CN107471343A - Carbon fiber encased steel plate is modified the construction technology of quick growth poplar wood - Google Patents

Carbon fiber encased steel plate is modified the construction technology of quick growth poplar wood Download PDF

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Publication number
CN107471343A
CN107471343A CN201710804831.8A CN201710804831A CN107471343A CN 107471343 A CN107471343 A CN 107471343A CN 201710804831 A CN201710804831 A CN 201710804831A CN 107471343 A CN107471343 A CN 107471343A
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China
Prior art keywords
sheet material
steel plate
modified
carbon cloth
quick growth
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CN201710804831.8A
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Chinese (zh)
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CN107471343B (en
Inventor
王玉镯
李雪玲
黄颖
赵秀云
曹加林
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Shandong Xiehe University
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Shandong Xiehe University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D5/00Other working of veneer or plywood specially adapted to veneer or plywood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27GACCESSORY MACHINES OR APPARATUS FOR WORKING WOOD OR SIMILAR MATERIALS; TOOLS FOR WORKING WOOD OR SIMILAR MATERIALS; SAFETY DEVICES FOR WOOD WORKING MACHINES OR TOOLS
    • B27G11/00Applying adhesives or glue to surfaces of wood to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/0085Thermal treatments, i.e. involving chemical modification of wood at temperatures well over 100°C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/10Next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/042Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • B32B2307/734Dimensional stability

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention belongs to quick growth poplar wood technical field of modification, more particularly to a kind of carbon fiber encased steel plate to be modified the construction technology of quick growth poplar wood.Including following effective procedure:A, selection;B, cut;C, depths is managed;D, dry;E, heat modification;F, dry;G, cut;H, configuration structure glue;I, impregnate;J, combine;K, wrap up;L, conserve.Compared with prior art, the advantages and positive effects of the present invention are, the invention provides the construction technology that a kind of carbon fiber encased steel plate is modified quick growth poplar wood, processing is modified to the methods of quick growth poplar wood processing, bonding, maintenance, precompressed, post processing by carbon fiber, steel plate, structure glue and a series of construction technologies, and then change the mechanical properties such as the compression strength of quick growth poplar wood, modulus of elasticity, deformation rate, anti-seismic performance, it is allowed to the requirement for meeting building structural element (post, beam, plate, wall).

Description

Carbon fiber encased steel plate is modified the construction technology of quick growth poplar wood
Technical field
The invention belongs to quick growth poplar wood technical field of modification, is related to quick growth poplar wood modification, more particularly to outside a kind of carbon fiber Steel plated is modified the construction technology of quick growth poplar wood.
Background technology
Timber and wood materials are not only widely used in daily life as the important resources of production in social and economic construction In every field, be also widely used for the industrial circles such as traffic, building and space flight.With in world wide, the forest reserves are increasingly Shortage, particularly precious timber quantity increasingly fall sharply, and substantial amounts of fast growing tree is widely cultivated in recent years.Fast growing tree has The advantages that material time is short, yield is high, but because its growth year is shorter, such as:General artificial quick growth poplar wood become a useful person the time for 5~ 6 years, thus most of fast growing tree have low density, wooden soft, physical mechanics intensity difference, moisture content high and skewness and The defects of dry-shrinkage deformed is also easy to produce, so as to limit the use range of fast growing tree kind, generally artificial fast-growing woods uses next life The low economic value added product such as paper pulp, throwaway chopsticks is produced, and the application in high added value manufacture field is less.
As country promulgates that relevant policies carry out green building, fabricated construction energetically, and hereof it should be particularly mentioned that closing In the timber structure prefabricated construction the problem of.But nowadays the development of timber structure is because natural timber is forbidden felling and being limited System.Most of artificial material is but because its poor application of mechanical property is restricted.Quick growth poplar wood has that texture is straight, Yi Jia in itself The features such as work, growth are soon, environmental suitability is strong, and with the advantage such as environmentally friendly, attractive in appearance, and there is extensive planting matrix in China Plinth.But quick growth poplar wood is because its mechanical property is relatively low, the features such as corrosion resistance difference and big unstability, never apply In building structure.At present, how quick growth poplar wood to be applied in building structural element by the modification of carbon fiber encased steel plate, opened up The research of its wide application is less.
