CN107494576A - A kind of active compound based on camphor and n-octyl alcohol, striped rice borer attractant and application - Google Patents

A kind of active compound based on camphor and n-octyl alcohol, striped rice borer attractant and application Download PDF

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Publication number
CN107494576A
CN107494576A CN201710792026.8A CN201710792026A CN107494576A CN 107494576 A CN107494576 A CN 107494576A CN 201710792026 A CN201710792026 A CN 201710792026A CN 107494576 A CN107494576 A CN 107494576A
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CN
China
Prior art keywords
parts
striped rice
rice borer
active compound
attractant
Prior art date
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Pending
Application number
CN201710792026.8A
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Chinese (zh)
Inventor
吕仲贤
郑许松
鲁艳辉
徐红星
田俊策
杨亚军
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Zhejiang Academy of Agricultural Sciences
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Zhejiang Academy of Agricultural Sciences
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Priority to CN201710792026.8A priority Critical patent/CN107494576A/en
Publication of CN107494576A publication Critical patent/CN107494576A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N49/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/02Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M2200/00Kind of animal
    • A01M2200/01Insects
    • A01M2200/012Flying insects

Abstract

The invention discloses a kind of active compound based on camphor and n-octyl alcohol, include the component of following parts by weight:30~60 parts of camphor, 15~50 parts of n-octyl alcohol, 5~30 parts of aldehyde C-9,2~18 parts of linalool.Present invention additionally comprises the striped rice borer attractant that above-mentioned active compound and non-volatile organic solvent are formed, and striped rice borer lure striped rice borer attractant being packaged in isotropic silk.Active compound proposed by the present invention can directly lure the female moth of striped rice borer and male moth, higher than gyplure to the control efficiency of striped rice borer, can be used as largely trapping and killing, can substantially reduce field rice stem borer quantity, and reduce offspring's insect density.Striped rice borer prediction is applied also for, lures insect-catching amount energy Accurate Prediction Striped Rice Borer Population that dynamic occurs.

