CN107487037A - Environment friendly mildew resistant grid cloth and preparation method thereof - Google Patents
Environment friendly mildew resistant grid cloth and preparation method thereof Download PDFInfo
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- CN107487037A CN107487037A CN201710783591.8A CN201710783591A CN107487037A CN 107487037 A CN107487037 A CN 107487037A CN 201710783591 A CN201710783591 A CN 201710783591A CN 107487037 A CN107487037 A CN 107487037A
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- grid cloth
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- mildew resistant
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- 239000004744 fabric Substances 0.000 title claims abstract description 111
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000010439 graphite Substances 0.000 claims abstract description 31
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 31
- 239000003381 stabilizer Substances 0.000 claims abstract description 25
- XUPZWMXQVSOBBU-UHFFFAOYSA-N [As].C1=CC=CC=2OC3=CC=CC=C3NC12 Chemical compound [As].C1=CC=CC=2OC3=CC=CC=C3NC12 XUPZWMXQVSOBBU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 238000007781 pre-processing Methods 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 23
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 17
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 17
- 241001330002 Bambuseae Species 0.000 claims description 17
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 17
- 239000011425 bamboo Substances 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 17
- 239000004568 cement Substances 0.000 claims description 14
- 239000004033 plastic Substances 0.000 claims description 13
- 229920003023 plastic Polymers 0.000 claims description 13
- 239000003365 glass fiber Substances 0.000 claims description 10
- 230000008595 infiltration Effects 0.000 claims description 10
- 238000001764 infiltration Methods 0.000 claims description 10
- 229920002748 Basalt fiber Polymers 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 239000004014 plasticizer Substances 0.000 abstract description 12
- 238000005034 decoration Methods 0.000 abstract description 8
- 239000004566 building material Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 12
- 238000001035 drying Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 238000007731 hot pressing Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- VCRZAKVGPJFABU-UHFFFAOYSA-N 10-phenoxarsinin-10-yloxyphenoxarsinine Chemical compound C12=CC=CC=C2OC2=CC=CC=C2[As]1O[As]1C2=CC=CC=C2OC2=CC=CC=C21 VCRZAKVGPJFABU-UHFFFAOYSA-N 0.000 description 1
- 101100188540 Candida albicans (strain SC5314 / ATCC MYA-2876) OBPA gene Proteins 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000000750 industrial fungicide Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to building material field, and more particularly to environment friendly mildew resistant grid cloth and preparation method thereof;Including infiltrating knitmesh raw material with pretreating agent, bake, obtain pre-processing raw material;Standby grid cloth is woven with pretreatment raw material;Will at least two layers standby grid cloth superposition bonding;Wherein, pretreating agent includes the double phenoxazine arsenic of the first stabilizer, the first powdered graphite, oxo, resin, plasticizer;The preparation method can quickly, easily prepare the grid cloth with stronger mildew-proof function, and the preparation method cost-effective can be put into;The mould proof grid cloth has stronger anti-mold effect, and the mould proof grid cloth is applied into the fields such as decorations, can effectively lift the anti-mold effect after building decoration and fitment.
Description
Technical field
The present invention relates to building material field, and more particularly to environment friendly mildew resistant grid cloth and preparation method thereof.
Background technology
Grid cloth is a kind of special material, and cloth more common than in general is more solid more robust, has intensity height, alkali resistance good
Feature.Grid cloth is mainly widely used in:Wall reinforcing material (such as:Glass wall mesh, GRC wallboards, inside and outside EPS
Wall heat-insulating board, plasterboard etc.);Enhancing cement products (such as:FRP Columns, flue etc.);It is the special mesh sheet of granite, mosaic, big
Reason stone back of the body patch net;Waterproof roll cloth, asphalt roofing waterproof;The framework material of reinforced plastics, rubber;Fire-proof plate;Emery wheel base
Step;Highway pavement GSZ;Filleting band for building etc..