The content of the invention
The present invention is directed to the above-mentioned technical problem being applied to quick growth poplar wood in the presence of building structural element, proposes one Kind is reasonable in design, technique is simple, easy to process and physical strength is high, resistance to rotten carbon fiber encased steel plate is modified quick growth poplar wood Construction technology.
In order to achieve the above object, the technical solution adopted by the present invention is that the present invention provides a kind of carbon fiber encased steel plate The construction technology of modified quick growth poplar wood, including following effective procedure:
A, selection:Logical straight, the tree-walk 20cm of quick growth poplar wood trunk or so log is chosen, and is put in shady place placement;
B, cut:The quick growth poplar wood chosen is cut into the sheet material that thickness is 10mm, rejects the sheet material for being unsatisfactory for requiring, place It is size needed for component to manage plate length and width;
C, depths is managed:The sheet material handled well is subjected to deep processing processing, groove processing is done in plate surface;
D, dry:Sheet material after deep processing is handled is put in shady place and dried 3-5 days or using dryer at 65 DEG C -85 DEG C Lower drying more than the 8h of effect;
E, heat modification:Sheet material after will be treated is put in nitrogen chamber, and nitrogen at elevated temperature room temperature is to 180 DEG C~260 DEG C Heat modification processing is done to sheet material;
F, dry:Sheet material drying baker after heat modification is handled dries more than 24h at 105 DEG C, carries out water ratio test Test, control moisture content are standby between 9~15%;
G, cut:Sheet material after cutting correspondingly sized steel plate according to the size of sheet material upper groove and being superimposed for parcel Carbon cloth, it is standby;
H, configuration structure glue:The structure glue includes being used to be bonded the carbon cloth glue of carbon cloth and for being bonded steel plate Steel plate glue, the carbon cloth glue include two groups of important components of A, B, wherein, A groups are modified epoxy, and B groups are what ethylenediamine was modified The intermixture of phenolic aldehyde ammonia curing agent and aromatic amine curing agent, according to mass ratio A:B=3:1, the component of A, B two is well mixed, it is standby With;The steel plate glue includes two groups of important components of C, B, wherein, C groups are acrylic modified epoxy resin, according to mass ratio C:B= 3:1, the component of C, B two is well mixed, it is standby;
I, impregnate:Sheet material after drying is put into vacuum impregnation tank, adds the carbon cloth glue configured, controls Vaccum Permeating Stain tank is 1MPa, controls 75 DEG C of temperature, impregnates 3h;
J, combine:Sheet material after dipping is taken out, the carbon cloth glue of plate surface is quickly scraped off, will be cut in g steps Steel plate be quickly coated to by steel plate glue in the groove of sheet material, and separately take one block of sheet material, cover its corresponding groove On steel plate, the groove between two plates and steel plate is set to cooperatively form an entirety, the rest may be inferred, combines required thickness Degree;
K, wrap up:The carbon cloth that g steps are cut is wrapped in into the sheet material that j steps combine using carbon cloth glue to be glued Knot, will ensure smooth, straight during bonding, paste second layer carbon cloth after the construction of first layer carbon cloth, during stickup, first In the external coating carbon cloth glue of first layer carbon cloth, second layer carbon cloth then is pasted by preceding method, to ensure carbon cloth The plumpness of glue;
L, conserve:The sheet material wrapped is compressed with mould, control temperature is conserved at 40~50 DEG C, and curing time is The time of 1~2 week, that is, obtain required finished product.
Preferably, in the step c, long side direction of the groove along sheet material is arranged at intervals.
Preferably, in the step c, the groove is staggered along the short side direction of sheet material.
Preferably, in the step c, the groove is along sheet material short side direction at least provided with three row.
Preferably, in the step e, the sheet material after treating first is put in nitrogen chamber, then nitrogen at elevated temperature Room temperature starts to inject nitrogen, control temperature is incubated 2h at 180 DEG C~260 DEG C, is then shut off nitrogen injection, closes to 140 DEG C Temperature control is closed, after placement makes nitrogen room temperature be down to 40 DEG C, sheet material is taken out.
Preferably, phenolic aldehyde ammonia curing agent and aromatic amine curing agent that the B component ethylenediamine is modified are according to mass ratio 1:2 ~5 ratio mixing.
Preferably, in the i steps, sheet material is put into vacuum impregnation tank first, then with vavuum pump by vacuum Impregnating autoclave is pumped into -0.2MPa vacuum, then turns on imported valve, and carbon cloth glue is pressed into vacuum impregnation tank using atmospheric pressure It is interior, after carbon cloth glue submerges sheet material, vacuum impregnation tank is transferred to 1MPa, controls 75 DEG C of temperature, impregnates 3h.
