CN107488460A - A kind of light ends fractionation hydrogenation plant - Google Patents
A kind of light ends fractionation hydrogenation plant Download PDFInfo
- Publication number
- CN107488460A CN107488460A CN201610408247.6A CN201610408247A CN107488460A CN 107488460 A CN107488460 A CN 107488460A CN 201610408247 A CN201610408247 A CN 201610408247A CN 107488460 A CN107488460 A CN 107488460A
- Authority
- CN
- China
- Prior art keywords
- layer
- temperature
- light ends
- heating
- outting pipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
For overcome the deficiencies in the prior art, the present invention provides a kind of device, and it is hydrogenated with suitable for light ends fractionation, and light ends fractionation hydrogenation catalyst reduces at high temperature, the strongly exothermic reaction started at low temperature.It is specific to be applicable light ends fractionation selective hydrogenation or the complete miniature or small testing device for being hydrogenated with the undesirable components effectively removed in unsaturated hydro carbons therein.Specifically, the inventive system comprises the reactor positioned at internal layer, the exothermic layer positioned at intermediate layer and the zone of heating positioned at outer layer.
Description
Technical field
The present invention relates to a kind of light ends fractionation hydrogenation plant.
Background technology
Hydrogenation catalyst is in petroleum refining with possessing oil product lighting in chemical industry, cleaning and increase economic efficiency, tap the latent power
The important function of synergy, it is developed needs to carry out substantial amounts of experimental evaluation work with performance test, and Hydrogenation Experiment is evaluation catalysis
The sole mode of agent activity, selectivity and stability, process conditions, catalyst and the requirement meeting basis to experimental rig of hydrogenation
Raw material oil nature and the difference of target product have differences, for example, can be divided into low pressure, middle pressure, high pressure according to pressure rating and surpass
High-pressure hydrogenation, heat absorption, heat release and strong exothermal reaction can be divided into according to heat, therefore, it is poor that hydrogenation plant exists according to technical process
It is different, exploitation and the performance evaluation of hydrogenation catalyst collect needs targetedly established according to requirement of experiment it is a set of reliable and stable
Experimental provision.
Light ends fractionation is because of the one or more in the multiple monoolefine containing C2~C5, alkadienes and alkynes, it is impossible to carries out effective
Comprehensive utilization, larger economic loss and environmental pollution be present, its selective hydrogenation or full unifining process can effectively take off
Except undesirable components therein, the hydrogenation process of low-carbon unsaturated hydrocarbons is mostly strong exothermal reaction, typically expensive using Pd, Au, Pt etc.
Metallic catalyst low temperature hydrogenation, temperature near room temperature, and reactor can meet the requirement for removing heat in time, and it is controllable to reach temperature rise
Purpose.But metal contained by the noble metal catalysts such as Pd, Au, Pt is mostly oxidation state, and its activity is mostly mutually metallic state, reaction
Need catalyst carrying out high temperature reduction before, temperature is generally greater than 200 DEG C, so the control of bed reaction temperature is a difficulty
Topic, it is therefore necessary to which, according to requirement of experiment, the experimental provision of temperature control can be stablized by establishing under a high/low temperature.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of device, and it is hydrogenated with suitable for light ends fractionation, and gently
Hydrocarbon-fraction hydrogenation catalyst reduces at high temperature, the strongly exothermic reaction started at low temperature.Specifically applicable light ends fractionation selection
Property hydrogenation or full hydrogenation effectively remove the miniature or small testing devices of the undesirable components in unsaturated hydro carbons therein.
Specifically, light ends fractionation hydrogenation plant of the invention includes the reactor positioned at internal layer, positioned at putting for intermediate layer
Thermosphere and the zone of heating positioned at outer layer.
In a specific embodiment, calorimetric device is provided with the inside of the reactor, preferably described calorimetric device is
Electroheat pair.
In a specific embodiment, the reactor is tubular reactor, and the exothermic layer is made up of heat outting pipe；Institute
Stating the outer surface of tubular reactor has groove, and the heat outting pipe is embedded in the groove of the outer surface of the tubular reactor, excellent
It is screw type groove to select the groove, and the heat outting pipe is spirally in the groove of the outer surface of the tubular reactor.
In a specific embodiment, the exothermic layer includes the internal heat outting pipe that fluid is housed.For example, it can react
The groove being adapted with heat outting pipe is carved with the outer surface of device, so as to which heat outting pipe is placed in groove.
In a specific embodiment, the fluid is selected from water or conduction oil, and the temperature of preferably described conduction oil is 0-300
℃。
In a specific embodiment, the entrance and exit of the heat outting pipe respectively with the first temperature filled with the fluid
Control unit is connected, and the control unit can be used for controlling fluid to required temperature.The control unit is at least by sensor, processing
Device and executing agency's composition, so as to control fluid to required temperature.
Also include in the port of export of the heat outting pipe parallel arrangement of for being vented gas in the heat outting pipe with the outlet
The drain of body.The outlet of wherein described heat outting pipe and the drain of the heat outting pipe are connected by three-way valve and the heat outting pipe
Connect.
In a specific embodiment, the zone of heating is electrothermal layer.
In a specific embodiment, the zone of heating is connected with second temperature control unit, the temperature control unit control
The temperature of zone of heating processed.The temperature of the zone of heating is determined by electroheat pair.The control unit at least by sensor, processor and
Executing agency forms, so as to control the temperature of zone of heating.
The light ends fractionation hydrogenation plant of the present invention, is a kind of tubular fixed-bed reactor, its course of reaction possess heating and
Heat release function.
Present invention also offers a kind of application of device as described above in light ends fractionation hydrogenation.
The advantage of the invention is that it can be used for reduction temperature high, the low temperature hydrogenation of the low light ends fractionation of reaction temperature it is strong
Exothermic reaction, and can prevent from highly exothermic in course of reaction causing temperature runaway so as to cause reaction temperature can not stability contorting etc.
Problem.
Brief description of the drawings
The side schematic view when outer layer zone of heating is in open mode of the device of Fig. 1 present invention.
Embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention is not limited to following realities
Apply example.
As shown in figure 1, the device of the present invention is divided into internal layer, intermediate layer and outer layer, internal layer is tubular reactor 1, and tubular type is anti-
The inside of device 1 is answered to be provided with thermocouple 2, thermocouple 2 is placed in catalyst and filler centre.Intermediate layer is exothermic layer, along pipe reaction
A screw type groove of circle circle is carved with the outer surface of device 1, is embedded in groove among the conduct of stainless steel tubule 3 of certain diameter
Layer, makes it closely be fit together with tubular reactor 1, and one end of stainless steel tubule 3 is entrance 4, and entrance 4 and heat conduction
5 yuan of the first temperature control list of liquid is connected, and the other end of stainless steel tube 3 is the outlet being connected with the first temperature control unit 5
61 and the drain 62 of gas in stainless steel tube 3 can be vented, the junction of its middle outlet 61 and drain 62 can be set
There is three-way valve.Outer layer is electric heating layer 7, and electric heating layer is stainless steel casing, and interior is resistive heater or heating Elema and guarantor
Adiabator, electric heating layer 7 are connected with for the second temperature control unit 8 of its heating, and electric heating layer 7 by electroheat pair 2
Temperature control.During catalyst reduction, the heat-conducting liquid in the stainless steel tube 3 in middle level is emptied, and needs stainless steel tube 3
Interior air emptying, so, will not because when gases are heated, they expand in heat-conducting liquid or stainless steel tube can not drain damage it is stainless
Steel pipe 3.Because stainless steel tube 3 is embedded in the surface of tubular reactor 1, and stainless steel tube 3 is the good conductor of heat in itself, so
Intermediate layer does not influence outer layer to the heat transfer of tubular reactor 1.Then, by outer layer the heated Tube reactor 1 of electric heating layer 7 to
Predetermined temperature, such as 500 DEG C.During low-temp reaction, the zone of heating of outer layer, which is in, stops heated condition, by heat-conducting liquid
Fluid therein is simultaneously continuously sent to stainless steel tube by the speed and temperature of the first temperature control unit 5 control conductive fluid
In 3, the flowing velocity of heat-conducting liquid and the fast cooling of temperature controlled tubular reactor 1 of thermosphere are taken with centre, so as to reach
To the purpose of temperature control.It can ensure that light ends fractionation hydrogenation and removing alkynes, alkene etc. are low from there through the combined use of heat supply and heat release
The normal operation of warm strong exothermal reaction.
As described above, embodiments of the invention are explained, as long as but essentially without this hair of disengaging
There can be various deformation in bright spirit and scope, this will be readily apparent to persons skilled in the art.Therefore, so
Variation be also integrally incorporated within protection scope of the present invention.
Obviously, those skilled in the art belong to the protection model of the present invention based on the modifications and variations that spirit of the invention is made
Enclose.
Claims (10)
1. a kind of light ends fractionation hydrogenation plant, it includes：
Positioned at the reactor of internal layer,
Exothermic layer positioned at intermediate layer,
Positioned at the zone of heating of outer layer.
2. device according to claim 1, it is characterised in that be provided with calorimetric device in the inside of the reactor, preferably
The calorimetric device is electroheat pair.
3. device according to claim 1 or 2, it is characterised in that the reactor is tubular reactor, the exothermic layer
It is made up of heat outting pipe；There is groove in the outer surface of the tubular reactor, the heat outting pipe is embedded in the tubular reactor
In the groove of outer surface, preferably described groove is screw type groove, and the heat outting pipe is spirally embedded in the tubular reactor
Outer surface groove in.
4. according to the device described in any one in claim 1-3, it is characterised in that the exothermic layer includes internal equipped with stream
The heat outting pipe of body.
5. according to the device described in any one in claim 1-4, it is characterised in that the fluid is selected from water or conduction oil,
It is preferred that the temperature of the conduction oil is 0-300 DEG C.
6. the device according to claim 3 or 4, it is characterised in that the entrance and exit of the heat outting pipe respectively with filled with
First temperature control unit of the fluid is connected, and first temperature control unit is used for controlling the temperature of the fluid.
7. device according to claim 6, it is characterised in that also include and the outlet in the port of export of the heat outting pipe
The parallel arrangement of drain for being used to be vented gas in the heat outting pipe.
8. according to the device described in any one in claim 1-7, it is characterised in that the zone of heating is electrothermal layer.
9. device according to claim 8, it is characterised in that the zone of heating is connected with second temperature control unit, institute
State the temperature of second temperature control unit control zone of heating.
10. application of the device in light ends fractionation hydrogenation as described in any one in claim 1-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610408247.6A CN107488460A (en) | 2016-06-12 | 2016-06-12 | A kind of light ends fractionation hydrogenation plant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610408247.6A CN107488460A (en) | 2016-06-12 | 2016-06-12 | A kind of light ends fractionation hydrogenation plant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107488460A true CN107488460A (en) | 2017-12-19 |
Family
ID=60641925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610408247.6A Pending CN107488460A (en) | 2016-06-12 | 2016-06-12 | A kind of light ends fractionation hydrogenation plant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107488460A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2535797Y (en) * | 2002-04-27 | 2003-02-12 | 中国工程物理研究院激光聚变研究中心 | Heat-treatment device |
| CN101993989A (en) * | 2009-08-18 | 2011-03-30 | 赵岩 | Matching temperature-controlling device of heat treatment furnace |
| CN203489640U (en) * | 2013-08-12 | 2014-03-19 | 合肥国轩高科动力能源股份公司 | Oven capable of decreasing temperature forcedly for lithium ion battery production |
| CN203513598U (en) * | 2013-09-04 | 2014-04-02 | 中国石油天然气股份有限公司 | Light dydrocarbon fraction hydrogenation test device |
| CN203725069U (en) * | 2014-02-27 | 2014-07-23 | 彭映 | Electrical heating type cold and hot cylinder |
| CN104419463A (en) * | 2013-09-04 | 2015-03-18 | 中国石油天然气股份有限公司 | Device and method applied to hydrogenation test of light hydrocarbon fraction |
-
2016
- 2016-06-12 CN CN201610408247.6A patent/CN107488460A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2535797Y (en) * | 2002-04-27 | 2003-02-12 | 中国工程物理研究院激光聚变研究中心 | Heat-treatment device |
| CN101993989A (en) * | 2009-08-18 | 2011-03-30 | 赵岩 | Matching temperature-controlling device of heat treatment furnace |
| CN203489640U (en) * | 2013-08-12 | 2014-03-19 | 合肥国轩高科动力能源股份公司 | Oven capable of decreasing temperature forcedly for lithium ion battery production |
| CN203513598U (en) * | 2013-09-04 | 2014-04-02 | 中国石油天然气股份有限公司 | Light dydrocarbon fraction hydrogenation test device |
| CN104419463A (en) * | 2013-09-04 | 2015-03-18 | 中国石油天然气股份有限公司 | Device and method applied to hydrogenation test of light hydrocarbon fraction |
| CN203725069U (en) * | 2014-02-27 | 2014-07-23 | 彭映 | Electrical heating type cold and hot cylinder |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107488460A (en) | A kind of light ends fractionation hydrogenation plant | |
| CN202452038U (en) | Electric heating oil tube | |
| CN108246220A (en) | A kind of temperature control reaction kettle | |
| CN203829918U (en) | Automatic ozone decomposition device of ozone testing device | |
| CN2913791Y (en) | Electromagnetic heating tube for crude oil gathering pipeline | |
| CN203215985U (en) | Non-contact electric heating circulating system | |
| CN203525346U (en) | Electromagnetic self-heating type scraper blade thin-film evaporator for high-temperature cracking of waste lubricating oil | |
| CN208583326U (en) | A kind of device preventing the thermally conductive deterioration of oil of electric heating reacting kettle | |
| CN202119273U (en) | Comprehensive utilization device of flue gas waste heat of heating furnace | |
| CN205700497U (en) | Conduction oil circulating-heating reactor automatic temp controller | |
| CN205308304U (en) | Heating system suitable for former bit map levies | |
| CN216361042U (en) | Full oil way preheating device suitable for low-temperature low-power diesel burner | |
| CN202532008U (en) | Quick heating faucet | |
| CN209199668U (en) | A kind of auxiliary device of cable extruding machine | |
| CN204765070U (en) | Beverage heating heat preservation device | |
| CN201997317U (en) | Reaction regenerating device of circulating fluidized bed | |
| CN203139286U (en) | Flowing liquid heating device for infusion set | |
| CN103599640A (en) | Electromagnetic self-heating scraper film evaporator for waste lubricant pyrolysis | |
| RU57874U1 (en) | SINGLE-PHASE ELECTRODE WATER HEATER | |
| CN106000239A (en) | Combined reactor | |
| CN202537691U (en) | Dental fluid heating and heat preservation device | |
| CN203507994U (en) | High-temperature reaction kettle electric heating device | |
| CN109107497A (en) | A kind of hydrogenation reaction of unsaturated hydrocarbon device | |
| CN201613837U (en) | Heating device using automobile engine waste heat | |
| CN206862132U (en) | Fast cooling system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171219 |