CN107446545A - A kind of heat-insulating flame-retardant double glazing and preparation method thereof - Google Patents
A kind of heat-insulating flame-retardant double glazing and preparation method thereof Download PDFInfo
- Publication number
- CN107446545A CN107446545A CN201710642404.4A CN201710642404A CN107446545A CN 107446545 A CN107446545 A CN 107446545A CN 201710642404 A CN201710642404 A CN 201710642404A CN 107446545 A CN107446545 A CN 107446545A
- Authority
- CN
- China
- Prior art keywords
- heat
- double glazing
- glass
- retardant
- insulating flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- B32B17/064—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/162—Cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to glass for building purposes technical field, specifically a kind of double glazing of heat-insulating flame-retardant and preparation method thereof, described heat-insulating flame-retardant double glazing, including glass outer piece, inner layer glass piece and positioned at outer, wall between inner layer glass piece, described is outer, coated with the heat-insulated glue-line that thickness is 10~20 μm on relative side between layer sheet glass, anti-flammability PET film is also bonded with outside described heat-insulated glue-line, heat-insulating flame-retardant double glazing provided by the invention, heat-insulated glue-line is with the addition of in double glazing, the heat-proof quality of double glazing is greatly improved, the PET film of anti-flammability has also been bonded on heat-insulated glue-line simultaneously, the explosion of glass even occurs in a fire, described PET anti-flammabilitys film also can further prevent the sprawling of the intensity of a fire.
Description
Technical field
The present invention relates to glass for building purposes technical field, the double glazing of specifically a kind of heat-insulating flame-retardant and its preparation
Method.
Background technology
In recent years, with human society science and economic sustainable development, the glass that more represent the aesthetics of architecture moves towards
Huge numbers of families, building is using natural lighting and the aesthetic feeling of increase building that glass is for building.The natural lighting of building is in profit
While with visible ray, ultraviolet, infrared ray also enter interior.The shorter ultraviolet of wavelength in sunshine is not only to furniture
Damage, while the damage of skin can be also caused to human body, produces the diseases such as canceration;Infrared ray in sunshine is got in
Cause indoor object or spacial temperature elevation, heating of this thermogenic action to winter be it is beneficial, still, the excessive infrared ray of summer
The thermogenic action got in, the comfort level of human body is impacted.How effectively to make glass that there is heat insulating function, suitable for the summer
Season heat-insulated demand and Winter protection demand building glass exploitation into research importance.
With increasing for skyscraper, the use of safety glass is paid much attention to by various circles of society.In order to avoid high level
Disintegrating slag of the glass of building after broken is hurted sb.'s feelings event, and what current skyscraper used is all glue doubling steel glass, such as existing
PVB laminated glass is the safety glass that modern architecture uses, and is the real safety glass in the market with practical significance.
Glass fragment after the glass breakage of PVB laminated glass is still firmly sticked on PVB intermediate coats, effectively prevents glass breakage
Secondary injury accident afterwards occurs.However, barrier of the common PVB laminated glass to ultraviolet and infrared solar radiation is small, reach
Less than the ultraviolet and the purpose of infrared ray effectively obstructed in sunray.
In the prior art, the safety glass with heat-proof quality has had substantial amounts of research, such as CN103011622A at present
A kind of coated laminated glass and its manufacture method are disclosed, the preparation method of the laminated glass is the table in first layer glass
Face metal-plated membrane layer or metal oxide layer, then form laminated glass with polymeric film and second layer glass.Because its is heat-insulated
Mechanism is the heat reflection effect of metallic diaphragm or metal oxide layer used, therefore the metallic diaphragm or metal oxide layer are to week
Surrounding environment produces light pollution;The metallic diaphragm or metal oxide layer be using vacuum plasma method of spray plating formed, it is necessary to
Expensive equipment production;In order to prevent metallic diaphragm or metal oxide layer ingress of air from going bad, before laminated glass is prepared,
Metal level close to glass edge and metal oxide layer must also be polished off, then with polymer glued membrane edge sealing, its technique
Complicated and equipment investment is big;Insulation problem of the patented technology without reference to building glass simultaneously.
In addition, as cut-off material common in skyscraper, the anti-flammability of glass is also mentioned suitable to heat-insulated demand
Level, and have fire-retardant and heat-insulated glass concurrently at present and be rarely reported.
The content of the invention
For the problems of the prior art, it is an object of the invention to provide a kind of hollow glass for having heat-insulating flame-retardant performance concurrently
Glass.
