CN107457158A - A kind of extruding spin coating device for coating machine - Google Patents

A kind of extruding spin coating device for coating machine Download PDF

Info

Publication number
CN107457158A
CN107457158A CN201710841901.7A CN201710841901A CN107457158A CN 107457158 A CN107457158 A CN 107457158A CN 201710841901 A CN201710841901 A CN 201710841901A CN 107457158 A CN107457158 A CN 107457158A
Authority
CN
China
Prior art keywords
extruding
spin coating
coating
smoothing roller
roller
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710841901.7A
Other languages
Chinese (zh)
Inventor
张浩合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi Ho Ho Machinery Co Ltd
Original Assignee
Shaanxi Ho Ho Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Ho Ho Machinery Co Ltd filed Critical Shaanxi Ho Ho Machinery Co Ltd
Priority to CN201710841901.7A priority Critical patent/CN107457158A/en
Publication of CN107457158A publication Critical patent/CN107457158A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/023Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface
    • B05C11/025Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface with an essentially cylindrical body, e.g. roll or rod

Landscapes

  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a kind of extruding spin coating device for coating machine, including power transmission unit, pressure regulating unit and extruding smoothing roller, extruding smoothing roller is arranged in swing arm, and overlayed in the presence of pressure regulating unit and scribbling the substrate surface of material, described extruding smoothing roller rotates under the driving of power transmission unit along the reverse direction in substrate transport direction.The present invention is further increased the contact area of material grain and substrate, adds adhesive force, improved the conductive characteristic that finished product applies carbon metal foil using the smoothing roller floating spin coating of opposite direction extruding after coating of pressure adjustable.

