CN107474439A - A kind of special printing opacity mantle of soft-film ceiling - Google Patents
A kind of special printing opacity mantle of soft-film ceiling Download PDFInfo
- Publication number
- CN107474439A CN107474439A CN201710793284.8A CN201710793284A CN107474439A CN 107474439 A CN107474439 A CN 107474439A CN 201710793284 A CN201710793284 A CN 201710793284A CN 107474439 A CN107474439 A CN 107474439A
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- Prior art keywords
- soft
- printing opacity
- mantle
- special printing
- film ceiling
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B9/00—Ceilings; Construction of ceilings, e.g. false ceilings; Ceiling construction with regard to insulation
- E04B9/32—Translucent ceilings, i.e. permitting both the transmission and diffusion of light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of special printing opacity mantle of soft-film ceiling, belong to decorative materials technology.Product of the present invention is first by talcum powder and hydrogenated petroleum resin ball milling mixing, add nano magnesia, butyl rubber, organo-silicic oil, ether and age resistor, it is uniformly mixed obtained premix, after polyvinyl chloride, plasticizer and surfactant heat are mixed again, gained premix is added, continues to be stirred obtained compound, then mixed material heating is plasticated, film forming, produce the special printing opacity mantle of soft-film ceiling.The gained special printing opacity mantle light transmittance of soft-film ceiling of the invention has obtained effective raising, solves the problems, such as that traditional mantle translucency is bad.
Description
Technical field
The invention discloses a kind of special printing opacity mantle of soft-film ceiling, belong to decorative materials technology.
Background technology
Soft-film ceiling is a kind of house decorative material being widely used in recent years.Soft-film ceiling mainly have mantle, button edge strip,
Keel three parts form;(1)Mantle.It is made of special pvc material, without cadmium, its fire rating is B1 levels, is led to
One or many cutting formings are crossed, and are completed with high-frequency welding, it is will be according in the smallpox shape and size measured on the spot
Manufacture and form in factory.(2)Side profile.It is semi-rigid, extrusion molding, using pvc material, its level of preventing fires
Not Wei B1 levels, it is welded on the edge of smallpox mantle, is buckled in being tensioned mantle on wall code-bar.(3)Hard wall code-bar.Adopt
It is made of pvc material, its fire rating is B1 levels, and another kind is squeezed into using alloy aluminum, and its fire rating is B1
Level.It has various suitable different shape, straight, curved, has plenty of and is reassembled after being cut into suitable angle
Together, and it is fixed in the surrounding of indoor ceiling, with for clasping joint smallpox mantle.
Mantle is completed by one or many cutting formings, and with high-frequency welding.Mantle needs measuring on the spot smallpox
After size, completed in factory.The stability of mantle size is in Celsius -15 degree to 45 degree.Light-transmissive film smallpox can coordinate respectively
Kind lighting system(Such as neon light, fluorescent lamp, LED)Build indoor light effect fantasy, without shadow.Glass is abandoned simultaneously
Or the heaviness of lucite, the shortcomings that dangerous and fritter assembly, progressively turn into new decoration bright spot.
Soft-film ceiling can coordinate as a kind of new material that instead of traditional suspended ceiling and metope, this flexible material
The advanced artistic conception of designer produces a variety of planes and the design effect of three-dimensional shape.It thoroughly breaches traditional smallpox and made
The assembled limitation of type, color and fritter, public place of entertainment is widely applied to, club, stadiums, office, hospital, has been learned
School, large-scale sales field, household, the place such as music hall and hall, just progressively as the preferred day flower prod of interior decoration.But pass
Unite mantle there is also translucency it is bad the problem of, have impact on the final effect of soft-film ceiling.Therefore, it is also desirable to mantle is entered to advance
One step research.
The content of the invention
The present invention solves the technical problem of:For traditional soft-film ceiling mantle translucency it is bad the problem of, carry
A kind of special printing opacity mantle of soft-film ceiling is supplied.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of special printing opacity mantle of soft-film ceiling, is made up of the raw material of following parts by weight:80~100 parts of polyvinyl chloride trees
Fat, 2~4 parts of talcum powder, 1~3 part of nano magnesia, 8~10 parts of Petropols, 8~10 parts of butyl rubbers, 2~4 parts of plasticising
Agent, 0.2~0.6 part of organo-silicic oil, 0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor;
The special specific preparation process of printing opacity mantle of soft-film ceiling is:
(1)Each raw material is weighed by raw material composition;
(2)By talcum powder and Petropols ball milling mixing, ball milling material is obtained, then gained ball milling material is stirred with nano magnesia
After 10~15min, sequentially add butyl rubber, organo-silicic oil, ether and age resistor, continue constant temperature be stirred 45~
60min, obtain premix;
(3)By Corvic, plasticizer and surfactant, heat mixed 10 under the conditions of being 110~120 DEG C in temperature~
15min, 60~65 DEG C are cooled to, add above-mentioned gained premix, continue 10~15min of mixing, obtain compound;
(4)Plasticated under the conditions of being 150~175 DEG C in temperature by compound, film forming, produce the special printing opacity mantle of soft-film ceiling.