To achieve these goals, the present invention is achieved using following technical scheme:A kind of heat-insulating flame-retardant double glazing,
Including glass outer piece, inner layer glass piece and the wall between outer, inner layer glass piece, described outer, layer sheet glass
Between on relative side coated with the heat-insulated glue-line that thickness is 10~20 μm, be also bonded with anti-flammability outside described heat-insulated glue-line
PET film.
Heat-insulated glue-line is coated in the adjacent side of double glazing, with reference to the low heat conductivity of air in double glazing, significantly
The heat-proof quality of double glazing is improved, meanwhile, the PET film of anti-flammability is also bonded with heat-insulated glue-line, even if glass is in height
Temperature is lower to burst, and the PET film of anti-flammability is also avoided that the sprawling of the intensity of a fire.
In the present invention, described heat-insulated glue-line includes the material of following parts by weight:70~83 parts of solidified glue, coated particle
5~15 parts, 0.2~2 part of glass microballoon, 3~10 parts of titanium dioxide, 0.01~0.1 part of levelling agent, 0.01~0.1 part of defoamer, resistance
Fire 0.1~2 part of agent, 0.1~1 part of ultra-violet absorber.
Glass microballoon is hollow structure, is filled in the thermal conductivity factor for being easy to reduce glue-line in glue-line, and titanium dioxide can have
Reflecting light for effect, avoids infrared ray etc. from being directed through effect of the glass to being internally heated.
According to the present invention, described levelling agent, defoamer are well known to those skilled in the art, can be selected from silicone oil,
One kind or more in dimethyl silicone polymer class, polydimethylsiloxane, polyethers or polyester modified organic siloxane, esters of acrylic acid
Kind;The one kind or more of described defoamer in tributyl phosphate, isooctanol, dimethicone, silicone grease class, SPA~202
Kind.
According to the present invention, described ultra-violet absorber is known to those skilled in the art, specifically, such as azimidobenzene class
UV absorbers.
The crystal formation of the titanium dioxide of rutile-type tends to hexahedron, compared to the titanium dioxide of anatase titanium dioxide, rutile type titanium
White powder is easier to be uniformly dispersed, and particle diameter distribution is also more narrow, and heretofore described titanium dioxide is rutile-type, and titanium dioxide is put down
Equal particle diameter is 0.1~0.5 μm.
According to the present invention, described fire retardant includes phosphorus-nitrogen containing flame retardant or halogenated flame retardant or its combination, specifically, institute
Stating phosphorus-nitrogen containing flame retardant includes hydroxy phenyl phosphonoacetic acid, hydroxy phenyl phosphinylidyne propionic acid, triphenyl phosphate, APP, phosphoric acid
Three (2,3~bis- chloropropyl) esters (TDCPP), melamine pyrophosphate (MPP) or melamine cyanurate (MCA);It is described
Halogenated flame retardant includes TDE or deca-BDE.
According to the present invention, the bulk density of described glass microballoon is 80~120kg/m3。
The effect of coated particle is to be scattered light, and described coated particle is well known to those skilled in the art
, it may be selected from one kind in silica, polymethyl methacrylate, polybutyl methacrylate or polyester or at least two
Combination, further, the particle diameter of the coated particle is 2~10 μm.
Present invention also offers a kind of preparation method of heat-insulating flame-retardant double glazing, comprise the following steps:
(1) after outer, inner layer glass is cleaned up, 0.01mol/L hydrofluoric acid etches are imposed go out bumps on precoating cloth cover
Point, then clean up rear standby;
(2) by formula weigh solidified glue, coated particle, glass microballoon, titanium dioxide, levelling agent, defoamer, fire retardant and
Ultra-violet absorber, outer, the inner layer glass being then coated in agitator with agitator after well mixed in step (1) are located in advance
On the side managed, upper anti-flammability PET film is then bonded respectively, is placed in 100~120 DEG C of dry 3~5min in baking oven;
(3) one side that outer, the inner layer glass in step (2) are pasted with to anti-flammability PET film is involutory piece, glue to be sealed
After being fully cured, double glazing is produced.
According to the present invention, in order to improve the adhesive property of PET film, pre-bonding junction passes through Electrostatic Treatment.
Compared with prior art, heat-insulating flame-retardant double glazing provided by the invention, with the addition of adiabatic gum in double glazing
Layer, the heat-proof quality of double glazing is greatly improved, while the PET film of anti-flammability has also been bonded on heat-insulated glue-line,
The explosion of glass even occurs in a fire, described PET anti-flammabilitys film also can further prevent the sprawling of the intensity of a fire.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is furture elucidated.
Embodiment 1
A kind of heat-insulating flame-retardant double glazing, including glass outer piece, inner layer glass piece and positioned at outer, inner layer glass piece it
Between wall, it is described coated with the heat-insulated glue-line that thickness is 15 μm on relative side between described outer, layer sheet glass
Anti-flammability PET film is also bonded with outside heat-insulated glue-line.
Described heat-insulated glue-line includes the material of following parts by weight:78 parts of solidified glue, 10 parts of polymethyl methacrylate,
1 part of glass microballoon, 8 parts of rutile type titanium white, 0.05 part of silicone oil, 0.05 part of tributyl phosphate, the resistance of hydroxy phenyl phosphonoacetic acid
Fire 1 part of agent, 0.5 part of azimidobenzene class ultra-violet absorber.
The average grain diameter of described rutile type titanium white is 0.2 μm;
The bulk density of described glass microballoon is 100kg/m3;
The particle diameter of described polymethyl methacrylate is 5 μm;
The preparation method of the heat-insulating flame-retardant double glazing comprises the following steps:
(1) after outer, inner layer glass is cleaned up, precoating cloth cover on impose 0.01mol/L hydrofluoric acid etch go out it is recessed
Salient point, then clean up rear standby;
(2) by formula weigh solidified glue, polymethyl methacrylate, glass microballoon, rutile type titanium white, silicone oil,
Tributyl phosphate, hydroxy phenyl phosphonoacetic acid fire retardant and azimidobenzene class ultra-violet absorber, then in agitator with stirring
Mix device it is well mixed after be coated on the outer, side that inner layer glass is pretreated in step (1), then fitting is upper fire-retardant respectively
Property PET film, is placed in 110 DEG C of dry 5min in baking oven;
(3) one side that outer, the inner layer glass in step (2) are pasted with to anti-flammability PET film is involutory piece, glue to be sealed
After being fully cured, double glazing is produced, the pre-bonding junction of described anti-flammability PET film passes through Electrostatic Treatment.
Embodiment 2
A kind of heat-insulating flame-retardant double glazing, including glass outer piece, inner layer glass piece and positioned at outer, inner layer glass piece it
Between wall, it is described coated with the heat-insulated glue-line that thickness is 10 μm on relative side between described outer, layer sheet glass
Anti-flammability PET film is also bonded with outside heat-insulated glue-line.
Described heat-insulated glue-line includes the material of following parts by weight:70 parts of solidified glue, 5 parts of polybutyl methacrylate,
0.2 part of glass microballoon, 3 parts of rutile type titanium white, 0.01 part of polydimethylsiloxane, 0.01 part of isooctanol, triphenyl phosphate 0.1
Part, 0.1 part of azimidobenzene class ultra-violet absorber.
The average grain diameter of described rutile type titanium white is 0.3 μm;
The bulk density of described glass microballoon is 110kg/m3;
The particle diameter of described polybutyl methacrylate is 8 μm;
The preparation method of the heat-insulating flame-retardant double glazing comprises the following steps:
(1) after outer, inner layer glass is cleaned up, precoating cloth cover on impose 0.01mol/L hydrofluoric acid etch go out it is recessed
Salient point, then clean up rear standby;
(2) solidified glue, polybutyl methacrylate, glass microballoon, rutile type titanium white, poly- diformazan are weighed by formula
Base silane, isooctanol, triphenyl phosphate and azimidobenzene class ultra-violet absorber, then mixed in agitator with agitator equal
It is coated to after even on outer, side that inner layer glass is pretreated in step (1), is then bonded upper anti-flammability PET film respectively,
It is placed in 120 DEG C of dry 4min in baking oven;
(3) one side that outer, the inner layer glass in step (2) are pasted with to anti-flammability PET film is involutory piece, glue to be sealed
After being fully cured, double glazing is produced, the pre-bonding junction of described anti-flammability PET film passes through Electrostatic Treatment.
Embodiment 3
A kind of heat-insulating flame-retardant double glazing, including glass outer piece, inner layer glass piece and positioned at outer, inner layer glass piece it
Between wall, it is described coated with the heat-insulated glue-line that thickness is 20 μm on relative side between described outer, layer sheet glass
Anti-flammability PET film is also bonded with outside heat-insulated glue-line.
Described heat-insulated glue-line includes the material of following parts by weight:83 parts of solidified glue, 15 parts of polyester coated particle, glass
2 parts of microballon, 10 parts of rutile type titanium white, 0.1 part of polydimethylsiloxane, defoamer SPA~2020.1 part, melamine cyanurea
2 parts of hydrochlorate fire retardant, 1 part of azimidobenzene class ultra-violet absorber.
The average grain diameter of described rutile type titanium white is 0.2 μm;
The bulk density of described glass microballoon is 120kg/m3;
The particle diameter of described polyester coated particle is 10 μm;
The preparation method of the heat-insulating flame-retardant double glazing comprises the following steps:
(1) after outer, inner layer glass is cleaned up, precoating cloth cover on impose 0.01mol/L hydrofluoric acid etch go out it is recessed
Salient point, then clean up rear standby;
(2) solidified glue, polyester coated particle, glass microballoon, rutile type titanium white, poly dimethyl silicon are weighed by formula
Alkane, defoamer SPA~202, melamine cyanurate flame retardant and azimidobenzene class ultra-violet absorber, then in agitator
It is interior to be coated to agitator after well mixed on outer, side that inner layer glass is pretreated in step (1), then it is bonded respectively
Upper anti-flammability PET film, it is placed in 100 DEG C of dry 5min in baking oven;
(3) one side that outer, the inner layer glass in step (2) are pasted with to anti-flammability PET film is involutory piece, glue to be sealed
After being fully cured, double glazing is produced, the pre-bonding junction of described anti-flammability PET film passes through Electrostatic Treatment.
The thermal conductivity factor of testing example 1~3 and common double glazing, using leading for capital of a country Electronics Industry Company manufacture
Hot coefficient meter " quick conductive coefficient measuring instrument QTM~500 " are determined to the thermal conductivity factor of insulating trip, and by test result
It recorded in table 1.
The thermal conductivity factor of the embodiment 1~3 of table 1 and common double glazing
Embodiment | Thermal conductivity factor (W/ (m2·K)) |
Embodiment 1 | 0.9 |
Embodiment 2 | 0.9 |
Embodiment 3 | 1.0 |
Ordinary insulating glass | 1.9 |
It can be drawn by above test data, insulating hollow glass provided by the invention has relatively low thermal conductivity factor.
General principle, principal character and the features of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement is both fallen within the range of claimed invention.The scope of protection of present invention is by appended claims
And its equivalent thereof.
Claims (10)
1. a kind of heat-insulating flame-retardant double glazing, including glass outer piece, inner layer glass piece and between outer, inner layer glass piece
Wall, it is characterised in that:Between described outer, layer sheet glass on relative side coated with thickness be 10~20 μm every
Hot glue layer, described heat-insulated glue-line are also bonded with anti-flammability PET film outside.
2. heat-insulating flame-retardant double glazing according to claim 1, it is characterised in that:Described heat-insulated glue-line includes following heavy
Measure the material of part:70~83 parts of solidified glue, 5~15 parts of coated particle, 0.2~2 part of glass microballoon, 3~10 parts of titanium dioxide, stream
Flat 0.01~0.1 part of agent, 0.01~0.1 part of defoamer, 0.1~2 part of fire retardant, 0.1~1 part of ultra-violet absorber.
3. heat-insulating flame-retardant double glazing according to claim 2, it is characterised in that:Described titanium dioxide is rutile-type,
The average grain diameter of titanium dioxide is 0.1~0.5 μm.
4. heat-insulating flame-retardant double glazing according to claim 2, it is characterised in that:Described fire retardant hinders including phosphorus nitrogen system
Fire agent or halogenated flame retardant or its combination.
5. heat-insulating flame-retardant double glazing according to claim 2, it is characterised in that:The bulk density of described glass microballoon
For 80~120kg/m3。
6. heat-insulating flame-retardant double glazing according to claim 1, it is characterised in that:Described coated particle is selected from titanium dioxide
One kind or at least two combination in silicon, polymethyl methacrylate, polybutyl methacrylate or polyester.
7. heat-insulating flame-retardant double glazing according to claim 1, it is characterised in that:The particle diameter of the coated particle be 2~
10μm。
A kind of 8. preparation method of heat-insulating flame-retardant double glazing as described in claim 1~7 any one, it is characterised in that:
Comprise the following steps:
(1) after outer, inner layer glass is cleaned up, impose hydrofluoric acid etch on precoating cloth cover and go out sags and crests, then clean up
It is standby afterwards;
(2) solidified glue, coated particle, glass microballoon, titanium dioxide, levelling agent, defoamer, fire retardant and ultraviolet are weighed by formula
Light absorbers, the outer, inner layer glass being then coated in agitator with agitator after well mixed in step (1) are pretreated
Side on, be then bonded upper anti-flammability PET film respectively, be placed in 100~120 DEG C of dry 3~5min in baking oven;
(3) one side that outer, the inner layer glass in step (2) are pasted with to anti-flammability PET film is involutory piece, and glue to be sealed is complete
After solidification, double glazing is produced.