Description

A kind of active compound based on camphor and n-octyl alcohol, striped rice borer attractant and application
Technical field
The present invention relates to a kind of attractant, attractant that is more particularly to a kind of while luring female, the male moth of striped rice borer.
Background technology
Insect attractant is by plant generation or the artificial synthesized active material for having behavior attracting action to specific insect. During the Tropical area of insect, special " finger-print " volatile materials of plant often plays critical effect, can be with Pest trap preventing and treating is carried out using active principle therein.
US 4880624 (A) describe these compounds such as dimethoxy benzene, trimethoxy-benzene or guaiacol and one or The mixing of a variety of indoles, phenylacetaldehyde, anethole, eugenol, cinnamic acid and cinnamonitrile is chrysomelid for preventing and treating bar as attractant Belong to the application of the insect of species.US 4600581 (A) describes the synthetic pheromone work for being suitable for Spined Soldier Bug Property composition, described active compound include the mixture of Α~terpenol, (E) -2- hexenoic aldehydes and phenmethylol.JP 56087511 describe and are suitable for pine tree moth (Pine Tree Borers), bark beetle (Bark Beetle) and wood borer The insect attractant of (Wood Borers), described attractant include lubricating oil, disinfectant and attractant compound such as salicylide, Salicylic acid isobutyl, n-butanal, salicylic acid benzyl ester, isoamyl salicylate, benzaldehyde, phenylacetaldehyde, acetophenone or just Aldehyde C-9.JP 59062504 (A) describes the attractant active compound for being suitable for Hylemyia (Hylemia) species, described work Property composition includes one or more propionic acid, n-butyric acie, isobutyric acid, positive valeric acid, isovaleric acid, isocaproic acid and 2~phenylethanol.
Although prior art literature describes some compounds or compound mixing attractive to different insects species The application of thing, but from the diversity of prior art it will already have become clear that the tool used for the attractant of different insects species Body compound or compound mixture are also different.
More in the prior art that striped rice borer is lured using gyplure, its action principle is trapping striped rice borer hero moth, done The mating between striped rice borer male and female moth is disturbed, so as to reduce the Mating opportunity of the female moth of striped rice borer, reduces female moth egg amount.But lure mesh Mark can only be directed to striped rice borer male worm, and the number of copulations in striped rice borer hero moth all one's life has as many as 4~5 times, when the population of field striped rice borer When quantity is low, preferable preventive and therapeutic effect can be played, and when striped rice borer field population density is higher, then preventive and therapeutic effect is limited.CN 104782594 A disclose a kind of compound attractant that can lure female, the male moth of striped rice borer simultaneously, but the attractant is stilled need in property Good attractant effect can be just played under the cooperation of lure, adds the cost of manufacture of attractant.
The content of the invention
Primary technical problem to be solved by this invention is to provide that a kind of attracting action is strong, it is female to trap striped rice borer simultaneously Moth and the active compound of male moth, and the formula trapping male moth is significantly better than gyplure.
The invention provides a kind of active compound based on camphor and n-octyl alcohol, include the component of following parts by weight:Camphor tree 30~60 parts of brain, 15~50 parts of n-octyl alcohol, 5~30 parts of aldehyde C-9,2~18 parts of linalool.
Optionally, the active compound, the component of following parts by weight is included:40~50 parts of camphor, n-octyl alcohol 25~38 Part, 12~22 parts of aldehyde C-9,4~12 parts of linalool.
Preferably, the active compound, include the component of following parts by weight:42~57 parts of camphor, n-octyl alcohol 27~35 Part, 14~18 parts of aldehyde C-9,5~10 parts of linalool.
Preferably, the active compound, the component of following parts by weight is included:45.2 parts of camphor, 32.4 parts of n-octyl alcohol, nonyl 15.3 parts of aldehyde, 7.1 parts of linalool.
Another object of the present invention is to provide a kind of striped rice borer attractant, including it is above-mentioned any one lure striped rice borer The active compound and non-volatile organic solvent of male and female moth.
Optionally, the non-volatile organic solvent is at least one of atoleine, mineral oil, sunflower oil or two kinds Mixture above, the present invention include but is not limited to above-mentioned several non-volatile organic solvents.
Optionally, the volume ratio of the quality of the active compound and the non-volatile organic solvent for 100~ 400mg:0.1~0.3mL, preferably 200~300mg:0.15~0.25mL.
Another object of the present invention is to provide a kind of striped rice borer lure, includes the isotropic silk of a sealing two ends, described The striped rice borer attractant of above-mentioned record is packaged with isotropic silk.The present invention is not special to the dosage of the striped rice borer attractant of encapsulation Limit, according to striped rice borer the time can be lured to determine to encapsulate the dosage of attractant.
Optionally, the striped rice borer attractant of striped rice borer lure of the invention encapsulation, including lived described in 100~400mg Property composition and 0.1~0.3mL non-volatile organic solvents.
Preferably, the striped rice borer attractant includes active compound described in 200~300mg and 0.15~0.25mL is non-waves Hair property organic solvent.
Specifically, the active compound can be 120mg, 150mg, 190mg, 250mg, 270mg, 330mg, 360mg, 390mg;The non-volatile organic solvent can be 0.1mL, 0.13mL, 0.18mL, 0.2mL, 0.22mL, 0.25mL, 0.27mL, 0.3mL.
Optionally, the isotropic silk is one or both of polythene material and polypropylene plastics.The polyethylene material Material is preferably high-density polyethylene material, and the present invention includes but is not limited to above-mentioned different materials.
Optionally, the isotropic fiber tube wall thickness is 0.01~0.1mm, preferably 0.02~0.08mm, further preferably For 0.04~0.06mm.
Another object of the present invention is to provide a kind of application of above-mentioned striped rice borer lure, and the striped rice borer lure is put In trapper, the striped rice borer attractant is discharged, trapping striped rice borer is female, male moth.
The present invention compared with prior art, has advantages below:
The present invention lures striped rice borer active compound to lure female moth and male moth simultaneously, is higher than property to striped rice borer control efficiency It lure, can be used as largely trapping and killing, field rice stem borer quantity can be substantially reduced, and reduce offspring's insect density.The present invention carries The striped rice borer attractant and lure of confession apply also for striped rice borer prediction, lure insect-catching amount energy Accurate Prediction Striped Rice Borer Population to send out Lively state.The striped rice borer attractant selectivity of the present invention is strong, does not produce resistance, natural enemy is not injured, environment nontoxic to people and animals It is friendly;Strong stress resistance, it is not afraid of wind, drenches with rain and Exposure to Sunlight;Prepare simply, use simple, lasting period length.