The logical production of existing grid cloth does not possess mould proof fungi-proofing effect, it is difficult to meets the needs of market is changeable.It is more in high temperature
The weather of rain descends, and decorating and renovating material tends to go mouldy because being produced by moist, does not only result in the attractive in appearance of fitting-up
Degree reduces, and can also be unfavorable for the health of the living environment of people, threatens the health of people.
The content of the invention
It is an object of the invention to provide a kind of preparation method of environment friendly mildew resistant grid cloth, the preparation method can quickly,
The grid cloth with stronger mildew-proof function is easily prepared, and the preparation method cost-effective can be put into.
Another object of the present invention is to provide a kind of environment friendly mildew resistant grid cloth, the mould proof grid cloth has stronger mould proof
Effect, the mould proof grid cloth is applied to the fields such as decorations, can effectively lift the mould proof effect after building decoration and fitment
Fruit, aesthetic property is kept, also lift the sanitation degree of living environment, be advantageous to the health of people;The mould proof grid cloth also has excellent
Different mechanical strength, toughness etc..
The present invention is realized using following technical scheme.
The present invention proposes a kind of preparation method of environment friendly mildew resistant grid cloth, and it includes infiltrating knitmesh former material with pretreating agent
Material, bake, obtain pre-processing raw material;Standby grid cloth is woven with pretreatment raw material;At least two layers standby grid cloth is folded
Add bonding;Wherein, pretreating agent includes the double phenoxazine arsenic of the first stabilizer, the first powdered graphite, oxo, resin, plasticizer.
The present invention proposes a kind of environment friendly mildew resistant grid cloth, and it is the preparation method making by above-mentioned environment friendly mildew resistant grid cloth
's.
The beneficial effect of the environment friendly mildew resistant grid cloth of the embodiment of the present invention and preparation method thereof is:The preparation method can be fast
Speed, the grid cloth with stronger mildew-proof function is easily prepared, and the preparation method cost-effective can be put into.By this
Mould proof grid cloth prepared by preparation method has stronger anti-mold effect, and the mould proof grid cloth is applied into the neck such as decorations
Domain, the anti-mold effect after building decoration and fitment can be effectively lifted, keep aesthetic property, also lift the hygienic journey of living environment
Degree, be advantageous to the health of people;The mould proof grid cloth also has excellent mechanical strength, toughness etc..
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer
Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment
The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, it is the conventional production that can be obtained by commercially available purchase
Product.
Environment friendly mildew resistant grid cloth of the embodiment of the present invention and preparation method thereof is specifically described below.
The preparation method of the environment friendly mildew resistant grid cloth of the present invention mainly includes:Knitmesh raw material are infiltrated with pretreating agent, are dried
System, obtain pre-processing raw material;Standby grid cloth is woven with pretreatment raw material;At least two layers standby grid cloth superposition is glued
Connect.
Above-mentioned knitmesh raw material can include at least one of basalt fibre and glass fibre;Basalt fibre has
Good toughness, rub resistance, corrosion resistance etc., good insulating, the heat resistance of glass fibre are strong, corrosion resistance is good, mechanical strong
Degree is high, and clathrum is worked out jointly with basalt fibre and glass fibre, and the machinery that can effectively lift obtained clathrum is strong
Degree, toughness, corrosion resistance etc..
The mesh of standby grid cloth in the present invention can be various polygons, such as:Triangle, quadrangle, six sides
Shape etc., it is possible to further be various regular polygons.
Above-mentioned pretreating agent includes the double fens of stabilizer (the first stabilizer), powdered graphite (the first powdered graphite), oxo
Dislike arsenic, resin and plasticizer.In detail, the stabilizer including 10-20 parts by weight, 30-50 are heavy in parts by weight for pretreating agent
Measure the powdered graphite, the double phenoxazine arsenic of the oxo of 10-20 parts by weight, the resin of 120-150 parts by weight of part, 5-10 plasticizer.
The double phenoxazine arsenic (OBPA systems organic compound containing arsenic) of oxo are a kind of new industrial fungicides, can and meanwhile it is mould proof,
Antibacterial, algae-resistant, it is one of maximally effective antiseptic of industrial circle.