Compared with prior art, the advantages and positive effects of the present invention are:
The invention provides a kind of carbon fiber encased steel plate be modified quick growth poplar wood construction technology, by carbon fiber, steel plate, Structure glue and a series of construction technologies are modified place to the methods of quick growth poplar wood processing, bonding, maintenance, precompressed, post processing Reason, and then the mechanical property such as the compression strength of change quick growth poplar wood, modulus of elasticity, deformation rate, anti-seismic performance, are allowed to meet building The requirement of structural elements (post, beam, plate, wall).
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Accompanying drawing be briefly described, it should be apparent that, drawings in the following description are some embodiments of the present invention, for ability For the those of ordinary skill of domain, without having to pay creative labor, it can also be obtained according to these accompanying drawings other Accompanying drawing.
Fig. 1 is the structure that the carbon fiber encased steel plate that embodiment 1 provides is modified finished product obtained by the construction technology of quick growth poplar wood Schematic diagram;
Fig. 2 is the structural representation for the individual layer cottonwood plank stuff that embodiment 1 provides;
Fig. 3 is the structural representation for the individual layer cottonwood plank stuff that embodiment 2 provides;
More than in each figure, 1, carbon cloth;2nd, sheet material;21st, groove.
Embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to the accompanying drawings and examples The present invention will be further described.It should be noted that in the case where not conflicting, in embodiments herein and embodiment Feature can be mutually combined.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still, the present invention may be used also To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below The limitation of embodiment.
Embodiment 1, as shown in Figure 1 and Figure 2, the present embodiment provide the construction work that carbon fiber encased steel plate is modified quick growth poplar wood Skill
First, selection, it is contemplated that the modification quick growth poplar wood that the present embodiment is provided is used in building, therefore in the present embodiment In, the selection of material also functions to vital effect to the intensity of later stage finished product, first, choose quick growth poplar wood trunk it is logical it is straight, Tree-walk 20cm or so log, and shady place placement is put in, lead to straight poplar from trunk mainly leads to straight poplar in view of trunk It is more convenient in processing for wood, is mainly in view of from tree-walk 20cm or so log needed for the present embodiment construction, and places Shady place is set, primarily to avoiding being exposed to the sun, is caused the cracking of poplar, is influenceed its intensity.
Then, the quick growth poplar wood chosen is cut into the sheet material 2 that thickness is 10mm, rejects the sheet material for being unsatisfactory for requiring, place It is size needed for component to manage plate length and width, in the present embodiment, it is necessary to which the length 2400mm of configuration, width are 140mm sheet material, If the length and width of sheet material is unable to reach corresponding size, the size of required sheet material can be obtained by cohesive mode, is glued Become the conventional means of existing fast-growing sheet material, therefore in the present embodiment, without detailed description.The sheet material 2 handled well is entered Row deep processing is handled, and is done groove 21 on the surface of sheet material 2 and is set, in the present embodiment, groove 21 is set along the long side direction interval of sheet material 2 Put, i.e., timber, groove, the structure setting of timber are formed on sheet material, in order to further increase the intensity after finished product, in this reality Apply in example, groove 21 is staggered along the short side direction of sheet material 2, i.e., forms crisscross layout in the upper groove 21 of sheet material 2, each All wrapped up around groove 21 by sheet material, the groove between adjacent two plates is symmetrically arranged, so in groove 21 Steel plate is placed, the steel plate in groove 21 just made forms the effect of key, increases the intensity of finished product.
In order to further improve the intensity of finished product, groove 21 arranges along the short side direction of sheet material 2 at least provided with three, such to set Put, staggeredly area of the groove 21 on sheet material 2 can be increased, and then increase bulk strength, in the present embodiment, there is provided three altogether Row.
In order to further increase the intensity of sheet material, the moisture of sheet material is removed, the sheet material after deep processing is handled is put in cool place Place dries 3~5 days or more than 8h is dried under 65 DEG C~85 DEG C effects using dryer, carries out removing water process, the mesh so done , moisture is slowly evaporated from sheet material, avoid moisture from being quickly lost in, cause the cracking of sheet material.