The Petropols can also be hydrogenated petroleum resin.
The plasticizer is any one in dioctyl phthalate, dioctyl adipate or octyl epoxy stearate
Kind.
The organo-silicic oil is appointing in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane
Meaning is a kind of.
The surfactant is that stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.
The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
The beneficial effects of the invention are as follows:
(1)The present invention in mechanical milling process, can make talcum powder first by the talcum powder of layer structure and Petropols ball milling mixing
Fully coated by Petropols, while talcum powder can be made further to refine, improve its surface-active, improve butyl rubber, organic
The organic matters such as silicone lubricant allow organic matter well to sprawl and are adsorbed in talcum powder table to the wettability of inorganic talcum powder
Face, so as to improve the compatibility of lamellar talc powder and polyvinyl chloride resin matrix, in addition, PVC and butyl rubber are all macromolecular linear junction
Structure, both mutually wind molecular structure in preparation process, can further improve the adhesion between interiors of products component, so as to carry
The stability in use of high product, product light transmittance is set well to be kept in use;
(2)The present invention by adding a small amount of nano magnesia in system, the defects of having benefited from nano oxidized magnesium surface structure, make
Nano magnesia has higher activity, after being added in system, can effectively improve macromolecule polyalcohol in system and use
Heat endurance and photostability in journey, product service life is improved, in addition, the addition of nano magnesia can also adsorb big point
Gaseous matter caused by sub- organic matter decomposition, is secured in system, avoids the pollution to environment;
(3)Technical solution of the present invention makes system transparency further be lifted, so as to enter one by using hydrogenated petroleum resin
Step improves overall light transmittance.
Embodiment
Count in parts by weight, take 80~100 parts of Corvics successively, 2~4 parts of talcum powder, 1~3 part nano oxidized
Magnesium, 8~10 parts of hydrogenated petroleum resins, 8~10 parts of butyl rubbers, 2~4 parts of plasticizer, 0.2~0.6 part of organo-silicic oil,
0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor, first talcum powder and hydrogenated petroleum resin are added in ball grinder, pressed
Ball material mass ratio is 15:1~25:1 adds zirconium oxide ball milling pearl, and 3~5h of ball milling mixing obtains ball milling material, then by gained ball milling material
Poured into nano magnesia in three-necked flask, be stirred 10~15min with glass bar, then fourth is sequentially added into three-necked flask
Base rubber, organo-silicic oil, ether and age resistor, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, Yu Wen
Spend for 60~65 DEG C, under the conditions of rotating speed is 400~600r/min, constant temperature is stirred 45~60min, obtains premix, then will be poly-
Vinyl chloride resin, plasticizer and surfactant add batch mixer, are 110~120 DEG C in temperature, rotating speed is 200~300r/
Under the conditions of min, the mixed 10~15min of heat, 60~65 DEG C are cooled to, then gained premix is added into batch mixer, continue to stir
10~15min is mixed, obtains compound, and gained compound is transferred to double rod plasticators, under the conditions of temperature is 150~175 DEG C
Plasticate 10~20min, then through film forming, it is 1.8~2.2mm to control thickness, is cooled to room temperature, produces the special printing opacity of soft-film ceiling
Mantle.:The plasticizer is any one in dioctyl phthalate, dioctyl adipate or octyl epoxy stearate.
The organo-silicic oil is any one in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane.
The surfactant is that stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.The age resistor
It is 1 in mass ratio for age resistor 288, anti-aging agent RD and microwax:1:1 compounding forms.