Graphite, there is stronger lubricant effect;Stone mill powder is added in pretreating agent to be promoted in pretreating agent
Various components are quick, uniformly scatter, and can also make pretreating agent when using pretreating agent pretreatment knitmesh raw material
Rapidly permeated in knitmesh raw material, it is ensured that knitmesh raw material obtain the performances such as corresponding mould proof, antibacterial.
Stabilizer can make the stable performance of pretreating agent, prevent the active principle in pretreating agent from decomposing, aoxidizing.Increase
Modeling agent is a kind of high polymer material auxiliary agent, and plasticizer can be with the toughness of reinforcing material, and plasticizer is added in pretreating agent can be with
Toughness and mechanical strength of grid cloth etc. are improved, thus the service life of grid cloth can be extended etc..
The mechanical strength and toughness that knitmesh raw material can be lifted using one side of resin, on the other hand can be by graphite
The double phenoxazine arsenic of powder, oxo are uniform, are securely attached on knitmesh raw material, it is ensured that the grid cloth of preparation can have excellent
Anti-mold effect.
Further, with pretreating agent knitmesh raw material are carried out with infiltration to carry out in such a way:Knitmesh is former
Material is positioned in pretreating agent, vibrates 30-50min under 100-120Hz frequency.Knitmesh former material is being infiltrated with pretreating agent
During material, coordinate vibration to carry out, the mould proof material in pretreating agent can be promoted to go deep into the inside of knitmesh raw material, and then effectively carry
The anti-mold effect of grid cloth made from height.
After the completion of the infiltration of knitmesh raw material, baked, pretreating agent is solidified on knitmesh raw material, obtain pre- place
Raw material are managed, the temperature of above-mentioned baking can be 70-80 DEG C.
Standby grid cloth is woven into pretreatment raw material, and at least two layers standby grid cloth superposition is bonded, you can system
Obtain environment friendly mildew resistant grid cloth of the invention.
In detail, the superposition bonding of standby grid cloth can be carried out in such a way:It is being overlapped mutually two of bonding
Viscous glutinous agent is smeared between standby grid cloth, and is dried, such as:The viscous glutinous agent of the surface smear of a standby grid cloth wherein, then
Another standby grid cloth is attached to the surface for having smeared viscous glutinous agent, then dried.
Above-mentioned viscous glutinous agent can include plastic cement, stabilizer (the second stabilizer), powdered graphite (the second powdered graphite) and bamboo
Fiber dust.By weight, the plastic cement of 120-150 parts by weight, the stabilizer of 10-30 parts by weight, 5-10 weight can be included
The powdered graphite, the bamboo fibre powder of 10-20 parts by weight of part.
On the one hand plastic cement can be successfully bonded between grid cloth, on the other hand can make powdered graphite, bamboo fibre powder
More it is uniformly dispersed in plastic cement, and can be uniformly attached to grid cloth, on the one hand net can be further enhanced by also having
Mechanical strength and toughness of lattice cloth etc..Bamboo fibre powder has the performances such as stronger antibacterial, antibacterial, except mite, deodorization, by bamboo fibre
Powder makes an addition in bonding agent the anti-mold effect that can further lift environment friendly mildew resistant grid cloth.Lubricated possessed by powdered graphite
It is more uniform that effect can aid in bamboo fibre powder to disperse in viscous glutinous agent, on the one hand makes the anti-mold effect of grid cloth uniform
Improve, on the other hand ensure that the cementability of plastic cement is not destroyed, make the bonding that can stablize between standby grid cloth.
Preferably, the particle diameter of powdered graphite can be 1000-1200 mesh, the particle diameter of bamboo fibre can be 1000-1200
Mesh.The tiny powdered graphite of particle diameter and bamboo fibre powder can more rapidly, uniformly scatter in plastic cement, also may be used after smearing
To be more uniformly distributed in grid cloth, and then make the performance of grid cloth, quality more stable, uniform.
