CN107497644A - The flexible output from driver prepared based on electrostatic spraying method - Google Patents
The flexible output from driver prepared based on electrostatic spraying method Download PDFInfo
- Publication number
- CN107497644A CN107497644A CN201710875164.2A CN201710875164A CN107497644A CN 107497644 A CN107497644 A CN 107497644A CN 201710875164 A CN201710875164 A CN 201710875164A CN 107497644 A CN107497644 A CN 107497644A
- Authority
- CN
- China
- Prior art keywords
- amberplex
- silver electrode
- thin film
- ito thin
- p3ht
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/002—Pretreatement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Spray Control Apparatus (AREA)
- Electrostatic Spraying Apparatus (AREA)
Abstract
The flexible output from driver prepared based on electrostatic spraying method, is related to flexible actuator.Provided with amberplex, silver electrode, P3HT and PCBM mixing materials, ito thin film, PET film, wire and switch；The PET film and ito thin film use ITO flexible conductive films, and the PET film and ito thin film cut, etched, cleaning forms standby basement membrane；The P3HT is sprayed on ito thin film with PCBM mixing materials by the method for electrostatic spray；The amberplex is located among flexible output from driver, and amberplex surface coats silver electrode of the conductive silver glue as amberplex；The silver electrode side connects amberplex, silver electrode opposite side connection P3HT and PCBM mixing materials；Described wire one end is connected with silver electrode, and the wire other end is connected with ito thin film, and centre is connected to break-make of the switch for control circuit.
Description
Technical field
The present invention relates to flexible actuator, more particularly, to the flexible output from driver prepared based on electrostatic spraying method.
Background technology
At present, traditional power drive mainly has three kinds of motor, hydraulic pressure and air pressure drive forms, and legacy drive often has
There is very high control accuracy, but universal rigidity is high, flexibility is poor, volume is big, big (Zhou Zhihao, Wang Qining, Wang Long the one kind of noise
Flexible controllable joint driver, CN103029126A [P] .2014.), in addition, three kinds of type of drive are also required for outside confession
Can, however, new flexible output from driver can make up the deficiency of conventional ADS driving.
Electrostatic Spraying technique is one kind of electrohydraulic dynamic coupling technique, is to be produced using extra electric field induced fluid at nozzle
Change shape, and when electric field force exceedes Rayleigh limit, liquid sprays from nozzle, because the liquid of ejection carries like charges, in sky
In middle flight course, liquid can split into uniform fine droplet, be then deposited on collecting board and form uniform film (Huang Wei
Experimental study [D] the Xiamen of big electrostatic atomizations technique and zinc-oxide film gas-sensitive property:Xiamen University, 2015.), electrostatic
Mist as a kind of manufacture method has the advantages that large area film, patterned film can be manufactured.
The content of the invention
It is an object of the invention to provide when having light irradiation and closure switch driver can produce flexural deformation, drive
Device can be with the self-driven flexible self-powered prepared based on electrostatic spraying method without extra drive circuit and external power supply
Dynamic device.
The present invention be provided with amberplex, silver electrode, P3HT and PCBM mixing materials, ito thin film, PET film, wire and
Switch；
The PET film and ito thin film use ITO flexible conductive films (PET), and the PET film and ito thin film are cut out
Cut, etch, cleaning and form standby basement membrane；
The P3HT is sprayed on ito thin film with PCBM mixing materials by the method for electrostatic spray；
The amberplex is located among flexible output from driver, and amberplex surface coats conductive silver glue as ion
The silver electrode of exchange membrane；
The silver electrode side connects amberplex, silver electrode opposite side connection P3HT and PCBM mixing materials；
Described wire one end is connected with silver electrode, and the wire other end is connected with ito thin film, and centre is connected to switch and is used to control
The break-make of circuit.
The ito thin film is connected with silver electrode, forms series circuit to improve driver itself driving electrical potential difference.
The area of the PET film is more than the area of amberplex, is mixed P3HT with PCBM by hot pressing PET film
Material, silver electrode and amberplex are packaged.
