CN107456320A - A kind of high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper - Google Patents
A kind of high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper Download PDFInfo
- Publication number
- CN107456320A CN107456320A CN201710847919.8A CN201710847919A CN107456320A CN 107456320 A CN107456320 A CN 107456320A CN 201710847919 A CN201710847919 A CN 201710847919A CN 107456320 A CN107456320 A CN 107456320A
- Authority
- CN
- China
- Prior art keywords
- diaper
- fiber
- oozes
- fibers
- nano silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 230000003667 anti-reflective effect Effects 0.000 title claims abstract description 41
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 35
- 239000000835 fiber Substances 0.000 claims abstract description 160
- 239000002344 surface layer Substances 0.000 claims abstract description 60
- 241000208202 Linaceae Species 0.000 claims abstract description 39
- 235000004431 Linum usitatissimum Nutrition 0.000 claims abstract description 39
- 229920002101 Chitin Polymers 0.000 claims abstract description 34
- 239000002250 absorbent Substances 0.000 claims abstract description 29
- 230000002745 absorbent Effects 0.000 claims abstract description 29
- 239000012792 core layer Substances 0.000 claims abstract description 25
- 239000010410 layer Substances 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 238000005516 engineering process Methods 0.000 claims abstract description 10
- 238000003475 lamination Methods 0.000 claims abstract description 5
- 238000010276 construction Methods 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 32
- 229910052709 silver Inorganic materials 0.000 claims description 27
- 239000004332 silver Substances 0.000 claims description 27
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 26
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000005520 cutting process Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- -1 octyl group ammonium chlorides Chemical class 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- 238000005538 encapsulation Methods 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- YGYQHTPQUJUSLI-UHFFFAOYSA-N 3-(2-bromo-3-dodecylpyridin-4-yl)propyl 2-methylprop-2-enoate Chemical group C(C(=C)C)(=O)OCCCC1=C(C(=NC=C1)Br)CCCCCCCCCCCC YGYQHTPQUJUSLI-UHFFFAOYSA-N 0.000 claims description 3
- ODCGZJQTDHLGGN-UHFFFAOYSA-M benzyl-dimethyl-(2-methylprop-2-enoyloxy)azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)O[N+](C)(C)CC1=CC=CC=C1 ODCGZJQTDHLGGN-UHFFFAOYSA-M 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical class CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 210000002700 urine Anatomy 0.000 description 28
- 239000000463 material Substances 0.000 description 20
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 20
- 239000007788 liquid Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 230000000844 anti-bacterial effect Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000001223 reverse osmosis Methods 0.000 description 12
- 229910001961 silver nitrate Inorganic materials 0.000 description 10
- 229920003043 Cellulose fiber Polymers 0.000 description 8
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 8
- 229910052901 montmorillonite Inorganic materials 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 239000012279 sodium borohydride Substances 0.000 description 7
- 229910000033 sodium borohydride Inorganic materials 0.000 description 7
- 201000004624 Dermatitis Diseases 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 208000010668 atopic eczema Diseases 0.000 description 6
- 238000009960 carding Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
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- 241000894006 Bacteria Species 0.000 description 5
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- 239000002253 acid Substances 0.000 description 5
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- 238000002156 mixing Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000012209 synthetic fiber Substances 0.000 description 5
- 229920002994 synthetic fiber Polymers 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000010148 water-pollination Effects 0.000 description 4
- 238000005491 wire drawing Methods 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 230000003110 anti-inflammatory effect Effects 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 230000001225 therapeutic effect Effects 0.000 description 3
- 241000143437 Aciculosporium take Species 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- OZTGBXJMZLYFEN-UHFFFAOYSA-N N1C=CC=C1.C(C(=C)C)(=O)OCCCC(CCCCCCCCCCC)Br Chemical group N1C=CC=C1.C(C(=C)C)(=O)OCCCC(CCCCCCCCCCC)Br OZTGBXJMZLYFEN-UHFFFAOYSA-N 0.000 description 2
- 241000235070 Saccharomyces Species 0.000 description 2
- 241000194017 Streptococcus Species 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 239000011259 mixed solution Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
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- 239000004753 textile Substances 0.000 description 2
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- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
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- 241000208204 Linum Species 0.000 description 1
- 206010027439 Metal poisoning Diseases 0.000 description 1
- 102000016943 Muramidase Human genes 0.000 description 1
- 108010014251 Muramidase Proteins 0.000 description 1
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
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- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 description 1
- 230000036592 analgesia Effects 0.000 description 1
- 230000000202 analgesic effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
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- 229940095731 candida albicans Drugs 0.000 description 1
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- 229960002442 glucosamine Drugs 0.000 description 1
- MSWZFWKMSRAUBD-IVMDWMLBSA-N glucosamine group Chemical group OC1[C@H](N)[C@@H](O)[C@H](O)[C@H](O1)CO MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 208000010501 heavy metal poisoning Diseases 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
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- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
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- 229960000274 lysozyme Drugs 0.000 description 1
- 235000010335 lysozyme Nutrition 0.000 description 1
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- 231100000252 nontoxic Toxicity 0.000 description 1
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- 150000002894 organic compounds Chemical class 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
- A61F13/47—Sanitary towels, incontinence pads or napkins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
- A61F2013/15821—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing
- A61F2013/15861—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing for bonding
- A61F2013/15878—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing for bonding by thermal bonding
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
- A61F2013/8408—Additives, e.g. for odour, disinfectant or pH control with odour control
- A61F2013/8414—Additives, e.g. for odour, disinfectant or pH control with odour control with anti-microbic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/10—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing inorganic materials
- A61L2300/102—Metals or metal compounds, e.g. salts such as bicarbonates, carbonates, oxides, zeolites, silicates
- A61L2300/104—Silver, e.g. silver sulfadiazine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/40—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
- A61L2300/404—Biocides, antimicrobial agents, antiseptic agents
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Biomedical Technology (AREA)
- Manufacturing & Machinery (AREA)
- Hematology (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
The present invention relates to hygiene article sector, and in particular to oozes diaper to a kind of high-efficiency antimicrobial anti-reflective containing Nano Silver.A kind of high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper, including from top to bottom successively lamination set surface layer, absorbent core layer, leakproof bottom film, diaper both sides are pasted with stereo enclosure, described surface layer is upper, middle and lower-ranking composite construction, and described upper and lower layer is flax fiber, ES fibers, the composite fiber web of chitin fiber composition；Described middle level is made up of modified PP fiber；Described surface layer is made by thermal bonding technology.
