CN107448083A - A kind of environment-friendly type hinge and its processing technology - Google Patents
A kind of environment-friendly type hinge and its processing technology Download PDFInfo
- Publication number
- CN107448083A CN107448083A CN201710521613.3A CN201710521613A CN107448083A CN 107448083 A CN107448083 A CN 107448083A CN 201710521613 A CN201710521613 A CN 201710521613A CN 107448083 A CN107448083 A CN 107448083A
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- China
- Prior art keywords
- hinge
- axle sleeve
- weight
- parts
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000012545 processing Methods 0.000 title claims description 24
- 238000005516 engineering process Methods 0.000 title claims description 19
- 238000005260 corrosion Methods 0.000 claims abstract description 24
- 230000007797 corrosion Effects 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims description 31
- 239000002184 metal Substances 0.000 claims description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 23
- 238000005498 polishing Methods 0.000 claims description 22
- 229910045601 alloy Inorganic materials 0.000 claims description 19
- 239000000956 alloy Substances 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 19
- 238000004070 electrodeposition Methods 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000007800 oxidant agent Substances 0.000 claims description 17
- 230000001590 oxidative effect Effects 0.000 claims description 16
- 238000005238 degreasing Methods 0.000 claims description 15
- 239000003814 drug Substances 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 12
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- 239000001509 sodium citrate Substances 0.000 claims description 9
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 9
- 238000001962 electrophoresis Methods 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002738 chelating agent Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- FHHAOPXGDLWQQM-UHFFFAOYSA-N N.[K] Chemical compound N.[K] FHHAOPXGDLWQQM-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000005864 Sulphur Substances 0.000 claims description 6
- 229910003460 diamond Inorganic materials 0.000 claims description 6
- 239000010432 diamond Substances 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 239000004310 lactic acid Substances 0.000 claims description 6
- 235000014655 lactic acid Nutrition 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 6
- 238000005554 pickling Methods 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- -1 potassium ferricyanide Chemical compound 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 3
- GFZPUGCMGGUPHH-UHFFFAOYSA-N [I].[Na] Chemical compound [I].[Na] GFZPUGCMGGUPHH-UHFFFAOYSA-N 0.000 claims description 3
- 150000001253 acrylic acids Chemical class 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002609 medium Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 3
- 239000011684 sodium molybdate Chemical group 0.000 claims description 3
- 235000015393 sodium molybdate Nutrition 0.000 claims description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical group [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 230000009182 swimming Effects 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical group [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000000084 colloidal system Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 4
- 238000009434 installation Methods 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 35
- 239000000463 material Substances 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 238000007517 polishing process Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical group C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000004696 coordination complex Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000006056 electrooxidation reaction Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229960000502 poloxamer Drugs 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 239000006061 abrasive grain Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- ANXVAOKSKNKMKO-UHFFFAOYSA-L dihydroxy(dioxo)chromium;sodium Chemical group [Na].O[Cr](O)(=O)=O ANXVAOKSKNKMKO-UHFFFAOYSA-L 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- YKHQSWIVNHQJSW-UHFFFAOYSA-N iron;oxalonitrile Chemical compound [Fe].N#CC#N YKHQSWIVNHQJSW-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E05—LOCKS; KEYS; WINDOW OR DOOR FITTINGS; SAFES
- E05D—HINGES OR SUSPENSION DEVICES FOR DOORS, WINDOWS OR WINGS
- E05D9/00—Flaps or sleeves specially designed for making from particular material, e.g. hoop-iron, sheet metal, plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
- C23F3/04—Heavy metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- ing And Chemical Polishing (AREA)
Abstract
The present invention relates to a kind of environment-friendly type hinge, including the first hinge, the second hinge and hinge axis, the first described hinge is provided with the first axle sleeve, and the first hinge and the first axle sleeve are integral type structure;The second described hinge is provided with the second axle sleeve, and the second hinge and the second axle sleeve are integral type structure;The interlaced laying of first axle sleeve and the second axle sleeve, described hinge axis sequentially passes through the first axle sleeve and the second axle sleeve, and the both ends of hinge axis, in two the first axle sleeves of the first hinge, the second described hinge is rotatably assorted with the first hinge;Insulating corrosion layer is provided with first hinge, the second hinge, the first axle sleeve and the second axle sleeve;The present invention has the advantages that simple in construction, easy for installation, monoblock cast, intensity is high, and service life is long.
Description
Technical field
The present invention relates to a kind of environment-friendly type hinge and its processing technology.
Background technology
Hinge is also known as hinge and is for connection to two solids and allows the mechanical device to rotate between the two, Furniture fittings
Hinge occupies critical positions in accessory;Hinge generally includes the second hinge of the second hinge, the first hinge and connection, first hinge
Bearing pin, usual first hinge are used to be fixed on column, vehicle frame or wall, the second hinge and door Joint so that Men Raoxiao
Axle rotation is with two states opened or closed.During real life, due to the second hinge rotational angle of hinge
Do not have spacing, when causing rotating opening, easily contacted with the column or vehicle body of surrounding so that occur scar on door, influence
Client uses.
Existing hood, trunk lid, lifting door and side door etc. are iron-based material(Density 7.784g/cm3);Phase
It is lighter than iron-based material, mg-based material(Density 1.738g/cm3), there is more preferable specific strength, specific stiffness, in body lightening side
There is obvious advantage in face, therefore can be mg-based material by hood, trunk lid, the lifting part design such as door and side door.
But the hinge for location engine cover, trunk lid, lifting door and side door to be arranged on vehicle body is mostly iron
Sill, and mg-based material(Electrical potential difference -2.732V)With iron-based material(Electrical potential difference -0.447V)There are larger potential difference, iron-based
Material directly contacts with mg-based material can produce electrochemical corrosion.That is, hold between the part such as hinge and hood
Electrochemical corrosion is also easy to produce, so as to limit the extensive use of mg-based material.
In order to solve the above technical problems, as Chinese patent literature discloses a kind of anti-corrosion hinge(Application number:
201320719232.3 ), including the body and support being fixed together, the body is used for and body of a motor car is fixed and connected
Connect, the support is used to be fixedly connected with automobile door cover, and the support is provided with absolutely with the one side that the automobile door cover is in contact
Edge anticorrosive coat;Conventional hinge, insulating corrosion layer are electroplated using dark nickel, as its surface treatment, are had a disadvantage in that:First, dark nickel
Plating, no matter its finishing process or negative product is processed, owe environmental protection, influence product competitiveness;Second, corrosion resistance
Can be relatively low, influence the life-span;Third, high expensive, influences occupation rate of market rate.
Because existing insulating corrosion typically uses zincincation, conventional zinc-plated processing include surface cleaning processing,
3 important steps of zinc-plated processing and sequent surface Passivation Treatment in electroplate liquid.Metal Substrate be present in the part of conventional electroplating processes
Body and zinc-plated inter-layer bonding force be poor, easily in installation and use plates damage layer, causes antiseptic property to decline;
For problem above, therefore, it is necessary to make improvements.
The content of the invention
The present invention be in order to overcome it is above-mentioned in the prior art the defects of, there is provided it is a kind of simple in construction, easy to use, improve anti-
The environment-friendly type hinge of rotten performance.
In order to reach object above, the technical solution adopted in the present invention is:A kind of environment-friendly type hinge, including the first conjunction
Page, the second hinge and hinge axis, the first described hinge are provided with the first axle sleeve, and the first hinge and the first axle sleeve are integral type knot
Structure;The second described hinge is provided with the second axle sleeve, and the second hinge and the second axle sleeve are integral type structure;First axle sleeve with
The interlaced laying of second axle sleeve, described hinge axis sequentially passes through the first axle sleeve and the second axle sleeve, and the both ends of hinge axis are set
In in two the first axle sleeves of the first hinge, the second described hinge is rotatably assorted with the first hinge;First hinge, second
Insulating corrosion layer is provided with hinge, the first axle sleeve and the second axle sleeve.
As a preferred embodiment of the present invention, the insulating corrosion layer includes layer of iron-nickel alloy and electrocoating film;Electrocoating film
Fit in layer of iron-nickel alloy, layer of iron-nickel alloy is attached on the first hinge, the second hinge, the first axle sleeve and the second axle sleeve.
As a preferred embodiment of the present invention, the thickness of the layer of iron-nickel alloy is 1~2 μm, and the thickness of electrocoating film is
12~16 μm, the transparent color of electrocoating film.
As a preferred embodiment of the present invention, the middle part of the hinge axis is provided with Anti-theft groove, and Anti-theft groove annular is laid in
Corresponding on hinge axis, the first axle, which is put, is provided with the anti-theft hole corresponding with antitheft groove location, pacifies in anti-theft hole
Equipped with anti-theft bolt;Anti-theft bolt is mutually butted in Anti-theft groove through anti-theft hole.
As a preferred embodiment of the present invention, the both ends of the hinge axis are connected on described screw thread formed with screw thread
Limited location cap, limited cap are connected with threads turn.
