CN107475612A - A kind of alloy material for IC engine cylinder block - Google Patents
A kind of alloy material for IC engine cylinder block Download PDFInfo
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- CN107475612A CN107475612A CN201710755943.9A CN201710755943A CN107475612A CN 107475612 A CN107475612 A CN 107475612A CN 201710755943 A CN201710755943 A CN 201710755943A CN 107475612 A CN107475612 A CN 107475612A
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- cylinder block
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- iron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/60—Aqueous agents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/04—Heavy metals
- F05C2201/0433—Iron group; Ferrous alloys, e.g. steel
- F05C2201/0448—Steel
- F05C2201/0451—Cast steel
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
Abstract
The invention mainly relates to automobile engine manufacturing field, discloses a kind of alloy material for IC engine cylinder block, consists of the following components in percentage by weight:Silicon 6 ~ 7%, graphene 6 ~ 7%, boron modified phenolic resin 3.4 ~ 3.6%, nickel 2.1 ~ 2.3%, magnesium 1.7 ~ 1.9%, chromium 1.4 ~ 1.6%, manganese 1.2 ~ 1.4%, niobium 0.7 ~ 0.9%, rhenium 0.7 ~ 0.9%, scandium 0.5 ~ 0.7%, remaining is iron and inevitable impurity;IC engine cylinder block is set to reduce 33 ~ 35% compared with the weight of traditional cast iron cylinder block, the more traditional Aluminum Alloy Cylinder Barrel of cost reduces 26 ~ 28%;Caused efficacy and structural stress during metal phase change are eliminated after adding silicon and graphene, improves the weatherability of cylinder block, avoids the temperature of cataclysm from producing injury to cylinder block, improves the wearability of cylinder block, the service life of cylinder block is extended 20 ~ 22%.
Description
Technical field
The invention mainly relates to automobile engine manufacturing field, more particularly to a kind of alloy material for IC engine cylinder block
Material.
Background technology
Cylinder block is the main body of engine, and each cylinder and crankcase are connected by it, be installation piston, bent axle and
The support framework of other parts and annex, the condition of work of cylinder block is very severe, and it will bear pressure and temperature in combustion process
The abrupt change of the drastically environment of change, the strong friction of piston movement and ambient temperature of degree, it is therefore desirable to which cylinder block has
There are higher strength and stiffness, good cooling performance and higher wearability;Cylinder block has cast iron or aluminium to close mostly at present
Gold casting forms, and aluminium alloy is in light weight, cooling performance is good, obtains more and more extensive application, but Aluminum Alloy Cylinder Barrel
Production cost it is higher.
The content of the invention
The defects of in order to make up prior art, it is an object of the invention to provide a kind of alloy material for IC engine cylinder block
Material.
A kind of alloy material for IC engine cylinder block, consist of the following components in percentage by weight:Silicon 6 ~ 7%, graphite
Alkene 6 ~ 7%, boron modified phenolic resin 3.4 ~ 3.6%, nickel 2.1 ~ 2.3%, magnesium 1.7 ~ 1.9%, chromium 1.4 ~ 1.6%, manganese 1.2 ~ 1.4%, niobium
0.7 ~ 0.9%, rhenium 0.7 ~ 0.9%, scandium 0.5 ~ 0.7%, remaining is iron and inevitable impurity.