When there is light irradiation ITO flexible conductive films (PET), P3HT absorbs photon with PCBM mixing materials and produces exciton,
Electronics by the P3HT vacant track of minimum electronics transit to P3HT highest electronics take track, P3HT minimum electronics not
Take track and form hole, electronics then takes track transmission from P3HT highest electronics and takes rail to PCBM highest electronics
Road, last electric transmission are collected to silver electrode, at the same time hole transport to ITO poles.When the switch is closed, ITO poles and from
The silver electrode of proton exchange side connects and composes loop and produces electrical potential difference, and the hydrated cation in amberplex is in electrical potential difference
Make whole film to anode flexural deformation to movable cathode under effect.
The advantage of the invention is that：
1) relative to legacy drive, the flexible output from driver small volume prepared based on electrostatic spraying method, in light weight, nothing
Noise, there is flexibility, big moving displacement can be produced and driving is not required to outside energy supply.
2) it can realize prepared by the large area of the driver, patterning by the method for electrostatic spray.
3) when there is light irradiation, the flexural deformation of the driver is conveniently controlled by the folding can of controlling switch.
4) the flexible output from driver prepared based on electrostatic spraying method can solve amberplex by last encapsulation
The aerial ion losing issue of exposure for a long time.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Embodiment
As shown in figure 1, the embodiment of the present invention is provided with amberplex 5, silver electrode 4, P3HT and PCBM mixing materials 3, ITO
Film 2, PET film 1, wire 6 and switch 7；
The PET film 1 and ito thin film 2 are using ITO flexible conductive films (PET), the PET film 1 and ito thin film 2
Cut, etch, cleaning forms standby basement membrane；The P3HT is sprayed on ITO with PCBM mixing materials 3 by the method for electrostatic spray
On film 2；The amberplex 5 is located among flexible output from driver, the surface of amberplex 5 coating conductive silver glue be used as from
The silver electrode 4 of proton exchange 5；The side of silver electrode 4 connects amberplex 5, the opposite side of silver electrode 4 connection P3HT and PCBM
Mixing material 3；Described one end of wire 6 is connected with silver electrode 4, and the other end of wire 6 is connected with ito thin film 2, and centre is connected to switch and used
In the break-make of control circuit.The ito thin film 2 is connected with silver electrode 4, forms series circuit to improve driver itself driving
Electrical potential difference.The area of the PET film 1 is more than the area of amberplex 5, is mixed P3HT and PCBM by hot pressing PET film 1
Condensation material 3, silver electrode 4 and amberplex 5 are packaged.
When there is light irradiation ITO flexible conductive films (PET), P3HT absorbs photon with PCBM mixing materials and produces exciton,
Electronics by the P3HT vacant track of minimum electronics transit to P3HT highest electronics take track, P3HT minimum electronics not
Take track and form hole, electronics then takes track transmission from P3HT highest electronics and takes rail to PCBM highest electronics
Road, last electric transmission are collected to silver electrode, at the same time hole transport to ITO poles.When the switch is closed, ITO poles and from
The silver electrode of proton exchange side connects and composes loop and produces electrical potential difference, and the hydrated cation in amberplex is in electrical potential difference
Make whole film to anode flexural deformation to movable cathode under effect.
Film is cut growth 5cm, width by the PET film 1 and ito thin film 2 using ITO flexible conductive films (PET)
Then 3cm rectangle is placed in hydrochloric acid solution and etches 5min, further take out, it is necessary to adhesive tape is sticked in the part for leaving ito thin film 2
ITO flexible conductive films (PET) with clear water remove residual hydrochloric acid and adhesive tape of tearing, then successively be placed on cleaning dilution agent it is molten
Ultrasonic wave cleaning 30min is distinguished in liquid, deionized water, acetone, isopropanol.
It for 1 ︰ 1, o-dichlorohenzene is solvent, concentration that the P3HT and PCBM mixing materials 3, which use P3HT and PCBM mass ratioes,
For 2mg/ml mixed solution, it will be sprayed because being not all of film, mask plate is covered on ito thin film 2, then passed through
P3HT and PCBM mixing materials 3 are sprayed on ito thin film 2 by the method for electrostatic spray, the parameter of electrostatic spray is voltage 4kv,
Electrode spacing 5cm.
The amberplex 5 uses cation-exchange membrane, and amberplex 5 is cut to growth 3cm, wide 1cm rectangle,
Polishing upper and lower surface is simultaneously cleaned, and forms standby matrix film layer, and amberplex 5 is put into saturation lithium chloride solution stands 24 hours
Carry out ion exchange.
By coating conductive silver glue in the one side of amberplex 5, another side connection P3HT and PCBM is mixed the silver electrode 4
Condensation material 3,60 DEG C of holding 12h are then heated in drying box, are formed by curing silver electrode.
The wire 6 is connected in silver electrode 4 at an end in above-mentioned preparation silver electrode 4, another to be terminated on ito thin film 2, in
Between connecting valve 7 be used for control circuit break-make.
The area of the PET film 1 is more than the area of the amberplex 5, and amberplex 5 is located at PET film 1
Center, P3HT and PCBM mixing materials 3, silver electrode 4 and amberplex 5 are packaged by hot pressing PET film 1.
The flexible output from driver prepared based on electrostatic spraying method is related to flexible actuator, provided with amberplex, silver electricity
Pole, P3HT and PCBM mixing materials, ito thin film, PET film, wire and switch, compared to legacy drive, based on electrostatic
Flexible output from driver small volume prepared by mist method, in light weight, noiseless, there is flexible, driving to be not required to outside energy supply, driver
Using cation-exchange membrane as matrix, silver electrode connection amberplex passes through with photosensitive activity material layer, photosensitive activity material
The method of electrostatic spray carries out large area preparation, and when there is light irradiation, this is controlled by the way that the folding can of controlling switch is convenient
Invent the flexural deformation of flexible output from driver.
Claims (3)
1. the flexible output from driver prepared based on electrostatic spraying method, it is characterised in that provided with amberplex, silver electrode, P3HT
With PCBM mixing materials, ito thin film, PET film, wire and switch；
The PET film and ito thin film use ITO flexible conductive films, and the PET film and ito thin film cut, etched, be clear
Wash to form standby basement membrane；
The P3HT is sprayed on ito thin film with PCBM mixing materials by the method for electrostatic spray；
The amberplex is located among flexible output from driver, and amberplex surface coats conductive silver glue as ion exchange
The silver electrode of film；
The silver electrode side connects amberplex, silver electrode opposite side connection P3HT and PCBM mixing materials；
Described wire one end is connected with silver electrode, and the wire other end is connected with ito thin film, and centre is connected to switch and is used for control circuit
Break-make.
2. the flexible output from driver prepared as claimed in claim 1 based on electrostatic spraying method, it is characterised in that the ito thin film
It is connected with silver electrode, forms series circuit.
3. the flexible output from driver prepared as claimed in claim 1 based on electrostatic spraying method, it is characterised in that the PET film
Area be more than the area of amberplex, P3HT and PCBM mixing materials, silver electrode and ion are handed over by hot pressing PET film
Film is changed to be packaged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710875164.2A CN107497644B (en) | 2017-09-25 | 2017-09-25 | Flexible self-driver prepared based on electrostatic spraying method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710875164.2A CN107497644B (en) | 2017-09-25 | 2017-09-25 | Flexible self-driver prepared based on electrostatic spraying method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107497644A true CN107497644A (en) | 2017-12-22 |
| CN107497644B CN107497644B (en) | 2023-10-20 |
Family
ID=60698686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710875164.2A Active CN107497644B (en) | 2017-09-25 | 2017-09-25 | Flexible self-driver prepared based on electrostatic spraying method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107497644B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104078566A (en) * | 2014-07-02 | 2014-10-01 | 厦门大学 | Method for preparing polymer thin-film solar cell active layer through electrospinning |
| CN105789429A (en) * | 2016-04-08 | 2016-07-20 | 合肥工业大学 | Array flexible curved surface self-sensing driver based on IPMC and preparation method thereof |
-
2017
- 2017-09-25 CN CN201710875164.2A patent/CN107497644B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104078566A (en) * | 2014-07-02 | 2014-10-01 | 厦门大学 | Method for preparing polymer thin-film solar cell active layer through electrospinning |
| CN105789429A (en) * | 2016-04-08 | 2016-07-20 | 合肥工业大学 | Array flexible curved surface self-sensing driver based on IPMC and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张春福等, 西安电子科技大学出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107497644B (en) | 2023-10-20 |
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