CN107474697A - A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint - Google Patents
A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint Download PDFInfo
- Publication number
- CN107474697A CN107474697A CN201710847433.4A CN201710847433A CN107474697A CN 107474697 A CN107474697 A CN 107474697A CN 201710847433 A CN201710847433 A CN 201710847433A CN 107474697 A CN107474697 A CN 107474697A
- Authority
- CN
- China
- Prior art keywords
- powder
- conducting paint
- parts
- corrosion
- wear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003973 paint Substances 0.000 title claims abstract description 38
- 230000007797 corrosion Effects 0.000 title claims abstract description 26
- 238000005260 corrosion Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 37
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 32
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 30
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003822 epoxy resin Substances 0.000 claims abstract description 26
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 26
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000006004 Quartz sand Substances 0.000 claims abstract description 19
- 239000012046 mixed solvent Substances 0.000 claims abstract description 17
- 229920002050 silicone resin Polymers 0.000 claims abstract description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 8
- 238000000855 fermentation Methods 0.000 claims description 48
- 230000004151 fermentation Effects 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 47
- 238000002156 mixing Methods 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 10
- 150000004645 aluminates Chemical class 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000011044 quartzite Substances 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000010802 sludge Substances 0.000 claims description 3
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 6
- 244000005700 microbiome Species 0.000 abstract description 6
- 125000003545 alkoxy group Chemical group 0.000 abstract description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 5
- 238000004132 cross linking Methods 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 230000002421 anti-septic effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- 235000013618 yogurt Nutrition 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011231 conductive filler Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- 101000905241 Mus musculus Heart- and neural crest derivatives-expressed protein 1 Proteins 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to electrically-conducting paint technical field, and in particular to a kind of preparation method of wear-and corrosion-resistant electrically-conducting paint.The present invention mixes PFPE, modified organic silicone resin, bisphenol A type epoxy resin and zinc powder, it is blended and ferments with biogas slurry again, modified organic silicone resin is decomposed using microorganism and produces hydroxyl, amino and alkoxy, and hydroxyl, amino and alkoxy are incorporated into epoxy resin surface under the self-crosslinking of microorganism, generate block high polymer, so that final obtained electrically-conducting paint has splendid anti-wear performance, ethyl acetate, hexone and toluene Mixed Solvent, quartz sand powder are added, improves the antiseptic property and anti-wear performance of electrically-conducting paint again.A certain amount of conductive zinc powder, copper powder, talcum powder and strontium chromate are added, the anti-wear performance of electrically-conducting paint is further increased and suppresses the ability of corrosion, there can be extensive prospect of the application.
Description
Technical field
The present invention relates to electrically-conducting paint technical field, and in particular to a kind of preparation method of wear-and corrosion-resistant electrically-conducting paint.
Background technology
Electrically-conducting paint is that conductive filler and auxiliary agent are dispersed in resin by one kind, is formed with certain conductive capability
High polymer material, it is applied to high resistivity material surface, can makes material that there is conduction electric current, eliminate the energy of accumulation electrostatic charge
Power, therefore electrically-conducting paint is except the surfacecti proteon with common coating, attractive in appearance, mark etc. are in addition to basic function, also with part conductor
Property.Electrically-conducting paint has good electric conductivity, mechanical property, and high praise that is simple and easy and enjoying industry, quilt concurrently because of it
It is widely used in numerous technical fields such as chemical industry, printing, electronics, electrical equipment, space flight and aviation.In electrically-conducting paint, doping type
Electrically-conducting paint is especially important a kind of electrically-conducting paint, and it is generally made up of resin, conductive filler, solvent and other auxiliary agents.With
The continuous progress of science and technology, the performance requirement of electrically-conducting paint is also improving constantly.
At present, the abrasion-proof rust-preventing deficiency of electrically-conducting paint has become the major issue for hindering electrically-conducting paint development, urgently
Need to develop the electrically-conducting paint that a kind of abrasion-proof rust-preventing effectively improves, to meet the needs in market.