Description

A kind of extruding spin coating device for coating machine
Technical field
The invention belongs to electrokinetic cell/supercapacitor technologies field, and in particular to a kind of two-sided set position coating machine of pole piece, Especially a kind of extruding spin coating device for coating machine.
Background technology
Electrokinetic cell and ultracapacitor are widely used for field of new energy technologies, in electrokinetic cell and ultracapacitor The pole piece of electrode is a critical component, it usually needs functional material is coated uniformly on metal foil (copper foil or aluminium foil) by coating machine On surface.Coiled base material is sent to application to printed by the principle of common coating machine similar to intaglio press by transmission mechanism Area, functional material is coated to the specified location of substrate surface, then by drying, winding etc., the system for subsequent product Make.Thickness, uniformity, adhesion, breadth size, positional precision and the coating speed of wherein coated medium are that its measurement refers to Mark.
Chinese patent " lithium battery pole piece coating machine (201320299315.1) " discloses a kind of lithium battery pole piece coating machine, The machine is made up of unreeling device for pole piece, tension-adjusting gear, slurry coats device, drying unit and wrap-up, existing for it Problem is using conventional coating machine scheme, can not realize quick wide cut and the coating of two-sided set position, while functional material is in metal The adhesive ability of paper tinsel is not strong, has influence on the electrical parameter of pole piece.
The content of the invention
The present invention proposes a kind of extruding spin coating device for coating machine, and the metal foil finished to coating is extruded Spin coating is handled, and adds the contact area for further increasing material grain and substrate.
Technical scheme is as follows:
A kind of extruding spin coating device for coating machine, including power transmission unit, pressure regulating unit and extruding spin coating Roller, extruding smoothing roller is arranged in swing arm, and is overlayed in the presence of pressure regulating unit and scribbled the substrate surface of material, institute The extruding smoothing roller stated rotates under the driving of power transmission unit along the reverse direction in substrate transport direction.
In the above-mentioned extruding spin coating device for coating machine, swing arm includes fixing end and swinging end, and fixing end passes through rotating shaft It is actively connected in frame, extruding smoothing roller is arranged on the swinging end of swing arm, and pressure regulating unit changes the angle of oscillation of swing arm Degree so that extruding smoothing roller, which overlays, is scribbling the substrate surface of material.
In the above-mentioned extruding spin coating device for coating machine, power transmission unit includes first pulley, the second belt wheel, the 3rd Belt wheel and spin coating motor, described first pulley are arranged on the swinging end of swing arm, and the second belt wheel is arranged on the fixing end of swing arm, institute The first pulley and extruding smoothing roller stated coaxially couple, and the 3rd belt wheel and spin coating motor are arranged in frame, the driving of spin coating motor 3rd belt wheel rotates, and by the pulley rotation of belt drive second, and drives first pulley and extruding smoothing roller synchronous axial system.
In the above-mentioned extruding spin coating device for coating machine, spin coating motor is frequency control motor.
In the above-mentioned extruding spin coating device for coating machine, pressure regulating unit includes being supported in frame and matching transmission Worm gear and worm screw, described worm gear connect firmly the fixing end in swing arm, and rotated around the axis under the driving that worm screw rotates.
In the above-mentioned extruding spin coating device for coating machine, the front end of worm screw is provided with handwheel.
In the above-mentioned extruding spin coating device for coating machine, base material is metal foil.
In the above-mentioned extruding spin coating device for coating machine, extruding smoothing roller is the steel rider of chrome-faced.
The advantageous effects that the present invention has are as follows:
First, the present invention has carried out real-time online surface high pressure to base material and put before metal foil coats graphite or carbon particle Electroetching and roughening processing, it is carried in using more high voltage power supplies on electrion roller and high density is carried out to the positive and negative of base material The high-power multiple discharge processing of large area, the nano-graphite or carbon particle yardstick with coating are formd on the positive and negative surface of metal foil Suitable and equally distributed pit, therefore (ferric phosphate lithium cell positive and negative pole material is pre- for the carbon-coated aluminum foils of coating machine production or copper foil Apply;The positive and negative material precoating of lithium manganate battery;Electrode of super capacitor coating:Ternary material battery electrode coating) can provide it is splendid Static conductive performance, the micro-currents of active goods and materials is collected, so as to which the contact between positive and negative pole material and afflux be greatly lowered Resistance, and can improve between the two adhesive ability (adhesive ability than it is conventional without discharging surface processing surface improve 5 times with On), the usage amount of adhesive can be reduced, and then the overall performance of battery is produced huge lifting, that is, suppress battery polarization, subtract Few fuel factor, improve high rate performance;The internal resistance of cell is reduced, and significantly reduces the dynamic internal resistance amplification of cyclic process battery core, is carried High uniformity, the cycle life of battery is significantly increased;The adhesion of active goods and materials and collector is improved, pole piece is reduced and is manufactured into This;Protect collector not by electrolytic corrosion;Improve the processing characteristics of LiFePO 4 material.
2nd, the present invention added after coating station extruding spin coating device, using pressure adjustable smoothing roller after coating Opposite direction extrudes floating spin coating, further increases the contact area of material grain and substrate, adds adhesive force, improves finished product painting The conductive characteristic of carbon metal foil.
3rd, the present invention is based on electrion surface treatment, multilevel tensions control, segmentation cascade baking, multistage correction, material grain The core technology such as floating is extruded, the present invention realizes breadth 1.5m, operating rate 150m/min, the aluminium for covering position precision ± 0.3mm Paper tinsel and the coating of copper foil positive and negative, in the manufacture that can be widely used for electrokinetic cell/super-capacitor pole piece, for developing hybrid power The rechargeable battery of car and electric automobile, and electric power storage rechargeable battery of wind-power electricity generation and solar power generation etc. have important work With.
Brief description of the drawings
Fig. 1 is the topology layout figure of coating machine of the present invention;
Fig. 2 is the theory of constitution schematic diagram of coating machine of the present invention;
Fig. 3 is the principle schematic of electrion processing unit of the present invention;
Fig. 4 is the principle schematic of electrion processing unit of the present invention;
Fig. 5 is the principle schematic of tenslator of the present invention;
Fig. 6 is big little gear mesh schematic representation in tenslator of the present invention;
Fig. 7 is principle of moment balance schematic diagram in tenslator of the present invention;
Fig. 8 is the principle schematic of present invention extruding spin coating device;
In figure:1-unwinding unit;2-tension sensor;3-electrion processing unit;4-the first deviation correcting device; 5-metal foil;6-transfer roller;7-the first tension control units;8-front coating and printing unit;9-front apparatus for coating; 11-front vertical drying passage;The horizontal drying channel in 12-front;16-the second deviation correcting device;17-the second tension force list Member;18-reverse side coating and printing unit;19-reverse side apparatus for coating;21-reverse side vertical drying passage;The horizontal baking of 22-reverse side Dry passage;23-live-roller;27-the three tension control units;28-the three deviation correcting device;30-the four deviation correcting device;31— Electrion processing unit;41-rolling unit;42-floating roller unit;43-positive spin coating device;44-reverse side spin coating device; 51-lower drying tunnel;52-go up drying tunnel;55-support base;56-steelframe;58-ground;701-drive roll;702-motor; 703-little gear;704-gear wheel;705-cylinder;706-piston rod;707-swing rod;708-pendulum roller;709-current potential Device;710-control axis;711-air accumulator;The rotating shaft of 712-potentiometer;715-go up transfer roller;716-lower transfer roller;81-air-out Mouthful;82-high pressure casing;83-sparking electrode;84-air-flow;85-electrion roller;86-electric arc;901-conducting medium thing Material;902-coating roller;903-scraper;904-impressing rubber roll;905-first pulley;906-extruding smoothing roller;907— Spin coating motor;908-belt;909-swing arm;911-worm gear;912-worm screw;913-handwheel;914-smoothing roller rotation side To;915-the second belt wheel;916-swing arm swaying direction;925-the three belt wheel;920-fixing end;921-swinging end; 923-rotating shaft.
Embodiment
Electrokinetic cell/ultracapacitor with the two-sided set position coating machine of wide cut pole piece be by scattered conductive nano graphite and Carbon coating grain uniformly, fine and smooth ground, front reverse side position correspondence, be disposably coated on aluminium foil or copper foil, in the power of Large Copacity The high electrical power storage equipment such as battery, super bulky capacitor, particularly requires that the charging interval is short, electrical power storage amount is big, has extended cycle life Electrokinetic cell/ultracapacitor have tremendous skill upgrading.
As shown in figure 1, the coating machine of the present invention includes being laid in lower drying tunnel 51, upper drying tunnel 52 and the cloth above frame structure Put unwinding unit, rolling unit, electrion processing unit 3, front apparatus for coating 9 and the reverse side coating below frame structure Device 19, frame structure include steelframe 56 and some support bases 55 for being supported on ground 58, wherein unwinding unit, rolling unit, Electrion processing unit 3 is arranged on the space between support base 55.This space have the advantage that heavier-weight and The unwinding unit, rolling unit, electrion processing unit 3 of manual operation intervention is needed to be placed on the ground below framework, And the lower drying tunnel 51 of lighter in weight, upper drying tunnel 52 are placed on above framework, and lower drying tunnel 51 and upper drying tunnel 52 are according to base material Overlapping placement is moved towards, has saved space, facilitates operation.In addition front apparatus for coating 9 and reverse side apparatus for coating 19 then depend on branch Support seat 55 is fixed, and the base material between disparate modules and device rides in transition and fixation on support base 55, facilitates these portions Being fixedly connected between part and structure and framework, an entirety is become, and simplify system architecture.
As shown in Fig. 2 whole coating machine includes control unit and unreels list along what metal foil transmission direction was set gradually Member 1, electrion processing unit 3, front apparatus for coating 9, lower drying tunnel 51, reverse side apparatus for coating 19, upper drying tunnel 52 and winding are single Member 41, and some transfer rollers 6.
First, unwinding unit
Unreeling wheel acts on driving metal foil 5 in magnetic powder brake to deploy, and tension sensor 2 is provided with metal foil 5, Magnetic powder brake on force controller 2 and unreeling wheel forms closed-loop control, it is ensured that the tension force of metal foil 5 keeps constant, and can be with It is manually set.The first deviation correcting device 4 is also provided with the opening position of unwinding unit 1 of metal foil 5, is detected using ultrasonic wave electric eye, Realize that metal foil 5 runs pilot process correction, ensure that lateral attitude is consistent when metal foil 5 is coated with.Wherein metal foil is maximum It is φ 700mm to unreel straight warp, and the fixed single-station that can carry out upper and lower uncoiling unreels.
2nd, electrion processing unit
Electrion processing is that the present invention is different from one of main points of traditional pole piece coating machine, traditional pole piece coating machine one As will base material carry out cleaning treatment after be directly coated, also have using sided corona treatment.Sided corona treatment is that its principle is to utilize height Frequency high voltage produces low temperature plasma in processed frosting corona discharge, frosting is produced free radical React and crosslink polymer surfaces are roughening and increase its wetability to polar solvent, and these gas ions are by shocking by electricity With penetrate into by its molecular structure of the surface breakdown of print body, and then will be processed surface molecular oxidation and polarization, ion-conductance Erosion surface is hit, so that increasing the adhesive ability on stock surface, is mainly used in the surface treatment of silicon rubber, plastic basis material.
The present invention is provided with electrion processing links before printing process, the method punctured using electrion, and one Aspect causes the grease of metal foil surface to gasify, and serves the effect of cleaning, at the same air ionization caused by sparking electrode, with And under ozone caused by ionization and oxygen atom effect, the surface of metal foil is etched and roughening is handled so that metal foil To form and equally distributed pit, coated media suitable with the nano-graphite or carbon particle yardstick coated easy on positive and negative surface It is embedded in inside pit, and is combined closely with substrate, improve contact area and adhesive force, is reducing the bar of adhesive usage amount Under part, the contact resistance between medium and substrate is reduced, the charge-discharge characteristic of battery can be improved.
As shown in Figure 3 and Figure 4, electrion processing unit of the invention is included in what positive and negative two surfaces of metal foil were set More electrion processing units 31, every unit include high pressure casing 82, negative pressure extractor fan, high-voltage power supply and some electric discharges Electrode 83, sparking electrode 83 is arranged in an axially parallel mode the circumference in electrion roller 85 along electrion roller 85, and is protected with metal foil 5 Certain spacing is held, sparking electrode 83 produces electric arc 86 and acted on to metal foil 5.Sparking electrode 83 is arranged on inside high pressure casing 82 Front end, the rear end of high pressure casing 82 is provided with negative pressure air outlet 81, and air outlet 81 is connected with the negative pressure extractor fan of outside. 1-2 group electrion processing units can be put around a usual electrion roller 85, every group of electrion processing unit then wraps Include 2-6 sparking electrode 83.