A kind of preparation method of alloy material for IC engine cylinder block, comprises the following steps:
(1)Iron is added in melting furnace, 1400 ~ 1600 DEG C is heated to, insulation melting 40 ~ 50 minutes, obtains molten iron;
(2)Nickel, magnesium, chromium, manganese, niobium, rhenium and scandium are added in molten iron, stirred, 30 ~ 40 points are incubated in 1200 ~ 1400 DEG C
Clock, raw material is sufficiently mixed the stability for uniformly, improving iron, hardness and cooling performance, 900 are cooled to 1.4 ~ 2.2 DEG C/min
~ 1000 DEG C, 50 ~ 60 minutes are incubated, then room temperature is down to 2.3 ~ 2.7 DEG C/min, gradually cooling annealing, improves intensity and hardness,
Obtain a cooling thing;
(3)Silicon and graphene are added in a fused mass, 1.8 ~ 2.2 DEG C/min are heated to 1000 ~ 1200 DEG C, stir,
Insulation 20 ~ 30 minutes, 800 ~ 900 DEG C are cooled to, eliminate caused efficacy and structural stress during metal phase change, improve gas
Weatherability during cylinder body use, the low temperature and high temperature for avoiding cataclysm produce injury to cylinder block, improve the wear-resisting of cylinder block
Property, extend the service life of cylinder block, add boron modified phenolic resin, stir, be incubated 3 ~ 4 hours, improve cylinder block
Intensity, reduce brittleness, improve the ability to bear of cylinder block, obtain mixed melting thing;
(4)Mixed melting thing is injected in mould and cast, is stripped after cooling, obtains casting;
(5)Casting is heated to 400 ~ 500 DEG C, 20 ~ 30 minutes is incubated, is placed in sodium bicarbonate solution and is quenched, improves and closes
The stability of golden material, avoid corroding, extend the service life of cylinder block, obtain the alloy material for IC engine cylinder block.
The step(1)Heating, programming rate be 2.1 ~ 2.3 DEG C/min.
The step(4)Cooling, cooling rate be 0.6 ~ 0.8 DEG C/min.
The step(5)Heating, programming rate be 3.2 ~ 3.6 DEG C/min.
The step(5)Sodium bicarbonate solution, mass concentration is that 1.2 ~ 1.4%, temperature is 10 ~ 15 DEG C.
It is an advantage of the invention that:Provided by the present invention for the alloy material of IC engine cylinder block, added in raw material a variety of
Metal and nonmetallic ingredient, IC engine cylinder block is set to reduce 33 ~ 35% compared with the weight of traditional cast iron cylinder block, cost is compared with conventional aluminum
Alloy cylinder block reduces 26 ~ 28%;Iron is slowly heated up nickel is added after melting, magnesium, chromium, manganese, niobium, rhenium and scandium carry out insulation melting,
Raw material is set to be sufficiently mixed the stability for uniformly, improving iron, hardness and cooling performance;Gradually cooling annealing, obtains a cooling thing,
Improve intensity and hardness;Carry out second melting after adding silicon and graphene, eliminate during metal phase change caused efficacy and
Structural stress, the weatherability during cylinder block use is improved, the low temperature and high temperature for avoiding cataclysm produce injury to cylinder block, add
The silicon and graphene that enter can improve the wearability of cylinder block, the service life of cylinder block is extended 20 ~ 22%;Add boron modification
Insulation when carrying out long after phenolic resin, improve the intensity of cylinder block, reduce brittleness, improve the ability to bear of cylinder block;After casting
The gradually cooling demoulding, then quickly heat after being quenched in sodium bicarbonate solution, the stability of alloy material is improved, avoids corruption
Erosion, extend the service life of cylinder block.
Embodiment
Illustrate the present invention with specific embodiment below.
Embodiment 1
A kind of alloy material for IC engine cylinder block, consist of the following components in percentage by weight:Silicon 6%, graphene 6%,
Boron modified phenolic resin 3.4%, nickel 2.1%, magnesium 1.7%, chromium 1.4%, manganese 1.2%, niobium 0.7%, rhenium 0.7%, scandium 0.5%, remaining is iron
With inevitable impurity.