The content of the invention
The technical problems to be solved by the invention：It is poor poor with anticorrosive property for the wearability of current electrically-conducting paint
A kind of defect, there is provided preparation method of wear-and corrosion-resistant electrically-conducting paint.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint, it is characterised in that specifically preparation process is：
（1）PET and poly- methyl silicon resin are mixed, obtain modified organic silicone resin；
（2）PFPE, polyester modified organic silicon resin, bisphenol A type epoxy resin and zinc powder are mixed again, after stirring
To mixture, continue to add the biogas slurry of mixture quality 0.5% into mixture, be fitted into fermentation tank, be sealed by fermentation, fermentation knot
Shu Hou, tunning is taken out, as make modified bisphenol A type epoxy resin by oneself；
（3）Ethyl acetate, hexone and toluene are mixed, obtain making mixed solvent by oneself；
（4）Continue to weigh the crushing of 30~50g quartzite sand grinds, quartz sand powder is obtained after grinding, by quartz sand powder and Aluminate
ASA is mixed, and obtains mixture 1, continues to add the peanut oil and the mass of mixture 1 of the mass 5% of mixture 1 into mixture 1
0.6% sludge, is fitted into fermentation tank, is sealed by fermentation, and after fermentation ends, takes out tunning, as Modified Quartz Sand powder；
（5）Count in parts by weight, weigh self-control modified bisphenol A type epoxy resin, self-control mixed solvent, water and maleic anhydride respectively
Mix, mixer is placed in after adding carborundum, talcum powder, Modified Quartz Sand powder, strontium chromate, zinc powder and copper powder mixing
Middle mixing, dry discharging, you can wear-and corrosion-resistant electrically-conducting paint is made.
Step（1）Described PET and the mass ratio of poly- methyl silicon resin are 1：6, whipping temp is
150~200 DEG C, mixing time is 8~10min.
Step（2）Described PFPE, polyester modified organic silicon resin, the quality of bisphenol A type epoxy resin and zinc powder
Than for 2：5：7：1；Whipping temp is 30~50 DEG C, and mixing time be 12~15min, and fermentation temperature is 30~45 DEG C, during fermentation
Between be 5~7 days.
Step（3）The mass ratio of described ethyl acetate, hexone and toluene is 1：2：1, mixing time is
30~45min.
Step（4）Described milling time is 8~10min, and quartz sand powder and Aluminate ASA mass ratio are 5：1, stir
It is 10~15min to mix the time, and fermentation temperature is 35~45 DEG C, and fermentation time is 6~8 days.
Step（5）Described meter in parts by weight, weigh respectively 30~50 parts of self-control modified bisphenol A type epoxy resin, 8~
10 parts self-control mixed solvents, 10~12 parts of water, 1~3 part of maleic anhydride, 3~5 parts of carborundum, 4~6 parts of talcum powder, 1~3 part change
Property quartz sand powder, 2~4 parts of strontium chromates, 3~5 parts of zinc powders and 1~3 part of copper powder, mixing time are 10~30min, whipping temp
For 15~35 DEG C, mixing time is 1~3h.