The insulating corrosion layer processing technology of a kind of environment-friendly type hinge, it is characterized in that comprising the following steps:
Step 1:Ultrasonic oil removal:Using medium temperature removing oil-removing wax powder hinge workpiece surface oily waste treatment clean, removing oil-removing wax powder
100-500g, temperature are generally 60-80 degree, minute time 2-10;
Step 2:Surface cleaning processing, hinge workpiece is immersed into degreasing fluid, degreasing fluid is two-in-one degreasing and rust removal liquid medicine, two-in-one
Degreasing and rust removal liquid medicine dosage is 1000-2000 milliliters;Degreasing and rust removal time 2-10min, 60-80 DEG C of temperature;By above-mentioned by removing
The hinge workpiece of oil derusting, which is put into 40-50 DEG C of hot water, to be cleaned repeatedly;Hinge workpiece surface oxide skin and iron rust are removed, will be passed through
The product of hot water wash is put into cold water wash;The part washed through subcooled water is subjected to pickling, then washed;
Step 3:Ironware chemical polishing:By the part in step 2 after surface cleaning is handled, the table being polished is needed to it
Face carries out ironware chemical polishing processing, using ironware chemical polishing liquid medicine, thoroughly removes surface oxide layer, removes cut and hair
Thorn, expose workpiece surface iron true qualities, normal temperature processing, minute time 2-10;
Step 4:Alloy as catalyst:Using environmentally friendly alloy as catalyst technique, on the surface substrate for the hinge workpiece handled well in step 3
The layer of iron-nickel alloy of one layer of 1-2 micron is catalyzed out, black nickel background color, temperature 85-90 degree, time 2-10 point is presented in the layer of iron-nickel alloy
Clock;
Step 5:Silane antirust:Using silane anti-corrosive technology, on the basis of step 4, protection hinge workpiece ground is not urged completely
The ground of alloy is melted into, prevents from getting rusty, improves antirust ability, under normal temperature state, minute time 2-5;
Step 6:Electrophoresis blooming:Using the ECB-700 high-performance acrylic acids electricity of the high outstanding science and technology limited Company production in Jiangxi Province
Swimming paint, the transparent electrocoating film that electrophoresis on the ground of alloy as catalyst adds one layer of 12-16 micron is carried out in step 5, protects ground, is improved
Alloy-layer anti-corrosion and chemical-resistance, salt spray resistance test is set to reach more than 48 hours;
Step 7:Baking:Half an hour is toasted using 160 °C of temperature, makes electrodeposited paint film that film forming be fully cured, is adsorbed in hinge workpiece
Surface.
As a preferred embodiment of the present invention, the solution of the pickling for be 8%~50% containing volume ratio nitric acid
With hydrofluoric acid and the mixed solution of the deionized water of surplus that volume ratio is 0.05%~6%, etching time is 1~2 minute.
As a preferred embodiment of the present invention, described polishing liquid medicine its raw material by weight, including following component:Throw
Light particle:0.1~100 part;Oxidant A:0.05~2 part;Oxidant B:0.05~2 part;Metal chelating agent:0.1~10 part;Gold
Belong to corrosion inhibiter:0.1~10 part;Metal solubilizer:0.01~0.5 part;Metal thickener:0.01~0.2 part;Builder;0.5~
1 part;Aqueous medium:80~90 parts;
As a preferred embodiment of the present invention, polishing liquid medicine its raw material by weight, including following component:Polishing particles:5
~50 parts;Oxidant A:0.1~1 part;Oxidant B:0.1~1 part;Metal chelating agent:0.5~5 part;Metal inhibitor:0.5~
5 parts;Metal solubilizer:0.1~0.2 part;Metal thickener:0.08~0.1 part;Builder;0.7~0.9 part;Aqueous medium:
85~88 parts;
As a preferred embodiment of the present invention, the polishing particles are selected from single-crystal diamond, polycrystalline diamond, three oxidations two
At least one of aluminium, zirconium dioxide, titanium dioxide, ceria, fumed silica and cataloid;The oxygen
One or more combinations of the agent A in the potassium ferricyanide, potassium permanganate, periodic acid and hydrogen peroxide;The oxidant B is selected from
Sodium nitrate, sodium chromate, sodium molybdate, one or more combinations in natrium nitrosum;The metal chelating agent is selected from ammonia, amino acid
At least one of with organic acid;The metal inhibitor is selected from nitogen-contained heterocycle derivant, sulfur heterocyclic ring derivative and simultaneously
At least one of Hete rocyclic derivatives containing nitrogen, sulphur;Metal solubilizer is poloxamer, Tween-80, dodecyl sulphate
One kind, two or more composition in sodium;Metal thickener is PEG-4000, polyacrylic acid, polyacrylamide
Amine;Builder is sodium phosphate, potassium carbonate or benzene sulfonic acid sodium salt.
