CN107488444A - A kind of preparation method of efficiently paraffin remover - Google Patents
A kind of preparation method of efficiently paraffin remover Download PDFInfo
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- CN107488444A CN107488444A CN201710835838.6A CN201710835838A CN107488444A CN 107488444 A CN107488444 A CN 107488444A CN 201710835838 A CN201710835838 A CN 201710835838A CN 107488444 A CN107488444 A CN 107488444A
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- oil
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- paraffin
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- 239000012188 paraffin wax Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000003921 oil Substances 0.000 claims abstract description 41
- 235000019198 oils Nutrition 0.000 claims abstract description 37
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 30
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000019482 Palm oil Nutrition 0.000 claims abstract description 28
- 239000002540 palm oil Substances 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000002425 crystallisation Methods 0.000 claims abstract description 10
- 230000008025 crystallization Effects 0.000 claims abstract description 10
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 21
- 235000005979 Citrus limon Nutrition 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 14
- 244000248349 Citrus limon Species 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 244000131522 Citrus pyriformis Species 0.000 claims description 6
- 235000019738 Limestone Nutrition 0.000 claims description 6
- 239000005457 ice water Substances 0.000 claims description 6
- 239000006028 limestone Substances 0.000 claims description 6
- 238000003828 vacuum filtration Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical class OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 239000001993 wax Substances 0.000 abstract description 29
- 238000004090 dissolution Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract description 4
- 125000000962 organic group Chemical group 0.000 abstract description 4
- 238000005253 cladding Methods 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 abstract description 2
- 239000004530 micro-emulsion Substances 0.000 abstract description 2
- 239000007764 o/w emulsion Substances 0.000 abstract description 2
- 238000012856 packing Methods 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 18
- 239000003129 oil well Substances 0.000 description 6
- 238000001514 detection method Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical group OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
- E21B37/06—Methods or apparatus for cleaning boreholes or wells using chemical means for preventing or limiting, e.g. eliminating, the deposition of paraffins or like substances
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention relates to a kind of preparation method of efficiently paraffin remover, belong to paraffin remover preparing technical field.The organic group of citrate can be dispersed in oil phase well in efficient paraffin remover in the present invention,Because its molecular weight is larger,Citrate can increase microemulsion density,Improve injection efficiency,And cause Water-In-Oil,Oil-in-water emulsion can more be stablized,Profit is avoided to be separated,Other simple grain Water-In-Oil molecule or oil-in-water molecule can be adsorbed in oily wax surface faster and further permeate,Wettability reversal causes peeling rate to accelerate,Increase the speed of paraffin dissolution,So as to reach the purpose of efficient molten wax,Palm oil after the purification that the present invention adds is similar to the organo moiety of wax,Both compatibilities are preferable,After paraffin remover is added,Palm oil spreads intrusion wax layer by the mixing oil phase of toluene and benzene,Crystallization is easily formed under water cladding,So that wax layer packing of molecules structure is destroyed,Rapid deterioration is simultaneously dispersed into small pieces,Accelerate molten wax effect,So as to reach the effect of efficient molten wax.
Description
Technical field
The present invention relates to a kind of preparation method of efficiently paraffin remover, belong to paraffin remover preparing technical field.
Background technology
All contain certain wax in crude oil, wax generally exists with dissolved state in the earth formation.However, in oil extraction process
In, temperature and pressure constantly reduces, and when temperature and pressure is reduced to a certain numerical value, the wax dissolved in crude oil just starts to analyse
Go out.With pressure, the continuous spilling for continuing reduction and light components of temperature, the wax in crude oil just constantly separates out, and crystallizes, be long
Greatly, assemble, and deposited on sucker rod surface and tube inner wall.
The paraffin deposited in oil well pipe and ground gathering line can cause the reduction of pipeline net sectional area or even block,
Pump efficiency is caused to decline, oilwell produced fluid amount decline, sucker rod can fracture because of overload (uplink load and friction in down stroke increase), oil well
The problems such as back pressure raises and thus causes the increasing of oil pumper power consumption and fault rate to rise.Paraffin deposit problem is opened as oil
Adopt, collect defeated during a major issue.The whole world economic loss caused by paraffin deposit and sinks for paraffin every year
Product controls costly up to tens dollars.To ensure oil extraction and collecting defeated to be smoothed out, the oil well of wax deposition need to be carried out clearly
Wax control.For oil field Paraffin Removal mainly based on wax removal, supplemented by wax control, the method for cleaning wax deposition mainly has mechanical treatment process, deep fat
Or steam hot wash method.
