CN107474318A - A kind of fire retardant and preparation method - Google Patents
A kind of fire retardant and preparation method Download PDFInfo
- Publication number
- CN107474318A CN107474318A CN201710724759.8A CN201710724759A CN107474318A CN 107474318 A CN107474318 A CN 107474318A CN 201710724759 A CN201710724759 A CN 201710724759A CN 107474318 A CN107474318 A CN 107474318A
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- parts
- fire retardant
- retardant according
- antioxidant
- coupling agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The present invention relates to a kind of fire retardant of offer and preparation method, including the raw material of following parts by weight to be made：15 parts ~ 25 parts of magnesium hydroxide, 10 parts ~ 25 parts of tartaric acid, 10 parts ~ 20 parts of Firebrake ZB, 5 parts ~ 10 parts of coupling agent, 10 parts ~ 20 parts of smoke suppressant, into 15 parts ~ 20 parts of carbon accelerator, 5 parts ~ 15 parts of antioxidant.Flame retarding efficiency of the present invention is high, can prevent flaming combustion, and can suppresses to glow, good with the compatibility of material, can be dispersed in fire-retardant material, and has preferable affinity, and stability is strong, does not influence to be added the physics of material and processing performance.
Description
Technical field
The present invention relates to technical field of buildings, and in particular to a kind of fire retardant and preparation method.
Background technology
Macromolecular materials industry is fast-developing at present, and application field is constantly expanded, but it has flammable feature, is being pacified
Full property requires higher field, such as chemical building material, electronic apparatus, communications and transportation, space flight and aviation, household furniture, interior decoration
Field, the application of retardant polymer material are more and more.The fire retardant being added in high polymer material is broadly divided into halogen system resistance
Fire agent, phosphorus flame retardant, nitrogen phosphorus Compound intumescent flame retardant, inorganic combustion inhibitor.Red phosphorus, APP are phosphorus flame retardant, nitrogen
The usual component of phosphorus Compound intumescent flame retardant, because phosphorus content is high, good flame retardation effect, flame retarding efficiency is also higher, APP
Also have that chemical stability is good, hygroscopicity is small, dispersiveness is excellent, proportion is small, low toxin, but red phosphorus, APP
The defects of with polymeric matrix poor compatibility all be present, cause the mechanical properties decrease of fire proofing.
The content of the invention
In view of the above-mentioned problems, the main object of the present invention is to provide a kind of fire retardant and preparation method, with polymeric matrix
Compatibility is good, does not influence Material Physics and processing performance.
The present invention is achieved by the following technical solutions：A kind of fire retardant is provided, includes the raw material of following parts by weight
It is made：15 parts ~ 25 parts of magnesium hydroxide, 10 parts ~ 25 parts of tartaric acid, 10 parts ~ 20 parts of Firebrake ZB, 5 parts ~ 10 parts of coupling agent, smoke suppressant
10 parts ~ 20 parts, into 15 parts ~ 20 parts of carbon accelerator, 5 parts ~ 15 parts of antioxidant.
Preferably, including the raw material of following parts by weight are made：20 parts ~ 25 parts of magnesium hydroxide, 15 parts ~ 25 parts of tartaric acid,
15 parts ~ 20 parts of Firebrake ZB, 5 parts ~ 8 parts of coupling agent, 12 parts ~ 15 parts of smoke suppressant, into 15 parts ~ 18 parts of carbon accelerator, 5 parts of antioxidant
~ 10 parts.
Preferably, described into the composition that carbon accelerator is silica and titanium dioxide, both weight ratios are 1:1.
Preferably, the smoke suppressant is silicic acid nickel and silicic acid manganese composition, and both weight ratios are 1:3.
Preferably, the coupling agent is γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy
Silane, γ-methacryloxy trimethoxy silane, N- β-aminoethyl-γ-aminopropyltrimethoxysilane, N- β-ammonia second
One kind in base-γ-aminopropyltriethoxy dimethoxysilane.
Preferably, the antioxidant is one or both of tea polyphenol-palmitate, hindered phenol, amino-compound.
The present invention provides a kind of preparation method of fire retardant, comprises the following steps：
S01, magnesium hydroxide, tartaric acid, Firebrake ZB, coupling agent uniformly mixed；
S02, it is sent into tank body addition smoke suppressant, into carbon accelerator and antioxidant, is mixed again after heating.
Preferably, the hybrid mode is ultrasonic mixing, and the power of ultrasonic mixing is 60-80w.
Preferably, the time of ultrasonic mixing is 20-40min.
A kind of fire retardant of the present invention and preparation method：Flame retarding efficiency of the present invention is high, can prevent flaming combustion, again
It can suppress to glow, it is good with the compatibility of material, can be dispersed in fire-retardant material, and have preferable affinity,
Stability is strong, does not influence to be added the physics of material and processing performance.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, those skilled in the art can be by this specification institute
The content of exposure understands other advantages and effect of the present invention easily.The present invention can also pass through specific implementations different in addition
Mode is embodied or practiced, and the various details in this specification can also be based on different viewpoints and application, without departing from this
Various modifications or alterations are carried out under the spirit of invention.
