CN107459601A - A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof - Google Patents
A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof Download PDFInfo
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- CN107459601A CN107459601A CN201710729881.4A CN201710729881A CN107459601A CN 107459601 A CN107459601 A CN 107459601A CN 201710729881 A CN201710729881 A CN 201710729881A CN 107459601 A CN107459601 A CN 107459601A
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- Prior art keywords
- butyl
- material include
- drying
- acrylic resin
- methacrylate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof, including following raw material：Including A material, B material and C material, according to percentage by weight, A material include：Butyl acetate 10 20%, dimethylbenzene 15 25%；B material include：Acrylic or methacrylic acid 1 2%, methyl methacrylate or styrene 30 40%, butyl acrylate or butyl methacrylate 10 20%, hydroxy-ethyl acrylate or hydroxyethyl methacrylate 5 18%, 4 hy-droxybutyls 10 30%, benzoyl peroxide add acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 5 10%；C material include：Benzoyl peroxide adds acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 1 3%.More similar resin can substantially accelerate paint film reaction speed to car refinishing paint Hydroxylated acrylic resin produced by the present invention, hardness rises faster during drying varniss, the time is done solid work in shortening, 4h can reach polishing and require, while resin pot life, weather-proof, wear-resisting have different degrees of raising.
Description
Technical field
The present invention relates to a kind of Hydroxylated acrylic resin, specifically, is related to a kind of car refinishing paint quick-drying hydroxyl third
Olefin(e) acid resin and preparation method thereof.
Background technology
In the work progress of car refinishing paint, just the paint film constructed will wait for a period of time the ability after drying varniss
Sanding and polishing processing is carried out, is efficiently repaiied for quick service with the continuous improvement of human cost, car refinishing paint industry over time
Benefit requires more and more higher, it is desirable to which paint film energy rapid draing sanding and polishing, this paper emphasis are thought from resins synthesis technology and formula design
Road is set about, and proposes the synthetic method of car refinishing paint quick-drying acrylic resin, the poly- ammonia of car refinishing paint bi-component acrylic
Ester paint is mainly made up of Hydroxylated acrylic resin and polyisocyanates, and the species of carboxylic monomer, dosage are equal in hydroxy resin
The rate of drying of acroleic acid polyurethane coating can be influenceed in various degree, and conventional carboxylic monomer has:Hydroxy-ethyl acrylate (HEA),
Hydroxyethyl methacrylate (HEMA), hydroxypropyl acrylate (HPA), the reactivity order of these three carboxylic monomers is HEMA>
HEA>HPA, reactivity is higher, and rate of drying is faster.
It is more next to automobile repairing paint rate of drying that the Hydroxylated acrylic resin of conventional carboxylic monomer synthesis does not reach client
Faster requirement.
The content of the invention
Instant invention overcomes in the prior art the shortcomings that, there is provided a kind of car refinishing paint quick-drying Hydroxylated acrylic resin
And preparation method thereof, hence it is evident that accelerate paint film reaction speed, hardness rises faster during drying varniss, and the time is done solid work in shortening.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of car refinishing paint quick-drying Hydroxylated acrylic resin, including following raw material：Expect including A material, B material and C, according to
Percentage by weight,
The A material include：Butyl acetate 10-20%, dimethylbenzene 15-25%；
The B material include：Acrylic or methacrylic acid 1-2%, methyl methacrylate or styrene 30-40%, third
Olefin(e) acid butyl ester or butyl methacrylate 10-20%, hydroxy-ethyl acrylate or hydroxyethyl methacrylate 5-18%, 4- acrylic acid
Hydroxy butyl ester 10-30%, benzoyl peroxide add acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 5-10%；
The C material include：Benzoyl peroxide adds acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 1-3%.
Further, the A material include：Butyl acetate 10kg, dimethylbenzene 25kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 30kg, butyl acrylate 10kg, hydroxy-ethyl acrylate
15kg, 4- hy-droxybutyl 10kg and benzoyl peroxide add acyl 10kg；
The C material include：Benzoyl peroxide adds acyl 1kg.
Further, the A material include：Butyl acetate 15kg, dimethylbenzene 20kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 35kg, butyl acrylate 10kg, hydroxy-ethyl acrylate
10kg, 4- hy-droxybutyl 15kg and benzoyl peroxide add acyl 12kg；
The C material include：Benzoyl peroxide adds acyl 1kg.
Further, the A material include：Butyl acetate 20kg, dimethylbenzene 15kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 30kg, butyl methacrylate 10kg, metering system
Sour hydroxyl ethyl ester 15kg, 4- hy-droxybutyl 20kg and peroxidized t-butyl perbenzoate 10kg；
The C material include：Peroxidized t-butyl perbenzoate 1kg.
Further, the A material include：Butyl acetate 10kg, dimethylbenzene 30kg；
The B material include：Acrylic acid 1kg, styrene 35kg, butyl methacrylate 10kg, hydroxyethyl methacrylate
10kg, 4- hy-droxybutyl 30kg and di-t-butyl peroxide 10kg；
The C material include：Di-t-butyl peroxide 1kg.
A kind of car refinishing paint preparation method of quick-drying Hydroxylated acrylic resin, comprises the following steps：
1) throw A to expect in reactor, be warming up to 120-140 DEG C；
2) B material are added dropwise, time for adding 3-4 hours, temperature control is at 120-140 DEG C；
3) after being added dropwise, 2-3 hours are maintained at a temperature of 120-140 DEG C；
4) C material are added, 2-3 hours are maintained at a temperature of 120-140 DEG C；
5) 80-90 DEG C is cooled to, discharging.
Compared with prior art, the beneficial effects of the invention are as follows：
More similar resin can substantially be accelerated car refinishing paint Hydroxylated acrylic resin produced by the present invention
Paint film reaction speed, hardness rises faster during drying varniss, and shortening is done solid work the time, and 4h can reach polishing and require, simultaneously
Resin pot life, weather-proof, wear-resisting there is different degrees of raising.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of car refinishing paint quick-drying Hydroxylated acrylic resin, including following raw material：Expect including A material, B material and C, according to
Percentage by weight,
A material include：Butyl acetate 10-20%, dimethylbenzene 15-25%；
B material include：Acrylic or methacrylic acid 1-2%, methyl methacrylate or styrene 30-40%, acrylic acid
Butyl ester or butyl methacrylate 10-20%, hydroxy-ethyl acrylate or hydroxyethyl methacrylate 5-18%, 4- acrylic acid hydroxyl fourth
Ester 10-30%, benzoyl peroxide add acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 5-10%；
C material include：Benzoyl peroxide adds acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 1-3%.
Embodiment 1：
1) throw A material butyl acetate 10kg dimethylbenzene 25kg to enter in reactor, be warming up to 130 DEG C；
2) acrylic acid 1kg, methyl methacrylate 30kg, butyl acrylate 10kg, hydroxy-ethyl acrylate 15kg, 4- third are taken
Olefin(e) acid hydroxy butyl ester 10kg, benzoyl peroxide add acyl 10kg composition B material, stir, are uniformly instilled with 3h in reactor, temperature control
At 130 DEG C；
3) after being added dropwise, maintained 2 hours at 130 DEG C；
4) C material benzoyl peroxides are added and add acyl 1kg, 130 DEG C maintain 3 hours；
5) 80 DEG C are cooled to, discharging.
Embodiment 2：
1) throw A material butyl acetate 15kg dimethylbenzene 20kg to enter in reactor, be warming up to 130 DEG C；
2) acrylic acid 1kg, methyl methacrylate 35kg, butyl acrylate 10kg, hydroxy-ethyl acrylate 10kg, 4- third are taken
Olefin(e) acid hydroxy butyl ester 15kg, benzoyl peroxide add acyl 12kg composition B material, stir, are uniformly instilled with 3h in reactor, temperature control
At 130 DEG C；
3) after being added dropwise, 130 DEG C maintain 2 hours；
4) C material benzoyl peroxides are added and add acyl 1kg, 130 DEG C maintain 3 hours；
5) 80 DEG C are cooled to, discharging.