In order to meet that the effect of etching and roughening processing is formed on the surface of metal foil 5, it usually needs in same height The pressure surrounding of discharge roller 85 sets more sparking electrodes 83, and these sparking electrodes 83 can produce substantial amounts of heat in electrion, such as These heat of fruit can not be discharged instantaneously, then metal foil surface can be caused to produce higher temperatures liter, and metal foil physical property becomes because of annealing Change.Generally for big heat radiating using water-cooling pattern, i.e., some pipelines are processed inside electrion roller 85 and are passed through Cold water, heat caused by electrion roller 85 are conducted by metal foil and metal high voltage discharge roller 85 and taken away by water, this mode The heat of electrion can be effectively reduced, but can not meet that electrokinetic cell/ultracapacitor applies carbon technological requirement, because After discharge roller 64 is passed through frozen water, roll body surface causes metal foil 5 because of the meeting precooling condensation frosting of temperature difference roll body surface Surface produces water smoke, and applies in carbon technique using aqueous medium material, meets water performance change after the meeting, influences coating quality. In addition in the 85 inside water flowing of electrion roller, dynamic balancing when electrion roller 85 rotates is influenced whether, causes rotary speed unstabilization, The uniformity of coating is had influence on, therefore can only be by the way of air-cooled.
In order to meet the air-cooled of big heat, the present invention uses powerful negative pressure extractor fan, the connection of negative pressure extractor fan On the air outlet 81 of the rear side of high pressure casing 82, while the gap setting of electrode and metal foil is 2-4mm, preferably 3mm, only this Sample just can guarantee that the air-flow 84 of big flow walks the torrid zone, reach the purpose of cooling, meanwhile, the effect of the air of big flow in high pressure Lower ionization effect is strengthened, and generates more ozone and oxygen atom, be etched so as to the surface strengthened to metal foil and Roughening processing.In addition electrion roller 85 is made of aluminum alloy surface spraying oxidation-resistant ceramic, has high temperature resistant and antifriction Characteristic is damaged, prolonged electrion is born and still keeps original transmission accuracy.The metal foil needs that electrion is disposed Enter the coating link of next step as early as possible, after preventing metal foil especially aluminium foil exposed in atmosphere can Quick Oxidation into three oxidations Two aluminium, influence inner resistance.
The present invention uses ceramic electrode of the length for 600mm-1200mm, and the mean power loaded on every electrode is 1- The gap of 2kW, electric voltage frequency 10-20KHz, electrode and metal foil is 2-4mm, and metal foil walks to expect that speed is 50m/min- 180m/min, a diameter of 320mm of electrion roller, 4-12 electrode, whole coating machine are set on every electrion roller 85 The upper electrion roller 85 that positive and negative quantity half and half is set.Wherein discharge power, electrode radical and delivery speed and spraying carbon The diameter of grain is related, and in the case of structure determination, different delivery speed and different chis can be met by adjusting discharge power The spraying requirement of very little carbon particle.
By before and after HIGH PRESSURE TREATMENT aluminium foil surface brush dyne water gaging surface tension, micro- sem observation material surface with And measurement applies the internal resistance of product after carbon, the results showed that:
(1) aluminium foil after electrion is handled observes that its surface generates average dimension about under the microscope 50nm -500nm pit and salient point, it is substantially suitable with the carbon particle yardstick of coating, and it is loaded onto the electricity of electrode by changing Pressure, thus it is possible to vary the yardstick of pit and salient point, so as to the carbon particle material suitable for different-diameter.
Mechanism caused by this pit and salient point not yet learns that simply conjecture is due to that heat is burnt caused by high-voltage arc at present Under pit caused by erosion, plasma attack, or ozone and oxygen atom effect caused by oxygen ionization so that original aluminium foil The alundum (Al2O3) of surface compact is reduced into no longer fine and close aluminium, and then is rendered as bowl configurations under the microscope, it is also possible to It is that two kinds of effects be combined with each other.
(2) by brushing the aluminium foil that dyne water gaging is handled without electrion and the aluminium foil handled by electrion, its Surface tension is improved to 50gf by average 10gf, improves 5 times.
(3) using same process carbon-coated aluminum foils product made of identical equipment, by electrion handle product internal resistance It is decreased to more than 1/3 of the product without electrion processing, internal resistance is close to zero under limiting case, and the discharge and recharge of battery is special Property is significantly increased.
(4) using same process carbon-coated aluminum foils product made of identical equipment and identical electrion handling process, point The granularity D50 of nano-graphite and CNT, wherein Nano graphite powder is not coated with<400nm, and the caliber of CNT about 2- 5nm, length are 10-20 μm, the results showed that, the internal resistance of nano-graphite product will be much smaller than CNT, and analysis reason is, receives The pit of rice graphite particle and aluminium foil surface is basically identical, can be very good to be embedded in the inside of pit, forms carbon and substrate aluminium Close contact, effectively reduce internal resistance;Although and CNT particle mean size be hundred nanometers, due to length direction beyond The yardstick of pit, caliber is much smaller than the yardstick of pit again, it is difficult to the pit for being embedded in aluminium foil surface is internally formed close contact, therefore The internal resistance of product is relatively large.
3rd, apparatus for coating
Apparatus for coating includes middle correction unit, tension control units, coating and printing unit and extruding spin coating unit, is applying Need to carry out middle correction and tension force before cloth printing element.
(1) correction unit among
Material needs to carry out middle correction and tension force before coating and printing unit.Centre correction unit is using ultrasound Ripple electric eye detector, metal foil are rectified a deviation among the double roller into before being coated with, and it is permanent to ensure that material enters painting process front position It is fixed, and ensure that metal foil is wrinkle resistant during correction.Wherein the first deviation correcting device realizes the base material entirety before discharge process Correction, it is ensured that the uniformity of lateral attitude when view picture metal foil high pressure is surface-treated;There is provided second before the coating of front to entangle Deflection device, it is ensured that material lateral attitude is with being coated with the constant of roller position during the coating of front;The is provided with before reverse side coating Three deviation correcting devices, it is ensured that the stability of material lateral attitude and coating roller position when reverse side is coated with;Set before winding 4th deviation correcting device, it is ensured that the regularity of finished product end face after winding.The required precision transmitted according to metal foil, it can be set more Correction unit among group.
(2) tension control units
The purpose of tension control units is that the tension force for realizing metal foil in whole coating process keeps constant and lateral attitude It is stable, particularly in positive and negative coating process, the printing coating only under constant-tension, metal foil surface printing could be ensured The uniformity and uniformity of material, it finally ensure that the uniformity and stability of the painting carbon metal foil conductive characteristic prepared.
The present invention multigroup tension control units are provided with link is coated with, wherein the first tension control units be arranged on into Before material traction is coated with front, it is ensured that material tension is constant stable with lateral attitude during the coating of front;Second tension force Unit is arranged on before discharging traction, it is ensured that the stabilization and lateral attitude stability of reverse side coating tension force.Additionally winding The 3rd tension control units are provided with before, it is ensured that the tension stability of finished product after winding.According to the transmission precision of metal foil It is required that link and similar tension control units can also be set in other intermediate links unreeling, feeding traction, it is ensured that whole Constant tension and base material lateral attitude in process is stable.
As illustrated in figs. 5-7, tension control units of the invention include drive roll 701, gear wheel 704, swing rod 707, pendulum roller 708th, cylinder 705, potentiometer 709 and control axis 710.When usually working, metal foil 5 along drive roll 701, upper transfer roller 715, pendulum The signal direction sequential advancement of roller 708 and lower transfer roller 716, drive roll 701 are driven by motor 702, or are passed through by motor same Step band driving drive roll 701 rotates.Core component is a swing rod 707 vertically, and pendulum roller 708 is then fixed on swing rod 707 lower end.The upper end of swing rod 707 is fixed together with gear wheel 704, and can be along the axis swing of gear wheel 704;Cylinder 705 are fixed on support, and the piston rod 706 of cylinder 705 is fixed on the middle part of swing rod 707 by hinges, with swing rod 707 Oscillating-piston bar 706 it is flexible.
Potentiometer 709 is installed, the spindle nose of potentiometer rotating shaft 712 is provided with little gear on the correspondence position of gear wheel 704 703, gear wheel 704 and the parameter of little gear 703 are matched and are intermeshed, and when swing rod 707 is swung, drive gear wheel 704 to rotate One less angle, while drive little gear 703 to rotate a larger angle, cause the resistance variations of potentiometer 709.
The effect of little gear 703, gear wheel 704 and swing rod 707 be an angle enlargement and measure effect, swing rod 707 Minor variations angle, by the amplification of big little gear, be reflected in the resistance variations of potentiometer 709.
As shown in fig. 7, during real work, the tension force of metal foil can act on to pendulum roller 708 formed pulling force F2 to putting roller and F3, and cylinder can produce F1 pulling force when negative pressure works to swing rod 707, wherein F1 and F2, F3 are in opposite direction.In poised state When, swing rod 707 vertically downward when, F1 and F2+F3 holding torques balance, the resistance parameter at this moment recording potentiometer 709 is R, one The tension force of denier metal foil 5 becomes big suddenly, i.e. F2+F3 becomes big, then the equalising torque on swing rod 707 is destroyed, and swing rod 707 is inverse around the shaft Hour hands rotate, and deviate upright position, while after the angle enlargement by big little gear, the resistance R changes of potentiometer 709, it is assumed that Resistance R becomes big, then control axis 710 is according to the input electrical parameter of resistance R increase amplitude regulation motor 702 so that motor 702 Output speed increase, drive roll 701 consequently also rotating speed increase, be released into pendulum roller in more metal foils 5 of increased moment On 708, then putting roller 708 can overcome F2 and F3 effect to recover to equilbrium position, while potentiometer 709 under F1 pulling force effect Resistance revert to R, control axis 710 can the output speed of motor 702 recover to conventional parameter, so as to keep metal foil Constant tension.Vice versa, that is to say, that after the change of tension force is acted on by the angle enlargement of swing rod and size dimension, instead The change of potentiometer resistance is fed to, is further compensated by adjusting the rotating speed of motor so that the tension force of metal foil begins Keep eventually constant.
It should be noted that the cylinder 705 of the present invention is connected with air accumulator 711, the output pressure F1 of air accumulator 711 can The change of pressure is realized by the parameter of the change pressure regulating valve of control axis 710, meets the needs of different metal foil tension.This Outside, due to the limited angle that gear wheel 704 rotates, half gear structure can also be used;Cylinder 705 uses low rubbing cylinder, living Resistance can be neglected during plug is mobile.Whole coating machine is provided with some groups of tension control mechanisms, before being respectively used to coating, winding it is preceding etc. The tension force of multiple links.
(3) coating and printing unit
As shown in figure 8, graphite or carbon particle are mainly passed through gravure printing roller even spread by the coating and printing unit of the present invention On two surfaces of metal foil, by the way of intaglio plate coating, the printing figure that intaglio plate is carved with the roll body of roller 902 is coated with Case, coating roller 902 is immersed in the conducting medium material 901 of liquid, during operating by conducting medium material sticks on roll body, warp Scraper 903 hangs unnecessary material, with impressing rubber roll 904 by the even spread of conducting medium material 901 on metal foil.
Impressing rubber roll 904 uses ethylene propylene diene rubber, and 75~80 ° of its Shao Er hardness, roller structure is swing arm structure, pendulum There is the long compensation deflector roll of material on arm simultaneously so that smaller in the length change of motion process material.Scraper 903 has enough thickness and width Degree, is pressurizeed using Pneumatic floating, and adjustable with three-dimensional.Conducting medium material 901 be graphite, carbon particle, CNT, Graphene etc. mixes the sticky liquid material formed after bonding agent and water.
(4) spin coating unit is extruded
The present invention is provided with extruding spin coating unit, and medium is more uniform after the purpose of spin coating is to ensure that coating, passes through extruding Process, medium material grain are pressed into the pit of material surface, and adhesive force is stronger.As shown in Fig. 2 the present invention in coating machine in positive and negative Positive spin coating device 43 and reverse side spin coating device 44 are added after coating respectively, is added in the case where material grain is also without drying Press it is floating, further increase material grain and substrate contact area, reduce the internal resistance of finished product, improve product quality.
As shown in figure 8, the core of present invention extruding spin coating device is the extruding smoothing roller 906 of a high-speed rotation, and Power transmission unit and pressure regulating unit.Extrude smoothing roller 906 to be arranged in swing arm 909, overlayed with certain pressure firm The surface of metal foil 5 of coated conducting medium material, and under power drive along the direction opposite with the direction of advance of metal foil 5 Rotate.
Power transmission unit includes spin coating motor 907, first pulley 905, the second belt wheel 915, the 3rd belt wheel 925 and corresponding Belt 908, wherein extruding smoothing roller 906 be arranged on the swinging end 921 of swing arm 909, the fixing end 920 of swing arm passes through rotating shaft 923 are actively connected in frame, and the spin coating motor 907 being fixed in frame drives the 3rd belt wheel 925 to rotate, and passes through belt drive Second belt pulley 915 and the first belt pulley 905 rotate, and the first belt pulley 905 and extruding smoothing roller 906 coaxially couple and synchronously turned Dynamic, wherein spin coating motor 907 uses frequency control motor, can adjust rotating speed according to material difference.