A kind of preparation method of alloy material for IC engine cylinder block, comprises the following steps:
(1)Iron is added in melting furnace, is heated to 1400 DEG C, programming rate is 2.1 DEG C/min, insulation melting 40 minutes, is obtained molten
Melt iron;
(2)Nickel, magnesium, chromium, manganese, niobium, rhenium and scandium are added in molten iron, stirred, 30 minutes is incubated in 1200 DEG C, makes raw material
The stability, hardness and cooling performance for uniformly, improving iron are sufficiently mixed, 900 DEG C is cooled to 1.4 DEG C/min, is incubated 50 points
Clock, then room temperature is down to 2.3 DEG C/min, gradually cooling annealing, intensity and hardness are improved, obtains a cooling thing;
(3)Silicon and graphene are added in a fused mass, 1.8 DEG C/min are heated to 1000 DEG C, stir, and are incubated 20 points
Clock, 800 DEG C are cooled to, caused efficacy and structural stress during metal phase change are eliminated, during raising cylinder block use
Weatherability, avoid cataclysm low temperature and high temperature to cylinder block produce injury, improve the wearability of cylinder block, extend cylinder block
Service life, boron modified phenolic resin is added, is stirred, be incubated 3 hours, improved the intensity of cylinder block, reduce brittleness, improve
The ability to bear of cylinder block, obtain mixed melting thing;
(4)Mixed melting thing is injected in mould and cast, cooling rate is 0.6 DEG C/min, is stripped after cooling, obtains casting;
(5)Casting is heated to 400 DEG C, programming rate is 3.2 DEG C/min, is incubated 20 minutes, is placed in sodium bicarbonate solution
Row quenching, mass concentration 1.2%, temperature are 10 DEG C, improve the stability of alloy material, avoid corroding, and extend making for cylinder block
With the life-span, the alloy material for IC engine cylinder block is obtained.
Embodiment 2
A kind of alloy material for IC engine cylinder block, consist of the following components in percentage by weight:Silicon 6.5%, graphene
6.5%th, boron modified phenolic resin 3.5%, nickel 2.2%, magnesium 1.8%, chromium 1.5%, manganese 1.3%, niobium 0.8%, rhenium 0.8%, scandium 0.6%, remaining
For iron and inevitable impurity.
A kind of preparation method of alloy material for IC engine cylinder block, comprises the following steps:
(1)Iron is added in melting furnace, is heated to 1500 DEG C, programming rate is 2.2 DEG C/min, insulation melting 45 minutes, is obtained molten
Melt iron;
(2)Nickel, magnesium, chromium, manganese, niobium, rhenium and scandium are added in molten iron, stirred, 35 minutes is incubated in 1300 DEG C, makes raw material
The stability, hardness and cooling performance for uniformly, improving iron are sufficiently mixed, 950 DEG C is cooled to 1.8 DEG C/min, is incubated 55 points
Clock, then room temperature is down to 2.5 DEG C/min, gradually cooling annealing, intensity and hardness are improved, obtains a cooling thing;
(3)Silicon and graphene are added in a fused mass, 1.9 DEG C/min are heated to 1100 DEG C, stir, and are incubated 25 points
Clock, 850 DEG C are cooled to, caused efficacy and structural stress during metal phase change are eliminated, during raising cylinder block use
Weatherability, avoid cataclysm low temperature and high temperature to cylinder block produce injury, improve the wearability of cylinder block, extend cylinder block
Service life, boron modified phenolic resin is added, is stirred, be incubated 3.5 hours, improved the intensity of cylinder block, reduce brittleness, carry
The ability to bear of high cylinder block, obtain mixed melting thing;
(4)Mixed melting thing is injected in mould and cast, cooling rate is 0.7 DEG C/min, is stripped after cooling, obtains casting;
(5)Casting is heated to 450 DEG C, programming rate is 3.4 DEG C/min, is incubated 25 minutes, is placed in sodium bicarbonate solution
Row quenching, mass concentration 1.3%, temperature are 13 DEG C, improve the stability of alloy material, avoid corroding, and extend making for cylinder block
With the life-span, the alloy material for IC engine cylinder block is obtained.
Embodiment 3
A kind of alloy material for IC engine cylinder block, consist of the following components in percentage by weight:Silicon 7%, graphene 7%,
Boron modified phenolic resin 3.6%, nickel 2.3%, magnesium 1.9%, chromium 1.6%, manganese 1.4%, niobium 0.9%, rhenium 0.9%, scandium 0.7%, remaining is iron
With inevitable impurity.