Embodiment 3：
1) throw A material butyl acetate 20kg dimethylbenzene 15kg to enter in reactor, be warming up to 135 DEG C；
2) acrylic acid 1kg, methyl methacrylate 30kg, butyl methacrylate 10kg, hydroxyethyl methacrylate are taken
15kg, 4- hy-droxybutyl 20kg, peroxidized t-butyl perbenzoate 10kg composition B material, stir, are uniformly instilled with 3h anti-
Answer in kettle, temperature control is at 135 DEG C；
3) after being added dropwise, 135 DEG C maintain 2 hours；
4) C material peroxidized t-butyl perbenzoates 1kg is added, 135 DEG C maintain 3 hours；
5) 80 DEG C are cooled to, discharging.
Embodiment 4：
1) throw A material butyl acetate 10kg dimethylbenzene 30kg to enter in reactor, be warming up to 140 DEG C；
2) acrylic acid 1kg, styrene 35kg, butyl methacrylate 10kg, hydroxyethyl methacrylate 10kg, 4- third are taken
Olefin(e) acid hydroxy butyl ester 30kg, di-t-butyl peroxide 10kg composition B material, stir, are uniformly instilled with 4h in reactor, temperature control
System is at 140 DEG C；
3) after being added dropwise, 140 DEG C maintain 2 hours；
4) C material di-t-butyl peroxides 1kg is added, 140 DEG C maintain 3 hours；
5) 80 DEG C are cooled to, discharging.
There is the bigger free degree using hydroxyl in 4- hy-droxybutyls (4-HBA) more conventional carboxylic monomer, with more isocyanides
Acid esters has faster reactivity, so as to realize the purpose of quick-drying.Experiment replaces portion from 4- hy-droxybutyls (4-HBA)
Divide conventional carboxylic monomer synthesis of hydroxy acrylic resin.
Paint film property is shown in Table 1 after embodiment 1 to the gained resin painting of embodiment 4
It is more existing that car refinishing paint Hydroxylated acrylic resin produced by the present invention can be seen that according to the comparing result of table 1
Similar resin can substantially accelerate paint film reaction speed in technology, and hardness rises faster during drying varniss, and the time is done solid work in shortening,
Simultaneously resin pot life, weather-proof have different degrees of raising.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in
Within the scope of.
Claims (6)
1. a kind of car refinishing paint quick-drying Hydroxylated acrylic resin, it is characterised in that including following raw material：Including A material, B material
Expect with C, according to percentage by weight,
The A material include：Butyl acetate 10-20%, dimethylbenzene 15-25%；
The B material include：Acrylic or methacrylic acid 1-2%, methyl methacrylate or styrene 30-40%, acrylic acid
Butyl ester or butyl methacrylate 10-20%, hydroxy-ethyl acrylate or hydroxyethyl methacrylate 5-18%, 4- acrylic acid hydroxyl fourth
Ester 10-30%, benzoyl peroxide add acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 5-10%；
The C material include：Benzoyl peroxide adds acyl or peroxidized t-butyl perbenzoate or di-t-butyl peroxide 1-3%.
A kind of 2. car refinishing paint quick-drying Hydroxylated acrylic resin according to claim 1, it is characterised in that the A material
Including：Butyl acetate 10kg, dimethylbenzene 25kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 30kg, butyl acrylate 10kg, hydroxy-ethyl acrylate 15kg,
4- hy-droxybutyls 10kg and benzoyl peroxide add acyl 10kg；
The C material include：Benzoyl peroxide adds acyl 1kg.