Pressure regulating unit includes worm gear 911 and worm screw 912, wherein worm gear 911, the first belt pulley 905 and extruding spin coating Roller 906 is arranged in swing arm 909, and worm gear 911 connects firmly the fixing end 920 in swing arm 909, and the driving rotated in worm screw 912 Under can with around the shaft 923 rotate.Worm screw 912 is fixed in frame, and the front end of worm screw is provided with handwheel 913, rotates handwheel 913, The concomitant rotation of worm screw 912, and worm gear 911 is driven around axis rotation so that the swing arm swaying direction 916 along figure of swing arm 909 is swung Certain angle, at this moment extrude smoothing roller 906 and then overlay on the surface of metal foil 5, and pressure can be adjusted by handwheel 913 Section, after regulation again the self-locking of worm and gear push try hard to keep hold it is constant.
Since so, extruding smoothing roller 906 is overlayed on the surface of metal foil 5 and run at high speed with certain pressure, and spin coating Roller rotation direction 914 and the direction of advance of metal foil 5 are on the contrary, therefore floating by coated material and be compacted handle in electrion In the pit arrived, the contact area of material grain and substrate is further increased, reduces the internal resistance for applying carbon metal foil product.
Smoothing roller 906 is extruded using chrome-faced after 45# steel modifier treatment, coating is sufficiently thick, and maximum line velocity reaches 150m/min, the regulation of pressure and rotating speed can be achieved, meet the needs of different clothes.
The painting process of the present invention includes obverse and reverse, and it is coated with principle and structural parameters are consistent.
4th, drying tunnel
In order to realize spraying after product rapid shaping, it is necessary to carry out baking processing to the product after coating.Drying tunnel uses The concrete scheme of gradient increased temperature and gradient cooling, every drying tunnel are made up of more piece baking oven, real under conditions of continuous high speed production Show gradient increased temperature and the cooling of coated substrate, overcome the wrinkle of the prominent cold belt of the prominent heat of metal foil, it is ensured that product quality, And it ensure that continuous high speed is uninterruptedly coated with production.
As illustrated in fig. 1 and 2, drying tunnel is divided into drying tunnel 52 and lower drying tunnel 51.Lower drying tunnel 51 is used for the first of front coated product Step drying, upper drying tunnel 52 is then for front coated product and reverse side coated product thorough drying.
Lower drying tunnel 51 includes the horizontal drying channel 12 of front vertical drying passage 11 and some fronts, every drying channel length About 2-5 rice is spent, it is real under conditions of coating machine continuous production by the way of the blowing of electric heating exchanger combination high pressure positive blower Temperature-gradient method and cooling of the metal foil from 40 DEG C of -120 DEG C of -200 DEG C -100 DEG C-normal temperature are showed.Temperature control uses PID (ratios-product Point-derivative controller) automatic temperature-controlled mode, it is ensured that accuracy of temperature control reaches 1 DEG C.
Same principle, upper drying tunnel 52 then include reverse side vertical drying passage 21 and the horizontal drying channel 22 of some reverse side, often Drying channel length about 2-5 rice, by the way of the blowing of electric heating exchanger combination high pressure positive blower, in coating machine continuous production Under conditions of, realize temperature-gradient method and cooling of the metal foil 5 from 40 DEG C -100 DEG C -150-200 DEG C -100 DEG C-normal temperature.Temperature control By the way of PID (proportional-integral derivative controller) is automatic temperature-controlled, it is ensured that accuracy of temperature control reaches 1 DEG C.
The mode of temperature control under conditions of continuous high speed production, overcomes the prominent cold belt of the prominent heat of metal foil 5 step by step above Wrinkle, it is ensured that product quality, and ensure that continuous high speed is uninterruptedly coated with production.
Traditional double-face spray painting drying tunnel is typically suspended in drying tunnel due to meeting dual oven simultaneously using metal foil 5 Both ends, live-roller is avoided to contact some coating surface when being made, the tension force of metal foil is inconsistent when this mode causes to toast, Coating material baking after-contraction is inconsistent and quality occur uneven.Instant invention overcomes disadvantage mentioned above, the metal after coating Paper tinsel whole tension support in drying tunnel.Either upper drying tunnel 52 or all built-in live-roller of lower drying tunnel 51, by timing belt and outside Portion's power is connected and is driven, and bearing is placed in outside baking oven.Drying tunnel 51 is wherein descended to be only used for preliminary baking when front is coated with, really Protect that carbon particle bonding is substantially firm, and live-roller is supported on reverse side during baking, front coating will not be had an impact;Upper drying tunnel 52 is then For front coated product and reverse side coated product thorough drying, live-roller, which is supported on, during baking has already passed through preliminary baking Front.The live-roller of drying tunnel is mirror roller, and steel surface chromium plating is simultaneously processed by super grinding, and finish 0.8, mirror roller adds Work precision is high, frictional force is small, and damage of the roll body surface to material can be avoided in transmission, reduces wrinkle, meets precision drive It is required that.Supported during baking using mirror roller, avoid the tension force uneven influence to product when toasting that suspends.High temperature drying combines cold But wind, it is ensured that the uniformity of product, while drying tunnel superposition is set up and down, can greatly save space, reduces manufacturing cost.
5th, rolling unit
The traction of rolling unit 41 is using a pair of steel riders and rubber roll to pressure relative rolling type traction, steel roller faces chromium plating.Rubber roll Press and separate using pneumatic control, commutated by solenoid directional control valve, the pressure of both ends cylinder can show and adjust.Unreel Traction electric machine uses floating roller tension force, and cornerite of the metal foil in floating roller is very big, and floating roller uses surface anodization aluminium roller.Mesh The preceding a diameter of φ 750mm of maximum rewinding accomplished.
The coating process flow of the present invention is as follows:
Metal foil uncoiling → integral error correcting and position → electrion processing → charging traction → middle correction → front coating → even Glue is floating → and drying → cooling → middle correction → middle correction → reverse side coating → spin coating is floating → drying → cooling → centre Correction → winding traction → winding.
The major parameter of high-speed broad-width coating machine is as follows at present:
(1) set type arrangement is coated with, overall type top-bottom layout, comprising two printing stations, one unreels station, one Wind station;
(2) drying tunnel is divided into baking oven and lower baking oven, and heat drying mode is that electric energy changes Hot-blast Heating;
(3) base material is adapted to:8um-40um duralumin paper tinsel, 8um-15um copper foil and other metal foils;
(4) highest delivery speed:180m/min (is determined) according to coating and material;
(5) alignment precision:Positive and negative laterally covers position:±0.3mm;Positive and negative longitudinal sleeve position:±0.3mm;
(6) maximum gauge is unreeled:φ700mm;Wind maximum gauge:φ750mm;Base material Breadth Maximum 1.5m;
(7) coating type:Solvent-borne type or water paint.
Described above is only the preferred embodiment of the present invention, it should be pointed out that:For the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (8)

  1. A kind of 1. extruding spin coating device for coating machine, it is characterised in that:Including power transmission unit, pressure regulating unit and Smoothing roller (906) is extruded, extruding smoothing roller (906) is arranged in swing arm (909), and is overlayed in the presence of pressure regulating unit The substrate surface of material is being scribbled, described extruding smoothing roller (906) is under the driving of power transmission unit along substrate transport side To reverse direction rotate.
  2. 2. the extruding spin coating device according to claim 1 for coating machine, it is characterised in that:Described swing arm (909) Including fixing end (920) and swinging end (921), fixing end (920) is actively connected in frame by rotating shaft (923), and extruding is even Rubber roll (906) is arranged on the swinging end (921) of swing arm (909), and pressure regulating unit changes the swing angle of swing arm (909), So that extruding smoothing roller (906) overlays and is scribbling the substrate surface of material.
  3. 3. the extruding spin coating device according to claim 2 for coating machine, it is characterised in that:Described power transmission list Member includes first pulley (905), the second belt wheel (915), the 3rd belt wheel (925) and spin coating motor (907), described first pulley (905) swinging end (921) of swing arm (909) is arranged on, the second belt wheel (915) is arranged on the fixing end (920) of swing arm (909), Described first pulley (905) and extruding smoothing roller (906) coaxially couples, and the 3rd belt wheel (925) and spin coating motor (907) are set In frame, spin coating motor (907) drives the 3rd belt wheel (925) to rotate, and the second belt pulley (915) is driven by belt (908) Rotate, and drive first pulley (905) and extruding smoothing roller (906) synchronous axial system.
  4. 4. the extruding spin coating device according to claim 3 for coating machine, it is characterised in that:Spin coating motor (907) is Frequency control motor.
  5. 5. the extruding spin coating device according to claim 2 for coating machine, it is characterised in that:Described pressure regulation is single Member is included being supported in frame and the worm gear (911) of pairing transmission and worm screw (912), described worm gear (911) are connected firmly in swing arm (909) fixing end (920), and (923) rotate around the shaft under the driving that worm screw (912) rotates.
  6. 6. the extruding spin coating device according to claim 5 for coating machine, it is characterised in that:The front end of worm screw (911) It is provided with handwheel (913).
  7. 7. the extruding spin coating device according to claim 1 for coating machine, it is characterised in that:Described base material is metal Paper tinsel (5).
  8. 8. the extruding spin coating device according to claim 1 for coating machine, it is characterised in that:Extrude smoothing roller (906) For the steel rider of chrome-faced.
CN201710841901.7A 2017-09-18 2017-09-18 A kind of extruding spin coating device for coating machine Pending CN107457158A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710841901.7A CN107457158A (en) 2017-09-18 2017-09-18 A kind of extruding spin coating device for coating machine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710841901.7A CN107457158A (en) 2017-09-18 2017-09-18 A kind of extruding spin coating device for coating machine

Publications (1)

Publication Number Publication Date
CN107457158A true CN107457158A (en) 2017-12-12

Family

ID=60552597

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710841901.7A Pending CN107457158A (en) 2017-09-18 2017-09-18 A kind of extruding spin coating device for coating machine

Country Status (1)

Country Link
CN (1) CN107457158A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108943852A (en) * 2018-08-10 2018-12-07 芜湖三华包装科技有限公司 A kind of carton production paperboard bonding device
CN108973210A (en) * 2018-08-10 2018-12-11 芜湖三华包装科技有限公司 A kind of binding appts for carton processing
CN115318542A (en) * 2022-08-10 2022-11-11 成都中建材光电材料有限公司 Wet film coating equipment for solar cell
CN115970993A (en) * 2023-01-06 2023-04-18 广东聚德机械有限公司 Combined coating equipment and coating method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203664130U (en) * 2014-01-10 2014-06-25 瑞安市皓宇机械有限公司 Glue uniformizing mechanism of coating machine
CN205012148U (en) * 2015-08-13 2016-02-03 福建省晋江优兰发纸业有限公司 Thin paper surface gluing system
CN205436224U (en) * 2015-12-31 2016-08-10 上海兰庆新材料技术股份有限公司 Even rubber roll device and cisoid reticulation coating unit
CN205949224U (en) * 2016-07-13 2017-02-15 蔡蔚珍 Glue -even device
CN207204501U (en) * 2017-09-18 2018-04-10 陕西浩合机械有限责任公司 A kind of extruding spin coating device for coating machine

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203664130U (en) * 2014-01-10 2014-06-25 瑞安市皓宇机械有限公司 Glue uniformizing mechanism of coating machine
CN205012148U (en) * 2015-08-13 2016-02-03 福建省晋江优兰发纸业有限公司 Thin paper surface gluing system
CN205436224U (en) * 2015-12-31 2016-08-10 上海兰庆新材料技术股份有限公司 Even rubber roll device and cisoid reticulation coating unit
CN205949224U (en) * 2016-07-13 2017-02-15 蔡蔚珍 Glue -even device
CN207204501U (en) * 2017-09-18 2018-04-10 陕西浩合机械有限责任公司 A kind of extruding spin coating device for coating machine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108943852A (en) * 2018-08-10 2018-12-07 芜湖三华包装科技有限公司 A kind of carton production paperboard bonding device
CN108973210A (en) * 2018-08-10 2018-12-11 芜湖三华包装科技有限公司 A kind of binding appts for carton processing
CN115318542A (en) * 2022-08-10 2022-11-11 成都中建材光电材料有限公司 Wet film coating equipment for solar cell
CN115970993A (en) * 2023-01-06 2023-04-18 广东聚德机械有限公司 Combined coating equipment and coating method

Similar Documents

Publication Publication Date Title
CN107611350A (en) Electrokinetic cell and the ultracapacitor two-sided set position coating machine of wide cut pole piece
CN207204501U (en) A kind of extruding spin coating device for coating machine
CN107457141B (en) Device for coating graphene on surface of metal foil
CN107457158A (en) A kind of extruding spin coating device for coating machine
CN207325175U (en) A kind of device in metal foil surface coating graphene
CN108199005B (en) Rolling method and equipment for battery pole piece
JP3953911B2 (en) Method for producing coating sheet
CN107634178A (en) Electrion processing unit for metal foil surface processing
CN107342394B (en) Double-sided continuous coating equipment and coating method for lithium ion battery
CN207872532U (en) A kind of lithium battery pole piece coating machine
WO2017008290A1 (en) Device and method for coating secondary battery electrode sheet
CN207217662U (en) Electrion processing unit for metal foil surface processing
CN207204524U (en) A kind of unicoater drying unit
CN207572457U (en) Power battery and the ultracapacitor two-sided set position coating machine of wide cut pole piece
CN216500419U (en) Pole piece drying device and coating device
CN216404518U (en) Metallized film coating device with protection function
JP3851195B2 (en) Battery electrode manufacturing drying apparatus and battery electrode manufacturing method
CN207209533U (en) The tenslator amplified based on swing rod and gear
KR102137656B1 (en) One side or double side coating equipment for manufacturing coating separator for middle or large sized secondary battery of electric vehicle or energy storage system
JP2011048912A (en) Lithium ion secondary battery electrode, and coater for electrode mixture
CN111370719A (en) High-conductivity bipolar plate for flow battery and continuous processing device and method thereof
KR20200088533A (en) Electrode manufacturing equipment for rechargeable battery
JPH11329416A (en) Manufacture of sheet electrode
CN106521393B (en) A kind of coating production and device based on spark discharge
JP5782927B2 (en) Powder molding apparatus and method for producing powder molded sheet

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171212

RJ01 Rejection of invention patent application after publication