Example 1
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of non-hydrogenated petroleums successively
Resin, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first
Talcum powder and hydrogenated petroleum resin are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, and ball milling mixes
5h is closed, obtains ball milling material, then gained ball milling material and nano magnesia are poured into three-necked flask, 15min is stirred with glass bar,
Butyl rubber, organo-silicic oil, ether and age resistor are sequentially added into three-necked flask again, and three-necked flask is moved into digital display
Test the speed constant temperature blender with magnetic force, is 65 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, must premix
Material, then by Corvic, plasticizer and surfactant add batch mixer, in temperature be 120 DEG C, rotating speed 300r/min
Under the conditions of, the mixed 15min of heat, 65 DEG C are cooled to, then gained premix is added into batch mixer, continue to be stirred 15min, obtain
Compound, and gained compound is transferred to double rod plasticators, plasticate 20min under the conditions of being 175 DEG C in temperature, then through film forming, control
Film thickness is 2.2mm, is cooled to room temperature, produces the special printing opacity mantle of soft-film ceiling.:The plasticizer is phthalic acid two
Monooctyl ester.The organo-silicic oil is phenyl trichlorosilane.The surfactant is stearic acid and neopelex
It is 1 in mass ratio:3 compoundings form.The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 is multiple
With into.
Example 2
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of non-hydrogenated petroleums successively
Resin, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.3 part of surfactant, 0.4 part of age resistor, first by talcum powder and non-hydrogenated petroleum
Resin is added in ball grinder, is 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains ball milling material, then will
Gained ball milling material and nano magnesia are poured into three-necked flask, and 15min is stirred with glass bar, then into three-necked flask successively
Add butyl rubber, ether and age resistor, and three-necked flask immigration digital display tested the speed constant temperature blender with magnetic force, in temperature be 65
DEG C, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, obtains premix, then by Corvic, plasticizer and
Surfactant adds batch mixer, is 120 DEG C in temperature, under the conditions of rotating speed is 300r/min, the mixed 15min of heat, is cooled to 65
DEG C, then gained premix is added into batch mixer, continue to be stirred 15min, obtain compound, and gained compound is transferred to double
Rod plasticator, plasticated 20min under the conditions of being 175 DEG C in temperature, then through film forming, it is 2.2mm to control thickness, is cooled to room temperature,
Produce the special printing opacity mantle of soft-film ceiling.:The plasticizer is dioctyl phthalate.The surfactant is stearic acid
It is 1 in mass ratio with neopelex:3 compoundings form.The age resistor is age resistor 288, anti-aging agent RD and crystallite
Wax is 1 in mass ratio:1:1 compounding forms.
Example 3
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 10 parts of hydrogenated petroleum resins, 10 parts of butyl successively
Rubber, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first by talcum powder and hydrogenation
Petropols are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains ball milling material,
Gained ball milling material is poured into three-necked flask again, then butyl rubber, organo-silicic oil, ether are sequentially added into three-necked flask
And age resistor, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, it is 65 DEG C in temperature, rotating speed is 600r/min bars
Under part, constant temperature is stirred 60min, obtains premix, then Corvic, plasticizer and surfactant are added into batch mixing
Machine, it is 120 DEG C in temperature, under the conditions of rotating speed is 300r/min, the mixed 15min of heat, is cooled to 65 DEG C, then add into batch mixer
Gained premix, continue to be stirred 15min, obtain compound, and gained compound is transferred to double rod plasticators, be in temperature
Plasticate 20min under the conditions of 175 DEG C, then through film forming, it is 2.2mm to control thickness, is cooled to room temperature, it is special to produce soft-film ceiling
Light mantle.:The plasticizer is dioctyl phthalate.The organo-silicic oil is phenyl trichlorosilane.The surface
Activating agent is that stearic acid and neopelex are 1 in mass ratio:3 compoundings form.The age resistor be age resistor 288,
Anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
Example 4
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of oil trees successively
Fat, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first will
Talcum powder and Petropols are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains
Ball milling material, then gained ball milling material and nano magnesia are poured into three-necked flask, 15min is stirred with glass bar, then to three
Sequentially add butyl rubber, organo-silicic oil, ether and age resistor in mouthful flask, and three-necked flask immigration digital display is tested the speed perseverance
Warm magnetic stirring apparatus, it is 65 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, obtains premix, then
Corvic, plasticizer and surfactant are added into batch mixer, are 120 DEG C in temperature, rotating speed is 300r/min conditions
Under, the mixed 15min of heat, 65 DEG C are cooled to, then gained premix is added into batch mixer, continue to be stirred 15min, must mix
Material, and gained compound is transferred to double rod plasticators, plasticate 20min under the conditions of being 175 DEG C in temperature, then through film forming, controls film
Thickness is 2.2mm, is cooled to room temperature, produces the special printing opacity mantle of soft-film ceiling.:The plasticizer is that phthalic acid two is pungent
Ester.The organo-silicic oil is phenyl trichlorosilane.The surfactant is that stearic acid and neopelex are pressed
Mass ratio is 1:3 compoundings form.The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding
Form.
