CN107474439A - A kind of special printing opacity mantle of soft-film ceiling - Google Patents

A kind of special printing opacity mantle of soft-film ceiling Download PDF

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Publication number
CN107474439A
CN107474439A CN201710793284.8A CN201710793284A CN107474439A CN 107474439 A CN107474439 A CN 107474439A CN 201710793284 A CN201710793284 A CN 201710793284A CN 107474439 A CN107474439 A CN 107474439A
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China
Prior art keywords
soft
printing opacity
mantle
special printing
film ceiling
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CN201710793284.8A
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Chinese (zh)
Inventor
郭舒洋
许蘅
张琳
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Priority to CN201710793284.8A priority Critical patent/CN107474439A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B9/00Ceilings; Construction of ceilings, e.g. false ceilings; Ceiling construction with regard to insulation
    • E04B9/32Translucent ceilings, i.e. permitting both the transmission and diffusion of light
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of special printing opacity mantle of soft-film ceiling, belong to decorative materials technology.Product of the present invention is first by talcum powder and hydrogenated petroleum resin ball milling mixing, add nano magnesia, butyl rubber, organo-silicic oil, ether and age resistor, it is uniformly mixed obtained premix, after polyvinyl chloride, plasticizer and surfactant heat are mixed again, gained premix is added, continues to be stirred obtained compound, then mixed material heating is plasticated, film forming, produce the special printing opacity mantle of soft-film ceiling.The gained special printing opacity mantle light transmittance of soft-film ceiling of the invention has obtained effective raising, solves the problems, such as that traditional mantle translucency is bad.

Description

A kind of special printing opacity mantle of soft-film ceiling
Technical field
The invention discloses a kind of special printing opacity mantle of soft-film ceiling, belong to decorative materials technology.
Background technology
Soft-film ceiling is a kind of house decorative material being widely used in recent years.Soft-film ceiling mainly have mantle, button edge strip, Keel three parts form;(1)Mantle.It is made of special pvc material, without cadmium, its fire rating is B1 levels, is led to One or many cutting formings are crossed, and are completed with high-frequency welding, it is will be according in the smallpox shape and size measured on the spot Manufacture and form in factory.(2)Side profile.It is semi-rigid, extrusion molding, using pvc material, its level of preventing fires Not Wei B1 levels, it is welded on the edge of smallpox mantle, is buckled in being tensioned mantle on wall code-bar.(3)Hard wall code-bar.Adopt It is made of pvc material, its fire rating is B1 levels, and another kind is squeezed into using alloy aluminum, and its fire rating is B1 Level.It has various suitable different shape, straight, curved, has plenty of and is reassembled after being cut into suitable angle Together, and it is fixed in the surrounding of indoor ceiling, with for clasping joint smallpox mantle.
Mantle is completed by one or many cutting formings, and with high-frequency welding.Mantle needs measuring on the spot smallpox After size, completed in factory.The stability of mantle size is in Celsius -15 degree to 45 degree.Light-transmissive film smallpox can coordinate respectively Kind lighting system(Such as neon light, fluorescent lamp, LED)Build indoor light effect fantasy, without shadow.Glass is abandoned simultaneously Or the heaviness of lucite, the shortcomings that dangerous and fritter assembly, progressively turn into new decoration bright spot.
Soft-film ceiling can coordinate as a kind of new material that instead of traditional suspended ceiling and metope, this flexible material The advanced artistic conception of designer produces a variety of planes and the design effect of three-dimensional shape.It thoroughly breaches traditional smallpox and made The assembled limitation of type, color and fritter, public place of entertainment is widely applied to, club, stadiums, office, hospital, has been learned School, large-scale sales field, household, the place such as music hall and hall, just progressively as the preferred day flower prod of interior decoration.But pass Unite mantle there is also translucency it is bad the problem of, have impact on the final effect of soft-film ceiling.Therefore, it is also desirable to mantle is entered to advance One step research.
The content of the invention
The present invention solves the technical problem of:For traditional soft-film ceiling mantle translucency it is bad the problem of, carry A kind of special printing opacity mantle of soft-film ceiling is supplied.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of special printing opacity mantle of soft-film ceiling, is made up of the raw material of following parts by weight:80~100 parts of polyvinyl chloride trees Fat, 2~4 parts of talcum powder, 1~3 part of nano magnesia, 8~10 parts of Petropols, 8~10 parts of butyl rubbers, 2~4 parts of plasticising Agent, 0.2~0.6 part of organo-silicic oil, 0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor;
The special specific preparation process of printing opacity mantle of soft-film ceiling is:
(1)Each raw material is weighed by raw material composition;
(2)By talcum powder and Petropols ball milling mixing, ball milling material is obtained, then gained ball milling material is stirred with nano magnesia After 10~15min, sequentially add butyl rubber, organo-silicic oil, ether and age resistor, continue constant temperature be stirred 45~ 60min, obtain premix;
(3)By Corvic, plasticizer and surfactant, heat mixed 10 under the conditions of being 110~120 DEG C in temperature~ 15min, 60~65 DEG C are cooled to, add above-mentioned gained premix, continue 10~15min of mixing, obtain compound;
(4)Plasticated under the conditions of being 150~175 DEG C in temperature by compound, film forming, produce the special printing opacity mantle of soft-film ceiling.
The Petropols can also be hydrogenated petroleum resin.
The plasticizer is any one in dioctyl phthalate, dioctyl adipate or octyl epoxy stearate Kind.
The organo-silicic oil is appointing in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane Meaning is a kind of.
The surfactant is that stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.
The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
The beneficial effects of the invention are as follows:
(1)The present invention in mechanical milling process, can make talcum powder first by the talcum powder of layer structure and Petropols ball milling mixing Fully coated by Petropols, while talcum powder can be made further to refine, improve its surface-active, improve butyl rubber, organic The organic matters such as silicone lubricant allow organic matter well to sprawl and are adsorbed in talcum powder table to the wettability of inorganic talcum powder Face, so as to improve the compatibility of lamellar talc powder and polyvinyl chloride resin matrix, in addition, PVC and butyl rubber are all macromolecular linear junction Structure, both mutually wind molecular structure in preparation process, can further improve the adhesion between interiors of products component, so as to carry The stability in use of high product, product light transmittance is set well to be kept in use;
(2)The present invention by adding a small amount of nano magnesia in system, the defects of having benefited from nano oxidized magnesium surface structure, make Nano magnesia has higher activity, after being added in system, can effectively improve macromolecule polyalcohol in system and use Heat endurance and photostability in journey, product service life is improved, in addition, the addition of nano magnesia can also adsorb big point Gaseous matter caused by sub- organic matter decomposition, is secured in system, avoids the pollution to environment;
(3)Technical solution of the present invention makes system transparency further be lifted, so as to enter one by using hydrogenated petroleum resin Step improves overall light transmittance.
Embodiment
Count in parts by weight, take 80~100 parts of Corvics successively, 2~4 parts of talcum powder, 1~3 part nano oxidized Magnesium, 8~10 parts of hydrogenated petroleum resins, 8~10 parts of butyl rubbers, 2~4 parts of plasticizer, 0.2~0.6 part of organo-silicic oil, 0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor, first talcum powder and hydrogenated petroleum resin are added in ball grinder, pressed Ball material mass ratio is 15:1~25:1 adds zirconium oxide ball milling pearl, and 3~5h of ball milling mixing obtains ball milling material, then by gained ball milling material Poured into nano magnesia in three-necked flask, be stirred 10~15min with glass bar, then fourth is sequentially added into three-necked flask Base rubber, organo-silicic oil, ether and age resistor, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, Yu Wen Spend for 60~65 DEG C, under the conditions of rotating speed is 400~600r/min, constant temperature is stirred 45~60min, obtains premix, then will be poly- Vinyl chloride resin, plasticizer and surfactant add batch mixer, are 110~120 DEG C in temperature, rotating speed is 200~300r/ Under the conditions of min, the mixed 10~15min of heat, 60~65 DEG C are cooled to, then gained premix is added into batch mixer, continue to stir 10~15min is mixed, obtains compound, and gained compound is transferred to double rod plasticators, under the conditions of temperature is 150~175 DEG C Plasticate 10~20min, then through film forming, it is 1.8~2.2mm to control thickness, is cooled to room temperature, produces the special printing opacity of soft-film ceiling Mantle.:The plasticizer is any one in dioctyl phthalate, dioctyl adipate or octyl epoxy stearate. The organo-silicic oil is any one in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane. The surfactant is that stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.The age resistor It is 1 in mass ratio for age resistor 288, anti-aging agent RD and microwax:1:1 compounding forms.
Example 1
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of non-hydrogenated petroleums successively Resin, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first Talcum powder and hydrogenated petroleum resin are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, and ball milling mixes 5h is closed, obtains ball milling material, then gained ball milling material and nano magnesia are poured into three-necked flask, 15min is stirred with glass bar, Butyl rubber, organo-silicic oil, ether and age resistor are sequentially added into three-necked flask again, and three-necked flask is moved into digital display Test the speed constant temperature blender with magnetic force, is 65 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, must premix Material, then by Corvic, plasticizer and surfactant add batch mixer, in temperature be 120 DEG C, rotating speed 300r/min Under the conditions of, the mixed 15min of heat, 65 DEG C are cooled to, then gained premix is added into batch mixer, continue to be stirred 15min, obtain Compound, and gained compound is transferred to double rod plasticators, plasticate 20min under the conditions of being 175 DEG C in temperature, then through film forming, control Film thickness is 2.2mm, is cooled to room temperature, produces the special printing opacity mantle of soft-film ceiling.:The plasticizer is phthalic acid two Monooctyl ester.The organo-silicic oil is phenyl trichlorosilane.The surfactant is stearic acid and neopelex It is 1 in mass ratio:3 compoundings form.The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 is multiple With into.
Example 2
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of non-hydrogenated petroleums successively Resin, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.3 part of surfactant, 0.4 part of age resistor, first by talcum powder and non-hydrogenated petroleum Resin is added in ball grinder, is 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains ball milling material, then will Gained ball milling material and nano magnesia are poured into three-necked flask, and 15min is stirred with glass bar, then into three-necked flask successively Add butyl rubber, ether and age resistor, and three-necked flask immigration digital display tested the speed constant temperature blender with magnetic force, in temperature be 65 DEG C, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, obtains premix, then by Corvic, plasticizer and Surfactant adds batch mixer, is 120 DEG C in temperature, under the conditions of rotating speed is 300r/min, the mixed 15min of heat, is cooled to 65 DEG C, then gained premix is added into batch mixer, continue to be stirred 15min, obtain compound, and gained compound is transferred to double Rod plasticator, plasticated 20min under the conditions of being 175 DEG C in temperature, then through film forming, it is 2.2mm to control thickness, is cooled to room temperature, Produce the special printing opacity mantle of soft-film ceiling.:The plasticizer is dioctyl phthalate.The surfactant is stearic acid It is 1 in mass ratio with neopelex:3 compoundings form.The age resistor is age resistor 288, anti-aging agent RD and crystallite Wax is 1 in mass ratio:1:1 compounding forms.
Example 3
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 10 parts of hydrogenated petroleum resins, 10 parts of butyl successively Rubber, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first by talcum powder and hydrogenation Petropols are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains ball milling material, Gained ball milling material is poured into three-necked flask again, then butyl rubber, organo-silicic oil, ether are sequentially added into three-necked flask And age resistor, and three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, it is 65 DEG C in temperature, rotating speed is 600r/min bars Under part, constant temperature is stirred 60min, obtains premix, then Corvic, plasticizer and surfactant are added into batch mixing Machine, it is 120 DEG C in temperature, under the conditions of rotating speed is 300r/min, the mixed 15min of heat, is cooled to 65 DEG C, then add into batch mixer Gained premix, continue to be stirred 15min, obtain compound, and gained compound is transferred to double rod plasticators, be in temperature Plasticate 20min under the conditions of 175 DEG C, then through film forming, it is 2.2mm to control thickness, is cooled to room temperature, it is special to produce soft-film ceiling Light mantle.:The plasticizer is dioctyl phthalate.The organo-silicic oil is phenyl trichlorosilane.The surface Activating agent is that stearic acid and neopelex are 1 in mass ratio:3 compoundings form.The age resistor be age resistor 288, Anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
Example 4
Count in parts by weight, take 100 parts of Corvics, 4 parts of talcum powder, 3 parts of nano magnesias, 10 parts of oil trees successively Fat, 10 parts of butyl rubbers, 4 parts of plasticizer, 0.6 part of organo-silicic oil, 0.3 part of surfactant, 0.4 part of age resistor, first will Talcum powder and Petropols are added in ball grinder, are 25 by ball material mass ratio:1 adds zirconium oxide ball milling pearl, ball milling mixing 5h, obtains Ball milling material, then gained ball milling material and nano magnesia are poured into three-necked flask, 15min is stirred with glass bar, then to three Sequentially add butyl rubber, organo-silicic oil, ether and age resistor in mouthful flask, and three-necked flask immigration digital display is tested the speed perseverance Warm magnetic stirring apparatus, it is 65 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred 60min, obtains premix, then Corvic, plasticizer and surfactant are added into batch mixer, are 120 DEG C in temperature, rotating speed is 300r/min conditions Under, the mixed 15min of heat, 65 DEG C are cooled to, then gained premix is added into batch mixer, continue to be stirred 15min, must mix Material, and gained compound is transferred to double rod plasticators, plasticate 20min under the conditions of being 175 DEG C in temperature, then through film forming, controls film Thickness is 2.2mm, is cooled to room temperature, produces the special printing opacity mantle of soft-film ceiling.:The plasticizer is that phthalic acid two is pungent Ester.The organo-silicic oil is phenyl trichlorosilane.The surfactant is that stearic acid and neopelex are pressed Mass ratio is 1:3 compoundings form.The age resistor is that age resistor 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding Form.
Comparative example:The mantle of Wuxi soft-film ceiling company production.
The gained of example 1 to 4 mantle and comparative example product are subjected to performance detection, specific detection method is as follows:
It is as shown in table 1 with the transmitance of 724 type spectrophotometer measurement mantle light in visible light wave range, specific testing result:
Table 1
Detection content Example 1 Example 2 Example 3 Example 4 Comparative example
Transmitance/% 80 60 62 73 58
From the testing result of table 1, the present invention gained special printing opacity mantle light transmittance of soft-film ceiling has obtained effective raising, solves The problem of traditional mantle translucency of having determined is bad.

Claims (6)

  1. A kind of 1. special printing opacity mantle of soft-film ceiling, it is characterised in that:It is made up of the raw material of following parts by weight:80~100 Part Corvic, 2~4 parts of talcum powder, 1~3 part of nano magnesia, 8~10 parts of Petropols, 8~10 parts of butyl rubbers, 2~4 parts of plasticizer, 0.2~0.6 part of organo-silicic oil, 0.1~0.3 part of surfactant, 0.2~0.4 part of age resistor;
    The special specific preparation process of printing opacity mantle of soft-film ceiling is:
    (1)Each raw material is weighed by raw material composition;
    (2)By talcum powder and Petropols ball milling mixing, ball milling material is obtained, then gained ball milling material is stirred with nano magnesia After 10~15min, sequentially add butyl rubber, organo-silicic oil, ether and age resistor, continue constant temperature be stirred 45~ 60min, obtain premix;
    (3)By Corvic, plasticizer and surfactant, heat mixed 10 under the conditions of being 110~120 DEG C in temperature~ 15min, 60~65 DEG C are cooled to, add above-mentioned gained premix, continue 10~15min of mixing, obtain compound;
    (4)Plasticated under the conditions of being 150~175 DEG C in temperature by compound, film forming, produce the special printing opacity mantle of soft-film ceiling.
  2. A kind of 2. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The Petropols may be used also Think hydrogenated petroleum resin.
  3. A kind of 3. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The plasticizer is adjacent benzene Any one in diformazan dioctyl phthalate, dioctyl adipate or octyl epoxy stearate.
  4. A kind of 4. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The organo-silicic oil For any one in phenyl trichlorosilane, diphenyl dichlorosilane or dichloromethyl phenylsilane.
  5. A kind of 5. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The surfactant is Stearic acid and neopelex are 1 in mass ratio:1~1:3 compoundings form.
  6. A kind of 6. special printing opacity mantle of soft-film ceiling according to claim 1, it is characterised in that:The age resistor is anti-old Agent 288, anti-aging agent RD and microwax are 1 in mass ratio:1:1 compounding forms.
CN201710793284.8A 2017-09-06 2017-09-06 A kind of special printing opacity mantle of soft-film ceiling Pending CN107474439A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108031306A (en) * 2017-12-23 2018-05-15 刘顶康 A kind of polyvinyl chloride filter membrane with hydrophilic stability

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102719033A (en) * 2012-06-07 2012-10-10 浙江海利得新材料股份有限公司 Ceiling decorative soft film material and production process thereof
CN102850690A (en) * 2012-08-02 2013-01-02 佛山市天安塑料有限公司 Soft film for decorating ceilings and manufacturing method thereof
CN103059463A (en) * 2012-12-25 2013-04-24 杭州弘泽新材料有限公司 Ceiling membrane and producing method thereof
CN104908392A (en) * 2015-05-12 2015-09-16 浙江明士达新材料有限公司 Sparkling high-gloss decoration flexible film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102719033A (en) * 2012-06-07 2012-10-10 浙江海利得新材料股份有限公司 Ceiling decorative soft film material and production process thereof
CN102850690A (en) * 2012-08-02 2013-01-02 佛山市天安塑料有限公司 Soft film for decorating ceilings and manufacturing method thereof
CN103059463A (en) * 2012-12-25 2013-04-24 杭州弘泽新材料有限公司 Ceiling membrane and producing method thereof
CN104908392A (en) * 2015-05-12 2015-09-16 浙江明士达新材料有限公司 Sparkling high-gloss decoration flexible film

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108031306A (en) * 2017-12-23 2018-05-15 刘顶康 A kind of polyvinyl chloride filter membrane with hydrophilic stability

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Application publication date: 20171215