Compared with other method, advantageous effects are the present invention：
The present invention carries out chemical modification to bisphenol A type epoxy resin with organic siliconresin, and organic siliconresin has good in itself
Low temperature flexibility and wearability, with its modified epoxy can improve toughness, wearability and reduce internal stress, by PFPE,
Modified organic silicone resin, bisphenol A type epoxy resin and zinc powder mixing, then be blended and ferment with biogas slurry, modification is had using microorganism
Machine silicones, which decomposes, produces hydroxyl, amino and alkoxy, and by hydroxyl, amino and alkoxy under the self-crosslinking of microorganism
Epoxy resin surface is incorporated into, the hydroxyl, amino and alkoxy in its modified organic silicone resin enter with the hydroxyl in epoxy resin
Row condensation reaction, block high polymer is generated, the resistance to of epoxy resin-base is improved using the anti-wear property of modified organic silicone resin
Mill property so that final obtained electrically-conducting paint has splendid anti-wear performance, add ethyl acetate, hexone and
Toluene Mixed Solvent, wherein ketones solvent have high fluidity and excellent chemical stability, improve mixed solvent and resin
Compatibility, quartz sand powder contains abundant silica, using aluminate coupling agent to quartz sand powder modification, by itself and
Vegetable oil and sludge microbe blending fermentation, lipophile ester group is produced using microorganism by plant oil decomposition, and in microorganism
Self-crosslinking under cause ester group be grafted to part resin surface, enhance the compatibility of quartz sand and high polymer, carry again
The antiseptic property and anti-wear performance of highly conductive coating, a certain amount of conductive zinc powder and copper powder are added, the surface of coating film can be made
Resistance substantially reduces, and so as to have certain conductive capability, continuously adds talcum powder and strontium chromate, further increases conductive painting
The anti-wear performance of material and the ability for suppressing corrosion, can there is extensive prospect of the application.
Embodiment
It is 1 in mass ratio：6 mix PET and poly- methyl silicon resin at 150~200 DEG C
8~10min, modified organic silicone resin is obtained, then be 2 in mass ratio：5：7：1 by PFPE, polyester modified organic silicon resin,
Bisphenol A type epoxy resin and zinc powder mix 12~15min at 30~50 DEG C, and mixture is obtained after stirring, continue to mixed
The biogas slurry of mixture quality 0.5% is added in compound, is fitted into fermentation tank, 5 are sealed by fermentation under conditions of being 30~45 DEG C in temperature
~7 days, after fermentation ends, tunning is taken out, modified bisphenol A type epoxy resin is as made by oneself, is in mass ratio 1：2：1 by vinegar
Acetoacetic ester, hexone and toluene mix 30~45min, obtain making mixed solvent by oneself, continue to weigh 30~50g
Quartzite sand grind crushes 8~10min, and quartz sand powder is obtained after grinding, is in mass ratio 5：1 by quartz sand powder and Aluminate
ASA mixes 10~15min, obtains mixture 1, continues to add the sunflower oil of the mass 5% of mixture 1 into mixture 1 and mixes
The Yoghourt of the mass 0.6% of compound 1, is fitted into fermentation tank, is sealed by fermentation 6~8 days under the conditions of being 35~45 DEG C in temperature, fermentation knot
Shu Hou, tunning, as Modified Quartz Sand powder are taken out, is counted in parts by weight, it is modified double to weigh 30~50 parts of self-controls respectively
Phenol A types epoxy resin, 8~10 parts of self-control mixed solvents, 10~12 parts of water and 1~3 part of maleic anhydride mixing 10~
30min, add 3~5 parts of carborundum, 4~6 parts of talcum powder, 1~3 part of Modified Quartz Sand powder, 2~4 parts of strontium chromates, 3~5
It is placed in after part zinc powder and 1~3 part of copper powder mixing in mixer, 1~3h is mixed at 15~35 DEG C, dries discharging, you can
Wear-and corrosion-resistant electrically-conducting paint is made.
