-energy electron beam transmitter (8) hardening with radiation, printing is completed.
  10. 10. a kind of, fiber reinforced thermosetting resin based composites 3D printing method, its feature exist according to claim 9 In printing nozzle (6) will be pressed into rectangle by traction guide roller (7) again after the moulding output into circular cross-section tow of fiber shredded dried bean curd beam Section tow, it is layed in print platform (9) or the fiber aspect printed.
CN201710852259.2A 2017-09-19 2017-09-19 A kind of fiber reinforced thermosetting resin based composites 3D printing method and device Pending CN107498858A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108724705A (en) * 2018-05-18 2018-11-02 航天特种材料及工艺技术研究所 Increasing material manufacturing device
CN109094055A (en) * 2018-09-29 2018-12-28 西安交通大学 A kind of continuous composite formed device of dry fibers 3D printing of Combined multi-channel
CN109532010A (en) * 2019-01-25 2019-03-29 南京航空航天大学 A kind of carbon fiber answers material varied angle electrical loss self-heating 3D printing device and method
CN109748573A (en) * 2019-01-20 2019-05-14 武汉因泰莱激光科技有限公司 The processing method of laser gain material manufacturing equipment and its long fiber reinforcement ceramic matric composite part
CN111844524A (en) * 2020-07-27 2020-10-30 西安交通大学 Preparation method of hybrid fiber reinforced resin matrix composite material 3D printing wire
CN112895425A (en) * 2021-01-15 2021-06-04 浙江大学 Eccentric multi-roller dipping composite fiber filament fused deposition extrusion printing spray head device
CN113102691A (en) * 2021-03-27 2021-07-13 武汉纺织大学 Three-dimensional printing microwave curing method and device for sodium silicate sand extrusion micro-hammer
CN113320151A (en) * 2021-06-08 2021-08-31 广西民族大学 3D printing head and printing method of continuous fiber reinforced resin composite material
CN113334764A (en) * 2021-07-08 2021-09-03 上海交通大学 3D printing method for transverse fiber tape laying
CN113414985A (en) * 2021-06-21 2021-09-21 中南大学 Composite material 3D printing platform and printing method thereof
CN113427752A (en) * 2021-08-06 2021-09-24 山东中恒景新碳纤维科技发展有限公司 Continuous fiber unidirectional prepreg tape additive manufacturing method
CN113787710A (en) * 2021-09-08 2021-12-14 西安交通大学 3D printing system and method for continuous fiber reinforced thermosetting resin composite material
CN115416133A (en) * 2022-09-13 2022-12-02 河南工程学院 3D printing device and method for cement-based material by using special-shaped steel fibers
CN116080062A (en) * 2023-01-09 2023-05-09 南京航空航天大学 Microwave compaction cooperative interlayer reinforced additive manufacturing method and device
CN116638758A (en) * 2023-05-20 2023-08-25 南京航空航天大学 Printing head with continuous fiber feeding direct-pressure type tension online control and printing method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308565A (en) * 1993-02-05 1994-05-03 General Electric Company Method of preparing modified polyphenylene oxide resin systems for electrical laminates having improved solderability and solvent resistance
US5413847A (en) * 1992-03-30 1995-05-09 Toray Industries, Inc. Prepreg and composite
US20030094734A1 (en) * 2001-10-22 2003-05-22 Deckard Luisa M. Preparing composites by using resins
CN101268301A (en) * 2005-08-17 2008-09-17 伊纳埃克威生公司 Dual gland air inversion and steam cure of cured in place liners
US20140096902A1 (en) * 2012-10-05 2014-04-10 The Boeing Company Method and Apparatus for Fabricating an Ultra-High Molecular Weight Polymer Structure
US20170015060A1 (en) * 2015-07-17 2017-01-19 Lawrence Livermore National Security, Llc Additive manufacturing continuous filament carbon fiber epoxy composites
CN106515041A (en) * 2016-11-10 2017-03-22 机械科学研究总院先进制造技术研究中心 Three-dimensional printing forming method of long fiber thermoplastic composite material component
US20170151728A1 (en) * 2015-11-30 2017-06-01 Ut-Battelle, Llc Machine and a Method for Additive Manufacturing with Continuous Fiber Reinforcements
CN207240859U (en) * 2017-09-19 2018-04-17 西安交通大学 A kind of fiber reinforced thermosetting resin based composites 3D printing device