Description
Technical field
The present invention relates to hygiene article sector, and in particular to oozes urine not to a kind of high-efficiency antimicrobial anti-reflective containing Nano Silver
It is wet.
Background technology
Diaper, it is the liquid absorption system established by multilayer material, mainly by surface layer, absorbent core layer, leakproof bottom film, vertical
The part such as body pad, elastic waistline, hasp forms, and surface layer, absorbent core layer and leakproof bottom film are arranged in order, made from top to bottom
It is glued together with thermosol adhesive.The structure of diaper is substantially perfect at present, and common diaper is respectively provided with ten on the market
Divide excellent absorbent properties, the liquid of own wt decades of times can be absorbed, but still can not use for a long time, when reason is long
Between wearing can form the environment of humidity, go down to trigger skin problem for a long time or even eczema, redness, " red hip " etc. can be induced ask
Topic.Make diaper keep surface layer dry and comfortable under long-time service condition, its scattering and permeating performance and oozing property of anti-reflective should be strengthened
Can, producing still can keep that uptake is big, reverse osmosis amount is small, infiltration rate in the case where long-time is using through multiple Liquid Penetrant
It hurry up, the product that diffusion is good is direction that current diaper industry needs to make great efforts.
The surface layer of existing diaper uses non-woven cloth made of hydrophobic synthetic fibers, hydrophilic by being carried out to it
Processing, it is obtained preferable hygroscopicity and wet guilding, but due to the uncontrollable urinary system of infant, frequency of micturition, use
After urine is repeatedly washed away, hydrophily is deteriorated the surface layer that synthetic fibers are made, and causes that urine infiltration rate is slack-off, anti-reflective oozes performance
It difference, will be chronically at using the buttocks of this diaper infant in wet environment, and eczema, redness, " red hip " easily occur
The problems such as.
For above-mentioned technical problem, the invention provides a kind of high-efficiency antimicrobial anti-reflective containing Nano Silver to ooze diaper, leads to
Cross and extraordinary absorbent properties are made it have to the particular design of surface layer structure, absorption urine speed is fast, and surface energy is protected for a long time
Hold dry and comfortable, oozing property of anti-reflective is good, and also has extraordinary antibacterial effect, while does not produce stimulation to infant's skin, to baby
Child's skin occur eczema, redness, " red hip " the problems such as have therapeutic effect.
The content of the invention
In order to solve the above-mentioned technical problem, first part of the invention provides a kind of high-efficiency antimicrobial containing Nano Silver
Anti-reflective oozes diaper, including from top to bottom the surface layer of lamination setting, absorbent core layer, leakproof bottom film, diaper both sides are pasted successively
There is stereo enclosure, described surface layer is upper, middle and lower-ranking composite construction, and described upper and lower layer is flax fiber, ES fibers, first
The composite fiber web of shell cellulose fiber composition；Described middle level is made up of modified PP fiber；Described surface layer passes through thermal bonding technology
It is made.
As a kind of preferable technical scheme of the present invention, described modified PP fiber is quaternary ammonium salt, silver particles are modified jointly
PP fibers.
As a kind of preferable technical scheme of the present invention, the particle diameter of described silver particles is 0~100nm.
As a kind of preferable technical scheme of the present invention, in described modified PP fiber the content of silver particles for 20~
45ppm。
As a kind of preferable technical scheme of the present invention, in described modified PP fiber the content of quaternary ammonium salt for 40~
85ppm。
As a kind of preferable technical scheme of the present invention, described quaternary ammonium salt is selected from methacryloxypropyl dodecyl bromide pyrrole
Any in pyridine, methacryloxy-benzyl-dimethyl ammonium chloride, three bay ammonium chlorides, the double octyl group ammonium chlorides of methyl
Kind.
As a kind of preferable technical scheme of the present invention, described quaternary ammonium salt is methacryloxypropyl dodecyl bromide pyrrole
Pyridine.
As a kind of preferable technical scheme of the present invention, described upper strata includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 5~20；ES fibers 75~90；Described lower floor includes：In parts by weight, flax fiber 100；Chitin fiber 15
~30；ES fibers 105~150.