Example 1
It is 1 in mass ratio：PET and poly- methyl silicon resin are mixed 8min by 6 at 150 DEG C, are obtained
Modified organic silicone resin, then be 2 in mass ratio：5：7：1 by PFPE, polyester modified organic silicon resin, bisphenol type epoxy tree
Fat and zinc powder mix 12min at 30 DEG C, and mixture is obtained after stirring, continue to add mixture quality into mixture
0.5% biogas slurry, is fitted into fermentation tank, is sealed by fermentation 5 days under conditions of being 30 DEG C in temperature, after fermentation ends, takes out fermentation production
Thing, as make modified bisphenol A type epoxy resin by oneself, be in mass ratio 1：2：1 by ethyl acetate, hexone and toluene
30min is mixed, obtains making mixed solvent by oneself, continues to weigh 30g quartzite sand grinds crushing 8min, quartz sand powder is obtained after grinding
End, it is in mass ratio 5：Quartz sand powder and Aluminate ASA are mixed 10min by 1, are obtained mixture 1, are continued to mixture
The sunflower oil of the mass 5% of mixture 1 and the Yoghourt of the mass 0.6% of mixture 1 are added in 1, is fitted into fermentation tank, is 35 DEG C in temperature
Under the conditions of be sealed by fermentation 6 days, after fermentation ends, take out tunning, as Modified Quartz Sand powder is counted in parts by weight, point
30 parts of self-control modified bisphenol A type epoxy resin, 8 parts of self-control mixed solvents, 10 parts of water and 1 part of maleic anhydride is also known as taken to mix
10min, add 3 parts of carborundum, 4 parts of talcum powder, 1 part of Modified Quartz Sand powder, 2 parts of strontium chromates, 3 parts of zinc powders and 1 part of copper powder
It is placed in after mixing in mixer, 1h is mixed at 15 DEG C, dry discharging, you can wear-and corrosion-resistant electrically-conducting paint is made.
Example 2
It is 1 in mass ratio：PET and poly- methyl silicon resin are mixed 9min by 6 at 175 DEG C, are obtained
Modified organic silicone resin, then be 2 in mass ratio：5：7：1 by PFPE, polyester modified organic silicon resin, bisphenol type epoxy tree
Fat and zinc powder mix 14min at 45 DEG C, and mixture is obtained after stirring, continue to add mixture quality into mixture
0.5% biogas slurry, is fitted into fermentation tank, is sealed by fermentation 6 days under conditions of being 40 DEG C in temperature, after fermentation ends, takes out fermentation production
Thing, as make modified bisphenol A type epoxy resin by oneself, be in mass ratio 1：2：1 by ethyl acetate, hexone and toluene
40min is mixed, obtains making mixed solvent by oneself, continues to weigh 40g quartzite sand grinds crushing 9min, quartz sand powder is obtained after grinding
End, it is in mass ratio 5：Quartz sand powder and Aluminate ASA are mixed 14min by 1, are obtained mixture 1, are continued to mixture
The sunflower oil of the mass 5% of mixture 1 and the Yoghourt of the mass 0.6% of mixture 1 are added in 1, is fitted into fermentation tank, is 40 DEG C in temperature
Under the conditions of be sealed by fermentation 7 days, after fermentation ends, take out tunning, as Modified Quartz Sand powder is counted in parts by weight, point
40 parts of self-control modified bisphenol A type epoxy resin, 9 parts of self-control mixed solvents, 11 parts of water and 2 parts of maleic anhydrides are also known as taken to mix
20min, add 4 parts of carborundum, 5 parts of talcum powder, 2 parts of Modified Quartz Sand powder, 3 parts of strontium chromates, 4 parts of zinc powders and 2 parts of copper powders
It is placed in after mixing in mixer, 2h is mixed at 25 DEG C, dry discharging, you can wear-and corrosion-resistant electrically-conducting paint is made.