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5413847A (en) * 1992-03-30 1995-05-09 Toray Industries, Inc. Prepreg and composite
US5308565A (en) * 1993-02-05 1994-05-03 General Electric Company Method of preparing modified polyphenylene oxide resin systems for electrical laminates having improved solderability and solvent resistance
US20030094734A1 (en) * 2001-10-22 2003-05-22 Deckard Luisa M. Preparing composites by using resins
CN101268301A (en) * 2005-08-17 2008-09-17 伊纳埃克威生公司 Dual gland air inversion and steam cure of cured in place liners
US20140096902A1 (en) * 2012-10-05 2014-04-10 The Boeing Company Method and Apparatus for Fabricating an Ultra-High Molecular Weight Polymer Structure
US20170015060A1 (en) * 2015-07-17 2017-01-19 Lawrence Livermore National Security, Llc Additive manufacturing continuous filament carbon fiber epoxy composites
US20170151728A1 (en) * 2015-11-30 2017-06-01 Ut-Battelle, Llc Machine and a Method for Additive Manufacturing with Continuous Fiber Reinforcements
CN106515041A (en) * 2016-11-10 2017-03-22 机械科学研究总院先进制造技术研究中心 Three-dimensional printing forming method of long fiber thermoplastic composite material component
CN207240859U (en) * 2017-09-19 2018-04-17 西安交通大学 A kind of fiber reinforced thermosetting resin based composites 3D printing device

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108724705B (en) * 2018-05-18 2020-10-16 航天特种材料及工艺技术研究所 Additive manufacturing device
CN108724705A (en) * 2018-05-18 2018-11-02 航天特种材料及工艺技术研究所 Increasing material manufacturing device
CN109094055A (en) * 2018-09-29 2018-12-28 西安交通大学 A kind of continuous composite formed device of dry fibers 3D printing of Combined multi-channel
CN109748573B (en) * 2019-01-20 2022-02-15 武汉因泰莱激光科技有限公司 Processing method of long fiber reinforced ceramic matrix composite part
CN109748573A (en) * 2019-01-20 2019-05-14 武汉因泰莱激光科技有限公司 The processing method of laser gain material manufacturing equipment and its long fiber reinforcement ceramic matric composite part
CN109532010A (en) * 2019-01-25 2019-03-29 南京航空航天大学 A kind of carbon fiber answers material varied angle electrical loss self-heating 3D printing device and method
CN109532010B (en) * 2019-01-25 2023-06-16 南京航空航天大学 Carbon fiber composite material variable-angle electric loss self-heating in-situ curing device and method
CN111844524A (en) * 2020-07-27 2020-10-30 西安交通大学 Preparation method of hybrid fiber reinforced resin matrix composite material 3D printing wire
CN111844524B (en) * 2020-07-27 2021-08-10 西安交通大学 Preparation method of hybrid fiber reinforced resin matrix composite material 3D printing wire
CN112895425A (en) * 2021-01-15 2021-06-04 浙江大学 Eccentric multi-roller dipping composite fiber filament fused deposition extrusion printing spray head device
CN113102691B (en) * 2021-03-27 2022-06-07 武汉纺织大学 Three-dimensional printing microwave curing method and device for sodium silicate sand extrusion micro-hammer
CN113102691A (en) * 2021-03-27 2021-07-13 武汉纺织大学 Three-dimensional printing microwave curing method and device for sodium silicate sand extrusion micro-hammer
CN113320151A (en) * 2021-06-08 2021-08-31 广西民族大学 3D printing head and printing method of continuous fiber reinforced resin composite material
CN113414985A (en) * 2021-06-21 2021-09-21 中南大学 Composite material 3D printing platform and printing method thereof
CN113334764A (en) * 2021-07-08 2021-09-03 上海交通大学 3D printing method for transverse fiber tape laying
CN113427752A (en) * 2021-08-06 2021-09-24 山东中恒景新碳纤维科技发展有限公司 Continuous fiber unidirectional prepreg tape additive manufacturing method
CN113787710A (en) * 2021-09-08 2021-12-14 西安交通大学 3D printing system and method for continuous fiber reinforced thermosetting resin composite material
CN115416133A (en) * 2022-09-13 2022-12-02 河南工程学院 3D printing device and method for cement-based material by using special-shaped steel fibers
CN115416133B (en) * 2022-09-13 2023-11-03 河南工程学院 3D printing device and printing method for cement-based material by utilizing special-shaped steel fibers
CN116080062A (en) * 2023-01-09 2023-05-09 南京航空航天大学 Microwave compaction cooperative interlayer reinforced additive manufacturing method and device
CN116638758A (en) * 2023-05-20 2023-08-25 南京航空航天大学 Printing head with continuous fiber feeding direct-pressure type tension online control and printing method thereof
CN116638758B (en) * 2023-05-20 2024-03-26 南京航空航天大学 Printing head with continuous fiber feeding direct-pressure type tension online control and printing method thereof

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Application publication date: 20171222