Embodiment
Some insects have obvious hobby property to indivedual plants, and rationally planting these plants can attract insect to protect For main cultivation crop from causing harm, this kind of plant is referred to as Trap plants.Vetiver Vetiveria zizanioides have to striped rice borer There is very strong attracting action, trap the female moth of striped rice borer and laid eggs on vetiver, but in test, it was also found that vetiver is for striped rice borer Male moth also there is same strong attraction aggtegation.
Our volatile ingredients to vetiver, which have carried out purification, separation, identification, and rice volatile materials, to be compared Compared with proposing the combination of specific compound and multiple compounds, tested by substantial amounts of indoor tentaculum electric potential physiological measurement and crop field Card, it is determined that 3 kinds of compounds combination of the invention can lure the female moth of striped rice borer and male moth simultaneously, and its field attractant effect is better than Gyplure on the market.
Active compound proposed by the present invention based on camphor and n-octyl alcohol, include the component of following parts by weight:Camphor 30 ~60 parts, 15~50 parts of n-octyl alcohol, 5~30 parts of aldehyde C-9,2~18 parts of linalool.The present invention is to camphor, n-octyl alcohol, aldehyde C-9 and virtue The source of camphor tree alcohol is not particularly limited, using commercial goods.
The striped rice borer attractant of the present invention includes above-mentioned active compound and non-volatile organic solvent.By the activearm Compound mixes with the non-volatile organic solvent, as striped rice borer attractant.Striped rice borer attractant is packaged in isotropic silk, As striped rice borer lure of the invention.The striped rice borer lure of the present invention is placed in trapper, trapping striped rice borer is female, male moth, uses Observe and predict in the striped rice borer worm phase and largely trap and kill.
For the object, technical solutions and advantages of the present invention are more clearly understood, the present invention is entered with reference to embodiment Row detailed description, but they can not be interpreted as limiting the scope of the present invention.
Embodiment 1
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:45.2 parts of camphor, 26.6 parts of n-octyl alcohol, 14.5 parts of aldehyde C-9,13.7 parts of linalool.
Embodiment 2
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:32.3 parts of camphor, 37.8 parts of n-octyl alcohol, 19.6 parts of aldehyde C-9,9.3 parts of linalool.
Embodiment 3
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:43.5 parts of camphor, 25.4 parts of n-octyl alcohol, 21.5 parts of aldehyde C-9,9.6 parts of linalool.
Embodiment 4
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:45.6 parts of camphor, 43.1 parts of n-octyl alcohol, 5.3 parts of aldehyde C-9,6.0 parts of linalool.
Embodiment 5
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:57.4 parts of camphor, 15.5 parts of n-octyl alcohol, 13.5 parts of aldehyde C-9,13.6 parts of linalool.
Embodiment 6
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:42.1 parts of camphor, 23.9 parts of n-octyl alcohol, 24.6 parts of aldehyde C-9,9.4 parts of linalool.
Embodiment 7
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:45.8 parts of camphor, 31.3 parts of n-octyl alcohol, 17.8 parts of aldehyde C-9,5.1 parts of linalool.
Embodiment 8
A kind of active compound that can lure striped rice borer male and female moth simultaneously, by following components according to respective parts by weight group Into:48.2 parts of camphor, 35.2 parts of n-octyl alcohol, 11.4 parts of aldehyde C-9,5.2 parts of linalool.
Embodiment 9
The active compound of the 250mg embodiment of the present invention 1~8 is dissolved in 0.25mL atoleines, obtains striped rice borer Attractant.The striped rice borer attractant being prepared is packaged in the isotropic silk of polyethylene pipe of sealing two ends, lured as striped rice borer Core.The pipe thickness of the isotropic silk is 0.05mm.
Embodiment 10
The active compound of the 150mg embodiment of the present invention 1~8 is dissolved in 0.2mL sunflower oils, striped rice borer is obtained and lures Agent.The striped rice borer attractant being prepared is packaged in the isotropic silk of PA tube of sealing two ends, as striped rice borer lure.Institute The pipe thickness for stating isotropic silk is 0.1mm.
Embodiment 11
The active compound of the 350mg embodiment of the present invention 1~8 is dissolved in 0.3mL mineral oil, striped rice borer is obtained and lures Agent.The striped rice borer attractant being prepared is packaged in the isotropic silk of high density polyethylene pipe of sealing two ends, as striped rice borer Lure.The pipe thickness of the isotropic silk is 0.02mm.
Embodiment 12
In order to further illustrate the feasibility of striped rice borer attractant provided by the invention, carried out with reference to specific experiment Explanation.
On 25 days-June 15 April in 2016, luring for striped rice borer attractant is carried out in Jinhua, Zhejiang Province city Wucheng District Tang Xi towns Catch effect test.
Select rice varieties, growing way, rich water quality management consistent, the rice field in flakes of 200 mu of area, will be real as experimental plot The striped rice borer lure for applying the different formulations that example 9 obtains is fixed in the special trapper of striped rice borer, for traping rice stem borer.Often The striped rice borer attractant of one formula is uniformly random to set 10 points, using commercially available gyplure as control.Investigated what is traped every 3 days Rice stem borer quantity, persistently investigate 50 days.
Test effect is as follows:
Attractant effect of the striped rice borer attractant of the different formulations of table 1 to rice stem borer
The isotropic silk of striped rice borer gyplure that wherein comparative example is provided using Ningbo NewCon Co., Ltd. lures Core.
Result of the test shows:Striped rice borer hero moth trapping amount provided by the invention is significantly higher than the trapping amount of comparative example, The female moth of striped rice borer can also be largely traped, striped rice borer gyplure can only then trap male moth.Timber quarantine provided by the invention is lived Property it is high, the prediction accuracy that the phase occurs for striped rice borer can be improved.Attractant especially provided by the invention can be lured largely simultaneously Striped rice borer hero moth and female moth are caught, field rice stem borer quantity can be reduced, reduce offspring's insect density, than current commercial two Changing snout moth's larva gyplure has higher preventing and treating efficiency.
The striped rice borer attractant selectivity is strong, does not produce resistance, and natural enemy is not injured, environment-friendly to person poultry harmless; Strong stress resistance, it is not afraid of wind, drenches with rain and Exposure to Sunlight;Prepare simply, use simple, lasting period length, to striped rice borer attractive activity holding effect More than 50 days.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (10)