As a kind of preferable technical scheme of the present invention, described upper strata includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 12；ES fibers 67；Described lower floor includes：In parts by weight, flax fiber 100；Chitin fiber 25；ES fibers
120。
The second part of the present invention provides the preparation that the described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper
Method, including at least following steps：
A. Time of Fluff Slurry is crushed, and with high hydroscopic resin mixed-forming；
B. the mixture that is obtained with non-woven fabrics encapsulation steps a, compacting, cutting, the absorbent core layer being molded；
C. absorbent core layer will be coated after described surface layer, leakproof bottom film, stereo enclosure applying glue, compound rolling, cutting, obtained
The described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
(1) the high-efficiency antimicrobial anti-reflective containing Nano Silver of the invention, which oozes diaper, has extraordinary absorbent properties, absorbs
Urine speed is fast, and surface energy keeps dry and comfortable for a long time, and it is good that anti-reflective oozes performance.
(2) the high-efficiency antimicrobial anti-reflective containing Nano Silver of the invention, which oozes diaper, has splendid antibacterial effect, and right
Infant's skin does not produce stimulation, at the same occur to infant's skin eczema, redness, " red hip " the problems such as have it is obvious
Therapeutic effect.
Embodiment
Participate in the election of the detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention
The identical implication that technical staff is generally understood that.When contradiction be present, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements
Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or
Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this
Phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme,
It is only limited to the key element described in the clause；Other key elements are not excluded outside the claim as entirety.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open
During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end
Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any
It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to represent that the present invention is not limited to this
Quantity, include the part of the amendment of the acceptable change without cause related basic function close to the quantity.Phase
Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.It is approximate in some examples
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope limits can be with
Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article " one kind " before key element of the present invention or component and "one" to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore "one" or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
In order to solve the above-mentioned technical problem, first part of the invention provides a kind of high-efficiency antimicrobial containing Nano Silver
Anti-reflective oozes diaper, including from top to bottom the surface layer of lamination setting, absorbent core layer, leakproof bottom film, diaper both sides are pasted successively
There is stereo enclosure, described surface layer is upper, middle and lower-ranking composite construction, and described upper and lower layer is flax fiber, ES fibers, first
The composite fiber web of shell cellulose fiber composition；Described middle level is made up of modified PP fiber；Described surface layer passes through thermal bonding technology
It is made.
Diaper, it is the liquid absorption system established by multilayer material, mainly by surface layer, absorbent core layer, leakproof bottom film, vertical
The part such as body pad, elastic waistline, hasp forms, and surface layer, absorbent core layer and leakproof bottom film are arranged in order, made from top to bottom
It is glued together with thermosol adhesive.
Surface layer
Surface layer directly with the tender and lovely skin contact of baby, receives urine at first, is the beginning of whole imbibition process.It is but actual
In, the liquid absorption of surface layer is almost nil, only serves urine guiding permeable effect to absorbent core layer, and surface layer typically has hydrophilic
Without the characteristic of water suction.The surface layer in baby's diaper is mainly synthetic fibers non-woven cloth at present.Synthetic fibers typically have
Have stronger hydrophobicity enables its hydrophilic so as to allow urine faster to pass through, it is necessary to carry out surface treatment to it with surfactant,
But due to the uncontrollable urinary system of infant, urine is more frequent, is repeatedly rushed through urine with the surface layer that synthetic fibers are made
After brush, hydrophily is deteriorated, and causes that urine infiltration rate is slack-off, and anti-reflective oozes degradation, uses the stern of this diaper infant
Portion will be chronically in wet environment, the problems such as eczema, redness, " red hip " easily occur.
Thermal bonding technology
Surface material the most frequently used at present is using the hot blast or hot rolling non-woven material of thermal bonding technology acquisition, hot blast
Non-woven material has good space structure, and liquid is weaving through by multiple holes complications, as through hole；And hot rolling is non-knits
Fiber distribution is relatively regular in producing material material, and a surrounding annulus is rolled after hot rolled and is mutually consolidated, the thickness of non-woven material is thinning, mainly
For blind hole and semiclosed hole, time of break-through is extended.
Reverse osmosis amount is to weigh an important indicator of surface layer performance.Hot rolling non-woven material at rolling due to being compacted and
Increase surface density, and it is in a little concave surface in surface layer front to roll, and the one side contacted with guide layer and absorbent core layer is in convex surface.Liquid
, can be because reverse osmosis be occurred by external force through being seeped under surface layer and guide layer in absorbent core layer, now liquid can be at first with rolling a shape
Into convex surface contact, arranged but because its fibre density is big, between fiber close and space is small, liquid can be hindered to rise, make it not
Easy reverse osmosis.The thickness of hot blast non-woven material is 3~5 times of hot rolling non-woven material under equal surface density, and hot blast is non-woven
The more fluffy softness of material, good space structure adds interfibrous space, and certain thickness causes liquid backs
Passage becomes complicated, also can be as the barrier for preventing liquid reverse osmosis, so as to reduce reverse osmosis amount.
As a kind of preferable technical scheme of the present invention, described surface layer is hot blast non-woven material.
Flax fiber
Flax is the important source material of textile industry, and its fiber is tough, soft and fine, has preferable color and luster.Flax fiber strength is big,
Not perishable in water, and have waterproof action, in addition with rub resistance, high temperature resistant, rapid heat dissipation, dust-absorbing rate is low, is not easy to tear, no
The advantages of easy firing, no electrostatic, acid and alkali-resistance etc. is unique, it is to pursue green preferred textile raw material, is described as natural fiber
In " queen ".
Flax fiber has natural spindle-type α-Fe2O3 and unique pectic substance hypotenuse pore structure.When it is with skin contact
Pore phenomenon is produced, skin perspiration can be assisted, and can cleaning skin.Meanwhile its heat is opened, the sweat and heat of human body are absorbed
Amount, and the sweat being absorbed to and even heat are conducted, decline human skin temperature.Then close to the cold, keep heat.