Example 3
It is 1 in mass ratio：PET and poly- methyl silicon resin are mixed 10min by 6 at 200 DEG C, are obtained
To modified organic silicone resin, then it is 2 in mass ratio：5：7：1 by PFPE, polyester modified organic silicon resin, bisphenol type epoxy
Resin and zinc powder mix 15min at 50 DEG C, and mixture is obtained after stirring, continue to add mixture quality into mixture
0.5% biogas slurry, is fitted into fermentation tank, is sealed by fermentation 7 days under conditions of being 45 DEG C in temperature, after fermentation ends, takes out fermentation production
Thing, as make modified bisphenol A type epoxy resin by oneself, be in mass ratio 1：2：1 by ethyl acetate, hexone and toluene
45min is mixed, obtains making mixed solvent by oneself, continues to weigh 50g quartzite sand grinds crushing 10min, quartz sand is obtained after grinding
Powder, it is in mass ratio 5：Quartz sand powder and Aluminate ASA are mixed 15min by 1, are obtained mixture 1, are continued to mixing
The sunflower oil of the mass 5% of mixture 1 and the Yoghourt of the mass 0.6% of mixture 1 are added in thing 1, is fitted into fermentation tank, is 45 in temperature
It is sealed by fermentation 8 days under the conditions of DEG C, after fermentation ends, takes out tunning, as Modified Quartz Sand powder, count in parts by weight,
50 parts of self-control modified bisphenol A type epoxy resin, 10 parts of self-control mixed solvents, 12 parts of water and 3 parts of maleic anhydride mixing are weighed respectively
30min is stirred, adds 5 parts of carborundum, 6 parts of talcum powder, 3 parts of Modified Quartz Sand powder, 4 parts of strontium chromates, 5 parts of zinc powders and 3 parts
It is placed in after copper powder mixing in mixer, 3h is mixed at 35 DEG C, dry discharging, you can wear-and corrosion-resistant electrically-conducting paint is made.
The electrically-conducting paint that comparative example is produced with Dongguan City company is as a comparison case to wear-and corrosion-resistant produced by the present invention
Property electrically-conducting paint and comparative example in wear-and corrosion-resistant material carry out performance detection, testing result is as shown in table 1：1st, test side
Method
Relative wear is detected with reference to GB/T 1768-2006 regulation.
Relatively corrosive property test is carried out in Neutral Salt Spray Corrosion, 96h environment, and salt spray test condition is according to reference to GB/T
10125 settings, relatively corrosive property are detected with reference to GB/T 1771 regulation.
Table 1
| Test event | Example 1 | Example 2 | Example 3 | Comparative example |
| Relative wear（%） | 22 | 20 | 18 | 25 |
| With respect to corrosion resistance（%） | 16 | 15 | 12 | 18 |
It can be seen from data in table 1, the relative wear of electrically-conducting paint produced by the present invention is low, and wearability is good, and relatively resistance to
Corrosion is low, and corrosion resistance is good, has wide prospect of the application.
Claims (6)
1. a kind of preparation method of wear-and corrosion-resistant electrically-conducting paint, it is characterised in that specifically preparation process is：
（1）PET and poly- methyl silicon resin are mixed, obtain modified organic silicone resin；
（2）PFPE, polyester modified organic silicon resin, bisphenol A type epoxy resin and zinc powder are mixed again, after stirring
To mixture, continue to add the biogas slurry of mixture quality 0.5% into mixture, be fitted into fermentation tank, be sealed by fermentation, fermentation knot
Shu Hou, tunning is taken out, as make modified bisphenol A type epoxy resin by oneself；
（3）Ethyl acetate, hexone and toluene are mixed, obtain making mixed solvent by oneself；
（4）Continue to weigh the crushing of 30~50g quartzite sand grinds, quartz sand powder is obtained after grinding, by quartz sand powder and Aluminate
ASA is mixed, and obtains mixture 1, continues to add the peanut oil and the mass of mixture 1 of the mass 5% of mixture 1 into mixture 1
0.6% sludge, is fitted into fermentation tank, is sealed by fermentation, and after fermentation ends, takes out tunning, as Modified Quartz Sand powder；
（5）Count in parts by weight, weigh self-control modified bisphenol A type epoxy resin, self-control mixed solvent, water and maleic anhydride respectively
Mix, mixer is placed in after adding carborundum, talcum powder, Modified Quartz Sand powder, strontium chromate, zinc powder and copper powder mixing
Middle mixing, dry discharging, you can wear-and corrosion-resistant electrically-conducting paint is made.