Embodiment one
The present invention provides a kind of fire retardant, including the raw material of following parts by weight are made：15 parts of magnesium hydroxide, 10 parts of tartaric acid,
20 parts of Firebrake ZB, 5 parts of coupling agent, 20 parts of smoke suppressant, into 15 parts of carbon accelerator, 5 parts of antioxidant.
Specifically, in the present embodiment, into the composition that carbon accelerator is silica and titanium dioxide, both are at weight ratio
1:1；Smoke suppressant is silicic acid nickel and silicic acid manganese composition, and both weight ratios are 1:3；Coupling agent is γ-aminopropyl-triethoxy
Silane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxy trimethoxy silane, N- β-ammonia second
One kind in base-γ-aminopropyltrimethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane；It is anti-oxidant
Agent is one or both of tea polyphenol-palmitate, hindered phenol, amino-compound.
The present invention provides a kind of preparation method of fire retardant, comprises the following steps：
S01, magnesium hydroxide, tartaric acid, Firebrake ZB, coupling agent uniformly mixed；Hybrid mode is ultrasonic mixing, ultrasonic mixing
Power is 60-80w；The time of ultrasonic mixing is 20-40min.
S02, it is sent into tank body addition smoke suppressant, into carbon accelerator and antioxidant, is mixed again after heating.
In summary, flame retarding efficiency of the present invention is high, can prevent flaming combustion, and can suppresses to glow, compatible with material
Property is good, can be dispersed in fire-retardant material, and has preferable affinity, and stability is strong, does not influence to be added material
The physics and processing performance of material.
Some preferred embodiments of the present invention have shown and described in described above, but as previously described, it should be understood that the present invention
Be not limited to form disclosed herein, be not to be taken as the exclusion to other embodiment, and available for various other combinations,
Modification and environment, and above-mentioned teaching or the technology or knowledge of association area can be passed through in the scope of the invention is set forth herein
It is modified., then all should be in this hair and the change and change that those skilled in the art are carried out do not depart from the spirit and scope of the present invention
In the protection domain of bright appended claims.
Claims (9)
1. a kind of fire retardant, it is characterised in that the raw material including following parts by weight are made：15 parts ~ 25 parts of magnesium hydroxide, winestone
10 parts ~ 25 parts of acid, 10 parts ~ 20 parts of Firebrake ZB, 5 parts ~ 10 parts of coupling agent, 10 parts ~ 20 parts of smoke suppressant, into carbon accelerator 15 parts ~ 20
Part, 5 parts ~ 15 parts of antioxidant.
2. fire retardant according to claim 1, it is characterised in that the raw material including following parts by weight are made：Hydroxide
20 parts ~ 25 parts of magnesium, 15 parts ~ 25 parts of tartaric acid, 15 parts ~ 20 parts of Firebrake ZB, 5 parts ~ 8 parts of coupling agent, 12 parts ~ 15 parts of smoke suppressant, into
15 parts ~ 18 parts of carbon accelerator, 5 parts ~ 10 parts of antioxidant.
3. fire retardant according to claim 1, it is characterised in that it is described into carbon accelerator be silica and titanium dioxide
Composition, both weight ratios be 1:1.
4. fire retardant according to claim 1, it is characterised in that the smoke suppressant is silicic acid nickel and silicic acid manganese composition,
Both weight ratios are 1:3.
5. fire retardant according to claim 1, it is characterised in that the coupling agent is γ-aminopropyl-triethoxy silicon
Alkane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxy trimethoxy silane, N- β-aminoethyls-
One kind in γ-aminopropyltrimethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane.
6. fire retardant according to claim 1, it is characterised in that the antioxidant is tea polyphenol-palmitate, is obstructed
One or both of phenol, amino-compound.
7. a kind of preparation method of fire retardant, it is characterised in that comprise the following steps：
S01, magnesium hydroxide, tartaric acid, Firebrake ZB, coupling agent uniformly mixed；
S02, it is sent into tank body addition smoke suppressant, into carbon accelerator and antioxidant, is mixed again after heating.
8. the preparation method of fire retardant according to claim 7, it is characterised in that the hybrid mode is ultrasonic mixing,
The power of ultrasonic mixing is 60-80w.
9. the preparation method of fire retardant according to claim 7, it is characterised in that the time of ultrasonic mixing is 20-
40min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710724759.8A CN107474318A (en) | 2017-08-22 | 2017-08-22 | A kind of fire retardant and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710724759.8A CN107474318A (en) | 2017-08-22 | 2017-08-22 | A kind of fire retardant and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107474318A true CN107474318A (en) | 2017-12-15 |
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ID=60601919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710724759.8A Pending CN107474318A (en) | 2017-08-22 | 2017-08-22 | A kind of fire retardant and preparation method |
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| Country | Link |
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| CN (1) | CN107474318A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114622416A (en) * | 2020-12-14 | 2022-06-14 | 无锡高仕康新材料科技有限公司 | Flame-retardant yarn |
-
2017
- 2017-08-22 CN CN201710724759.8A patent/CN107474318A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114622416A (en) * | 2020-12-14 | 2022-06-14 | 无锡高仕康新材料科技有限公司 | Flame-retardant yarn |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171215 |
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| WD01 | Invention patent application deemed withdrawn after publication |