Comparative example:The mantle of Wuxi soft-film ceiling company production.
The gained of example 1 to 4 mantle and comparative example product are subjected to performance detection, specific detection method is as follows:
It is as shown in table 1 with the transmitance of 724 type spectrophotometer measurement mantle light in visible light wave range, specific testing result:
Table 1
Detection content | Example 1 | Example 2 | Example 3 | Example 4 | Comparative example |
Transmitance/% | 80 | 60 | 62 | 73 | 58 |
From the testing result of table 1, the present invention gained special printing opacity mantle light transmittance of soft-film ceiling has obtained effective raising, solves
The problem of traditional mantle translucency of having determined is bad.
Claims (6)
- A kind of 1. special printing opacity mantle of soft-film ceiling, it is characterised in that:It is made up of the raw material of following parts by weight:80~100 Part Corvic, 2~4 parts of talcum powder, 1~3 part of nano magnesia, 8~10 parts of Petropols, 8~10 parts of butyl rubbers, 2~4 parts of plasticizer, 0.2~0.6 part of organo-silicic oil, 0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor;The special specific preparation process of printing opacity mantle of soft-film ceiling is:(1)Each raw material is weighed by raw material composition;(2)By talcum powder and Petropols ball milling mixing, ball milling material is obtained, then gained ball milling material is stirred with nano magnesia After 10~15min, sequentially add butyl rubber, organo-silicic oil, ether and age resistor, continue constant temperature be stirred 45~ 60min, obtain premix;(3)By Corvic, plasticizer and surfactant, heat mixed 10 under the conditions of being 110~120 DEG C in temperature~ 15min, 60~65 DEG C are cooled to, add above-mentioned gained premix, continue 10~15min of mixing, obtain compound;(4)Plasticated under the conditions of being 150~175 DEG C in temperature by compound, film forming, produce the special printing opacity mantle of soft-film ceiling.
- A kind of 2. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The Petropols may be used also Think hydrogenated petroleum resin.
- A kind of 3. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The plasticizer is adjacent benzene Any one in diformazan dioctyl phthalate, dioctyl adipate or octyl epoxy stearate.
- A kind of 4. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The organo-silicic oil For any one in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane.
- A kind of 5. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The surfactant is Stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.
- A kind of 6. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The age resistor is anti-old Agent 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
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CN201710793284.8A CN107474439A (en) | 2017-09-06 | 2017-09-06 | A kind of special printing opacity mantle of soft-film ceiling |
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CN201710793284.8A CN107474439A (en) | 2017-09-06 | 2017-09-06 | A kind of special printing opacity mantle of soft-film ceiling |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108031306A (en) * | 2017-12-23 | 2018-05-15 | 刘顶康 | A kind of polyvinyl chloride filter membrane with hydrophilic stability |
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CN102719033A (en) * | 2012-06-07 | 2012-10-10 | 浙江海利得新材料股份有限公司 | Ceiling decorative soft film material and production process thereof |
CN102850690A (en) * | 2012-08-02 | 2013-01-02 | 佛山市天安塑料有限公司 | Soft film for decorating ceilings and manufacturing method thereof |
CN103059463A (en) * | 2012-12-25 | 2013-04-24 | 杭州弘泽新材料有限公司 | Ceiling membrane and producing method thereof |
CN104908392A (en) * | 2015-05-12 | 2015-09-16 | 浙江明士达新材料有限公司 | Sparkling high-gloss decoration flexible film |
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2017
- 2017-09-06 CN CN201710793284.8A patent/CN107474439A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102719033A (en) * | 2012-06-07 | 2012-10-10 | 浙江海利得新材料股份有限公司 | Ceiling decorative soft film material and production process thereof |
CN102850690A (en) * | 2012-08-02 | 2013-01-02 | 佛山市天安塑料有限公司 | Soft film for decorating ceilings and manufacturing method thereof |
CN103059463A (en) * | 2012-12-25 | 2013-04-24 | 杭州弘泽新材料有限公司 | Ceiling membrane and producing method thereof |
CN104908392A (en) * | 2015-05-12 | 2015-09-16 | 浙江明士达新材料有限公司 | Sparkling high-gloss decoration flexible film |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108031306A (en) * | 2017-12-23 | 2018-05-15 | 刘顶康 | A kind of polyvinyl chloride filter membrane with hydrophilic stability |
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Application publication date: 20171215 |