A kind of 2. preparation method of wear-and corrosion-resistant electrically-conducting paint according to claim 1, it is characterised in that：Step（1）Institute
The PET and the mass ratio of poly- methyl silicon resin stated are 1：6, whipping temp is 150~200 DEG C, during stirring
Between be 8~10min.
A kind of 3. preparation method of wear-and corrosion-resistant electrically-conducting paint according to claim 1, it is characterised in that：Step（2）Institute
The mass ratio of PFPE, polyester modified organic silicon resin, bisphenol A type epoxy resin and the zinc powder stated is 2：5：7：1；Stirring temperature
Spend for 30~50 DEG C, mixing time is 12~15min, and fermentation temperature is 30~45 DEG C, and fermentation time is 5~7 days.
A kind of 4. preparation method of wear-and corrosion-resistant electrically-conducting paint according to claim 1, it is characterised in that：Step（3）Institute
The mass ratio of ethyl acetate, hexone and the toluene stated is 1：2：1, mixing time is 30~45min.
A kind of 5. preparation method of wear-and corrosion-resistant electrically-conducting paint according to claim 1, it is characterised in that：Step（4）Institute
The milling time stated is 8~10min, and quartz sand powder and Aluminate ASA mass ratio are 5：1, mixing time be 10~
15min, fermentation temperature are 35~45 DEG C, and fermentation time is 6~8 days.
A kind of 6. preparation method of wear-and corrosion-resistant electrically-conducting paint according to claim 1, it is characterised in that：Step（5）Institute
The meter in parts by weight stated, weigh respectively 30~50 parts of self-control modified bisphenol A type epoxy resin, 8~10 parts of self-control mixed solvents,
10~12 parts of water, 1~3 part of maleic anhydride, 3~5 parts of carborundum, 4~6 parts of talcum powder, 1~3 part of Modified Quartz Sand powder, 2~4
Part strontium chromate, 3~5 parts of zinc powders and 1~3 part of copper powder, mixing time be 10~30min, and whipping temp is 15~35 DEG C, during stirring
Between be 1~3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710847433.4A CN107474697A (en) | 2017-09-19 | 2017-09-19 | A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710847433.4A CN107474697A (en) | 2017-09-19 | 2017-09-19 | A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107474697A true CN107474697A (en) | 2017-12-15 |
Family
ID=60585560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710847433.4A Pending CN107474697A (en) | 2017-09-19 | 2017-09-19 | A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107474697A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108465809A (en) * | 2018-04-22 | 2018-08-31 | 唐林元 | A kind of preparation method of the special zinc flake of anticorrosive paint |
| CN109181934A (en) * | 2018-09-30 | 2019-01-11 | 广西秀美壮乡能源环保有限公司 | A kind of Brewing equipment of fen-flavor type white spirit |
| CN109651919A (en) * | 2018-11-05 | 2019-04-19 | 浙江山力得新材料科技有限公司 | A kind of ceramic filler epoxy zinc-rich anticorrosion coating material and preparation method thereof |
| CN110791356A (en) * | 2019-11-14 | 2020-02-14 | 王思记 | Method for preparing solid lubricating material by using cutting slurry after silicon wafer cutting |
| CN111138971A (en) * | 2019-12-23 | 2020-05-12 | 普施耐（苏州）工业技术有限公司 | Ultraviolet light ultra-fast curing wear-resistant coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194108A (en) * | 2013-04-16 | 2013-07-10 | 广东普赛特电子科技股份有限公司 | Wear-resistant conductive coating paint and preparation method thereof |
-
2017
- 2017-09-19 CN CN201710847433.4A patent/CN107474697A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194108A (en) * | 2013-04-16 | 2013-07-10 | 广东普赛特电子科技股份有限公司 | Wear-resistant conductive coating paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108465809A (en) * | 2018-04-22 | 2018-08-31 | 唐林元 | A kind of preparation method of the special zinc flake of anticorrosive paint |