A kind of 3. car refinishing paint quick-drying Hydroxylated acrylic resin according to claim 1, it is characterised in that the A material
Including：Butyl acetate 15kg, dimethylbenzene 20kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 35kg, butyl acrylate 10kg, hydroxy-ethyl acrylate 10kg,
4- hy-droxybutyls 15kg and benzoyl peroxide add acyl 12kg；
The C material include：Benzoyl peroxide adds acyl 1kg.
A kind of 4. car refinishing paint quick-drying Hydroxylated acrylic resin according to claim 1, it is characterised in that the A material
Including：Butyl acetate 20kg, dimethylbenzene 15kg；
The B material include：Acrylic acid 1kg, methyl methacrylate 30kg, butyl methacrylate 10kg, hydroxyethyl methacrylate
Ethyl ester 15kg, 4- hy-droxybutyl 20kg and peroxidized t-butyl perbenzoate 10kg；
The C material include：Peroxidized t-butyl perbenzoate 1kg.
A kind of 5. car refinishing paint quick-drying Hydroxylated acrylic resin according to claim 1, it is characterised in that the A material
Including：Butyl acetate 10kg, dimethylbenzene 30kg；
The B material include：Acrylic acid 1kg, styrene 35kg, butyl methacrylate 10kg, hydroxyethyl methacrylate 10kg,
4- hy-droxybutyls 30kg and di-t-butyl peroxide 10kg；
The C material include：Di-t-butyl peroxide 1kg.
6. a kind of preparation method of car refinishing paint quick-drying Hydroxylated acrylic resin, its feature exist according to claim 1
In comprising the following steps：
1) throw A to expect in reactor, be warming up to 120-140 DEG C；
2) B material are added dropwise, time for adding 3-4 hours, temperature control is at 120-140 DEG C；
3) after being added dropwise, 2-3 hours are maintained at a temperature of 120-140 DEG C；
4) C material are added, 2-3 hours are maintained at a temperature of 120-140 DEG C；
5) 80-90 DEG C is cooled to, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729881.4A CN107459601A (en) | 2017-08-23 | 2017-08-23 | A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729881.4A CN107459601A (en) | 2017-08-23 | 2017-08-23 | A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107459601A true CN107459601A (en) | 2017-12-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710729881.4A Pending CN107459601A (en) | 2017-08-23 | 2017-08-23 | A kind of car refinishing paint quick-drying Hydroxylated acrylic resin and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627377A (en) * | 2018-12-12 | 2019-04-16 | 英德市雅家涂料有限公司 | A kind of ultrafast dry type automobile varnish hydroxy propylene acid resin and preparation method thereof |
| CN112851849A (en) * | 2021-01-12 | 2021-05-28 | 广东彤德新材料有限公司 | Air-drying water-soluble acrylic resin and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153691A (en) * | 2011-04-19 | 2011-08-17 | 广东同步化工股份有限公司 | Hydroxy acrylic resin for ultra-fast dry automobile varnish and preparation method thereof |
| CN102181007A (en) * | 2011-04-12 | 2011-09-14 | 浙江德尚化工科技有限公司 | Hydroxy acrylic resin with high reactive activity and preparation method and application thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
-
2017
- 2017-08-23 CN CN201710729881.4A patent/CN107459601A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181007A (en) * | 2011-04-12 | 2011-09-14 | 浙江德尚化工科技有限公司 | Hydroxy acrylic resin with high reactive activity and preparation method and application thereof |
| CN102153691A (en) * | 2011-04-19 | 2011-08-17 | 广东同步化工股份有限公司 | Hydroxy acrylic resin for ultra-fast dry automobile varnish and preparation method thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627377A (en) * | 2018-12-12 | 2019-04-16 | 英德市雅家涂料有限公司 | A kind of ultrafast dry type automobile varnish hydroxy propylene acid resin and preparation method thereof |
| CN112851849A (en) * | 2021-01-12 | 2021-05-28 | 广东彤德新材料有限公司 | Air-drying water-soluble acrylic resin and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171212 |
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| RJ01 | Rejection of invention patent application after publication |