As a preferred embodiment of the present invention, the method for the alloy as catalyst technique, step is as follows:
1)Take the nickel sulfate of 17~23 parts by weight, the lactic acid of 2~3 parts by weight, the sodium citrate of 1~2 parts by weight, 0.0008~
The sulphur light powder of 0.0012 parts by weight is well mixed to obtain component A;
2)The sodium hypophosphite of 20~26 parts by weight, the sodium acetate of 6~10 parts by weight, the lactic acid of 2~3 parts by weight, 0.5~1
The sodium citrate of parts by weight, the iodine sodium powder of 0.04~0.08 parts by weight, the ammonia potassium powder of 0.3~0.5 parts by weight are well mixed and obtained
B component;
3)Take the well mixed obtained component C of sodium citrate, the ammonia potassium powder of 0.3~0.5 parts by weight of 0.5~1 parts by weight;
4)After adding water fully to dissolve component A obtained above, B component and component C, the environment-friendly type surface alloy catalyzing is produced
Liquid, i.e. layer of iron-nickel alloy.
The beneficial effects of the invention are as follows:
1. the present invention has the advantages that simple in construction, easy for installation, monoblock cast, intensity is high, and service life is long;
2. the present invention, without potassium polypropylene electrophoretic coating and electrophoresis processing technology, thoroughly takes leave of conventional hinge using dark using nanoscale
The history of nickel plating, the adhesion of hinge basic unit is added, reaches the effect for improving hinge antiseptic property;
3. by anti-theft hole, the cooperation between anti-theft bolt and Anti-theft groove, the safety in utilization of hinge is added.
Brief description of the drawings
Fig. 1 is structural representation of the embodiment of the present invention;
Fig. 2 is hinge axis structural representation of the embodiment of the present invention;
Fig. 3 is A-A sectional views of the embodiment of the present invention;
Reference in figure:First hinge 1, the second hinge 2, hinge axis 3, anti-theft hole 5, anti-theft bolt 6, screw thread 7, limited cap 8,
First axle sleeve 11, layer of iron-nickel alloy 13, electrocoating film 14, the second axle sleeve 24, Anti-theft groove 31.
Embodiment
The embodiment of the present invention is elaborated below in conjunction with the accompanying drawings.
Embodiment:As Figure 1-3, a kind of environment-friendly type hinge, including the first hinge 1, the second hinge 2 and hinge axis 3, institute
The first hinge 1 stated is provided with the first axle sleeve 11, and the first hinge 1 and the first axle sleeve 11 are integral type structure;Described second is closed
Page 2 is provided with the second axle sleeve 24, and the second hinge 2 and the second axle sleeve 24 are integral type structure;Add hinge bulk strength and
Firmness, it ensure that safety in utilization;First axle sleeve, 11 and second axle sleeve, the 24 interlaced laying, described hinge axis 3
The first axle sleeve 11 and the second axle sleeve 24 are sequentially passed through, and the both ends of hinge axis 3 are located at two the first axle sleeves 11 of the first hinge 1
Interior, the second described hinge 2 is rotatably assorted with the first hinge 1;The present invention has simple in construction, easy for installation, monoblock cast, by force
The advantages that degree is high, and service life is long;It is provided with first hinge 1, the second hinge 2, the first axle sleeve 11 and the second axle sleeve 24 absolutely
Edge anticorrosive coat;By setting insulating corrosion layer, the corrosion of hinge is ensure that, extends the service life of hinge.
Insulating corrosion layer includes layer of iron-nickel alloy 13 and electrocoating film 14;Electrocoating film 14 is used to protect hinge ground, improves hinge
The anti-corrosion and chemical-resistance of chain, electrocoating film 14 are fitted in layer of iron-nickel alloy 13, and layer of iron-nickel alloy 13 is attached to the first hinge
1st, on the second hinge 2, the first axle sleeve 11 and the second axle sleeve 24;The present invention is using nanoscale without potassium polypropylene electrophoretic coating and electrophoresis
Processing technology, the history that conventional hinge uses the plating of dark nickel is thoroughly taken leave of, improves decay resistance, extending influences the life-span.