It is the more extensive method of current field use chemically to carry out wax removal and wax control to oil well.Generally by medicament
Add or added by hollow rod from oil jacket annular space, do not interfere with the normal production and other operations of oil well.Except can be with
Play outside Paraffin Removal effect, can also play a part of pour point depression, viscosity reduction, de-plugging using some medicaments.Chemical clear, paraffin remover has oil
Three kinds of dissolubility, water solubility and emulsion-type liquid are clear, paraffin remover, in addition with a kind of solid paraffin remover.
But the speed of paraffin dissolution to be present unhappy for currently used oil-soluble paraffin remover, the defects of causing molten wax effect difference, therefore
Invent a kind of efficiently Wax dissolving agent has positive meaning to oil field wax removal technical field.
The content of the invention
Present invention mainly solves technical problem, oil-soluble paraffin remover the speed of paraffin dissolution is unhappy during for current oil extraction
A kind of defect, there is provided preparation method of efficiently paraffin remover.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of preparation method of efficiently paraffin remover, it is characterised in that specifically preparation process is：
（1）600~800g lemons are weighed, are squeezed the juice to obtain lemon juice with juice extractor, lemon juice is added in beaker, are added into beaker
Enter 300~400g lime stone, heat temperature raising, after reaction, filter off while hot except filtrate obtains filter residue；
（2）Filter residue is placed in beaker at normal temperatures, 300~400mL concentrated sulfuric acid solutions are slowly added to along beaker wall of cup, is stirred
Afterwards, 400~500mL sodium chloride solutions are added to beaker, mixed liquor is obtained after stirring；
（3）Oil phase is obtained after toluene is mixed with benzene, according to the mass fraction, 13~15 parts of distillations are added into high speed dispersor
Water, 10~20 portions of mixed liquors, 50~55 parts of oil phases, after disperseing, obtain pre-dispersed liquid；
（4）Acetone and n-hexane are mixed to get intermixture, weigh 200~300g palm oils, add 300 into palm oil~
400mL intermixtures, stirring, obtain premixing palm oil, premix palm oil is fitted into beaker, stirred crystallization, after vacuum filtration, gone
Except filtrate is crystallized, good oil is obtained after being cooled to room temperature；
（5）Count in parts by weight, 10~15 parts of dodecyl sodium sulfates are added into pre-dispersed liquid, then dripped with constant pressure funnel
Add 40~50 parts of good oils, stir, until solution is transparent, after insulation, standing obtains efficient paraffin remover.
Step（1）The described time of squeezing the juice is 30~40min, and temperature is 80~90 DEG C after heat temperature raising, the reaction time 1
~2h.
Step（2）The mass fraction of the described concentrated sulfuric acid be 75%, add concentrated sulfuric acid solution after mixing time be 10~
15min, sodium chloride solution mass fraction are 45%, and mixing time is 3~4min.
Step（3）Described toluene and the mixing quality ratio of benzene are 5 ︰ 1, and high speed dispersor rotating speed is 2000~3000r/
Min, jitter time are 3~4h.
Step（4）Described acetone and the mixing quality ratio of n-hexane are 2 ︰ 1, and mixing time is 5~10min, at beaker
In under the conditions of 0 DEG C of ice-water bath, the stirred crystallization time is 20~30min, and vacuum filtration temperature is 0 DEG C, is filtered by vacuum the time
For 30~40min.
Step（5）The drop rate of described constant pressure funnel is 5~10mL/min, and speed of agitator is 200~300r/
Min, mixing time are 10~20min, and temperature is 70~80 DEG C during insulation, and soaking time is 2~3h.
The beneficial effects of the invention are as follows：
（1）Mixed solution in the present invention in the pre-dispersed liquid of efficient paraffin remover is rich in citrate, the organic group of citrate
Group can be dispersed in oil phase well, and because its molecular weight is larger, citrate can increase microemulsion density, improve note
Enter efficiency, and Water-In-Oil, oil-in-water emulsion are more stablized, be unfavorable for profit phase separation, in addition simple grain Water-In-Oil point
Son or oil-in-water molecule can be adsorbed in faster oily wax surface further permeate, wettability reversal so that peeling rate is accelerated, increase
The speed of paraffin dissolution, so as to reach the purpose of efficient molten wax；
（2）Palm oil after the purification that the present invention adds is similar to the organo moiety of wax, and both compatibilities are preferable, adding
After paraffin remover, palm oil spreads intrusion wax layer by the mixing oil phase of toluene and benzene, and crystallization is easily formed under water cladding so that
Wax layer packing of molecules structure is destroyed, and rapid deterioration is simultaneously dispersed into small pieces, accelerates molten wax effect, so as to reach the effect of efficient molten wax
Fruit.
Embodiment
600~800g lemons are weighed, lemon juice is obtained with the juice extractor 30~40min that squeezes the juice, lemon juice is added in beaker,
300~400g lime stone is added into beaker, after being heated to 80~90 DEG C of 1~2h of reaction, is filtered off while hot except filtrate
Obtain filter residue；Filter residue is placed in beaker at normal temperatures, it is 75% to be slowly added to 300~400mL mass fractions along beaker wall of cup
Concentrated sulfuric acid solution, after stirring 10~15min, the sodium chloride solution that 400~500mL mass fractions are 45%, stirring are added to beaker
Mixed liquor is obtained after 3~4min；Oil phase is obtained after toluene is mixed with benzene for 5 ︰ 1 in mass ratio, according to the mass fraction, at a high speed
13~15 parts of distilled water, 10~20 portions of mixed liquors, 50~55 parts of oil phases are added in dispersion machine, with turning for 2000~3000r/min
After the scattered 3~4h of speed, pre-dispersed liquid is obtained；Acetone and n-hexane are mixed to get intermixture for 2 ︰ 1 in mass ratio, weigh 200
~300g palm oils, 300~400mL intermixtures are added into palm oil, stir 5~10min, obtain premixing palm oil, will be pre-
Mixed palm oil is fitted into beaker, under the conditions of 0 DEG C of ice-water bath, 20~30min of stirred crystallization, and it is filtered by vacuum 30 at 0 DEG C
After~40min, remove filtrate and crystallized, good oil is obtained after being cooled to room temperature；Count, add into pre-dispersed liquid in parts by weight
Enter 10~15 parts of dodecyl sodium sulfates, then 40~50 parts are added dropwise with 5~10mL/min drop rate with constant pressure funnel
Good oil, 10~20min is stirred with 200~300r/min rotating speeds, until solution is transparent, after being incubated 2~3h at 70~80 DEG C,
Standing obtains efficient paraffin remover.
Example 1
600g lemons are weighed, lemon juice is obtained with the juice extractor 30min that squeezes the juice, lemon juice is added in beaker, added into beaker
300g lime stone, after being heated to 80 DEG C of reaction 1h, filter off while hot except filtrate obtains filter residue；Filter residue is put at normal temperatures
In beaker, the concentrated sulfuric acid solution that 300mL mass fractions are 75% is slowly added to along beaker wall of cup, after stirring 10min, to beaker
The sodium chloride solution that 400mL mass fractions are 45% is added, mixed liquor is obtained after stirring 3min；In mass ratio for 5 ︰ 1 by toluene with
Oil phase is obtained after benzene mixing, according to the mass fraction, 13 parts of distilled water, 10 portions of mixed liquors, 50 parts of oil are added into high speed dispersor
Phase, after disperseing 3h with 2000r/min rotating speed, obtain pre-dispersed liquid；Acetone is mixed to get for 2 ︰ 1 in mass ratio with n-hexane
Intermixture, 200g palm oils are weighed, 300mL intermixtures are added into palm oil, stir 5min, obtain premixing palm oil, will be pre-
Mixed palm oil is fitted into beaker, under the conditions of 0 DEG C of ice-water bath, stirred crystallization 20min, and it is filtered by vacuum 30min at 0 DEG C
Afterwards, remove filtrate to be crystallized, good oil is obtained after being cooled to room temperature；Count in parts by weight, 10 parts are added into pre-dispersed liquid
Dodecyl sodium sulfate, then 40 parts of good oils are added dropwise with 5mL/min drop rate with constant pressure funnel, turned with 200r/min
Speed stirring 10min, until solution is transparent, after being incubated 2h at 70 DEG C, standing obtains efficient paraffin remover.
Example 2
700g lemons are weighed, lemon juice is obtained with the juice extractor 35min that squeezes the juice, lemon juice is added in beaker, added into beaker
350g lime stone, after being heated to 85 DEG C of reaction 1h, filter off while hot except filtrate obtains filter residue；Filter residue is put at normal temperatures
In beaker, the concentrated sulfuric acid solution that 350mL mass fractions are 75% is slowly added to along beaker wall of cup, after stirring 13min, to beaker
The sodium chloride solution that 450mL mass fractions are 45% is added, mixed liquor is obtained after stirring 4min；In mass ratio for 5 ︰ 1 by toluene with
Oil phase is obtained after benzene mixing, according to the mass fraction, 14 parts of distilled water, 15 portions of mixed liquors, 53 parts of oil are added into high speed dispersor
Phase, after disperseing 4h with 2500r/min rotating speed, obtain pre-dispersed liquid；Acetone is mixed to get for 2 ︰ 1 in mass ratio with n-hexane
Intermixture, 250g palm oils are weighed, 350mL intermixtures are added into palm oil, stir 8min, obtain premixing palm oil, will be pre-
Mixed palm oil is fitted into beaker, under the conditions of 0 DEG C of ice-water bath, stirred crystallization 25min, and it is filtered by vacuum 35min at 0 DEG C
Afterwards, remove filtrate to be crystallized, good oil is obtained after being cooled to room temperature；Count in parts by weight, 13 parts are added into pre-dispersed liquid
Dodecyl sodium sulfate, then 45 parts of good oils are added dropwise with 8mL/min drop rate with constant pressure funnel, turned with 250r/min
Speed stirring 15min, until solution is transparent, after being incubated 2h at 75 DEG C, standing obtains efficient paraffin remover.
Example 3
800g lemons are weighed, lemon juice is obtained with the juice extractor 40min that squeezes the juice, lemon juice is added in beaker, added into beaker
400g lime stone, after being heated to 90 DEG C of reaction 2h, filter off while hot except filtrate obtains filter residue；Filter residue is put at normal temperatures
In beaker, the concentrated sulfuric acid solution that 400mL mass fractions are 75% is slowly added to along beaker wall of cup, after stirring 15min, to beaker
The sodium chloride solution that 500mL mass fractions are 45% is added, mixed liquor is obtained after stirring 4min；In mass ratio for 5 ︰ 1 by toluene with
Oil phase is obtained after benzene mixing, according to the mass fraction, 15 parts of distilled water, 20 portions of mixed liquors, 55 parts of oil are added into high speed dispersor
Phase, after disperseing 4h with 3000r/min rotating speed, obtain pre-dispersed liquid；Acetone is mixed to get for 2 ︰ 1 in mass ratio with n-hexane
Intermixture, 300g palm oils are weighed, 400mL intermixtures are added into palm oil, stir 10min, obtain premixing palm oil, will be pre-
Mixed palm oil is fitted into beaker, under the conditions of 0 DEG C of ice-water bath, stirred crystallization 30min, and it is filtered by vacuum 40min at 0 DEG C
Afterwards, remove filtrate to be crystallized, good oil is obtained after being cooled to room temperature；Count in parts by weight, 15 parts are added into pre-dispersed liquid
Dodecyl sodium sulfate, then 50 parts of good oils are added dropwise with 10mL/min drop rate with constant pressure funnel, with 300r/min
Rotating speed stirs 20min, until solution is transparent, after being incubated 3h at 80 DEG C, standing obtains efficient paraffin remover.
Reference examples
Reference examples are used as using the paraffin remover of Shanghai City company production
The speed of paraffin dissolution detection is carried out to the paraffin remover in the present invention and reference examples, testing result is as shown in table 1：
Detection method：
By rower SY/T6300 evaluation method, the molten wax speed trial of paraffin remover is carried out at room temperature, i.e., is added in tool is filled in
15ml samples and 1g or so paraffin, detect the speed of paraffin dissolution of paraffin remover.
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| The speed of paraffin dissolution（mg/min） | 23 | 24 | 26 | 12 |
From detection data, paraffin remover the speed of paraffin dissolution produced by the present invention is fast, has broad application prospects.
Claims (6)
1. a kind of preparation method of efficiently paraffin remover, it is characterised in that specifically preparation process is：
（1）600~800g lemons are weighed, are squeezed the juice to obtain lemon juice with juice extractor, lemon juice is added in beaker, are added into beaker
Enter 300~400g lime stone, heat temperature raising, after reaction, filter off while hot except filtrate obtains filter residue；
（2）Filter residue is placed in beaker at normal temperatures, 300~400mL concentrated sulfuric acid solutions are slowly added to along beaker wall of cup, is stirred
Afterwards, 400~500mL sodium chloride solutions are added to beaker, mixed liquor is obtained after stirring；
（3）Oil phase is obtained after toluene is mixed with benzene, according to the mass fraction, 13~15 parts of distillations are added into high speed dispersor
Water, 10~20 portions of mixed liquors, 50~55 parts of oil phases, after disperseing, obtain pre-dispersed liquid；
（4）Acetone and n-hexane are mixed to get intermixture, weigh 200~300g palm oils, add 300 into palm oil~
400mL intermixtures, stirring, obtain premixing palm oil, premix palm oil is fitted into beaker, stirred crystallization, after vacuum filtration, gone
Except filtrate is crystallized, good oil is obtained after being cooled to room temperature；
（5）Count in parts by weight, 10~15 parts of dodecyl sodium sulfates are added into pre-dispersed liquid, then dripped with constant pressure funnel
Add 40~50 parts of good oils, stir, until solution is transparent, after insulation, standing obtains efficient paraffin remover.
A kind of 2. preparation method of efficiently paraffin remover according to claim 1, it is characterised in that：Step（1）It is described
Time of squeezing the juice be 30~40min, temperature is 80~90 DEG C after heat temperature raising, and the reaction time is 1~2h.
A kind of 3. preparation method of efficiently paraffin remover according to claim 1, it is characterised in that：Step（2）It is described
The mass fraction of the concentrated sulfuric acid be 75%, mixing time be 10~15min after adding concentrated sulfuric acid solution, and sodium chloride solution quality is divided
Number is 45%, and mixing time is 3~4min.
A kind of 4. preparation method of efficiently paraffin remover according to claim 1, it is characterised in that：Step（3）It is described
Toluene and the mixing quality ratio of benzene be 5 ︰ 1, high speed dispersor rotating speed is 2000~3000r/min, and jitter time is 3~4h.
A kind of 5. preparation method of efficiently paraffin remover according to claim 1, it is characterised in that：Step（4）It is described
Acetone and the mixing quality ratio of n-hexane be 2 ︰ 1, mixing time is 5~10min, and beaker is in the ice-water bath condition at 0 DEG C
Under, the stirred crystallization time is 20~30min, and vacuum filtration temperature is 0 DEG C, and the vacuum filtration time is 30~40min.
A kind of 6. preparation method of efficiently paraffin remover according to claim 1, it is characterised in that：Step（5）It is described
The drop rate of constant pressure funnel be 5~10mL/min, speed of agitator is 200~300r/min, mixing time is 10~
20min, temperature is 70~80 DEG C during insulation, and soaking time is 2~3h.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135703A (en) * | 2018-09-17 | 2019-01-04 | 佛山市禅城区诺高环保科技有限公司 | A kind of preparation method of heavy crude thinner |
| CN109837077A (en) * | 2019-03-13 | 2019-06-04 | 西安石油大学 | A kind of rubber wax ball clearing supporting wax-proofing agent and preparation method thereof, preparation facilities and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419759A (en) * | 2015-12-24 | 2016-03-23 | 陕西延安石油天然气有限公司 | High-effective environment-friendly oil-based wax removal agent |
| CN105567201A (en) * | 2014-10-09 | 2016-05-11 | 中国石油天然气股份有限公司 | Oil well oil-based wax removing agent |
| CN106085669A (en) * | 2016-06-08 | 2016-11-09 | 中国石油大学(华东) | A kind of oil-soluble paraffin remover |
| CN106350045A (en) * | 2016-08-26 | 2017-01-25 | 潍坊天福化学科技有限公司 | Novel low-temperature high-efficiency oil-base paraffin remover and preparation method thereof |
-
2017
- 2017-09-16 CN CN201710835838.6A patent/CN107488444A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567201A (en) * | 2014-10-09 | 2016-05-11 | 中国石油天然气股份有限公司 | Oil well oil-based wax removing agent |
| CN105419759A (en) * | 2015-12-24 | 2016-03-23 | 陕西延安石油天然气有限公司 | High-effective environment-friendly oil-based wax removal agent |
| CN106085669A (en) * | 2016-06-08 | 2016-11-09 | 中国石油大学(华东) | A kind of oil-soluble paraffin remover |
| CN106350045A (en) * | 2016-08-26 | 2017-01-25 | 潍坊天福化学科技有限公司 | Novel low-temperature high-efficiency oil-base paraffin remover and preparation method thereof |
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