Above-mentioned drying can be carried out under the conditions of 100-120 DEG C.In detail, can be in drying, with hot pressing one
And carry out, on the one hand can be rapidly completed the work of hot pressing, on the other hand can make between grid cloth it is viscous it is glutinous more firmly, enter
And improve the service life of the environment friendly mildew resistant grid cloth, mechanical strength etc..
Environment friendly mildew resistant grid cloth of the present invention and preparation method thereof is described in further detail with reference to embodiments.
Embodiment 1
Pretreating agent is prepared, by the stabilizer of 10 parts by weight, the powdered graphite (mesh of particle diameter 1000) of 30 parts by weight, 10 weight
The double phenoxazine arsenic of the oxo of part, the resin of 120 parts by weight, the mixing of 5 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 120 parts by weight, the stabilizer of 10 parts by weight, 5 parts by weight powdered graphite (particle diameter
1000 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1000) of 10 parts by weight.
With pretreating agent sized glass fibres, with the vibration of 100Hz frequencies during infiltration, 30min is infiltrated, in 70 DEG C of conditions
Lower drying, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is triangle.In the mutually viscous of standby grid cloth
The viscous glutinous agent of surface smear connect, two layers of standby grid cloth is superimposed, dried under the conditions of 100 DEG C, you can environment friendly mildew resistant net is made
Ge Bu.
Embodiment 2
Pretreating agent is prepared, by the stabilizer of 20 parts by weight, the powdered graphite (mesh of particle diameter 1200) of 50 parts by weight, 20 weight
The double phenoxazine arsenic of the oxo of part, the resin of 150 parts by weight, the mixing of 10 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 150 parts by weight, the stabilizer of 30 parts by weight, 10 parts by weight powdered graphite (particle diameter
1200 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1200) of 20 parts by weight.
Basalt fibre is infiltrated with pretreating agent, with the vibration of 120Hz frequencies during infiltration, 50min is infiltrated, in 80 DEG C of bars
Dried under part, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is quadrangle.In the mutually viscous of standby grid cloth
The viscous glutinous agent of surface smear connect, two layers of standby grid cloth is superimposed, drying is simultaneously with hot pressing under the conditions of 120 DEG C, you can is made
Environment friendly mildew resistant grid cloth.
Embodiment 3
Pretreating agent is prepared, by the stabilizer of 15 parts by weight, the powdered graphite (mesh of particle diameter 1100) of 40 parts by weight, 15 weight
The double phenoxazine arsenic of the oxo of part, the resin of 150 parts by weight, the mixing of 7 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 130 parts by weight, the stabilizer of 20 parts by weight, 7 parts by weight powdered graphite (particle diameter
1100 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1100) of 15 parts by weight.
With pretreating agent sized glass fibres and basalt fibre, with the vibration of 110Hz frequencies, infiltration during infiltration
45min, dried under the conditions of 75 DEG C, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is triangle, basalt fibre and glass fibre
Amount ratio be 1:2.In the viscous glutinous agent of the surface smear being mutually bonded of standby grid cloth, two layers of standby grid cloth is superimposed,
Dried under the conditions of 110 DEG C, you can environment friendly mildew resistant grid cloth is made.
Embodiment 4
Pretreating agent is prepared, by the stabilizer of 12 parts by weight, the powdered graphite (mesh of particle diameter 1150) of 45 parts by weight, 18 weight
The double phenoxazine arsenic of the oxo of part, the resin of 130 parts by weight, the mixing of 8 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 130 parts by weight, the stabilizer of 18 parts by weight, 7 parts by weight powdered graphite (particle diameter
1050 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1100) of 12 parts by weight.
With pretreating agent sized glass fibres, with the vibration of 120Hz frequencies during infiltration, 35min is infiltrated, in 70 DEG C of conditions
Lower drying, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is six corner shapes.In the mutual of standby grid cloth
The viscous glutinous agent of the surface smear of bonding, three layers of standby grid cloth are superimposed, dried under the conditions of 110 DEG C, you can environment friendly mildew resistant is made
Grid cloth.
Embodiment 5
Pretreating agent is prepared, by the stabilizer of 18 parts by weight, the powdered graphite (mesh of particle diameter 1100) of 32 parts by weight, 16 weight
The double phenoxazine arsenic of the oxo of part, the resin of 135 parts by weight, the mixing of 8 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 145 parts by weight, the stabilizer of 27 parts by weight, 8 parts by weight powdered graphite (particle diameter
1200 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1000) of 16 parts by weight.
With pretreating agent sized glass fibres, with the vibration of 100Hz frequencies during infiltration, 45min is infiltrated, in 78 DEG C of conditions
Lower drying, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is triangle.In the mutually viscous of standby grid cloth
The viscous glutinous agent of surface smear connect, four layers of standby grid cloth is superimposed, drying is simultaneously with hot pressing under the conditions of 110 DEG C, you can is made
Environment friendly mildew resistant grid cloth.
Embodiment 6
Pretreating agent is prepared, by the stabilizer of 14 parts by weight, the powdered graphite (mesh of particle diameter 1200) of 42 parts by weight, 12 weight
The double phenoxazine arsenic of the oxo of part, the resin of 125 parts by weight, the mixing of 9 plasticizer.
Prepare viscous glutinous agent, by the plastic cement of 125 parts by weight, the stabilizer of 16 parts by weight, 5 parts by weight powdered graphite (particle diameter
1100 mesh), the mixing of the bamboo fibre powder (mesh of particle diameter 1100) of 13 parts by weight.
With pretreating agent sized glass fibres, with the vibration of 110Hz frequencies during infiltration, 38min is infiltrated, in 74 DEG C of conditions
Lower drying, obtain pre-processing raw material.
Standby grid cloth is woven with pretreatment, the mesh of standby grid cloth is quadrangle.In the mutually viscous of standby grid cloth
The viscous glutinous agent of surface smear connect, three layers of standby grid cloth is superimposed, drying is simultaneously with hot pressing under the conditions of 115 DEG C, you can is made
Environment friendly mildew resistant grid cloth.
Comparative example
From commercially available grid cloth as a comparison case.
The detection of resistance to mould, the reagent used in detection method and training are carried out to embodiment 1-6 and the grid cloth of comparative example
Support the references such as base《GB/T 1741-2007》, in detail method be:In an aseptic environment, every group of grid cloth 5cm is taken2The sample of area
Product, it is positioned in culture dish, pours into the culture medium of identical weight, 7d is cultivated under the conditions of 28 DEG C, observes the bacterium colony in culture medium
Quantity (is repeated 3 times), the results are shown in Table 1.
The resistance to mould testing result of each group grid cloth of table 1
As seen from the results in Table 1, after incubation, it is (right that the quantity of bacterium colony is considerably less than commercially available grid cloth for grid cloth of the invention
Ratio) quantity, you can knowing the environment friendly mildew resistant grid cloth of the present invention has good mould proof, antibacterial effect.
In summary, the beneficial effect of environment friendly mildew resistant grid cloth of the embodiment of the present invention and preparation method thereof is:The preparation
Method can quickly, easily prepare the grid cloth with stronger mildew-proof function, and the preparation method can save cost
Input.The mould proof grid cloth prepared by the preparation method has stronger anti-mold effect, and the mould proof grid cloth is applied into dress
The fields such as decorations finishing, can effectively lift the anti-mold effect after building decoration and fitment, keep aesthetic property, also lift living environment
Sanitation degree, be advantageous to the health of people;The mould proof grid cloth also has excellent mechanical strength, toughness etc..
Embodiments described above is part of the embodiment of the present invention, rather than whole embodiments.The reality of the present invention
The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention
Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made
Every other embodiment, belongs to the scope of protection of the invention.
Claims (10)
1. a kind of preparation method of environment friendly mildew resistant grid cloth, it is characterised in that including infiltrating knitmesh raw material with pretreating agent, dry
System, obtain pre-processing raw material;Standby grid cloth is woven with the pretreatment raw material;By at least two layers standby grid cloth
Superposition bonding;Wherein, the pretreating agent includes the double phenoxazine arsenic of the first stabilizer, the first powdered graphite, oxo, resin, plasticising
Agent.
2. the preparation method of environment friendly mildew resistant grid cloth according to claim 1, it is characterised in that the knitmesh raw material bag
Include at least one of basalt fibre and glass fibre.
3. the preparation method of environment friendly mildew resistant grid cloth according to claim 1, it is characterised in that the pretreating agent is by weight
Measure part meter, including first powdered graphite of first stabilizer of 10-20 parts by weight, 30-50 parts by weight, 10-20 weight
Measure the double phenoxazine arsenic of the oxo, the resin of 120-150 parts by weight of part.
4. the preparation method of environment friendly mildew resistant grid cloth according to claim 1, it is characterised in that the infiltration is according to following
Mode is carried out:The knitmesh raw material are positioned in the pretreating agent, vibrate 30-50min under 100-120Hz frequencies.
5. the preparation method of environment friendly mildew resistant grid cloth according to claim 1, it is characterised in that it is described superposition bonding according to
In the following manner is carried out:Viscous glutinous agent is smeared between two standby grid cloths for being overlapped mutually bonding, and is dried.
6. the preparation method of environment friendly mildew resistant grid cloth according to claim 5, it is characterised in that the viscous glutinous agent includes modeling
Glue, the second stabilizer, the second powdered graphite and bamboo fibre powder.
7. the preparation method of environment friendly mildew resistant grid cloth according to claim 6, it is characterised in that the viscous glutinous agent is by weight
Part meter, including described in second stabilizer of the plastic cement of 120-150 parts by weight, 10-30 parts by weight, 5-10 parts by weight
The bamboo fibre powder of second powdered graphite, 10-20 parts by weight.
8. the preparation method of environment friendly mildew resistant grid cloth according to claim 6, it is characterised in that the bamboo fibre powder
Particle diameter is 1000-1200 mesh.
9. the preparation method of environment friendly mildew resistant grid cloth according to claim 6, it is characterised in that second powdered graphite
Particle diameter be 1000-1200 mesh.
10. a kind of environment friendly mildew resistant grid cloth, it is characterised in that it is as the environment friendly mildew resistant net described in claim any one of 1-9
What the preparation method of lattice cloth made.
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CN1296104A (en) * | 2000-06-06 | 2001-05-23 | 王全祥 | Double-fibre reinforced gypsum board and productive technology thereof |
CN102492378A (en) * | 2011-11-25 | 2012-06-13 | 上海夸耶特新材料科技有限公司 | Water-based viscous-elastic damping sound-insulation adhesive |
CN103114448A (en) * | 2013-03-08 | 2013-05-22 | 东莞市悠派户外用品制造有限公司 | Noctilucent environment-friendly PVC (Polyvinyl Chloride) coated fabric |
CN203846718U (en) * | 2014-05-13 | 2014-09-24 | 景泰县金龙化工建材有限公司 | Combined-type grid rib layer product with surface protective paper |
CN203994927U (en) * | 2014-08-06 | 2014-12-10 | 浙江汇锋新材料有限公司 | A kind of photomask structure |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1296104A (en) * | 2000-06-06 | 2001-05-23 | 王全祥 | Double-fibre reinforced gypsum board and productive technology thereof |
CN102492378A (en) * | 2011-11-25 | 2012-06-13 | 上海夸耶特新材料科技有限公司 | Water-based viscous-elastic damping sound-insulation adhesive |
CN103114448A (en) * | 2013-03-08 | 2013-05-22 | 东莞市悠派户外用品制造有限公司 | Noctilucent environment-friendly PVC (Polyvinyl Chloride) coated fabric |
CN203846718U (en) * | 2014-05-13 | 2014-09-24 | 景泰县金龙化工建材有限公司 | Combined-type grid rib layer product with surface protective paper |
CN203994927U (en) * | 2014-08-06 | 2014-12-10 | 浙江汇锋新材料有限公司 | A kind of photomask structure |
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