The thickness of layer of iron-nickel alloy 13 is 1~2 μm, and the thickness of electrocoating film 14 is 12~16 μm, 14 transparent color of electrocoating film.
The middle part of hinge axis 3 is provided with Anti-theft groove 31, and the annular of Anti-theft groove 31 is laid on hinge axis 3, corresponding, institute
State the first axle sleeve 11 and be provided with the anti-theft hole 5 corresponding with the position of Anti-theft groove 31, anti-theft bolt 6 is installed in anti-theft hole 5;It is antitheft
Bolt 6 is butted in Anti-theft groove 31 through the phase of anti-theft hole 5;By anti-theft hole 5, the cooperation between anti-theft bolt 6 and Anti-theft groove 31, increase
Added the safety in utilization of hinge, when anti-theft bolt 6 is connected in Anti-theft groove 31 by anti-theft hole 5, the upper end of anti-theft bolt 6 with
The upper end of second axle sleeve 24 is in same level, while ensureing antitheft safe to use, does not influence the use of hinge, also not
Influence the aesthetics of hinge.
The both ends of hinge axis 3 are connected with limited cap 8 formed with screw thread 7 on described screw thread 7,7 turns of limited cap 8 and screw thread
Dynamic connection;The setting of limited cap 8 causes hinge to be less likely to be damaged, and service life is longer.
The insulating corrosion layer processing technology of a kind of environment-friendly type hinge, it is characterized in that comprising the following steps:
Step 1:Ultrasonic oil removal:Using medium temperature removing oil-removing wax powder hinge workpiece surface oily waste treatment clean, removing oil-removing wax powder
100-500g, temperature are generally 60-80 degree, minute time 2-10;
Step 2:Surface cleaning processing, hinge workpiece is immersed into degreasing fluid, degreasing fluid is two-in-one degreasing and rust removal liquid medicine, two-in-one
Degreasing and rust removal liquid medicine dosage is 1000-2000 milliliters;Degreasing and rust removal time 2-10min, 60-80 DEG C of temperature;By above-mentioned by removing
The hinge workpiece of oil derusting, which is put into 40-50 DEG C of hot water, to be cleaned repeatedly;Hinge workpiece surface oxide skin and iron rust are removed, will be passed through
The product of hot water wash is put into cold water wash;The part washed through subcooled water is subjected to pickling, then washed;
Step 3:Ironware chemical polishing:By the part in step 2 after surface cleaning is handled, the table being polished is needed to it
Face carries out ironware chemical polishing processing, using ironware chemical polishing liquid medicine, thoroughly removes surface oxide layer, removes cut and hair
Thorn, expose workpiece surface iron true qualities, normal temperature processing, minute time 2-10;
Step 4:Alloy as catalyst:Using environmentally friendly alloy as catalyst technique, on the surface substrate for the hinge workpiece handled well in step 3
The layer of iron-nickel alloy 13 of one layer of 1-2 micron is catalyzed out, black nickel background color, temperature 85-90 degree, time 2- is presented in the layer of iron-nickel alloy 13
10 minutes;
Step 5:Silane antirust:Using silane anti-corrosive technology, on the basis of step 4, protection hinge workpiece ground is not urged completely
The ground of alloy is melted into, prevents from getting rusty, improves antirust ability, under normal temperature state, minute time 2-5;
Step 6:Electrophoresis blooming:Using the ECB-700 high-performance acrylic acids electricity of the high outstanding science and technology limited Company production in Jiangxi Province
Swimming paint, the transparent electrocoating film 14 that electrophoresis on the ground of alloy as catalyst adds one layer of 12-16 micron is carried out in step 5, ground is protected, carries
High alloy layer anti-corrosion and chemical-resistance, salt spray resistance test is set to reach more than 48 hours;
Step 7:Baking:Half an hour is toasted using 160 °C of temperature, makes electrodeposited paint film that film forming be fully cured, is adsorbed in hinge workpiece
Surface.
Hydrofluoric acid that nitric acid and the volume ratio that it is 8%~50% containing volume ratio that the solution of pickling, which is, are 0.05%~6% and
The mixed solution of the deionized water of surplus, etching time are 1~2 minute.
Polish liquid medicine its raw material by weight, including following component:Polishing particles:0.1~100 part;Oxidant A:
0.05~2 part;Oxidant B:0.05~2 part;Metal chelating agent:0.1~10 part;Metal inhibitor:0.1~10 part;Metal increases
Solvent:0.01~0.5 part;Metal thickener:0.01~0.2 part;Builder;0.5~1 part;Aqueous medium:80~90 parts;
Polishing particles provided by the present invention are selected from single-crystal diamond, polycrystalline diamond, alundum (Al2O3), zirconium dioxide, two
At least one of titanium oxide, ceria, fumed silica and cataloid;Inventor has found that polishing particles lead to
The ironware surface reactant being in contact with abrasive grains can be removed by crossing its mechanical abrasive action, so as to realize going for ironware material
Remove, and by adding metal complex so that the oxide or metal ion that metal complex can be formed with ironware surface
Carry out reaction and form soluble complexes, and then improve material removing rate, reduce the defects of metal oxide particle causes, separately
Outside, metal inhibitor can form one layer of fine and close passivating film on ironware surface, so as to prevent from occurring corruption in polishing
Erosion, therefore by using chemical reaction and the synergy of mechanical lapping, ultra-smooth ironware surface can be obtained, and invent
People is had been surprisingly found that by many experiments, the polishing liquid medicine combined using inventive formulation, ironware can be caused to have low surface
Roughness and it is low the defects of quantity functional characteristic.
Ironware chemical polishing liquid medicine provided by the invention includes oxidant A and oxidant B;The oxidant A is selected from iron cyanogen
Change one or more combinations in potassium, potassium permanganate, periodic acid and hydrogen peroxide;The oxidant B is selected from sodium nitrate, chromic acid
Sodium, sodium molybdate, one or more combinations in natrium nitrosum;For medal polish, generally accepted process aoxidizes for metal
The soft aquation oxide layer of matter is formed, then oxide layer is removed, and exposes fresh metal again.Such process is reciprocal, so as to real
Existing polishing process is carried out continuously.For hinge, most of hinge is made of iron or stainless steel material, Cr and Te tools
There is apparent metallicity.Therefore, in the polishing process of hinge surface, oxidant is carried out continuously with pole for polishing process
Its important effect.And inventor promotes Te oxidation, realizes three kinds by the synergy of two kinds of oxidants
The uniform alumina of element.
Metal chelating agent is selected from least one of ammonia, amino acid and organic acid;The metal inhibitor is selected from nitrogenous
Hete rocyclic derivatives, sulfur heterocyclic ring derivative and at least one of Hete rocyclic derivatives containing nitrogen, sulphur simultaneously;Metal solubilizer
For one kind in poloxamer, Tween-80, lauryl sodium sulfate, two or more composition;Metal thickener is
PEG-4000, polyacrylic acid, polyacrylamide;Builder is sodium phosphate, potassium carbonate or benzene sulfonic acid sodium salt.
The method of the alloy as catalyst technique, step are as follows:
1)Take the nickel sulfate of 17~23 parts by weight, the lactic acid of 2~3 parts by weight, the sodium citrate of 1~2 parts by weight, 0.0008~
The sulphur light powder of 0.0012 parts by weight is well mixed to obtain component A;
2)The sodium hypophosphite of 20~26 parts by weight, the sodium acetate of 6~10 parts by weight, the lactic acid of 2~3 parts by weight, 0.5~1
The sodium citrate of parts by weight, the iodine sodium powder of 0.04~0.08 parts by weight, the ammonia potassium powder of 0.3~0.5 parts by weight are well mixed and obtained
B component;
3)Take the well mixed obtained component C of sodium citrate, the ammonia potassium powder of 0.3~0.5 parts by weight of 0.5~1 parts by weight;
4)After adding water fully to dissolve component A obtained above, B component and component C, the environment-friendly type surface alloy catalyzing is produced
Liquid, i.e. layer of iron-nickel alloy 13.
The described above of the disclosed embodiments, professional and technical personnel in the field are enable to realize or using the present invention.It is right
A variety of modifications of these embodiments will be apparent for those skilled in the art, and as defined herein one
As principle can realize in other embodiments without departing from the spirit or scope of the present invention;Therefore, the present invention will
It will not be intended to be limited to the embodiments shown herein, and be to fit to consistent with principles disclosed herein and features of novelty
Most wide scope.
Although reference in figure has more been used herein:First hinge 1, the second hinge 2, hinge axis 3, anti-theft hole 5,
Anti-theft bolt 6, screw thread 7, limited cap 8, the first axle sleeve 11, layer of iron-nickel alloy 13, electrocoating film 14, the second axle sleeve 24, Anti-theft groove 31
Deng term, but it is not precluded from the possibility using other terms.Conciliate using these terms just for the sake of more easily description
Release the essence of the present invention;Any additional limitation is construed as all to disagree with spirit of the present invention.
Claims (10)
- A kind of 1. environment-friendly type hinge, it is characterised in that:Including the first hinge(1), the second hinge(2)And hinge axis(3), it is described First hinge(1)It is provided with the first axle sleeve(11), the first hinge(1)With the first axle sleeve(11)For integral type structure;Described Two hinges(2)It is provided with the second axle sleeve(24), the second hinge(2)With the second axle sleeve(24)For integral type structure;The first axle Set(11)With the second axle sleeve(24)Interlaced laying, described hinge axis(3)Sequentially pass through the first axle sleeve(11)With the second axle Set(24), and hinge axis(3)Both ends be located at the first hinge(1)Two the first axle sleeves(11)The second interior, described hinge(2) With the first hinge(1)It is rotatably assorted;First hinge(1), the second hinge(2), the first axle sleeve(11)With the second axle sleeve(24) On be provided with insulating corrosion layer.
- A kind of 2. environment-friendly type hinge according to claim 1, it is characterised in that:The insulating corrosion layer includes iron-nickel alloy Layer(13)And electrocoating film(14);Electrocoating film(14)Fit in layer of iron-nickel alloy(13)On, layer of iron-nickel alloy(13)It is attached to first Hinge(1), the second hinge(2), the first axle sleeve(11)With the second axle sleeve(24)On.
- A kind of 3. environment-friendly type hinge according to claim 2, it is characterised in that:The layer of iron-nickel alloy(13)Thickness be 1~2 μm, electrocoating film(14)Thickness be 12~16 μm, electrocoating film(14)Transparent color.
- A kind of 4. environment-friendly type hinge according to claim 1, it is characterised in that:The hinge axis(3)Middle part be provided with it is anti- Steal groove(31), Anti-theft groove(31)Annular is laid in hinge axis(3)On, corresponding, first axle sleeve(11)It is provided with With Anti-theft groove(31)The corresponding anti-theft hole in position(5), anti-theft hole(5)On anti-theft bolt is installed(6);Anti-theft bolt(6)Wear Cross anti-theft hole(5)Mutually it is butted on Anti-theft groove(31)It is interior.
- A kind of 5. environment-friendly type hinge according to claim 4, it is characterised in that:The hinge axis(3)Both ends formed with Screw thread(7), described screw thread(7)On be connected with limited cap(8), limited cap(8)With screw thread(7)Rotation connection.
- 6. it is a kind of apply as claim 1-5 arbitrarily as described in insulating corrosion layer processing technology, it is characterized in that including following step Suddenly:Step 1:Ultrasonic oil removal:Using medium temperature removing oil-removing wax powder hinge workpiece surface oily waste treatment clean, removing oil-removing wax powder 100-500g, temperature are generally 60-80 degree, minute time 2-10;Step 2:Surface cleaning processing, hinge workpiece is immersed into degreasing fluid, degreasing fluid is two-in-one degreasing and rust removal liquid medicine, two-in-one Degreasing and rust removal liquid medicine dosage is 1000-2000 milliliters;Degreasing and rust removal time 2-10min, 60-80 DEG C of temperature;By above-mentioned by removing The hinge workpiece of oil derusting, which is put into 40-50 DEG C of hot water, to be cleaned repeatedly;Hinge workpiece surface oxide skin and iron rust are removed, will be passed through The product of hot water wash is put into cold water wash;The part washed through subcooled water is subjected to pickling, then washed;Step 3:Ironware chemical polishing:By the part in step 2 after surface cleaning is handled, the table being polished is needed to it Face carries out ironware chemical polishing processing, using ironware chemical polishing liquid medicine, thoroughly removes surface oxide layer, removes cut and hair Thorn, expose workpiece surface iron true qualities, normal temperature processing, minute time 2-10;Step 4:Alloy as catalyst:Using environmentally friendly alloy as catalyst technique, on the surface substrate for the hinge workpiece handled well in step 3 It is catalyzed out the layer of iron-nickel alloy of one layer of 1-2 micron(13), the layer of iron-nickel alloy(13)It is presented black nickel background color, temperature 85-90 degree, when Between 2-10 minutes;Step 5:Silane antirust:Using silane anti-corrosive technology, on the basis of step 4, protection hinge workpiece ground is not urged completely The ground of alloy is melted into, prevents from getting rusty, improves antirust ability, under normal temperature state, minute time 2-5;Step 6:Electrophoresis blooming:Using the ECB-700 high-performance acrylic acids electricity of the high outstanding science and technology limited Company production in Jiangxi Province Swimming paint, the transparent electrocoating film that electrophoresis on the ground of alloy as catalyst adds one layer of 12-16 micron is carried out in step 5(14), ground is protected, Alloy-layer anti-corrosion and chemical-resistance are improved, salt spray resistance test is reached more than 48 hours;Step 7:Baking:Half an hour is toasted using 160 °C of temperature, makes electrodeposited paint film that film forming be fully cured, is adsorbed in hinge workpiece Surface.
- 7. insulating corrosion layer processing technology according to claim 6, it is characterised in that:The solution of the pickling be containing The hydrofluoric acid and the mixed solution of the deionized water of surplus that the nitric acid that volume ratio is 8%~50% is 0.05%~6% with volume ratio, acid It is 1~2 minute to lose the time.
- 8. insulating corrosion layer processing technology according to claim 6, it is characterised in that:Described its raw material of polishing liquid medicine is by weight Measure part meter, including following component:Polishing particles:0.1~100 part;Oxidant A:0.05~2 part;Oxidant B:0.05~2 part; Metal chelating agent:0.1~10 part;Metal inhibitor:0.1~10 part;Metal solubilizer:0.01~0.5 part;Metal thickener: 0.01~0.2 part;Builder;0.5~1 part;Aqueous medium:80~90 parts.
- 9. insulating corrosion layer processing technology according to claim 8, it is characterised in that:The polishing particles are selected from monocrystalline Diamond, polycrystalline diamond, alundum (Al2O3), zirconium dioxide, titanium dioxide, ceria, fumed silica and colloid two At least one of silica;One kind in the potassium ferricyanide, potassium permanganate, periodic acid and hydrogen peroxide of the oxidant A or A variety of combinations;The oxidant B is selected from sodium nitrate, sodium chromate, sodium molybdate, one or more combinations in natrium nitrosum; The metal chelating agent is selected from least one of ammonia, amino acid and organic acid;The metal inhibitor is selected from nitrogen heterocyclic ring Derivative, sulfur heterocyclic ring derivative and at least one of Hete rocyclic derivatives containing nitrogen, sulphur simultaneously;Metal solubilizer is pool One kind, two or more composition in Luo Shamu, Tween-80, lauryl sodium sulfate;Metal thickener is poly- second Glycol -4000, polyacrylic acid, polyacrylamide;Builder is sodium phosphate, potassium carbonate or benzene sulfonic acid sodium salt.
- 10. insulating corrosion layer processing technology according to claim 6, it is characterised in that:The side of the alloy as catalyst technique Method, step are as follows:1)Take the nickel sulfate of 17~23 parts by weight, the lactic acid of 2~3 parts by weight, the sodium citrate of 1~2 parts by weight, 0.0008~ The sulphur light powder of 0.0012 parts by weight is well mixed to obtain component A;2)The sodium hypophosphite of 20~26 parts by weight, the sodium acetate of 6~10 parts by weight, the lactic acid of 2~3 parts by weight, 0.5~1 The sodium citrate of parts by weight, the iodine sodium powder of 0.04~0.08 parts by weight, the ammonia potassium powder of 0.3~0.5 parts by weight are well mixed and obtained B component;3)Take the well mixed obtained component C of sodium citrate, the ammonia potassium powder of 0.3~0.5 parts by weight of 0.5~1 parts by weight;4)After adding water fully to dissolve component A obtained above, B component and component C, the environment-friendly type surface alloy catalyzing is produced Liquid, i.e. layer of iron-nickel alloy(13).
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CN103014783A (en) * | 2012-12-17 | 2013-04-03 | 北京中科创新科技发展中心 | Environment-friendly surface alloyed catalytic liquid, preparation method and application method thereof |
CN203285204U (en) * | 2013-03-18 | 2013-11-13 | 绍兴县飞凡车辆配件有限公司 | Hinge |
CN203547338U (en) * | 2013-09-25 | 2014-04-16 | 合肥美的电冰箱有限公司 | Corrosion-resistant refrigerator door hinge |
CN204715963U (en) * | 2015-06-18 | 2015-10-21 | 温州市隆泰铰链有限公司 | A kind of open limit hinge |
CN205822998U (en) * | 2016-07-26 | 2016-12-21 | 历延辉 | Adjustable hinge |
CN206844907U (en) * | 2017-06-30 | 2018-01-05 | 浙江省平湖铰链有限公司 | A kind of environment-friendly type hinge |
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CN112814506A (en) * | 2020-12-24 | 2021-05-18 | 江苏银奕达科技股份有限公司 | Connecting structure of connecting piece for aluminum alloy window and preparation process of connecting structure |
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