CN107469794A - 一种活性炭吸附剂 - Google Patents

一种活性炭吸附剂 Download PDF

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CN107469794A
CN107469794A CN201710851124.4A CN201710851124A CN107469794A CN 107469794 A CN107469794 A CN 107469794A CN 201710851124 A CN201710851124 A CN 201710851124A CN 107469794 A CN107469794 A CN 107469794A
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adsorbent
activated carbon
acticarbon
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陈天烨
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JIANGSU KELITE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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JIANGSU KELITE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

本发明公开了一种活性炭吸附剂，由以下按照重量份的原料组成：氯化钙49‑60份、活性炭17‑32份、水12‑15份、膨润土6‑7份、三氧化二铁1‑5份、聚氨酯2‑6份、乳化剂10‑20份、丁酯2‑10份、六次甲基四胺2‑6份。本发明的优点在于：本发明中混合吸附剂由于采用了活性炭为基质，大大提高了吸附剂的气体渗透性能以及体积填充量，同时由于填充密度加大，大大改善了吸附剂的传热性能，在同等体积吸附床的条件下，空调工况体积制冷量可以提高35％左右，制冰工况可以将制冷量提高28％左右。

Description

一种活性炭吸附剂
技术领域
本发明涉及一种吸附剂，特别涉及一种活性炭吸附剂。
背景技术
作为一种以再生能源或者低品位余热驱动的绿色制冷技术，吸附式制热/热泵技术越来越得到人们的关注。目前在吸附式制冷/热泵系统中所应用的吸附剂主要包括物理吸附剂、化学吸附剂以及物理-化学混合吸附剂。化学吸附剂相对于物理吸附剂来讲，具有吸附、解吸量大、制冷以及制热功率大等优点，同时也存在传热差、气体渗透性差以及膨胀现象严重等缺点，为了解决化学吸附剂的这些缺点，目前混合吸附剂的研究已经成为一个热点。
发明内容
本发明要解决的技术问题是提供一种能够提高传热和传质性能的活性炭吸附剂。
为解决上述技术问题，本发明的技术方案为：一种活性炭吸附剂，其创新点在于：由以下按照重量份的原料组成：氯化钙49-60份、活性炭17-32份、水12-15份、膨润土6-7份、三氧化二铁1-5份、聚氨酯2-6份、乳化剂10-20份、丁酯2-10份、六次甲基四胺2-6份。
进一步的，氯化钙49-60份、活性炭17-32份、水12-15份、膨润土6-7份、三氧化二铁3份、聚氨酯4份、乳化剂15份、丁酯6份、六次甲基四胺4份。
本发明的优点在于：
本发明中混合吸附剂由于采用了活性炭为基质，大大提高了吸附剂的气体渗透性能以及体积填充量，同时由于填充密度加大，大大改善了吸附剂的传热性能，在同等体积吸附床的条件下，空调工况体积制冷量可以提高35％左右，制冰工况可以将制冷量提高28％左右。
具体实施方式
下面的实施例可以使本专业的技术人员更全面地理解本发明，但并不因此将本发明限制在所述的实施例范围之中。
实施例1
一种活性炭吸附剂，由以下按照重量份的原料组成：氯化钙49份、活性炭17份、水12份、膨润土6份、三氧化二铁1份、聚氨酯2份、乳化剂10份、丁酯2份、六次甲基四胺2份。
实施例2
一种活性炭吸附剂，由以下按照重量份的原料组成：氯化钙60份、活性炭32份、水15份、膨润土7份、三氧化二铁5份、聚氨酯6份、乳化剂20份、丁酯10份、六次甲基四胺6份。
实施例3
一种活性炭吸附剂，由以下按照重量份的原料组成：氯化钙55份、活性炭25份、水14份、膨润土6份、三氧化二铁3份、聚氨酯4份、乳化剂15份、丁酯6份、六次甲基四胺4份。
本发明中混合吸附剂由于采用了活性炭为基质，大大提高了吸附剂的气体渗透性能以及体积填充量，同时由于填充密度加大，大大改善了吸附剂的传热性能，在同等体积吸附床的条件下，空调工况体积制冷量可以提高35％左右，制冰工况可以将制冷量提高28％左右。
以上显示和描述了本发明的基本原理和主要特征以及本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (2)

1.一种活性炭吸附剂，其特征在于：由以下按照重量份的原料组成：氯化钙49-60份、活性炭17-32份、水12-15份、膨润土6-7份、三氧化二铁1-5份、聚氨酯2-6份、乳化剂10-20份、丁酯2-10份、六次甲基四胺2-6份。
2.根据权利要求1所述的一种活性炭吸附剂，其特征在于：氯化钙55份、活性炭25份、水14份、膨润土6份、三氧化二铁3份、聚氨酯4份、乳化剂15份、丁酯6份、六次甲基四胺4份。
CN201710851124.4A 2017-09-20 2017-09-20 一种活性炭吸附剂 Pending CN107469794A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1569324A (zh) * 2004-04-29 2005-01-26 上海交通大学 氯化钙－活性炭混合吸附剂
CN104056600A (zh) * 2014-06-06 2014-09-24 广州韩研活性炭制造有限公司 一种改性活性炭吸附剂及其制备方法
CN105268405A (zh) * 2015-10-30 2016-01-27 安徽炭之馨环保科技有限公司 一种吸附能力高的活性炭吸附剂
CN106475066A (zh) * 2016-10-27 2017-03-08 浙江大学 磁性粉末活性炭吸附剂的制备方法、产品及应用

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1569324A (zh) * 2004-04-29 2005-01-26 上海交通大学 氯化钙－活性炭混合吸附剂
CN104056600A (zh) * 2014-06-06 2014-09-24 广州韩研活性炭制造有限公司 一种改性活性炭吸附剂及其制备方法
CN105268405A (zh) * 2015-10-30 2016-01-27 安徽炭之馨环保科技有限公司 一种吸附能力高的活性炭吸附剂
CN106475066A (zh) * 2016-10-27 2017-03-08 浙江大学 磁性粉末活性炭吸附剂的制备方法、产品及应用

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