CN107419362A - A kind of ageing-resistant fishing net - Google Patents

A kind of ageing-resistant fishing net Download PDF

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Publication number
CN107419362A
CN107419362A CN201710334603.9A CN201710334603A CN107419362A CN 107419362 A CN107419362 A CN 107419362A CN 201710334603 A CN201710334603 A CN 201710334603A CN 107419362 A CN107419362 A CN 107419362A
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CN
China
Prior art keywords
fishing net
ageing
composite
resistant
montmorillonite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710334603.9A
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Chinese (zh)
Inventor
陈世勤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chaohu Lotus Fishing Net Co Ltd
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Chaohu Lotus Fishing Net Co Ltd
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Publication date
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Priority to CN201710334603.9A priority Critical patent/CN107419362A/en
Publication of CN107419362A publication Critical patent/CN107419362A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02—Heat treatment
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
    • D01D5/0885—Cooling filaments, threads or the like, leaving the spinnerettes by means of a liquid
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/12—Stretch-spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D7/00—Collecting the newly-spun products
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Artificial Filaments (AREA)
  • Multicomponent Fibers (AREA)

Abstract

The invention discloses a kind of ageing-resistant fishing net, including：Dispensing, melting extrusion, cooling preliminary draft, drafting forming, wind, line processed, knitmesh；The ageing-resistant fishing net that the present invention makes has preferable ageing-resistant performance, the composite of polyamide fibre 6 is made by the modification to chinlon 6 section, the stability and resistance to ag(e)ing of fishing net made of can improving, by using treated montmorillonite, nano titanium oxide, epoxidized soybean oil carries out mixing with chinlon 6 section and composite is made, the molecule of polyamide fibre 6 is enabled to contain flexible group, manufactured composite has reactivity height, the features such as adhesive force is strong, to heat, photochemistry, oxidation Decomposition has good tolerance, so as to greatly improve the ageing-resistant performance of manufactured fishing net.

Description

A kind of ageing-resistant fishing net
Technical field
The invention belongs to fishing net preparing technical field, and in particular to a kind of ageing-resistant fishing net.
Background technology
Fishing net is the net of fishing, and men of old uses coarse cloth to be used as raw material plus fiber crops, and fishnet is made by the method for tying volume. Although this fishing net is perishable, toughness is poor, and it is fished efficiency and greatly improved.With the development of fishery, fishing and hunting Object is more than fish, and the instrument of fishing also grows with each passing hour.Men of old uses coarse cloth to be used as raw material plus fiber crops, the method by tying volume Fishnet is made.Although this fishing net is perishable, toughness is poor, and it is fished efficiency and greatly improved.With the hair of fishery Exhibition, the object of fishing and hunting are more than fish, and the instrument of fishing also grows with each passing hour.Modern fishing net mainly uses the raw material such as polyethylene, nylon It is processed, has longer service life, and higher catching rate, but existing fishing net makes to being chronically exposed in air With the requirement of its resistance to ag(e)ing gradually needs to improve, due to the comprehensive function of the factors such as light, oxygen, heat, water so that fishing net pole Easily there is aging, reduce fishing net service life.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of ageing-resistant fishing net.
The present invention is achieved by the following technical solutions：
A kind of ageing-resistant fishing net, comprises the following steps：
（1）Dispensing：
By weight by terylene 2.0-2.5, glass fibre 1.4-1.8, dimethicone 0.3-0.7, the fourth of phthalic acid two Ester 0.2-0.5, sodium alginate 0.3-0.6, the composite 70-80 of modified nylon 6 are mixed, and obtain compound；The modification The composite material and preparation method thereof of polyamide fibre 6 is：Hexadecyltrimethylammonium chloride and water are pressed 1：After 83 mass ratio uniformly mixes, Hexadecyltrimethylammonium chloride solution is obtained, montmorillonite of the particle diameter at 20-25 μm is then used into mass fraction as 2.5% Hydrochloric acid solution soaks 30min at 45 DEG C, then filters, deionized water washing, drying, then with hexadecyltrimethylammonium chloride Solution presses 1：80 mass ratios mix, and are heated to 55 DEG C, stir 40min with 250r/min rotating speeds, then filter, deionization washing Wash, dry, treated montmorillonite is obtained, by treated montmorillonite, epoxidized soybean oil, nano titanium oxide, polyamide fibre 6 Section presses 2：1：0.12：100 mass ratios uniformly after mixing, carry out being kneaded in banbury and fusion intercalation are compound, be kneaded temperature Spend for 168 DEG C, mixing time 12min, obtain the composite of modified nylon 6；
（2）Melting extrusion：
The compound prepared stirs by plastic extruder melting extrusion；
（3）Cool down preliminary draft：The fiber of melting extrusion is put into 18 DEG C of tanks of temperature and cooled down, 3.5 times of pre-draft multiple, after cooling Monfil carry out drawing-off, drawing temperature be 82 DEG C, 10 times of drafting multiple；
（4）Drafting forming：
The monofilament being drawn through is shaped, and setting temperature is 94 DEG C, relaxation shrinkage 2.4%；
（5）Winding：
The monfil shaped is batched on winder with winding tension 250cN, coiling speed 120m/min；
（6）Line processed：
By monofilament be made 80-100 twists/m of the twist, a diameter of 0.3-0.8mm netting twine；
（7）Knitmesh：
The a length of 10-100mm of mesh fishing net is spun into the netting twine.
Further, the montmorillonite cation exchange capacity (CEC) is 82-88mol/100g.
Further, the nano titanium oxide granularity is 30-32nm.
The present invention has advantages below compared with prior art：The ageing-resistant fishing net that the present invention makes has preferably ageing-resistant Performance, the composite of polyamide fibre 6 is made by the modification to chinlon 6 section, can improve made of fishing net stability and Resistance to ag(e)ing, it is kneaded by using treated montmorillonite, nano titanium oxide, epoxidized soybean oil and chinlon 6 section Composite is made, the molecular chain structure of polyamide fibre 6 can be changed so that the molecule of polyamide fibre 6 contains flexible group, manufactured composite wood Material has the characteristics that reactivity is high, adhesive force is strong, has good tolerance to heat, photochemistry, oxidation Decomposition, so as to greatly Improve made of fishing net ageing-resistant performance.
Embodiment
Embodiment 1
A kind of ageing-resistant fishing net, comprises the following steps：
（1）Dispensing：
By weight by terylene 2.0, glass fibre 1.4, dimethicone 0.3, dibutyl phthalate 0.2, alginic acid Sodium 0.3, the composite 70 of modified nylon 6 are mixed, and obtain compound；The composite material and preparation method thereof of modified nylon 6 is： Hexadecyltrimethylammonium chloride and water are pressed 1：83 mass ratio uniformly after mixing, obtains hexadecyltrimethylammonium chloride Solution, then mass fraction is used to soak 30min at 45 DEG C for 2.5% hydrochloric acid solution montmorillonite of the particle diameter at 20 μm, so After filter, deionized water washing, drying, then with hexadecyltrimethylammonium chloride solution press 1：80 mass ratios mix, heating To 55 DEG C, 40min is stirred with 250r/min rotating speeds, then filtered, deionized water washing, drying, obtained treated cover and take off Soil, treated montmorillonite, epoxidized soybean oil, nano titanium oxide, chinlon 6 section are pressed 2：1：0.12：100 mass ratios Uniformly after mixing, carrying out being kneaded in banbury and fusion intercalation is compound, melting temperature is 168 DEG C, mixing time 12min, Obtain the composite of modified nylon 6；
（2）Melting extrusion：
The compound prepared stirs by plastic extruder melting extrusion；
（3）Cool down preliminary draft：The fiber of melting extrusion is put into 18 DEG C of tanks of temperature and cooled down, 3.5 times of pre-draft multiple, after cooling Monfil carry out drawing-off, drawing temperature be 82 DEG C, 10 times of drafting multiple；
（4）Drafting forming：
The monofilament being drawn through is shaped, and setting temperature is 94 DEG C, relaxation shrinkage 2.4%；
（5）Winding：
The monfil shaped is batched on winder with winding tension 250cN, coiling speed 120m/min；
（6）Line processed：
By monofilament be made 80 twists/m of the twist, a diameter of 0.3mm netting twine；
（7）Knitmesh：
The a length of 10mm of mesh fishing net is spun into the netting twine.
The montmorillonite cation exchange capacity (CEC) is 82mol/100g.
The nano titanium oxide granularity is 30nm.
Embodiment 2
A kind of ageing-resistant fishing net, comprises the following steps：
（1）Dispensing：
By weight by terylene 2.5, glass fibre 1.8, dimethicone 0.7, dibutyl phthalate 0.5, alginic acid Sodium 0.6, the composite 80 of modified nylon 6 are mixed, and obtain compound；The composite material and preparation method thereof of modified nylon 6 is： Hexadecyltrimethylammonium chloride and water are pressed 1：83 mass ratio uniformly after mixing, obtains hexadecyltrimethylammonium chloride Solution, then mass fraction is used to soak 30min at 45 DEG C for 2.5% hydrochloric acid solution montmorillonite of the particle diameter at 25 μm, so After filter, deionized water washing, drying, then with hexadecyltrimethylammonium chloride solution press 1：80 mass ratios mix, heating To 55 DEG C, 40min is stirred with 250r/min rotating speeds, then filtered, deionized water washing, drying, obtained treated cover and take off Soil, treated montmorillonite, epoxidized soybean oil, nano titanium oxide, chinlon 6 section are pressed 2：1：0.12：100 mass ratios Uniformly after mixing, carrying out being kneaded in banbury and fusion intercalation is compound, melting temperature is 168 DEG C, mixing time 12min, Obtain the composite of modified nylon 6；
（2）Melting extrusion：
The compound prepared stirs by plastic extruder melting extrusion；
（3）Cool down preliminary draft：The fiber of melting extrusion is put into 18 DEG C of tanks of temperature and cooled down, 3.5 times of pre-draft multiple, after cooling Monfil carry out drawing-off, drawing temperature be 82 DEG C, 10 times of drafting multiple；
（4）Drafting forming：
The monofilament being drawn through is shaped, and setting temperature is 94 DEG C, relaxation shrinkage 2.4%；
（5）Winding：
The monfil shaped is batched on winder with winding tension 250cN, coiling speed 120m/min；
（6）Line processed：
By monofilament be made 100 twists/m of the twist, a diameter of 0.8mm netting twine；
（7）Knitmesh：
The a length of 100mm of mesh fishing net is spun into the netting twine.
The montmorillonite cation exchange capacity (CEC) is 88mol/100g.
The nano titanium oxide granularity is 32nm.
Embodiment 3
A kind of ageing-resistant fishing net, comprises the following steps：
（1）Dispensing：
By weight by terylene 2.2, glass fibre 1.6, dimethicone 0.5, dibutyl phthalate 0.3, alginic acid Sodium 0.4, the composite 75 of modified nylon 6 are mixed, and obtain compound；The composite material and preparation method thereof of modified nylon 6 is： Hexadecyltrimethylammonium chloride and water are pressed 1：83 mass ratio uniformly after mixing, obtains hexadecyltrimethylammonium chloride Solution, then mass fraction is used to soak 30min at 45 DEG C for 2.5% hydrochloric acid solution montmorillonite of the particle diameter at 22 μm, so After filter, deionized water washing, drying, then with hexadecyltrimethylammonium chloride solution press 1：80 mass ratios mix, heating To 55 DEG C, 40min is stirred with 250r/min rotating speeds, then filtered, deionized water washing, drying, obtained treated cover and take off Soil, treated montmorillonite, epoxidized soybean oil, nano titanium oxide, chinlon 6 section are pressed 2：1：0.12：100 mass ratios Uniformly after mixing, carrying out being kneaded in banbury and fusion intercalation is compound, melting temperature is 168 DEG C, mixing time 12min, Obtain the composite of modified nylon 6；
（2）Melting extrusion：
The compound prepared stirs by plastic extruder melting extrusion；
（3）Cool down preliminary draft：The fiber of melting extrusion is put into 18 DEG C of tanks of temperature and cooled down, 3.5 times of pre-draft multiple, after cooling Monfil carry out drawing-off, drawing temperature be 82 DEG C, 10 times of drafting multiple；
（4）Drafting forming：
The monofilament being drawn through is shaped, and setting temperature is 94 DEG C, relaxation shrinkage 2.4%；
（5）Winding：
The monfil shaped is batched on winder with winding tension 250cN, coiling speed 120m/min；
（6）Line processed：
By monofilament be made 90 twists/m of the twist, a diameter of 0.5mm netting twine；
（7）Knitmesh：
The a length of 600mm of mesh fishing net is spun into the netting twine.
The montmorillonite cation exchange capacity (CEC) is 85mol/100g.
The nano titanium oxide granularity is 31nm.
Comparative example 1：Step is differed only in embodiment 1（1）The middle brocade that the composite of polyamide fibre 6 is replaced with to common equivalent Synthetic fibre 6 is cut into slices.
Comparative example 2：Step is differed only in embodiment 1（1）The middle composite of polyamide fibre 6 is not added in preparing by processing Montmorillonite.
Comparative example 3：Step is differed only in embodiment 1（1）The middle composite of polyamide fibre 6 does not add nano-silica in preparing Change titanium.
Artificial accelerated aging test：
Instrument uses the Japanese weather-proof instrument of WEL-SUN-DC sunlight types, and condition is Continuous irradiation：43 ± 2 DEG C of test flume temperature, blackboard 58 ± 1 DEG C of generation trough temperature, humidity generation trough relative humidity 65-70%, rainfall cycle 12 divide/hour, will be single made of polyamide fibre 6 Silk, fishing lines made of embodiment, fishing lines made of comparative example are rotating around being 0.1cm aluminium sheets in long 30cm, wide 8cm, thickness On, around when adjacent filaments and line it is not overlapping, then model is fixed on ageing oven specimen holder and operated, carry out Continuous irradiation, periodically Sampling, sample sampling Hou Zai laboratories keep after being balanced 24 hours under standard atmosphere condition, tested, tester uses state Y361-30, Y361-3 strength tester are produced, condition is：20 ± 2 DEG C of room temperature, relative humidity are 65 ± 5%, and decrease speed is 300mm/min, upper and lower clamp distance 200mm, by a single line knot is made a call among every sample, write down in testing when breaking nodule Peak load, every sample test 8-10 times, takes arithmetic average,（Embodiment uses 1mm with comparative example fishing line fineness）It is right Than：
Table 1
As can be seen from Table 1, fishing net ageing-resistant performance made of adding the composite of polyamide fibre 6 of the inventive method preparation obtains pole Big raising, the composite of polyamide fibre 6 do not add fishing net resistance to ag(e)ing made of nano titanium oxide in preparing and slightly reduced, polyamide fibre 6 composites do not add fishing net resistance to ag(e)ing made of treated montmorillonite in preparing and declined to a certain extent.

Claims (3)

1. a kind of ageing-resistant fishing net, it is characterised in that comprise the following steps：
（1）Dispensing：
By weight by terylene 2.0-2.5, glass fibre 1.4-1.8, dimethicone 0.3-0.7, the fourth of phthalic acid two Ester 0.2-0.5, sodium alginate 0.3-0.6, the composite 70-80 of modified nylon 6 are mixed, and obtain compound；The modification The composite material and preparation method thereof of polyamide fibre 6 is：Hexadecyltrimethylammonium chloride and water are pressed 1：After 83 mass ratio uniformly mixes, Hexadecyltrimethylammonium chloride solution is obtained, montmorillonite of the particle diameter at 20-25 μm is then used into mass fraction as 2.5% Hydrochloric acid solution soaks 30min at 45 DEG C, then filters, deionized water washing, drying, then with hexadecyltrimethylammonium chloride Solution presses 1：80 mass ratios mix, and are heated to 55 DEG C, stir 40min with 250r/min rotating speeds, then filter, deionization washing Wash, dry, treated montmorillonite is obtained, by treated montmorillonite, epoxidized soybean oil, nano titanium oxide, polyamide fibre 6 Section presses 2：1：0.12：100 mass ratios uniformly after mixing, carry out being kneaded in banbury and fusion intercalation are compound, be kneaded temperature Spend for 168 DEG C, mixing time 12min, obtain the composite of modified nylon 6；
（2）Melting extrusion：
The compound prepared stirs by plastic extruder melting extrusion；
（3）Cool down preliminary draft：The fiber of melting extrusion is put into 18 DEG C of tanks of temperature and cooled down, 3.5 times of pre-draft multiple, after cooling Monfil carry out drawing-off, drawing temperature be 82 DEG C, 10 times of drafting multiple；
（4）Drafting forming：
The monofilament being drawn through is shaped, and setting temperature is 94 DEG C, relaxation shrinkage 2.4%；
（5）Winding：
The monfil shaped is batched on winder with winding tension 250cN, coiling speed 120m/min；
（6）Line processed：
By monofilament be made 80-100 twists/m of the twist, a diameter of 0.3-0.8mm netting twine；
（7）Knitmesh：
The a length of 10-100mm of mesh fishing net is spun into the netting twine.
2. a kind of ageing-resistant fishing net as claimed in claim 1, it is characterised in that the montmorillonite cation exchange capacity (CEC) is 82- 88mol/100g。
3. a kind of ageing-resistant fishing net as claimed in claim 1, it is characterised in that the nano titanium oxide granularity is 30- 32nm。
CN201710334603.9A 2017-05-12 2017-05-12 A kind of ageing-resistant fishing net Pending CN107419362A (en)

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
CN108588896A (en) * 2018-04-11 2018-09-28 安徽省义顺渔网渔具有限公司 A kind of preparation method of fishing lines short fiber composite material
CN108823677A (en) * 2018-07-02 2018-11-16 巢湖市天宇渔具有限公司 A kind of processing method of the heat resistant type fishing net wire drawing of good toughness
CN108866704A (en) * 2018-07-28 2018-11-23 安徽省义顺渔网渔具有限公司 A kind of ageing-resistant fishing lines of high-strength corrosion-resisting
CN109320960A (en) * 2018-10-11 2019-02-12 安庆市泽烨新材料技术推广服务有限公司 Nylon composite materials and preparation method thereof
CN109354869A (en) * 2018-10-11 2019-02-19 安庆市泽烨新材料技术推广服务有限公司 Anti-flaming nano enhances nylon composite materials and preparation method thereof
CN109354870A (en) * 2018-10-11 2019-02-19 安庆市泽烨新材料技术推广服务有限公司 Glass fiber enhanced nylon composite material and preparation method
CN110295412A (en) * 2019-06-18 2019-10-01 安徽省六安市兴渔绳网科技有限公司 A kind of fishing net drawing process
CN111394881A (en) * 2020-04-15 2020-07-10 巢湖市翔宇渔具有限公司 Preparation method of silica gel reinforced anti-aging fishing net
CN112553736A (en) * 2020-11-11 2021-03-26 山东金冠网具有限公司 Production method of reticular breathable hole yarn

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CN105585709A (en) * 2014-10-24 2016-05-18 广东新会美达锦纶股份有限公司 Preparation method for organic amine-modified montmorillonite/polyamide nano composite material
CN105778486A (en) * 2016-05-04 2016-07-20 巢湖市强力渔业有限责任公司 Fishing net made of modified nylon 6
CN105907086A (en) * 2016-05-04 2016-08-31 巢湖市强力渔业有限责任公司 High-quality antioxidative fishing net

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CN108588896A (en) * 2018-04-11 2018-09-28 安徽省义顺渔网渔具有限公司 A kind of preparation method of fishing lines short fiber composite material
CN108823677A (en) * 2018-07-02 2018-11-16 巢湖市天宇渔具有限公司 A kind of processing method of the heat resistant type fishing net wire drawing of good toughness
CN108866704A (en) * 2018-07-28 2018-11-23 安徽省义顺渔网渔具有限公司 A kind of ageing-resistant fishing lines of high-strength corrosion-resisting
CN109320960A (en) * 2018-10-11 2019-02-12 安庆市泽烨新材料技术推广服务有限公司 Nylon composite materials and preparation method thereof
CN109354869A (en) * 2018-10-11 2019-02-19 安庆市泽烨新材料技术推广服务有限公司 Anti-flaming nano enhances nylon composite materials and preparation method thereof
CN109354870A (en) * 2018-10-11 2019-02-19 安庆市泽烨新材料技术推广服务有限公司 Glass fiber enhanced nylon composite material and preparation method
CN110295412A (en) * 2019-06-18 2019-10-01 安徽省六安市兴渔绳网科技有限公司 A kind of fishing net drawing process
CN111394881A (en) * 2020-04-15 2020-07-10 巢湖市翔宇渔具有限公司 Preparation method of silica gel reinforced anti-aging fishing net
CN112553736A (en) * 2020-11-11 2021-03-26 山东金冠网具有限公司 Production method of reticular breathable hole yarn

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Application publication date: 20171201