Then, the sheet material after will be treated is put in nitrogen chamber, and nitrogen at elevated temperature room temperature is to 180 DEG C~260 DEG C to plate Material does heat modification processing, and content of cellulose is about the 40%~50% of lignocellulose raw material in poplar, and cellulose is D-Glucose The chain-like macromolecule compound that β-Isosorbide-5-Nitrae glycosidic bond links up, the degree of polymerization of cellulose are wooden from hundreds to thousands even more than 10,000 Content of cellulose and property in material cell membrane are the important factor in order of Wood mechanical property, and hemicellulose is the same as cellulose one Sample is polysaccharide, but hemicellulose is not homogeneous glycan, but the composition of a variety of complex plycans, and general hemicellulose gathers Right is 200 to 300, and the arrangement of hemicellulose is more loose, can form crystal region unit, have in hemicellulose structure more Hydrophilic group key (predominantly hydroxyl and carbonyl), therefore there is larger shadow to the bulking performance equidimension stability of wood cell wall Ring, hemicellulose is amorphous in usual hemicellulose compared with the hydroxyl in cellulose as the adhesive in wood components Contain substantial amounts of hydroxyl in area, these hydroxyl heat endurances are poor, easily decompose at high temperature, make the toughness of timber increase, right The viscoplasticity of timber has important influence, in order to improve the intensity of sheet material, in the present embodiment, first carries out hot place to timber Reason, specifically, the sheet material after treating are put in nitrogen chamber, and then nitrogen at elevated temperature room temperature starts to inject to 140 DEG C Nitrogen, control temperature are incubated 2h at 180 DEG C~260 DEG C, are then shut off nitrogen injection, closing temperature control, and placement makes nitrogen chamber After temperature is down to 40 DEG C, sheet material is taken out, you can complete the heat treatment step of sheet material, heat treatment step effectively raises sheet material Toughness, and then improve its intensity.
In order to further remove moisture, in the present embodiment, the sheet material drying baker after heat modification is handled is in 105 DEG C of bakings Dry more than 24h, water ratio test test is carried out, control moisture content is standby between 9~15%, if the water content mistake of timber Height, very big influence be present to its later strength, therefore, the water content of timber must be controlled, in the present embodiment, control Moisture content, certainly can be with 9~15% 12%.
In order to further strengthen its intensity, in the present embodiment, cut according to the size of sheet material upper groove corresponding big Small steel plate, in the present embodiment, tension, shearing resistance and seismic hardening of the steel plate for sheet material, the cooperation of steel plate and quick growth poplar wood, Effectively raise poplar finished product it is integral after intensity, it is met construction timber needs.
Meanwhile the carbon cloth 2 that corresponding size is cut according to the length of required finished product is opened, the face of carbon cloth Product so, the purpose of setting, should mainly be to ensure that carbon cloth can wrap completely less times greater than the lateral area of sheet material after finished product Wrap up in.
It is in the present embodiment, also special in order to further make that an entirety is formed between carbon cloth, steel plate and sheet material Corresponding structure glue is configured with, structure glue includes being used for the carbon cloth glue for being bonded carbon cloth and the steel plate for being bonded steel plate Glue, wherein, carbon cloth glue includes two groups of important components of A, B, and A groups are modified epoxy, the modified epoxy that the present embodiment is provided Resin includes 90 parts of epoxy resin, 16.2 parts of carboxylic acrylonitrile butadiene rubber latexs, 6 parts of polyacrylic ester latexs, 7 parts of quartz by mass fraction Powder, 1.3 parts of alumina silicate, 2.5 portions of anti-settling agents, 35 parts of polyamide curing agents and 1.1 parts of gamma-aminopropyl-triethoxy-silanes are made; After carboxylic acrylonitrile butadiene rubber latex is to be demulsified to specific processing method, it is dried for standby;After polyacrylic ester latex is demulsified, it is dried for standby; Carboxylic acrylonitrile butadiene rubber latex after drying is added in epoxy resin, 2h is reacted under conditions of being 120 DEG C in temperature, sequentially adds baking Polyacrylic ester latex and gamma-aminopropyl-triethoxy-silane after dry, 1h is reacted under conditions of being 120 DEG C in temperature, is obtained It is the epoxy resin for the thick liquid that can be trickled under normal temperature;Finally sequentially added in the epoxy resin of thick liquid anti-settling agent, Alumina silicate and silica flour, after stirring 40min, produce A group component modified epoxy resin.