Flax fiber is unique bundle fiber in natural fiber, is to be formed by unicellular be sticked together by colloid of flax, does not have
There are more conditions for leaving air, the ventilative ratio of sodolin is up to more than 25%, can effectively reduce skin table rapidly
4~8 DEG C of temperature of layer.The hidden savoury herb of linum, a kind of indistinct fragrance can be distributed.Expert thinks that this smell can kill many
Bacterium, and the growth of a variety of parasites can be suppressed.There is experiment to prove：Lingerie has significant bacteriostasis, to green pus bar
The bacteriostasis rate of the international standard bacterial strain such as bacterium, Candida albicans is up to more than 65%, to Escherichia coli and gold-coloured staphylococci pearl
Bacteriostasis rate exceeds more than 90%.And the positive and negative charge that flax fiber carries does not have electrostatic phenomenon close to balance.
ES fibers
ES fibers are a kind of composite fibres of skin-core structure, and its cortex polymer fusing point is low, and the melting point polymer of sandwich layer
Higher than cortex is more.When temperature reaches near cortex fusing point, top layer polymer starts softening melting, and sandwich layer also keeps form
Etc. stable physical property.PP, PE, PET are three kinds of the most frequently used polymer raw materials of ES fibers, cortexes of the PE as ES fibers, and
PP and PET are as sandwich layer.ES fibers are one of the most frequently used surface materials of diaper, because ES fibers itself are non-hygroscopic, one
As need carrying out hydrophilic treated with surfactant to ES fiber surfaces, so as to reduce the contact angle of ES fibers, accelerate urine
Absorb and spread.
PE, PP belong to TPO, and PET belongs to polyesters, and PE and PP viscosity differences are smaller, and PET's and PE is viscous
Degree differs greatly, and the two kinds of polymer of bicomponent composite fibre forms more visible level, PE/PP core-skins in spinning process
With reference to comparison it is close, and PE/PET core-skins are combined with lamination.But these features assign pair prepared by PE/PET fibers
The advantages that component woven cloths are soft, tearing brute force is big, production efficiency is high.
As a kind of preferable technical scheme of the present invention, described ES fibers are PE/PET composite fibres.
Chitin fiber
In natural organic-compound present on the earth, quantity it is maximum be cellulose, be secondly exactly chitin, chitin
Be widely present in the crust of Crustaceans shrimp and crab, the crust of insect, fungi (yeast, mould, mushroom) cell membrane in.First
Shell element and its derivative chitosan, have certain curtain coating and ropiness, are all good fibre-forming materials, it is appropriate to select
Spinning condition, the chitin fiber with higher intensity and elongation can be made by the wet spinning process of routine.
The macromolecular structure of chitin is identical with the composition of the Glucosamine in human body, and has and be similar to human body bone
Collagen tissue structure, this dual structure impart their fabulous biomedical characteristics, and it is nontoxic to human body non-stimulated, can quilt
Lysozyme in human body is decomposed and absorbed, and has good biocompatibility with tissue.It also have antibacterial, anti-inflammatory, hemostasis,
Analgesia, promote the function such as wound healing, have significantly the problems such as the eczema that occurs for infant's skin, redness, " red hip "
Therapeutic effect.Substantial amounts of hydroxyl (- OH) and amino (- NH on the macromolecular chain of chitin fiber be present2) etc. hydrophily base
Group, therefore chitin fiber has good hydrophily and very high hygroscopicity.
As a kind of preferable technical scheme of the present invention, described modified PP fiber is quaternary ammonium salt, silver particles are modified jointly
PP fibers.
Quaternary ammonium salt
Quaternary ammonium salt is the common name of a kind of compound, and its formula is R4NX, wherein four alkyl R can be with identical, also can be different,
Generally hydrogen atom, alkyl or the carbochain containing other function substituted radicals.X is mostly halogen anion (F-、Cl-、Br-、I-)。
Quaternary ammonium salt bactericide is functional, and compared with other antiseptics, has good permeability, low toxicity, stable performance, skin irritatin
Gently, low corrosion and the lasting advantage of biological effect, thus it is widely used in the neck such as industry, pharmacy industry, daily-use chemical industry industry
Domain.
Silver particles
Silver is silver-colored to be recognized because strong antibacterial, bacterial resistance incidence are low selected as the existing long history of anti-biotic material
For the antibacterial activity with wide spectrum, there is antibacterial action to Gram-negative bacteria, gram-positive bacteria, fungi, fractionated viral etc.,
Very strong antibacterial action is all even shown to antibody-resistant bacterium.Silver particles not only there is anti-inflammatory property to also have analgesic effect, can press down
DNA processed duplication, there is very strong permeability, enduringly discharge nanometer rapidly after hypodermis, with incision contacts can be penetrated into
Silver particles, fast and effeciently kill the pathogen on otch and suture.
The discovery of a large amount of drug-fast bacterias promotes silver to be again used as high-efficient antibacterial agent at present, and Nano Silver is to have gathered nanometer technology
The distinctive bactericidal property manufacture of excellent characteristic and silver element antibacterial agent, its excellent antibacterial, anti-inflammatory, antiviral work
With increasingly extensive in the application of medical domain.The anti-microbial property of Nano Silver is related to its size, and the size of Nano Silver is smaller, its
Toxicity is stronger.Because nano-Ag particles size reduce, its surface area/volume ratio is bigger, nano particle dissolving release silver from
The ability of son also strengthens.Small-size effect is advantageous to nano-Ag particles and penetrates biomembrane into the cell, effectively enhances nanometer
Silver-colored anti-microbial property, but its accumulation in human body is also result in, heavy metal poisoning etc. may be caused.Research shows particle diameter in 25nm
Following nano silver particles have the ability that very strong penetration cell wall is directly entered cell interior.
As a kind of preferable technical scheme of the present invention, the preparation method of described modified PP fiber, including at least following
Step：
A. take montmorillonite to be scattered in the deionized water of 20 times of quality, stir 30min, add described quaternary ammonium salt, it is described
Quaternary ammonium salt and montmorillonite mass ratio be 0.002~0.006：1,3h is stirred under 60 DEG C of water-baths, then suspension is filtered, water
Wash, be finally putting into drying in 65 DEG C of baking ovens and obtain product A, described montmorillonite is purchased from G105-NANOCOR companies, and the trade mark is
PGV；
B. 1.2mol/L silver nitrate solution is taken, adds 25wt% ammoniacal liquor and described modified montmorillonoid, nitre thereto
The volume ratio of the silver-colored solution of acid and ammoniacal liquor is 5：1, modified montmorillonoid and silver-colored mass ratio are 1：0.001~0.003,0.5h is stirred,
0.03mol/L bay acid solutions are added, are stirred continuously, 0.36mol/L NaBH is added dropwise with 1 drop/s speed4Solution, after dripping off
Continue to stir 30min, then stand 1h, described silver nitrate, NaBH4It is 3~12 with lauric mol ratio：3：1；Use phosphoric acid
Solution adjustment mixed solution pH is 4~6, and the volume ratio of phosphoric acid and deionized water is 1 in described phosphoric acid solution：4, filter, use
Water and alcohol flushing product remove laurate, and 12h is dried at 45 DEG C, obtain product B；
C. product B is mixed with PP plastic pellets, melted in pot is melted in electrical heating, melt temperature is 250 DEG C, stirring
15min, rotating speed 200r/min, it will directly melt thing and be placed in the wire drawing of wire drawing machine upper end, that is, obtain described modified PP fiber, institute
The mass ratio for product B and the PP plastic pellet stated is 1：55~75.
The present invention is by oxidation-reduction method synthesizing nano-silver, by controlling the silver nitrate, the reducing agent NaBH that are added in reaction4
Found and dispersant lauric ratio regulates and controls the particle diameter of obtained silver particles, in experiment when described silver nitrate,
NaBH4With lauric mol ratio 3~12：3：The particle diameter distribution of the silver particles obtained in the range of 1 is between 0~100nm；When
Described silver nitrate, NaBH4With lauric mol ratio 6：3：The particle diameter of the Argent grain obtained when 1 concentrates on 30~50nm.
As a kind of preferable technical scheme of the present invention, described silver nitrate, NaBH4It is 6 with lauric mol ratio：3：
1。
As a kind of preferable technical scheme of the present invention, the particle diameter of described silver particles is 0~100nm.
As a kind of preferable technical scheme of the present invention, the particle diameter of described silver particles is 30~50nm.
As a kind of preferable technical scheme of the present invention, in described modified PP fiber the content of silver particles for 20~
45ppm。
As a kind of preferable technical scheme of the present invention, in described modified PP fiber the content of quaternary ammonium salt for 40~
85ppm。
As a kind of preferable technical scheme of the present invention, described quaternary ammonium salt is selected from methacryloxypropyl dodecyl bromide pyrrole
Any in pyridine, methacryloxy-benzyl-dimethyl ammonium chloride, three bay ammonium chlorides, the double octyl group ammonium chlorides of methyl
Kind.
As a kind of preferable technical scheme of the present invention, described quaternary ammonium salt is methacryloxypropyl dodecyl bromide pyrrole
Pyridine.
As a kind of preferable technical scheme of the present invention, described upper strata includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 5~20；ES fibers 75~90；Described lower floor includes：In parts by weight, flax fiber 100；Chitin fiber 15
~30；ES fibers 105~150.
As a kind of preferable technical scheme of the present invention, described upper strata includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 12；ES fibers 67；Described lower floor includes：In parts by weight, flax fiber 100；Chitin fiber 25；ES fibers
120。
As a kind of preferable technical scheme of the present invention, the preparation method of described surface layer, including at least following steps：
A. the preparation on described upper strata：Flax fiber, chitin fiber and ES fibers are weighed respectively by proportioning to mix, then
It is mixed evenly respectively with blending box shredding, takes appropriate fiber to comb out 15g/m with cotton-carding tester respectively after placing 24h2It is flat
Row fibre web；
B. the preparation of described lower floor：Flax fiber, chitin fiber and ES fibers are weighed respectively by proportioning to mix, then
It is mixed evenly respectively with blending box shredding, takes appropriate fiber to comb out 25g/m with cotton-carding tester respectively after placing 24h2It is flat
Row fibre web；
C. the preparation in described middle level：Described modified PP fiber after appropriate shredding is taken to comb out 25g/ with cotton-carding tester
m2Parallel fibre web；
D. described surface layer upper, middle and lower layer is superimposed together according to order, is put into the hot-air oven that temperature is 130 DEG C
In, the uniform sprinkling of upper and lower layer to surface layer is configured with deionized water respectively 10% binder solution is shut oven door, put
10min is put, is taken out, is allowed to cool and obtains described surface layer；Described adhesive is purchased from Zhejiang development of evil in febrile disease Co., Ltd, and the trade mark is
TF-320。
As a kind of preferable technical scheme of the present invention, described surface layer can also use work well known by persons skilled in the art
Skill carries out concavo-convex stamp processing.
Absorbent core layer
Absorbent core layer is the key structure position of diaper absorption system, positioned at diaper surface layer and leakproof bottom film it
Between, the quality of its absorbent properties directly influences the quality of diaper.At present the absorbent core layer of diaper mainly by toilet paper or
Person's non-woven material wraps up high hydroscopic resin and the mixing body of Time of Fluff Slurry forms.High hydroscopic resin major function be it is a large amount of absorb and
Moisture is pinned, the function of Time of Fluff Slurry is then to speed up rate of liquid aspiration and accelerates liquid in the diffusion velocity of absorbent core layer, the two function
On complement each other.The design of this absorbent core layer enhances the rate of liquid aspiration of diaper, increases liquid absorption.
Leakproof bottom film
Leakproof bottom film is a part of structure that area is maximum in diaper, positioned at the orlop of diaper, is mainly used in preventing
The only seepage of urine, while also need possess good permeability, and preferably tensile property and tear resistance.Urine at present
Not wet leakproof bottom film mainly has PP breathable microporous films and the compound counterdies of Nonwovens PE.
As a kind of preferable technical scheme of the present invention, described leakproof bottom film is that PP breathable microporous films or hot rolling are non-woven
The compound counterdies of cloth PE.
The second part of the present invention provides the preparation that the described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper
Method, including at least following steps：
A. Time of Fluff Slurry is crushed, and with high hydroscopic resin mixed-forming；
B. the mixture that is obtained with non-woven fabrics encapsulation steps a, compacting, cutting, the absorbent core layer being molded；
C. absorbent core layer will be coated after described surface layer, leakproof bottom film, stereo enclosure applying glue, compound rolling, cutting, obtained
The described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper.
Flax fiber and chitin fiber are hydrophilic fibers, have good water imbibition and hydrofuge, when urine contact arrives
When the flax fiber and chitin fiber of surface layer, urine is more likely to vertically conduct；The intermediate layer of surface layer is MODIFIED PP
Fiber, PP fibers are non-hygroscopic, but have preferable wick effect, contribute to urine to penetrate into middle level, and due to PP fibers
Hydrophobic, urine is more likely to conduct in the horizontal direction in middle level, realizes the shunting of urine, and surface layer can become in shorter time
It is dry and comfortable；Bibulous flax fiber and chitin fiber are also contained in lower floor, urine is faster penetrated into absorbent core layer.Upper and lower two layers
The use of middle ES fibers can not only realize that three-decker has preferably elasticity and applicability, and due in hot-air drying process
The thawing of ES fiber sheaths makes to produce contact point inside three-decker, can realize that urine is preferably conducted.By to three-decker
The design of density, the high-efficiency antimicrobial anti-reflective containing Nano Silver of the present invention is oozed diaper, there is fabulous anti-reflective to ooze performance.And
And the electropositive of chitin fiber and quaternary ammonium salt makes to produce between three-decker Coulomb repulsion and the elecrtonegativity on silver particles surface makes
It attracts each other with chitin fiber, and their interaction makes the structure of surface layer more complicated, contributes to containing electrolyte
The absorption of urine, also as urine reverse osmosis large drag forces.
The high-efficiency antimicrobial anti-reflective containing Nano Silver in the present invention, which oozes diaper, has extraordinary antibacterial effect, the present invention
Silver particles, quaternary ammonium salt, flax fiber, chitin fiber be respectively provided with anti-microbial property, and do not produce stimulation to infant's skin.
The present invention realizes silver particles and quaternary ammonium salt in modified PP fiber by the interaction of montmorillonite, quaternary ammonium salt and PP plastic pellets
Interior is dispersed, and the synergistic effect of the electropositive and silver particles of quaternary ammonium salt and chitin fiber makes silver particles in larger grain
All there is extraordinary antibiotic property, and the height containing Nano Silver described in when silver particles particle diameter is 30~50nm in the range of footpath
Effect antibacterial anti-reflective, which oozes diaper, has best biocidal property.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following examples are only used
In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field
Some the nonessential modifications and adaptations made according to the content of the invention described above, still fall within protection scope of the present invention.
In addition, if without other explanations, raw materials used is all commercially available.
Embodiment 1：
Embodiment 1 provides a kind of high-efficiency antimicrobial anti-reflective containing Nano Silver and oozes diaper, including from top to bottom folds successively
The surface layer of layer setting, absorbent core layer, leakproof bottom film, diaper both sides are pasted with stereo enclosure, and described surface layer is upper, middle and lower
Three-layer composite structure, described upper and lower layer are flax fiber, ES fibers, the composite fiber web of chitin fiber composition；Described
Middle level is made up of modified PP fiber；Described surface layer is made by thermal bonding technology.
The preparation method of described modified PP fiber, including at least following steps：
A. take montmorillonite to be scattered in the deionized water of 20 times of quality, stir 30min, add described quaternary ammonium salt, it is described
Quaternary ammonium salt and montmorillonite mass ratio be 0.002：1,3h is stirred under 60 DEG C of water-baths, then suspension is filtered, wash, finally
It is put into drying in 65 DEG C of baking ovens and obtains product A, described montmorillonite is purchased from G105-NANOCOR companies, trade mark PGV；
B. 1.2mol/L silver nitrate solution is taken, adds 25wt% ammoniacal liquor and described modified montmorillonoid, nitre thereto
The volume ratio of the silver-colored solution of acid and ammoniacal liquor is 5：1, modified montmorillonoid and silver-colored mass ratio are 1：0.001,0.5h is stirred, is added
0.03mol/L bay acid solutions, are stirred continuously, and 0.36mol/L NaBH is added dropwise with 1 drop/s speed4Solution, continue after dripping off
30min is stirred, then stands 1h, described silver nitrate, NaBH4It is 3 with lauric mol ratio：3：1；Adjusted with phosphoric acid solution
Mixed solution pH is 5, and the volume ratio of phosphoric acid and deionized water is 1 in described phosphoric acid solution：4, filtering, with water and alcohol flushing
Product removes laurate, and 12h is dried at 45 DEG C, obtains product B；
C. product B is mixed with PP plastic pellets, melted in pot is melted in electrical heating, melt temperature is 250 DEG C, stirring
15min, rotating speed 200r/min, it will directly melt thing and be placed in the wire drawing of wire drawing machine upper end, that is, obtain described modified PP fiber, institute
The mass ratio for product B and the PP plastic pellet stated is 1：60.
Described quaternary ammonium salt is methacryloxypropyl dodecyl bromopyridine.
Described upper strata includes：In parts by weight, flax fiber 100；Chitin fiber 5；ES fibers 75；Described lower floor
Including：In parts by weight, flax fiber 100；Chitin fiber 15；ES fibers 105.
The preparation method of described surface layer, including at least following steps：
A. the preparation on described upper strata：Flax fiber, chitin fiber and ES fibers are weighed respectively by proportioning to mix, then
It is mixed evenly respectively with blending box shredding, takes appropriate fiber to comb out 15g/m with cotton-carding tester respectively after placing 24h2It is flat
Row fibre web；
B. the preparation of described lower floor：Flax fiber, chitin fiber and ES fibers are weighed respectively by proportioning to mix, then
It is mixed evenly respectively with blending box shredding, takes appropriate fiber to comb out 25g/m with cotton-carding tester respectively after placing 24h2It is flat
Row fibre web；
C. the preparation in described middle level：Described modified PP fiber after appropriate shredding is taken to comb out 25g/ with cotton-carding tester
m2Parallel fibre web；
D. described surface layer upper, middle and lower layer is superimposed together according to order, is put into the hot-air oven that temperature is 130 DEG C
In, the uniform sprinkling of upper and lower layer to surface layer is configured with deionized water respectively 10% binder solution is shut oven door, put
10min is put, is taken out, is allowed to cool and obtains described surface layer；Described adhesive is purchased from Zhejiang development of evil in febrile disease Co., Ltd, and the trade mark is
TF-320。
The described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes the preparation method of diaper, including at least following steps：
A. Time of Fluff Slurry is crushed, and with high hydroscopic resin mixed-forming；
B. the mixture that is obtained with non-woven fabrics encapsulation steps 1, compacting, cutting, the absorbent core layer being molded；
C. absorbent core layer will be coated after described surface layer, leakproof bottom film, stereo enclosure applying glue, compound rolling, cutting, obtained
The described high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper.
Embodiment 2：
With embodiment 1, difference is the embodiment of embodiment 2, described in the preparation method of MODIFIED PP
Quaternary ammonium salt and the mass ratio of montmorillonite are 0.003：1；Described modified montmorillonoid and the mass ratio of silver are 1：0.0015.
Embodiment 3：
With embodiment 2, difference is the embodiment of embodiment 3, described in the preparation method of MODIFIED PP
Silver nitrate, NaBH4It is 12 with lauric mol ratio：3：1.
Embodiment 4：
With embodiment 3, difference is the embodiment of embodiment 4, described in the preparation method of MODIFIED PP
Silver nitrate, NaBH4It is 6 with lauric mol ratio：3：1.
Embodiment 5：
The embodiment of embodiment 5 is with embodiment 4, and difference is, described upper strata includes：With parts by weight
Meter, flax fiber 100；Chitin fiber 20；ES fibers 90；Described lower floor includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 30；ES fibers 150.
Embodiment 6：
The embodiment of embodiment 6 is with embodiment 4, and difference is, described upper strata includes：With parts by weight
Meter, flax fiber 100；Chitin fiber 12；ES fibers 67；Described lower floor includes：In parts by weight, flax fiber 100；First
Shell cellulose fiber 25；ES fibers 120.
Comparative example 1
The embodiment of comparative example 1 is with embodiment 6, and difference is, described surface layer does not include middle level.
Comparative example 2
With embodiment 6, difference is the embodiment of comparative example 2, does not include in described surface layer described
Upper strata.
Comparative example 3
With embodiment 6, difference is the embodiment of comparative example 3, does not include in described surface layer described
Lower floor.
Comparative example 4
With embodiment 6, difference is the embodiment of comparative example 4, the upper strata described in described surface layer and
The fiber composition of lower floor is identical, including：In parts by weight, flax fiber 100；Chitin fiber 12；ES fibers 67.
Comparative example 5
With embodiment 6, difference is the embodiment of comparative example 5, and silver granuel is not included in described MODIFIED PP
Son.
Comparative example 6
With embodiment 6, difference is the embodiment of comparative example 6, and quaternary ammonium is not included in described MODIFIED PP
Salt.
Comparative example 7
The embodiment of comparative example 7 is with embodiment 6, and difference is, the upper strata of described surface layer is ES fibers
It is made, and it is surface-treated with hydrophilizing agent, described hydrophilizing agent is purchased from Zhejiang development of evil in febrile disease Co., Ltd, trade mark TF-
629。
Performance evaluation：
1. anti-reflective oozes performance
Judge that the anti-reflective of diaper oozes performance using reverse osmosis amount as foundation.Reverse osmosis amount refers to that urine does not have after entering diaper
It is completely absorbed, returns to the quality of the liquid of surface layer under the effect of the pressure.Method of testing：Quantitative 40mL artificial urine is pressed
Prescriptive procedure is poured on diaper surface layer, interval 5min second, then be spaced 5min third time ... down to required number
After artificial urine, if after Liquid Penetrant 5min rapidly by the filter paper dried layer of known quality (the superiors' Filter Paper Dry after imbibition need to being ensured
Dry no imbibition) be put into specimen surface, while 1.2kg standard briquettings are pressed on filter paper, and start timing, pressurize 1min when will mark
Quasi- briquetting is removed, the quality for the specimen surface filter paper that weighs with scale.
As a result calculate：Reverse osmosis amount represents with of poor quality before and after specimen surface filter paper test, m=m1-m2, m expression reverse osmosis
Amount, unit (g)；m1Represent the quality after specimen surface filter paper imbibition, unit (g)；m2Represent the matter before specimen surface filter paper imbibition
Amount, unit (g)；5 samples of test are averaged as measurement result.
2. anti-microbial property
First to toppling over the 100mL of physiological saline containing 10g/100mL on the diaper described in embodiment 1~6 and comparative example 1~7,
After it is fully absorbed, described diaper is placed in enclosed environment (room temperature, normal humidity), put in described enclosed environment
Put culture of Escherichia coli, saccharomyces albicanses culture and the streptococcus culture of open culture, after placing 12h, measurement
Clump count (CFU/mL) on described diaper surface layer, specific measuring method are dispersed in after described surface layer is shredded
In 100mL deionized water, 3h is soaked, filtering, takes 1mL samples to cultivate 48h at 37 DEG C, carries out total plate count measure.
The performance characterization of table 1 is tested
As can be seen from Table 1, the present invention in the high-efficiency antimicrobial anti-reflective containing Nano Silver ooze diaper have it is extraordinary
Anti-reflective oozes performance, and by washing away for five synthetic urines, the reverse osmosis amount of synthetic urine is below 5.5g, and to Escherichia coli,
Saccharomyces albicanses and streptococcus have extraordinary sterilization effect.
Foregoing example is merely illustrative, for explaining some features of the method for the invention.Appended right will
Ask and be intended to require the scope as wide as possible being contemplated that, and embodiments as presented herein is only according to all possible implementation
The explanation of the embodiment of the selection of the combination of example.Therefore, the purpose of applicant is that appended claim is not illustrated this hair
The selectional restriction of the example of bright feature.Some number ranges used also include sub- model within the claims
Enclose, the change in these scopes should be also construed to by appended claim covering in the conceived case.
Claims (10)
1. a kind of high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper, including the surface layer of lamination setting, suction successively from top to bottom
Sandwich layer, leakproof bottom film are received, diaper both sides are pasted with stereo enclosure, it is characterised in that described surface layer is upper, middle and lower-ranking
Composite construction, described upper and lower layer are flax fiber, ES fibers, the composite fiber web of chitin fiber composition；Described middle level
It is made up of modified PP fiber；Described surface layer is made by thermal bonding technology.
2. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 1, it is characterised in that described modification
The PP fibers that PP fibers are quaternary ammonium salt, silver particles are modified jointly.
3. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 2, it is characterised in that described silver granuel
The particle diameter of son is 0~100nm.
4. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 2, it is characterised in that described modification
The content of silver particles is 20~45ppm in PP fibers.
5. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 2, it is characterised in that described modification
The content of quaternary ammonium salt is 40~85ppm in PP fibers.
6. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 2, it is characterised in that described quaternary ammonium
Salt is selected from methacryloxypropyl dodecyl bromopyridine, methacryloxy-benzyl-dimethyl ammonium chloride, three lauryl chlorides
Change any of double octyl group ammonium chlorides of ammonium, methyl.
7. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 2, it is characterised in that described quaternary ammonium
Salt is methacryloxypropyl dodecyl bromopyridine.
8. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 1, it is characterised in that described upper strata
Including：In parts by weight, flax fiber 100；Chitin fiber 5~20；ES fibers 75~90；Described lower floor includes：With weight
Measure part meter, flax fiber 100；Chitin fiber 15~30；ES fibers 105~150.
9. the high-efficiency antimicrobial anti-reflective containing Nano Silver oozes diaper as claimed in claim 1, it is characterised in that described upper strata
Including：In parts by weight, flax fiber 100；Chitin fiber 12；ES fibers 67；Described lower floor includes：In parts by weight,
Flax fiber 100；Chitin fiber 25；ES fibers 120.
10. the high-efficiency antimicrobial anti-reflective containing Nano Silver as described in any one of claim 1~9 oozes the preparation method of diaper,
Including at least following steps：
A. Time of Fluff Slurry is crushed, and with high hydroscopic resin mixed-forming；
B. the mixture that is obtained with non-woven fabrics encapsulation steps a, compacting, cutting, the absorbent core layer being molded；
C. absorbent core layer will be coated after described surface layer, leakproof bottom film, stereo enclosure applying glue, compound rolling, cutting, obtained described
The high-efficiency antimicrobial anti-reflective containing Nano Silver ooze diaper.
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| CN107456320B (en) | 2018-04-24 |
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