1. a kind of active compound based on camphor and n-octyl alcohol, it is characterised in that include the component of following parts by weight:Camphor 30 ~60 parts, 15~50 parts of n-octyl alcohol, 5~30 parts of aldehyde C-9,2~18 parts of linalool.
2. active compound according to claim 1, it is characterised in that include the component of following parts by weight:Camphor 40~ 50 parts, 25~38 parts of n-octyl alcohol, 12~22 parts of aldehyde C-9,4~12 parts of linalool.
3. active compound according to claim 1, it is characterised in that include the component of following parts by weight:Camphor 42~ 57 parts, 27~35 parts of n-octyl alcohol, 14~18 parts of aldehyde C-9,5~10 parts of linalool.
A kind of 4. striped rice borer attractant, it is characterised in that including the active compound described in claims 1 to 3 any one and Non-volatile organic solvent.
5. striped rice borer attractant according to claim 4, it is characterised in that the non-volatile organic solvent is liquid stone Mixture more than one or both of wax, mineral oil and sunflower oil.
6. the striped rice borer attractant according to claim 4 or 5, it is characterised in that the quality of the active compound and institute The volume ratio for stating non-volatile organic solvent is 100~400mg:0.1~0.3mL.
7. a kind of striped rice borer lure, it is characterised in that the isotropic silk including sealing two ends, the interior encapsulation of the isotropic silk is had the right will Seek the striped rice borer attractant described in 4~6 any one.
8. striped rice borer lure according to claim 7, it is characterised in that the material of the isotropic silk is polyethylene and poly- third One or both of alkene plastics.
9. the striped rice borer lure according to claim 7 or 8, it is characterised in that the isotropic fiber tube wall thickness be 0.01~ 0.1mm。
10. the application of the striped rice borer lure described in claim 7~9 any one, it is characterised in that by the striped rice borer lure It is placed in trapper, discharges the striped rice borer attractant, traps striped rice borer male and female moth.
CN201710792026.8A 2017-09-05 2017-09-05 A kind of active compound based on camphor and n-octyl alcohol, striped rice borer attractant and application Pending CN107494576A (en)

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Publication number Priority date Publication date Assignee Title
CN112514911A (en) * 2020-11-17 2021-03-19 贵州师范大学 Sex pheromone synergist for small insects in noctuidae
EP4145999A1 (en) * 2020-05-05 2023-03-15 Macquarie University Fruit fly control

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4145999A1 (en) * 2020-05-05 2023-03-15 Macquarie University Fruit fly control
CN112514911A (en) * 2020-11-17 2021-03-19 贵州师范大学 Sex pheromone synergist for small insects in noctuidae

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