A kind of preparation method of alloy material for IC engine cylinder block, comprises the following steps:
(1)Iron is added in melting furnace, is heated to 1600 DEG C, programming rate is 2.3 DEG C/min, insulation melting 50 minutes, is obtained molten
Melt iron;
(2)Nickel, magnesium, chromium, manganese, niobium, rhenium and scandium are added in molten iron, stirred, 40 minutes is incubated in 1400 DEG C, makes raw material
The stability, hardness and cooling performance for uniformly, improving iron are sufficiently mixed, 1000 DEG C is cooled to 2.2 DEG C/min, is incubated 60 points
Clock, then room temperature is down to 2.7 DEG C/min, gradually cooling annealing, intensity and hardness are improved, obtains a cooling thing;
(3)Silicon and graphene are added in a fused mass, 2.2 DEG C/min are heated to 1200 DEG C, stir, and are incubated 30 points
Clock, 900 DEG C are cooled to, caused efficacy and structural stress during metal phase change are eliminated, during raising cylinder block use
Weatherability, avoid cataclysm low temperature and high temperature to cylinder block produce injury, improve the wearability of cylinder block, extend cylinder block
Service life, boron modified phenolic resin is added, is stirred, be incubated 3 ~ 4 hours, improved the intensity of cylinder block, reduce brittleness, carry
The ability to bear of high cylinder block, obtain mixed melting thing;
(4)Mixed melting thing is injected in mould and cast, cooling rate is 0.8 DEG C/min, is stripped after cooling, obtains casting;
(5)Casting is heated to 500 DEG C, programming rate is 3.6 DEG C/min, is incubated 30 minutes, is placed in sodium bicarbonate solution
Row quenching, mass concentration 1.4%, temperature are 15 DEG C, improve the stability of alloy material, avoid corroding, and extend making for cylinder block
With the life-span, the alloy material for IC engine cylinder block is obtained.
Comparative example 1
Remove graphene, remaining preparation method, with embodiment 1.
Comparative example 2
Remove boron modified phenolic resin, remaining preparation method, with embodiment 1.
Comparative example 3
Remove rhenium, remaining preparation method, with embodiment 1.
Comparative example 4
Remove scandium, remaining preparation method, with embodiment 1.
Comparative example 5
Step(1)In programming rate be changed to 4.3 DEG C/min, remaining preparation method, with embodiment 1.
Comparative example 6
Step(2)Direct Temperature fall, remaining preparation method, with embodiment 1.
Comparative example 7
Step(3)In with 4.2 DEG C/min heating, remaining preparation method, with embodiment 1.
Comparative example 8
Step(4)In cooling rate be 3.8 DEG C/min, remaining preparation method, with embodiment 1.
Comparative example 9
Removal step(5), remaining preparation method, with embodiment 1.
Comparative example 10
The material of existing traditional cast iron cylinder block.
Comparative example 11
The material of existing traditional Aluminum Alloy Cylinder Barrel.
The performance of embodiment and comparative example block material:
The block material of selection example and comparative example respectively, detect the tensile strength at room temperature, Brinell hardness, elongation of material
The performance of rate and wear rate, embodiment and comparative example block material is shown in Table 1.
Table 1:The performance of embodiment and comparative example block material
Project | At room temperature tensile strength/(Mpa) | Brinell hardness/(HBS) | Elongation/(%) | Wear rate/(g/(mm·N)) |
Embodiment 1 | 494 | 164 | 2.3 | 1.17×10-9 |
Embodiment 2 | 497 | 171 | 2.1 | 1.12×10-9 |
Embodiment 3 | 493 | 162 | 2.5 | 1.19×10-9 |
Comparative example 1 | 449 | 124 | 6.4 | 1.87×10-9 |
Comparative example 2 | 452 | 127 | 6.1 | 1.85×10-9 |
Comparative example 3 | 465 | 134 | 5.7 | 1.73×10-9 |
Comparative example 4 | 461 | 130 | 5.9 | 1.78×10-9 |
Comparative example 5 | 457 | 129 | 6.3 | 1.81×10-9 |
Comparative example 6 | 453 | 128 | 5.5 | 1.82×10-9 |
Comparative example 7 | 455 | 129 | 5.6 | 1.83×10-9 |
Comparative example 8 | 451 | 127 | 5.8 | 1.80×10-9 |
Comparative example 9 | 449 | 125 | 6.4 | 1.87×10-9 |
Comparative example 10 | 454 | 129 | 5.5 | 1.84×10-9 |
Comparative example 11 | 426 | 120 | 7.3 | 1.97×10-9 |
Show from the result of table 1, the alloy material for IC engine cylinder block of embodiment, tensile strength and Bu Shi are hard at room temperature
Degree is substantially high compared with comparative example, and elongation and wear rate are substantially low compared with comparative example, illustrate provided by the present invention for cylinder of internal-combustion engine
The alloy material of body has good performance index.
Claims (6)
1. a kind of alloy material for IC engine cylinder block, it is characterised in that consist of the following components in percentage by weight:Silicon
6 ~ 7%, graphene 6 ~ 7%, boron modified phenolic resin 3.4 ~ 3.6%, nickel 2.1 ~ 2.3%, magnesium 1.7 ~ 1.9%, chromium 1.4 ~ 1.6%, manganese 1.2
~ 1.4%, niobium 0.7 ~ 0.9%, rhenium 0.7 ~ 0.9%, scandium 0.5 ~ 0.7%, remaining is iron and inevitable impurity.
A kind of 2. preparation method for the alloy material for being used for IC engine cylinder block according to claim 1, it is characterised in that bag
Include following steps:
(1)Iron is added in melting furnace, 1400 ~ 1600 DEG C is heated to, insulation melting 40 ~ 50 minutes, obtains molten iron;
(2)Nickel, magnesium, chromium, manganese, niobium, rhenium and scandium are added in molten iron, stirred, 30 ~ 40 points are incubated in 1200 ~ 1400 DEG C
Clocks, 900 ~ 1000 DEG C are cooled to 1.4 ~ 2.2 DEG C/min, is incubated 50 ~ 60 minutes, then room temperature is down to 2.3 ~ 2.7 DEG C/min,
Obtain a cooling thing;
(3)Silicon and graphene are added in a fused mass, 1.8 ~ 2.2 DEG C/min are heated to 1000 ~ 1200 DEG C, stir,
Insulation 20 ~ 30 minutes, 800 ~ 900 DEG C are cooled to, add boron modified phenolic resin, stir, be incubated 3 ~ 4 hours, must mix
Fused mass;
(4)Mixed melting thing is injected in mould and cast, is stripped after cooling, obtains casting;
(5)Casting is heated to 400 ~ 500 DEG C, 20 ~ 30 minutes is incubated, is placed in sodium bicarbonate solution and is quenched, must be used for
The alloy material of IC engine cylinder block.
3. it is used for the preparation method of the alloy material of IC engine cylinder block according to claim 2, it is characterised in that the step
Suddenly(1)Heating, programming rate be 2.1 ~ 2.3 DEG C/min.
4. it is used for the preparation method of the alloy material of IC engine cylinder block according to claim 2, it is characterised in that the step
Suddenly(4)Cooling, cooling rate be 0.6 ~ 0.8 DEG C/min.
5. it is used for the preparation method of the alloy material of IC engine cylinder block according to claim 2, it is characterised in that the step
Suddenly(5)Heating, programming rate be 3.2 ~ 3.6 DEG C/min.
6. it is used for the preparation method of the alloy material of IC engine cylinder block according to claim 2, it is characterised in that the step
Suddenly(5)Sodium bicarbonate solution, mass concentration is that 1.2 ~ 1.4%, temperature is 10 ~ 15 DEG C.
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Cited By (1)
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CN109881098A (en) * | 2019-03-18 | 2019-06-14 | 刘闪闪 | A kind of anti-corrosive alloy material for food processing machinery |
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CN1176315A (en) * | 1996-07-25 | 1998-03-18 | Ae格策有限公司 | Iron casting alloy for producing piston ring of internal-combustion engine |
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---|---|---|---|---|
CN109881098A (en) * | 2019-03-18 | 2019-06-14 | 刘闪闪 | A kind of anti-corrosive alloy material for food processing machinery |
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Application publication date: 20171215 |