| CN109181934A (en) * | 2018-09-30 | 2019-01-11 | 广西秀美壮乡能源环保有限公司 | A kind of Brewing equipment of fen-flavor type white spirit |
| CN109651919A (en) * | 2018-11-05 | 2019-04-19 | 浙江山力得新材料科技有限公司 | A kind of ceramic filler epoxy zinc-rich anticorrosion coating material and preparation method thereof |
| CN110791356A (en) * | 2019-11-14 | 2020-02-14 | 王思记 | Method for preparing solid lubricating material by using cutting slurry after silicon wafer cutting |
| CN111138971A (en) * | 2019-12-23 | 2020-05-12 | 普施耐（苏州）工业技术有限公司 | Ultraviolet light ultra-fast curing wear-resistant coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107474697A (en) | A kind of preparation method of wear-and corrosion-resistant electrically-conducting paint | |
| CN110540790B (en) | Water-based epoxy anticorrosive primer for container | |
| CN105713481B (en) | A kind of graphene modified epoxy zinc rich primer and preparation method thereof | |
| CN103319981B (en) | A kind of double-component aqueous epoxy zinc-enriched paint of high-performance easily construction type and preparation method thereof | |
| CN105838195A (en) | Waterborne epoxy anti-corrosion paint containing graphene oxide and preparing method of waterborne epoxy anti-corrosion paint | |
| CN102964936B (en) | Aqueous acrylic acid based anticorrosive static conductive paint and preparation method thereof | |
| CN108997916A (en) | A kind of metal base long-effective corrosion floating coating and preparation method thereof | |
| CN109337503A (en) | A kind of water-base epoxy static electricity conductive anticorrosive paint of containing graphene and preparation method thereof | |
| CN106009799A (en) | Inorganic zinc dust primer containing graphene and preparation method of primer | |
| CN105907240A (en) | Aqueous epoxy anti-corrosion paint containing flash-rust inhibitors and preparation method thereof | |
| CN108359354A (en) | A kind of mechanical equipment anti-corrosion sealing wax and preparation method thereof | |
| CN105801524B (en) | A kind of fluorination bisphenol type glycidol ether and its preparation method and application | |
| CN107541134A (en) | A kind of preparation method of graphite-epoxy alkene zinc powder coating | |
| CN108329793A (en) | A kind of graphene is modified rust resisting pigment anti-corrosion primer and preparation method thereof | |
| CN102336874A (en) | High-performance silicone-acrylate-modified water-based epoxy emulsion and production method thereof | |
| CN108531033A (en) | A kind of dispersion type water-base epoxy zinc alkene band rust antirust heavy antisepsis priming paint | |
| CN106280992A (en) | A kind of water-base epoxy organosilicon Graphene coating | |
| CN104530913A (en) | Environment-friendly solvent-free epoxy ultrathin marking paint and preparing method thereof | |
| CN103525150A (en) | Rust-resistant compound phosphite pigment and production method thereof | |
| CN108795193A (en) | A kind of preparation method of water-and acrylate anticorrosive paint | |
| CN107254234A (en) | A kind of environment-friendly type aqueous canned motor pump paint special and its preparation, application method | |
| CN102234472A (en) | Conductive paint with strong heat-insulating and corrosion-resistant properties and manufacturing process thereof | |
| CN109321126B (en) | Solvent-free heavy-duty anticorrosive paint and preparation method thereof | |
| CN109880488A (en) | A kind of Diamines salicylide Schiff 's base is grapheme modified or graphene oxide metal anti-corrosive paint | |
| CN103805010A (en) | Special anticorrosive coating capable of avoiding rust removal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180420 Address after: 213000 Room 302, unit 101, new machinery village, Zhong Lou District, Changzhou, Jiangsu Applicant after: Xue Xiangdong Address before: 213102 No. 18, No. 600 Tongjiang Middle Road, Xinbei District, Changzhou, Jiangsu 335 Applicant before: Changzhou Connaught composite material Co., Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |