CN107459716A - A kind of non-woven fabrics antibacterial copolymer rubber filler and preparation method thereof - Google Patents

A kind of non-woven fabrics antibacterial copolymer rubber filler and preparation method thereof Download PDF

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Publication number
CN107459716A
CN107459716A CN201710666819.5A CN201710666819A CN107459716A CN 107459716 A CN107459716 A CN 107459716A CN 201710666819 A CN201710666819 A CN 201710666819A CN 107459716 A CN107459716 A CN 107459716A
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calcium carbonate
woven fabrics
minutes
preparation
added
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CN201710666819.5A
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Chinese (zh)
Inventor
朱存胜
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QINGYANG COUNTY JIXIANG PLASTIC Co Ltd
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QINGYANG COUNTY JIXIANG PLASTIC Co Ltd
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Priority to CN201710666819.5A priority Critical patent/CN107459716A/en
Publication of CN107459716A publication Critical patent/CN107459716A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of non-woven fabrics antibacterial copolymer rubber filler and preparation method thereof, is made up of the raw material components of following number：Superfine light calcium carbonate 50 80, ethylene propylene diene rubber 50 80, zinc oxide 47, carbon powder 30 50, precipitated calcium carbonate 20 30, sodium hydroxide 16 24, borax 6 10, saltcake 46, talcum powder 10 12, polyimide resin liquid 5 10, alkyl-modified phenolic resin 21 41, monoperphthalic acid 1.5 2.1, magnesium stearate 10 16, tall oil diglycollic amide 46, hydroxyethyl methacrylate 46, auxiliary agent 8 10, deionized water is some, the non-woven fabrics of the present invention not only has excellent anlistatig effect with antibacterial copolymer rubber filler and preparation method thereof, but also with heat-resisting, the characteristic such as fire-retardant, use demand with a greater variety can be met.

Description

A kind of non-woven fabrics antibacterial copolymer rubber filler and preparation method thereof
Technical field
The present invention relates to field of rubber technology, and in particular to a kind of non-woven fabrics antibacterial copolymer rubber filler and its preparation Method.
Background technology
Plastic tube is usually to be raw material, added stabilizer, lubricant, plasticizer etc. with synthetic resin, that is, polyester, with The method of " modeling " forms in tuber through extrusion process, due to it have light, corrosion-resistant, good appearance, without bad smell, Handling ease, it is easy for construction the features such as, more and more extensive application is obtained in architectural engineering, is mainly used as building construction Tap water supply system pipe arrangement, draining, exhaust and blowdown sanitary pipe, subsoil drain system, rain pipe and electric wire installation are matched somebody with somebody Penetration pipe applied mechanically etc..
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of non-woven fabrics antibacterial copolymer rubber filler and its preparation side Method.
The present invention is achieved through the following technical solutions：
A kind of non-woven fabrics antibacterial copolymer rubber filler, is made up of the raw material components of following number：Superfine light calcium carbonate 50-80, ethylene propylene diene rubber 50-80, zinc oxide 4-7, carbon powder 30-50, precipitated calcium carbonate 20-30, sodium hydroxide 16-24, Borax 6-10, saltcake 4-6, talcum powder 10-12, polyimide resin liquid 5-10, alkyl-modified phenolic resin 21-41, single peroxide Phthalic acid 1.5-2.1, magnesium stearate 10-16, tall oil diglycollic amide 4-6, hydroxyethyl methacrylate 4-6, auxiliary agent 8-10, deionized water are some.
The auxiliary agent is made up of the raw material of following weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, ethylene Double oleamide 0.4-0.6, OPE 0.3-0.5, tall oil diglycollic amide 0.3-0.4, graphene oxide 0.3- 0.5th, lanolin alcohol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, polyurethane propylene Acid esters 0.3-0.5, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, two contractings Tripropylene glycol diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two In contracting tripropylene glycol diacrylate, be heated to 50-55 DEG C, stir 20-30 minutes, add magnesium stearate, di-n-octyl sebacate, The double oleamide of ethylene, OPE, tall oil diglycollic amide, graphene oxide, lanolin alcohol APEO, receive Rice titanium dioxide, polyamide wax micropowder, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, 35-40 DEG C is cooled to, other residual components is added, stirring reaction 50-60 minutes, produces.
The preparation method of described non-woven fabrics antibacterial copolymer rubber filler, it is characterised in that comprise the following steps：
(1) will by superfine light calcium carbonate, ethylene propylene diene rubber, zinc oxide, carbon powder, precipitated calcium carbonate, sodium hydroxide, Borax, saltcake, talcum powder, polyimide resin liquid, alkyl-modified phenolic resin are added in deionized water, are sufficiently stirred It is even, 75-85 DEG C is heated to, obtains slurry；
(2) monoperphthalic acid, magnesium stearate, tall oil diglycollic amide, hydroxyethyl methacrylate are mixed, Blowing 75-85 DEG C of hot-air to it again seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, After being sufficiently mixed the two, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
The beneficial effects of the present invention are：Non-woven fabrics of the present invention not only has excellent resist with antibacterial copolymer rubber filler The effect of electrostatic, but also with the characteristic such as heat-resisting, fire-retardant, use demand with a greater variety can be met.
Embodiment
Embodiment:A kind of non-woven fabrics antibacterial copolymer rubber filler, is made up of the raw material components of following number：Superthin light Calcium carbonate 50-80, ethylene propylene diene rubber 50-80, zinc oxide 4-7, carbon powder 30-50, precipitated calcium carbonate 20-30, sodium hydroxide 16-24, borax 6-10, saltcake 4-6, talcum powder 10-12, polyimide resin liquid 5-10, alkyl-modified phenolic resin 21-41, Monoperphthalic acid 1.5-2.1, magnesium stearate 10-16, tall oil diglycollic amide 4-6, hydroxyethyl methacrylate 4- 6th, auxiliary agent 5-7, deionized water are some.
The auxiliary agent is made up of the raw material of following weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, ethylene Double oleamide 0.4-0.6, OPE 0.3-0.5, tall oil diglycollic amide 0.3-0.4, graphene oxide 0.3- 0.5th, lanolin alcohol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, polyurethane propylene Acid esters 0.3-0.5, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, two contractings Tripropylene glycol diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two In contracting tripropylene glycol diacrylate, be heated to 50-55 DEG C, stir 20-30 minutes, add magnesium stearate, di-n-octyl sebacate, The double oleamide of ethylene, OPE, tall oil diglycollic amide, graphene oxide, lanolin alcohol APEO, receive Rice titanium dioxide, polyamide wax micropowder, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, 35-40 DEG C is cooled to, other residual components is added, stirring reaction 50-60 minutes, produces.
The preparation method of described non-woven fabrics antibacterial copolymer rubber filler, it is characterised in that comprise the following steps：
(1) by superfine light calcium carbonate, ethylene propylene diene rubber, zinc oxide, carbon powder, precipitated calcium carbonate, sodium hydroxide, boron Sand, saltcake, talcum powder, polyimide resin liquid, alkyl-modified phenolic resin are added in deionized water, are stirred, 75-85 DEG C is heated to, obtains slurry；
(2) monoperphthalic acid, magnesium stearate, tall oil diglycollic amide, hydroxyethyl methacrylate are mixed, Blowing 75-85 DEG C of hot-air to it again seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, After being sufficiently mixed the two, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
Described above is only the preferred application implementation mode of the present invention, it is noted that for the common skill of the art For art personnel, without departing from the technical principles of the invention, some improvement can also be made.

Claims (2)

  1. A kind of 1. non-woven fabrics antibacterial copolymer rubber filler, it is characterised in that：It is made up of the raw material components of following number：It is ultra-fine light Matter calcium carbonate 50-80, ethylene propylene diene rubber 50-80, zinc oxide 4-7, carbon powder 30-50, precipitated calcium carbonate 20-30, hydroxide Sodium 16-24, borax 6-10, saltcake 4-6, talcum powder 10-12, polyimide resin liquid 5-10, alkyl-modified phenolic resin 21- 41st, monoperphthalic acid 1.5-2.1, magnesium stearate 10-16, tall oil diglycollic amide 4-6, hydroxyethyl methacrylate 4-6, auxiliary agent 8-10, deionized water are some.
    The auxiliary agent is made up of the raw material of following weight：The double oil of magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, ethylene Sour acid amides 0.4-0.6, OPE 0.3-0.5, tall oil diglycollic amide 0.3-0.4, graphene oxide 0.3-0.5, Lanolin alcohol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-0.5, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, two contractings 3 third Omega-diol diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two contractings three In propylene glycol diacrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds magnesium stearate, di-n-octyl sebacate, ethylene Double oleamides, OPE, tall oil diglycollic amide, graphene oxide, lanolin alcohol APEO, nanometer two Titanium oxide, polyamide wax micropowder, phosphate, 70-80 DEG C is continuously heating to after stirring, stirring reaction 30-40 minutes, is cooled To 35-40 DEG C, other residual components are added, stirring reaction 50-60 minutes, are produced.
  2. 2. the non-woven fabrics according to claim 1 preparation method of antibacterial copolymer rubber filler, it is characterised in that including Following steps：
    (1) by superfine light calcium carbonate, ethylene propylene diene rubber, zinc oxide, carbon powder, precipitated calcium carbonate, sodium hydroxide, borax, Saltcake, talcum powder, polyimide resin liquid, alkyl-modified phenolic resin are added in deionized water, are stirred, heating To 75-85 DEG C, slurry is obtained；
    (2) monoperphthalic acid, magnesium stearate, tall oil diglycollic amide, hydroxyethyl methacrylate are mixed, then to It, which blows 75-85 DEG C of hot-air, seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, makes two After person is sufficiently mixed, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
    (3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then be warming up to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
CN201710666819.5A 2017-08-07 2017-08-07 A kind of non-woven fabrics antibacterial copolymer rubber filler and preparation method thereof Pending CN107459716A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115504497A (en) * 2022-10-09 2022-12-23 陕西安东兴阳岗石科技有限公司 Preparation method and application of low-oil-absorption-value nano calcium carbonate
CN115602354A (en) * 2022-09-30 2023-01-13 江苏国嘉导体技术科技有限公司（Cn） Light aluminum alloy wire harness for automobile and processing technology thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194309A (en) * 2014-08-14 2014-12-10 青阳县吉祥塑胶有限公司 Plastic filler with high wear resistance and preparation method of plastic filler
CN104194058A (en) * 2014-08-14 2014-12-10 青阳县吉祥塑胶有限公司 Flame-retardant plastic packing and preparation method thereof
CN104592720A (en) * 2015-01-12 2015-05-06 安徽玉堂雨具有限公司 Calcium carbonate filler capable of enhancing toughness of plastic and preparation method thereof
CN104592742A (en) * 2015-01-12 2015-05-06 安徽玉堂雨具有限公司 Special filler for modified light calcium carbonate plastic and preparation method for special filler

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194309A (en) * 2014-08-14 2014-12-10 青阳县吉祥塑胶有限公司 Plastic filler with high wear resistance and preparation method of plastic filler
CN104194058A (en) * 2014-08-14 2014-12-10 青阳县吉祥塑胶有限公司 Flame-retardant plastic packing and preparation method thereof
CN104592720A (en) * 2015-01-12 2015-05-06 安徽玉堂雨具有限公司 Calcium carbonate filler capable of enhancing toughness of plastic and preparation method thereof
CN104592742A (en) * 2015-01-12 2015-05-06 安徽玉堂雨具有限公司 Special filler for modified light calcium carbonate plastic and preparation method for special filler

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115602354A (en) * 2022-09-30 2023-01-13 江苏国嘉导体技术科技有限公司（Cn） Light aluminum alloy wire harness for automobile and processing technology thereof
CN115602354B (en) * 2022-09-30 2023-08-25 江苏国嘉导体技术科技有限公司 Light aluminum alloy wire bundle for automobile and processing technology thereof
CN115504497A (en) * 2022-10-09 2022-12-23 陕西安东兴阳岗石科技有限公司 Preparation method and application of low-oil-absorption-value nano calcium carbonate

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Application publication date: 20171212