9. the preparation method of heat-insulating flame-retardant double glazing according to claim 8, it is characterised in that:Described step (1)
The concentration of middle hydrofluoric acid is 0.01mol/L.
10. the preparation method of heat-insulating flame-retardant double glazing according to claim 8, it is characterised in that:Described step (3)
The pre-bonding junction of middle anti-flammability PET film passes through Electrostatic Treatment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710642404.4A CN107446545B (en) | 2017-07-31 | 2017-07-31 | A kind of heat-insulating flame-retardant hollow glass and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710642404.4A CN107446545B (en) | 2017-07-31 | 2017-07-31 | A kind of heat-insulating flame-retardant hollow glass and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107446545A true CN107446545A (en) | 2017-12-08 |
CN107446545B CN107446545B (en) | 2019-03-22 |
Family
ID=60490570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710642404.4A Active CN107446545B (en) | 2017-07-31 | 2017-07-31 | A kind of heat-insulating flame-retardant hollow glass and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107446545B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111410438A (en) * | 2020-04-27 | 2020-07-14 | 东莞市嘉镁光学电子有限公司 | Wear-resisting vehicle-mounted glass outer screen |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102757754A (en) * | 2011-04-29 | 2012-10-31 | 中国林业科学研究院木材工业研究所 | Flame-retardant adhesive and preparation method thereof |
CN204095224U (en) * | 2014-08-18 | 2015-01-14 | 中国乐凯集团有限公司 | A kind of heat-insulating laminated glass |
CN105696916A (en) * | 2016-03-04 | 2016-06-22 | 王作刚 | Hollow glass with pasting film insides |
-
2017
- 2017-07-31 CN CN201710642404.4A patent/CN107446545B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102757754A (en) * | 2011-04-29 | 2012-10-31 | 中国林业科学研究院木材工业研究所 | Flame-retardant adhesive and preparation method thereof |
CN204095224U (en) * | 2014-08-18 | 2015-01-14 | 中国乐凯集团有限公司 | A kind of heat-insulating laminated glass |
CN105696916A (en) * | 2016-03-04 | 2016-06-22 | 王作刚 | Hollow glass with pasting film insides |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111410438A (en) * | 2020-04-27 | 2020-07-14 | 东莞市嘉镁光学电子有限公司 | Wear-resisting vehicle-mounted glass outer screen |
Also Published As
Publication number | Publication date |
---|---|
CN107446545B (en) | 2019-03-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101901486B1 (en) | Heat dissipation structure and wind power unit for heat generating equipment | |
Luo et al. | Experimental study and performance evaluation of a PV-blind embedded double skin façade in winter season | |
TW304177B (en) | ||
CN101289281B (en) | Insulating mold coating for high-transparent glass | |
CN102808495B (en) | Infrared spontaneously heating floor and process thereof | |
Zhang et al. | Experimental and numerical studies on the thermal and electrical performance of a CdTe ventilated window integrated with vacuum glazing | |
CN106746756A (en) | A kind of preparation method of pad pasting glass | |
CN104669745B (en) | A kind of building environmental-protection refrigeration pad pasting based on photonic crystal | |
CN107446545B (en) | A kind of heat-insulating flame-retardant hollow glass and preparation method thereof | |
CN104708875A (en) | Antifog heat insulating film | |
KR20170127403A (en) | Light-permeable heat protection element | |
CN203007140U (en) | Microbubble-free composite flameproof glass with antireflection film coating | |
Li et al. | A radiative cooling paper based on ceramic fiber for thermal management of human head | |
CN101798185A (en) | Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof | |
KR100870908B1 (en) | Composition for adiabatic material with hollow micro silica capsule, adiabatic material using thereit and preparation method of the adiabatic material, and adiabatic film of glass in building | |
Han et al. | Near-infrared blocking window based on ATO-CWO/PVB nano-lamination | |
CN206616741U (en) | Glass curtain wall | |
Huang et al. | Full-scale evaluation of fire-resistant building integrated photovoltaic systems with different installation positions of junction boxes | |
CN102936432A (en) | Infrared shielding composition and preparation method and application thereof | |
Liebold et al. | Fluiglass-Façade Elements for Active Solar Control for High-Rise Buildings | |
CN203410118U (en) | Energy-saving protective material mounted on surface of glass | |
CN204983416U (en) | High reflectivity sun thermoreflectance color steel sandwich panel that insulates against heat | |
CN110407486A (en) | The preparation method of laminated glass, the production equipment of laminated glass and laminated glass | |
CN110130791A (en) | A kind of high reflecting glass window | |
CN108930491A (en) | A kind of energy-saving and environment-friendly compound glass and installation method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |