CN107418326A - Acrylic antifouling paint - Google Patents
Acrylic antifouling paint Download PDFInfo
- Publication number
- CN107418326A CN107418326A CN201710387407.8A CN201710387407A CN107418326A CN 107418326 A CN107418326 A CN 107418326A CN 201710387407 A CN201710387407 A CN 201710387407A CN 107418326 A CN107418326 A CN 107418326A
- Authority
- CN
- China
- Prior art keywords
- antifouling paint
- acrylic
- staining agent
- diphenyl
- ferrosins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses acrylic antifouling paint, described material contains following material：Acrylic resin, rosin, talcum powder, barium sulfate, titanium dioxide, dimethylbenzene, anti-staining agent, the present invention are compared with prior art, without organotin, the inhibition zone of anti-staining agent is 16mm, and the adhesive force of made coating is 2 grades, hardness 3H, impact resistance 50Kg.cm.
Description
Technical field
The invention belongs to antifouling paint, marine antifouling coating this technical field is particularly belonged to.
Background technology
With the civilized progress of the mankind, utilization of the mankind to ocean is also more and more, but with contact with sea water in ocean
Various marine organisms are easily adsorbed on ship, bridge, the surface of marine petroleum exploitation platform, it is tarnished, form ocean
It is stained.Antifouling paint is the conventional coating for preventing marime fouling, and organotin, but International Maritime group are usually contained in antifouling paint
(IMO) is knitted to have forbidden using organotin in antifouling paint at present.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of acrylic antifouling paint without organotin.
The present invention solve technical problem technical scheme be：Acrylic antifouling paint, the material containing following parts by weight：
Described anti-staining agent is：Homopiperony lamine (C9H11NO2) with the mixtures of 4,7- diphenyl -1,10- ferrosins, pepper
The weight ratio of ethamine and 4,7- diphenyl -1,10- ferrosins is 100：1-3.
Described acrylic resin is BS-963 acrylic resins.
The addition of anti-staining agent can not be excessive, excessively makes energy under the mechanical performance of coating.
Compared with prior art, without organotin, the inhibition zone of anti-staining agent is 16mm to the present invention, the attachment of made coating
Power is 2 grades, hardness 3H, impact resistance 50Kg.cm.
Embodiment
With reference to embodiment, the present invention is described in detail.
The bs-963 acrylic resins of the present invention are provided by Jiangsu Miki Group chemical plant.
Embodiment 1：
Acrylic antifouling paint, the material containing following parts by weight：
Described anti-staining agent is homopiperony lamine (C9H11NO2) with the mixtures of 4,7- diphenyl -1,10- ferrosins, pepper
The weight ratio of ethamine and 4,7- diphenyl -1,10- ferrosins is 100：1.
Embodiment 2：
Acrylic antifouling paint, the material containing following parts by weight：
Described anti-staining agent is：Homopiperony lamine (C9H11NO2) with the mixtures of 4,7- diphenyl -1,10- ferrosins, pepper
The weight ratio of ethamine and 4,7- diphenyl -1,10- ferrosins is 100：2.
Embodiment 3：
Acrylic antifouling paint, the material containing following parts by weight：
Described anti-staining agent is：Homopiperony lamine (C9H11NO2) with the mixtures of 4,7- diphenyl -1,10- ferrosins, pepper
The weight ratio of ethamine and 4,7- diphenyl -1,10- ferrosins is 100：3.
Embodiment 4：
It is other same as Example 3 in addition to the dosage of anti-staining agent is 20 parts by weight.
The diameter of the conventional cylinder-plate method measurement inhibition zone of the anti-staining agent of the present invention, described bacterium is golden grape bacterium
(ATCC25923), its inhibition zone is 16mm.
By being sprayed on steel plate for embodiment 1-4, embodiment 1-3 adhesive force is 2 grades, hardness 3H, impact resistance
For 50Kg.cm, the impact resistance of embodiment 4 is 32Kg.cm.
Claims (3)
1. acrylic antifouling paint, it is characterised in that：Material containing following parts by weight：
2. acrylic antifouling paint according to claim 1, it is characterised in that：Described anti-staining agent is：Homopiperony lamine
(C9H11NO2) with the mixtures of 4,7- diphenyl -1,10- ferrosins, homopiperony lamine and 4,7- diphenyl -1,10- ferrosin
Weight ratio is 100：1-3.
3. acrylic antifouling paint according to claim 1, it is characterised in that：Described acrylic resin is BS-963 third
Olefin(e) acid resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710387407.8A CN107418326A (en) | 2017-05-26 | 2017-05-26 | Acrylic antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710387407.8A CN107418326A (en) | 2017-05-26 | 2017-05-26 | Acrylic antifouling paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107418326A true CN107418326A (en) | 2017-12-01 |
Family
ID=60429183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710387407.8A Withdrawn CN107418326A (en) | 2017-05-26 | 2017-05-26 | Acrylic antifouling paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107418326A (en) |
-
2017
- 2017-05-26 CN CN201710387407.8A patent/CN107418326A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171201 |
|
| WW01 | Invention patent application withdrawn after publication |