CN107435242A - Anti-ultraviolet wool fabric is prepared with the NMMO aqueous solution - Google Patents
Anti-ultraviolet wool fabric is prepared with the NMMO aqueous solution Download PDFInfo
- Publication number
- CN107435242A CN107435242A CN201710787931.4A CN201710787931A CN107435242A CN 107435242 A CN107435242 A CN 107435242A CN 201710787931 A CN201710787931 A CN 201710787931A CN 107435242 A CN107435242 A CN 107435242A
- Authority
- CN
- China
- Prior art keywords
- wool fabric
- wool
- particle
- lysate
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000002268 wool Anatomy 0.000 title claims abstract description 42
- 239000004744 fabric Substances 0.000 title claims abstract description 32
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002105 nanoparticle Substances 0.000 claims abstract description 17
- 239000000243 solution Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000006166 lysate Substances 0.000 claims abstract description 12
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- JLHMVTORNNQCRM-UHFFFAOYSA-N ethylphosphine Chemical compound CCP JLHMVTORNNQCRM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 239000003643 water by type Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229960001296 zinc oxide Drugs 0.000 description 8
- 102000004169 proteins and genes Human genes 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 102000018697 Membrane Proteins Human genes 0.000 description 1
- 108010052285 Membrane Proteins Proteins 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides a kind of method that anti-ultraviolet wool fabric is prepared using the NMMO aqueous solution, this method comprises the following steps：（1）NMMO, tricarboxylic ethyl phosphine are dissolved into ethanol/water（Volume ratio is 1:4）In；（2）In step（1）Zinc oxide nano-particle is added in obtained solution, is stirred vigorously down and obtains the lysate for being dispersed with zinc oxide nano-particle；（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained；（4）Wool fabric after padding is heated under hot blast；（5）Wool fabric after heating is impregnated in ethanol solution and solidified, then washes, dry.This technology of preparing is simple and easy, and cost is cheap, small to the strength damage of wool fabric, does not change wool surface performance, and zinc oxide nano-particle has good fastness on wool fabric；Any adhesive is not used in this preparation process, it is nontoxic.
Description
Technical field
It is especially a kind of to prepare uvioresistant sheep using the NMMO aqueous solution the present invention relates to a kind of preparation method of function fabric
The method of wool fabric.
Background technology
Nano-particle is introduced into textile fabric, functional fiber material can be prepared.Nano-particle is drawn at present
It is many to enter the preparation method of wool fiber, such as：Absorption method, sol-gal process, layer assembly method, coating etc..However, absorption method
By mainly making nano-particle be adsorbed onto wool surface by intermolecular Van der Waals force and ionic forces, washing fastness compared with
It is low；The technical process of sol-gal process and layer assembly method is longer, and more difficult control；Coating is to utilize adhesive by nanoparticle
Son is adhered to wool surface, reduces skin-friendly of the wool fiber to human body.
N-methylmorpholine-N- oxides（NMMO）A kind of white crystal, with certain proportion be dissolved in water water white transparency
N-methylmorpholine-N- oxide water solutions, be mainly used in plant cellulose high-performance solvent.After 100oC, NMMO can be with
Thorough solubilising protein macromolecular, obtains the regenerated protein solution of concentration 20% or so.
Tricarboxylic ethyl phosphine（TCEP）It is a kind of very effective thio-alcohol reducing agent, is widely used as protein chemistry and albumen
The Quantitative reduction agent of disulfide bond in the research of matter group.Reagent stability in aqueous and dissolubility are all fine.It is acid,
Stability in alkaline solution is also good.Compared with the thio-alcohol reducing agent such as DTT of other classifications, TCEP is not only a kind of efficient
Disulfide bond reducing agent, and need not be removed in the cross-linking reaction of some sulfydryls.TCEP in very wide pH range all
Selectively can quantitatively it reduce even water-soluble very poor alkyls disulfide.Generally react at room temperature less than 5 minutes
Can is completed.TCEP does not have niff, and is not afraid of oxidation in atmosphere.Thus in protein chemistry and protein group
Learn research usually prioritizing selection TCEP.
The content of the invention
The technical problems to be solved by the invention are the shortcomings that presence for above prior art, propose a kind of use
The method that the NMMO aqueous solution prepares anti-ultraviolet wool fabric.The technology of preparing is simple and easy, and cost is cheap, to the strong of wool fabric
Power damage is small, does not change wool surface performance, zinc oxide nano-particle has good fastness on wool fabric；The system
Any adhesive is not used during standby, it is nontoxic.
To achieve these goals, the solution taken of the present invention is：One kind prepares uvioresistant using the NMMO aqueous solution
The method of wool fabric, it is characterised in that comprise the following steps：
（1）5-40gNMMO, 1-3g tricarboxylic ethyl phosphine are dissolved into 100ml ethanol/waters（Volume ratio is 1:4）In；
（2）In step（1）0.1-1.5g zinc oxide nano-particles are added in obtained solution, be stirred vigorously down obtain it is scattered aerobic
Change the lysate of zinc nano-particle；
（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained；
（4）Wool fabric after padding is heated into 10-30min under 80-150 DEG C of hot blast；
（5）Wool fabric after heating is impregnated in ethanol solution and solidified, then washes, dry.
The beneficial effects of the present invention are,（1）The limited NMMO aqueous solution is set to be distributed mainly on wool fibre using padding method
The surface of dimension, the Hot-blast Heating of short time can only be partly dissolved to wool surface, without damaging in wool fiber
Portion, reduce the damage to wool fiber and fabric；（2）In the partly soluble wool protein of wool surface
Protein compression solution is formed, there is adhesive attraction to nano-particle；（3）The protein compression solution that wool surface is formed is in second
Solidified again in alcoholic solution, play bonding to nano-particle, package action；（4）Any adhesive is not used in preparation process,
It is nontoxic.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic is not construed as isolated, and they can be mutually combined so as to reach more preferable
Technique effect.
Embodiment 1
（1）30gNMMO, 3g tricarboxylic ethyl phosphine are dissolved into 100ml ethanol/waters（Volume ratio is 1:4）In；
（2）In step（1）0.4g zinc oxide nano-particles are added in resulting solution, is stirred vigorously down and obtains being dispersed with zinc oxide nano
The lysate of rice corpuscles；
（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained, pick-up 90%；
（4）Wool fabric after padding is heated into 20min under 120 DEG C of hot blasts；
（5）Wool fabric after heating is impregnated in ethanol solution and solidifies 10min, then washes, dry.
Embodiment 2
（1）35gNMMO, 2g tricarboxylic ethyl phosphine are dissolved into 100ml ethanol/waters（Volume ratio is 1:4）In；
（2）In step（1）0.6g zinc oxide nano-particles are added in resulting solution, is stirred vigorously down and obtains being dispersed with zinc oxide nano
The lysate of rice corpuscles；
（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained, pick-up 100%；
（4）Wool fabric after padding is heated into 10min under 150 DEG C of hot blasts；
（5）Wool fabric after heating is impregnated in ethanol solution and solidifies 10min, then washes, dry.
Embodiment 3
（1）5gNMMO, 2g tricarboxylic ethyl phosphine are dissolved into 100ml ethanol/waters（Volume ratio is 1:4）In；
（2）In step（1）1g zinc oxide nano-particles are added in resulting solution, is stirred vigorously down and obtains being dispersed with zinc-oxide nano
The lysate of particle；
（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained, pick-up 110%；
（4）Wool fabric after padding is heated into 15min under 130 DEG C of hot blasts；
（5）Wool fabric after heating is impregnated in ethanol solution and solidifies 10min, then washes, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
Restriction that should be using the embodiments herein as interest field of the present invention.
Claims (1)
- A kind of 1. method that anti-ultraviolet wool fabric is prepared using the NMMO aqueous solution, it is characterised in that comprise the following steps：（1）5-40gNMMO, 1-3g tricarboxylic ethyl phosphine are dissolved into 100ml ethanol/waters（Volume ratio is 1:4）In；（2）In step（1）0.1-1.5g zinc oxide nano-particles are added in obtained solution, be stirred vigorously down obtain it is scattered aerobic Change the lysate of zinc nano-particle；（3）By wool fabric in step（2）Repeatedly padded in the lysate of gained；（4）Wool fabric after padding is heated into 10-30min under 80-150 DEG C of hot blast；（5）Wool fabric after heating is impregnated in ethanol solution and solidified, then washes, dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710787931.4A CN107435242A (en) | 2017-09-04 | 2017-09-04 | Anti-ultraviolet wool fabric is prepared with the NMMO aqueous solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710787931.4A CN107435242A (en) | 2017-09-04 | 2017-09-04 | Anti-ultraviolet wool fabric is prepared with the NMMO aqueous solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107435242A true CN107435242A (en) | 2017-12-05 |
Family
ID=60461147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710787931.4A Pending CN107435242A (en) | 2017-09-04 | 2017-09-04 | Anti-ultraviolet wool fabric is prepared with the NMMO aqueous solution |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107435242A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361966A (en) * | 2013-07-25 | 2013-10-23 | 宁波康赛妮毛绒制品有限公司 | Active negative oxygen ion cashmere yarn after-treatment method |
-
2017
- 2017-09-04 CN CN201710787931.4A patent/CN107435242A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361966A (en) * | 2013-07-25 | 2013-10-23 | 宁波康赛妮毛绒制品有限公司 | Active negative oxygen ion cashmere yarn after-treatment method |
Non-Patent Citations (2)
| Title |
|---|
| 王江波等: ""TCEP在羊毛角蛋白上的应用"", 《毛纺科技》 * |
| 许莹等: ""丝素在NMMO·H2O中的溶解及溶液流变性能的研究"", 《河南师范大学学报（自然科学版）》 * |
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| PB01 | Publication | ||
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Application publication date: 20171205 |