B groups are the intermixture of the phenolic aldehyde ammonia curing agent that ethylenediamine is modified and aromatic amine curing agent, specifically, B component second The phenolic aldehyde ammonia curing agent and aromatic amine curing agent that diamines is modified are according to mass ratio 1:2~5 ratio mixes, in the present embodiment In, match as 1:2, the amount of aromatic amine curing agent mainly needs to set according to FUTURE ENVIRONMENT, such as, northern weather, according to 1:2, the weather of the moist more heat in south, to reach 1:5, wherein, the phenolic aldehyde ammonia curing agent and fragrance that ethylenediamine is modified Amine hardener provides by celebrating Da Feng engineering technology Co., Ltd, then, according to mass ratio A:B=3:1 ratio, by A, B two Component is well mixed, standby.
Steel plate glue includes two groups of important components of C, B, and B component is consistent with the B component of carbon cloth glue, and C groups are acrylic acid modified ring Oxygen tree fat, the acrylic modified epoxy resin that the present embodiment is provided take 30 parts of Bisphenol F diglycidyl ether, first by mass fraction 5 parts of base methyl acrylate, 5 parts of EMA, 6 parts of methacrylic acid, 4 parts of styrene, 1 part of lauryl methacrylate After being mixed, under protective gas atmosphere under 90 DEG C of oil bath temperatures, the BPO accelerator of 0.5 mass fraction of addition is reacted, Terminate to exothermic heat of reaction, produce the epoxy resin and acrylic copolymer of graft polymerization, then, in the asphalt mixtures modified by epoxy resin to graft polymerization In fat and acrylic copolymer add particle diameter be 800~1000 mesh 5 parts of coarse whiting, particle diameter be 800~5000 4 parts of kaolin, Particle diameter is 2000~8,000 10 parts of active fine particle calcium carbonate, and thick liquid is obtained after being uniformly mixed, and as C component acrylics are modified Epoxy resin, then, according to mass ratio C:B=3:1, the component of C, B two is well mixed, it is standby.
Then, the sheet material after drying is put into vacuum impregnation tank, adds the carbon cloth glue that part has configured, control vacuum Impregnating autoclave is 1MPa, controls 75 DEG C of temperature, impregnates 3h, 75 DEG C of temperature of control is primarily to avoid prepared carbon cloth from being gelled Gu and the mode of immersion is selected, it is a kind of porous capillary materials to be primarily due to quick growth poplar wood, by various permanent tubular units A kind of composite capillary system that (skilful capillary) and instantaneous tubulose unit (microcapillary) are connected with each other, so timber has There is certain permeability, vacuum impregnation is exactly to utilize this feature, and by physics mode, a certain amount of carbon cloth glue is impregnated into wood Inside material, the performances such as density of wood, physical mechanics intensity, heat resistance and antiseptic fire-retardation are improved by filling, in the present embodiment In, in order to reach vacuum-impregnated purpose, first sheet material is put into vacuum impregnation tank, then with vavuum pump by vacuum impregnation tank - 0.2MPa vacuum is pumped into, then turns on imported valve, carbon cloth glue is pressed into vacuum impregnation tank using atmospheric pressure, treats carbon After cloth glue submergence sheet material, vacuum impregnation tank is transferred to 1MPa, controls 75 DEG C of temperature, 3h is impregnated, in the present embodiment, from carbon cloth It is preferable relative to the mobility of steel plate glue that glue as dipping glue is mainly in view of carbon cloth glue, for carbon cloth glue, steel plate glue It is more more sticky.
Sheet material 2 after dipping is taken out, quickly scrapes off the carbon cloth glue on the surface of sheet material 2, the steel plate cut is passed through into steel Plate glue is quickly coated in the groove 21 of sheet material 2, and separately takes one block of sheet material, and the groove 21 for making its corresponding is sleeved on steel plate On, so, allow for steel plate and play a part of key between two plates 2, so, one is cooperatively formed between sheet material 2 and steel plate Individual entirety, the rest may be inferred, combines required thickness, in the present embodiment, is formed by stacking for 10 blocks of sheet materials, certainly in most Groove setting is not done in the outer surface of the two plates in outside.
In order to further improve its intensity, by the length and width according to the sheet material 2 combined, corresponding chi is cut The carbon cloth 2 of very little size is opened to be bonded to the sheet material combined, specifically, by carbon cloth 1 and the sheet material 2 combined Bonded, to be ensured during bonding smooth, straight using carbon cloth glue.Second is pasted after the construction of first layer carbon cloth 1 Layer carbon cloth 1, during stickup, one layer of carbon cloth glue first is applied on the surface of first layer carbon cloth 1, then paste the by preceding method Two layers of carbon cloth 1, to ensure the plumpness of carbon cloth glue.
Deng sheet material glue somewhat do after, the sheet material combined is compressed with compaction mold, control 40~50 DEG C of temperature, Conserved, curing time is time of 1~2 week, that is, obtains required finished product, during maintenance, will be combined with compaction mold Plate compact, curing period, are generally 1-2 weeks to reach design strength, (are conserved 2 weeks or so during about 40 DEG C of temperature on average, average air Conserved 1 week or so when warm about 50 DEG C), it should carry out blocking fencing lawn during maintenance, finally, obtain finished product.
Experiment detection:
In experimentation, tested using 100T YPE3000-4Z electron pressure testing machines, experimentation uses displacement The experimental method of loading, sample dimensions are 100mm × 100mm, thickness 105mm, loading velocity 2mm/min.It is loaded into most During big finder charge, reverse cyclic loadings 5 times, modulus of elasticity is calculated, be then loaded onto test specimen destruction, test different carbon fibers and match somebody with somebody fine rate In the case of, the mechanical property of modifying cotton wood.
1 different carbon fibers of table are matched somebody with somebody under fine rate, the mechanical property for the poplar finished product that embodiment 1 is provided
With fine rate Test specimen is numbered Peak value (kN) Compression strength (MPa) Deform (mm) Modulus of elasticity (MPa)
0.0017 A-11 402.5 40 4.986 1570.2
0.0034 A-21 411.3 35 7.542 1190.8
0.0051 A-31 430.5 33 5.525 1070.8
From the point of view of above-mentioned testing result, the present embodiment provides method and is modified obtained poplar, fully meets existing Building needs.
Embodiment 2, the present embodiment provide the construction technology that a kind of carbon fiber encased steel plate is modified quick growth poplar wood
As shown in figure 3, the present embodiment is modified the construction work of quick growth poplar wood with the carbon fiber encased steel plate that embodiment 1 is provided The difference of skill is the setting of groove 21, is arranged at intervals compared to the groove that embodiment 1 is provided along cottonwood plank stuff long side, along short The structure that edge direction is staggered, the groove 21 that the present embodiment is provided is sets through sheet material 2, i.e., groove 21 is only along poplar plate The long side direction of material 2 is arranged at intervals, and the benefit so set essentially consists in convenient processing, due in architectural process, it is necessary to not With the post of size, beam, plate, wall, the construction technology that the carbon fiber encased steel plate provided using embodiment 1 is modified quick growth poplar wood needs Will according to scene needs, be processed, and the technical scheme that the present embodiment is provided can the large-scale production in factory, be not required to Size required for considering in architectural process, it is only necessary to which scale processes, and then arrives live scene as needed and cuts Cutting to complete.
2 different carbon fibers of table are matched somebody with somebody under fine rate, the mechanical property for the poplar finished product that embodiment 2 is provided
With fine rate Test specimen is numbered Peak value (kN) Compression strength (MPa) Deform (mm) Modulus of elasticity (MPa)
0.0017 A-12 370.8 34 7.464 1450.3
0.0034 A-22 382.4 31 9.782 1098.5
0.0051 A-32 402.3 30 6.595 1045.2
From the point of view of above-mentioned testing result, the present embodiment provides method and is modified obtained poplar, fully meets existing Building needs.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Effect embodiment is applied to other fields, but every without departing from technical solution of the present invention content, the technical spirit according to the present invention Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.

Claims (7)

1. a kind of carbon fiber encased steel plate is modified the construction technology of quick growth poplar wood, it is characterised in that including following effective procedure:
A, selection:Logical straight, the tree-walk 20cm of quick growth poplar wood trunk or so log is chosen, and is put in shady place placement;
B, cut:The quick growth poplar wood chosen is cut into the sheet material that thickness is 10mm, rejects the sheet material for being unsatisfactory for requiring, process plate Length and width is size needed for component;
C, depths is managed:The sheet material handled well is subjected to deep processing processing, groove processing is done in plate surface;
D, dry:Sheet material after deep processing is handled is put in shady place and dried 3-5 days or using dryer in 65 DEG C of -85 DEG C of effects Lower drying more than 8h;
E, heat modification:Sheet material after will be treated is put in nitrogen chamber, and nitrogen at elevated temperature room temperature is to 180 DEG C~260 DEG C to plate Material does heat modification processing;
F, dry:Sheet material drying baker after heat modification is handled dries more than 24h at 105 DEG C, carries out water ratio test test, Moisture content is controlled between 9~15%, it is standby;
G, cut:The carbon of sheet material is fine after cutting correspondingly sized steel plate according to the size of sheet material upper groove and being superimposed for parcel Wei Bu, it is standby;
H, configuration structure glue:The structure glue includes being used for the carbon cloth glue for being bonded carbon cloth and the steel plate for being bonded steel plate Glue, the carbon cloth glue include two groups of important components of A, B, wherein, A groups are modified epoxy, and B groups are the phenolic aldehyde that ethylenediamine is modified The intermixture of ammonia curing agent and aromatic amine curing agent, according to mass ratio A:B=3:1, the component of A, B two is well mixed, it is standby;Institute Stating steel plate glue includes two groups of important components of C, B, wherein, C groups are acrylic modified epoxy resin, according to mass ratio C:B=3:1, The component of C, B two is well mixed, it is standby;
I, impregnate:Sheet material after drying is put into vacuum impregnation tank, adds the carbon cloth glue configured, controls vacuum impregnation tank For 1MPa, 75 DEG C of temperature is controlled, impregnates 3h;
J, combine:Sheet material after dipping is taken out, quickly scrapes off the carbon cloth glue of plate surface, the steel that will be cut in g steps Plate is quickly coated in the groove of sheet material by steel plate glue, and separately takes one block of sheet material, and the groove for making its corresponding is covered in steel On plate, the groove between two plates and steel plate is set to cooperatively form an entirety, the rest may be inferred, combines required thickness;
K, wrap up:The carbon cloth that g steps are cut is wrapped in into the sheet material that j steps combine using carbon cloth glue to be bonded, To ensure smooth, straight during bonding, paste second layer carbon cloth after the construction of first layer carbon cloth, during stickup, first exist The external coating carbon cloth glue of first layer carbon cloth, second layer carbon cloth then is pasted by preceding method, to ensure carbon cloth glue Plumpness;
L, conserve:The sheet material wrapped is compressed with mould, control temperature is conserved at 40~50 DEG C, and curing time is 1~2 The time in week, that is, obtain required finished product.
2. carbon fiber encased steel plate according to claim 1 is modified the construction technology of quick growth poplar wood, it is characterised in that described In step c, long side direction of the groove along sheet material is arranged at intervals.
3. carbon fiber encased steel plate according to claim 2 is modified the construction technology of quick growth poplar wood, it is characterised in that described In step c, the groove is staggered along the short side direction of sheet material.
4. carbon fiber encased steel plate according to claim 3 is modified the construction technology of quick growth poplar wood, it is characterised in that described In step c, the groove is along sheet material short side direction at least provided with three row.
5. carbon fiber encased steel plate according to claim 4 is modified the construction technology of quick growth poplar wood, it is characterised in that described In step e, the sheet material after treating first is put in nitrogen chamber, and then nitrogen at elevated temperature room temperature starts to inject to 140 DEG C Nitrogen, control temperature are incubated 2h at 180 DEG C~260 DEG C, are then shut off nitrogen injection, closing temperature control, and placement makes nitrogen chamber After temperature is down to 40 DEG C, sheet material is taken out.
6. carbon fiber encased steel plate according to claim 5 is modified the construction technology of quick growth poplar wood, it is characterised in that described The phenolic aldehyde ammonia curing agent and aromatic amine curing agent that B component ethylenediamine is modified are according to mass ratio 1:2~5 ratio mixing.
7. carbon fiber encased steel plate according to claim 6 is modified the construction technology of quick growth poplar wood, it is characterised in that described In i steps, sheet material is put into vacuum impregnation tank first, vacuum impregnation tank is then pumped into -0.2MPa vacuum with vavuum pump, Then imported valve is turned on, carbon cloth glue is pressed into vacuum impregnation tank using atmospheric pressure, will after carbon cloth glue submerges sheet material Vacuum impregnation tank is transferred to 1MPa, controls 75 DEG C of temperature, impregnates 3h.
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