CN107418323A - A kind of mould proof adhesive of high viscosity for handicraft processing and preparation method thereof - Google Patents
A kind of mould proof adhesive of high viscosity for handicraft processing and preparation method thereof Download PDFInfo
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- CN107418323A CN107418323A CN201710630111.4A CN201710630111A CN107418323A CN 107418323 A CN107418323 A CN 107418323A CN 201710630111 A CN201710630111 A CN 201710630111A CN 107418323 A CN107418323 A CN 107418323A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/04—Printing inks based on proteins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of mould proof adhesive of high viscosity for handicraft processing, its raw material includes vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropanol, ammonium persulfate, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyltin oxide, N alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal and is modified dimethyl polysiloxane, silane coupler KH 550, mould proof auxiliary agent, viscosity- increasing agent, polyvinyl alcohol and deionized water.The present invention also proposes a kind of preparation method of above-mentioned mould proof adhesive of high viscosity for handicraft processing.The adhesive applications that the present invention is prepared have high viscosity and fungicidal properties in the processing of handicraft.
Description
Technical field
The present invention relates to the technical field of adhesive, more particularly to a kind of high viscosity for handicraft processing are mould proof gluing
Agent and preparation method thereof.
Background technology
Adhesive be mainly used in furniture industry Sun combine, the splicing of core-board, veneer, plywood, wood-based plate are repaiied
The processing mended, be glued, can be also used for the gluing of the porous materials such as paper, leather, ceramics.Traditional adhesive is for technique
In the processing of product, its viscosity and fungicidal properties can not meet actual use when the needs of, so need badly design one kind be used for technique
The high viscosity mould proof adhesive of product processing solves the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that a kind of high viscosity for handicraft processing is prevented
Mould adhesive and preparation method thereof, the adhesive applications being prepared have high viscosity and fungicidal properties in the processing of handicraft.
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
Vinylacetate 80-120 parts, dibutyl phthalate 15-25 parts, allyl methacrylate 2-6 parts, methylol acryloyl
Amine 1-4 parts, isopropanol 3-6 parts, ammonium persulfate 3-6 parts, nano titanium oxide 1-4 parts, nano zine oxide 3-5 parts, zinc sulphide 1-5
Part, maleimide tributyltin oxide 2-5 parts, N- alkylated I pyridine 1-5 parts, cosmocil stearate 3-6 parts,
Quaternary ammonium salt terminal is modified dimethyl polysiloxane 2-6 parts, silane resin acceptor kh-550 4-8 parts, mould proof auxiliary agent 3-6 parts, viscosity increasing
Strong agent 2-5 parts, polyvinyl alcohol 1-4 parts, deionized water 15-35 parts.
Preferably, the raw material of mould proof auxiliary agent includes by weight：N- (4- hydroxy-3-methoxies-benzyl) acrylamide 5-
15 parts, it is DMAC N,N' dimethyl acetamide 2-5 parts, acrylamide 1-6 parts, ethyl acrylate 3-5 parts, azodiisobutyronitrile 2-4 parts, recessed
Convex rod soil 3-5 parts, Tea Saponin 1-3 parts, chlorinated paraffin 2-5 parts, ferrocenecarboxylic acid 3-5 parts, hexamethyl phosphoramide 2-5 parts, sulfurous
Sour hydrogen sodium 1-4 parts, boric acid 2-4 parts, methyl benzotriazazole 3-5 parts, silane resin acceptor kh-550 4-6 parts.
Preferably, mould proof auxiliary agent is prepared by following technique：By N- (4- hydroxy-3-methoxies-benzyl) acrylamide
It is well mixed with DMA, stirs, then heat up, be incubated, be then passed through nitrogen, adds acrylamide, propylene
Acetoacetic ester and azodiisobutyronitrile are well mixed, and stirring, are cooled to room temperature, then add attapulgite, Tea Saponin, chlorination stone
Wax, ferrocenecarboxylic acid, hexamethyl phosphoramide, sodium hydrogensulfite, boric acid, methyl benzotriazazole and silane resin acceptor kh-550 mix
Close uniformly, heat up, be incubated, filtering, dried after washing, be cooled to room temperature and obtain mould proof auxiliary agent.
Preferably, mould proof auxiliary agent is prepared by following technique：By N- (4- hydroxy-3-methoxies-benzyl) acrylamide
It is well mixed with DMA, stirs 20-40min in 650-850r/min rotating speeds, be then warming up to 75-85 DEG C,
1-3h is incubated, is then passed through nitrogen, acrylamide, ethyl acrylate and azodiisobutyronitrile is added and is well mixed, in 450-
550r/min rotating speeds stir 10-14h, are cooled to room temperature, then add attapulgite, Tea Saponin, chlorinated paraffin, ferrocene first
Acid, hexamethyl phosphoramide, sodium hydrogensulfite, boric acid, methyl benzotriazazole and silane resin acceptor kh-550 are well mixed, heating
To 70-80 DEG C, 1-3h is incubated, filtering, washs after 55-65 DEG C of dry 10-14h, is cooled to room temperature and obtains mould proof auxiliary agent.
Preferably, the raw material of viscosity- increasing agent includes by weight：Waxy corn starch 15-35 parts, mass fraction 15-
Maleic anhydride aqueous solution 2-5 part, sucrose 3-6 parts, palm that 25% sodium hydroxide solution 4-8 parts, mass fraction are 5-15%
Wax 1-4 parts, cellulose ether 3-6 parts, triethanolamine 2-5 parts, laurel alcohol ether phosphate 1-4 parts, ethylene glycol 3-5 parts, dodecyl
Glycine betaine 2-5 parts, alumina silicate 1-5 parts.
Preferably, viscosity- increasing agent is prepared by following technique：It is 15-25% by waxy corn starch and mass fraction
Sodium hydroxide solution be well mixed, be warming up to 45-55 DEG C, be incubated 20-40min, it is 5-15%'s then to add mass fraction
The maleic anhydride aqueous solution is well mixed, and is warming up to 80-90 DEG C, is incubated 10-30min, is adjusted pH to 6.5-7.5, is then added sugarcane
Sugar is well mixed, stirs 20-30min in 450-650r/min rotating speeds, then adds palm wax, cellulose ether, triethanolamine, the moon
Cinnamic alcohol ether phosphate, ethylene glycol and empgen BB are well mixed, and are warming up to 75-85 DEG C, 1-3h are incubated, then in 650-
850r/min rotating speeds stir 20-50min, are cooled to room temperature, then add alumina silicate and are well mixed, and are heated to 75-85 DEG C, insulation
1.5-3.5h, 1.5-3.5h is stirred in 1500-2500r/min rotating speeds, room temperature is cooled to and produces viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 80-90 DEG C, 1-3h is incubated, in 850-1050r/
Min rotating speeds stir 1-3h, are cooled to room temperature and obtain material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 120-140 DEG C, are incubated 20-40min, are then stirred in 650-850r/min rotating speeds
20-40min, it is cooled to room temperature and obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 110-130 DEG C, 1-3h are incubated, in 850-1050r/
Min rotating speeds stir 20-50min, are cooled to room temperature and obtain the mould proof adhesive of high viscosity for handicraft processing.
A kind of mould proof adhesive of high viscosity for handicraft processing of the present invention, its raw material include vinylacetate, neighbour
Dibatyl phithalate, allyl methacrylate, NMA, isopropanol, ammonium persulfate, nano titanium oxide,
Nano zine oxide, zinc sulphide, maleimide tributyltin oxide, N- alkylated Is pyridine, cosmocil stearate,
Quaternary ammonium salt terminal be modified dimethyl polysiloxane, silane resin acceptor kh-550, mould proof auxiliary agent, viscosity- increasing agent, polyvinyl alcohol and
Deionized water.Wherein, mould proof auxiliary agent is by by N- (4- hydroxy-3-methoxies-benzyl) acrylamides and N, N- dimethylacetamide
Amine is well mixed, and stirring, is then heated up, and is incubated, and is then passed through nitrogen, and it is different to add acrylamide, ethyl acrylate and azo two
Butyronitrile is well mixed, and stirring, is cooled to room temperature, then adds attapulgite, Tea Saponin, chlorinated paraffin, ferrocenecarboxylic acid, pregnancy
Base phosphamide, sodium hydrogensulfite, boric acid, methyl benzotriazazole and silane resin acceptor kh-550 are well mixed, and are heated up, insulation,
Filtering, dried after washing, be cooled to room temperature and obtain mould proof auxiliary agent, applied in the modified adhesive of the present invention, effectively improve this
The fungicidal properties of invention modified adhesive.Wherein, viscosity- increasing agent is by the way that waxy corn starch and sodium hydroxide solution are mixed
Uniformly, heat up, insulation, then add the maleic anhydride aqueous solution and be well mixed, heat up, insulation, adjust pH, then add sucrose and mix
Uniform, stirring is closed, then addition palm wax, cellulose ether, triethanolamine, laurel alcohol ether phosphate, ethylene glycol and dodecyl
Glycine betaine is well mixed, and is heated up, and insulation, is then stirred, is cooled to room temperature, is then added alumina silicate and is well mixed, heat, protects
Temperature, stirring, is cooled to room temperature and produces viscosity- increasing agent, applies in the modified adhesive of the present invention, effectively increases the present invention
The viscosity of modified adhesive.The adhesive applications that the present invention is prepared have high viscosity and mildew resistance in the processing of handicraft
Energy.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of vinylacetate can be 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105
Part, 110 parts, 115 parts, 120 parts；The parts by weight of dibutyl phthalate can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts,
20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts；The parts by weight of allyl methacrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6
Part；The parts by weight of NMA can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight of isopropanol
Part can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of ammonium persulfate can be 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of nano titanium oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts；The parts by weight of nano zine oxide can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of zinc sulphide can be 1
Part, 2 parts, 3 parts, 4 parts, 5 parts；The parts by weight of maleimide tributyltin oxide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The parts by weight of N- alkylated I pyridines can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Polyhexamethylene is double
The parts by weight of guanidinesalt can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Quaternary ammonium salt terminal is modified the poly- silicon of dimethyl
The parts by weight of oxygen alkane can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of silane resin acceptor kh-550 can be 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of mould proof auxiliary agent can be 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts；The parts by weight of viscosity- increasing agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；It is poly-
The parts by weight of vinyl alcohol can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of deionized water can be
15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30
Part, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts.
Embodiment 1
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
100 parts of vinylacetate, 20 parts of dibutyl phthalate, 4 parts of allyl methacrylate, 2.5 parts of NMA,
4.5 parts of isopropanol, 4.5 parts of ammonium persulfate, 2.5 parts of nano titanium oxide, 4 parts of nano zine oxide, 3 parts of zinc sulphide, maleimide
3.5 parts of amine tributyltin oxide, 3 parts of N- alkylated Is pyridine, 4.5 parts of cosmocil stearate, quaternary ammonium salt terminal change
4 parts of dimethyl polysiloxane of property, 6 parts of silane resin acceptor kh-550,4.5 parts of mould proof auxiliary agent, 3.5 parts of viscosity- increasing agent, polyethylene
2.5 parts of alcohol, 25 parts of deionized water.
Mould proof auxiliary agent is prepared by following technique：By weight by 10 parts of N- (4- hydroxy-3-methoxies-benzyl) propylene
Acid amides and 3.5 parts of DMAs are well mixed, and are stirred 30min in 750r/min rotating speeds, are then warming up to 80 DEG C, protect
Warm 2h, nitrogen is then passed through, adds 3.5 parts of acrylamides, 4 parts of ethyl acrylates and 3 parts of azodiisobutyronitriles and be well mixed, in
500r/min rotating speeds stir 12h, are cooled to room temperature, then add 4 parts of attapulgites, 2 parts of Tea Saponins, 3.5 parts of chlorinated paraffins, 4
Part ferrocenecarboxylic acid, 3.5 parts of hexamethyl phosphoramides, 2.5 parts of sodium hydrogensulfites, 3 parts of boric acid, 4 parts of methyl benzotriazazoles and 5 parts
Silane resin acceptor kh-550 is well mixed, and is warming up to 75 DEG C, is incubated 2h, filtering, is washed after 60 DEG C of dry 12h, be cooled to room
Temperature obtains mould proof auxiliary agent.
Viscosity- increasing agent is prepared by following technique：By weight by 25 parts of waxy corn starch and 6 parts of mass fractions
It is well mixed for 20% sodium hydroxide solution, is warming up to 50 DEG C, be incubated 30min, it is 10% then to add 3.5 parts of mass fractions
The maleic anhydride aqueous solution be well mixed, be warming up to 85 DEG C, be incubated 20min, adjust pH to 7.0, then add 4.5 portions of sucrose and mix
Close uniformly, stir 25min in 550r/min rotating speeds, then add 2.5 parts of palm waxs, 4.5 parts of cellulose ethers, 3.5 part of three ethanol
Amine, 2.5 parts of laurel alcohol ether phosphates, 4 parts of ethylene glycol and 3.5 parts of empgen BBs are well mixed, and are warming up to 80 DEG C, insulation
2h, 35min then is stirred in 750r/min rotating speeds, is cooled to room temperature, then added 3 parts of alumina silicate and be well mixed, be heated to 80
DEG C, 2.5h is incubated, 2.5h is stirred in 2000r/min rotating speeds, is cooled to room temperature and produces viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 85 DEG C, be incubated 2h, stirred in 950r/min rotating speeds
2h, it is cooled to room temperature and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 130 DEG C, are incubated 30min, are then stirred 30min in 750r/min rotating speeds, are cooled to
Room temperature obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 120 DEG C, are incubated 2h, are stirred in 950r/min rotating speeds
35min, it is cooled to room temperature and obtains the mould proof adhesive of high viscosity for handicraft processing.
Embodiment 2
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
It is 80 parts of vinylacetate, 25 parts of dibutyl phthalate, 2 parts of allyl methacrylate, 4 parts of NMA, different
3 parts of propyl alcohol, 6 parts of ammonium persulfate, 1 part of nano titanium oxide, 5 parts of nano zine oxide, 1 part of zinc sulphide, maleimide tributyl
5 parts of tin oxide, 1 part of N- alkylated Is pyridine, 6 parts of cosmocil stearate, quaternary ammonium salt terminal are modified the poly- silicon of dimethyl
2 parts of oxygen alkane, 8 parts of silane resin acceptor kh-550,3 parts of mould proof auxiliary agent, 5 parts of viscosity- increasing agent, 1 part of polyvinyl alcohol, deionized water 35
Part.
Mould proof auxiliary agent is prepared by following technique：By weight by 5 parts of N- (4- hydroxy-3-methoxies-benzyl) propylene
Acid amides and 5 parts of DMAs are well mixed, and 40min is stirred in 650r/min rotating speeds, are then warming up to 75 DEG C, insulation
3h, nitrogen is then passed through, adds 1 part of acrylamide, 5 parts of ethyl acrylates and 2 parts of azodiisobutyronitriles and be well mixed, in
550r/min rotating speeds stir 10h, be cooled to room temperature, then add 5 parts of attapulgites, 1 part of Tea Saponin, 5 parts of chlorinated paraffins, 3 parts
Ferrocenecarboxylic acid, 5 parts of hexamethyl phosphoramides, 1 part of sodium hydrogensulfite, 4 parts of boric acid, 3 parts of methyl benzotriazazoles and 6 parts of silane idols
Connection agent KH-550 is well mixed, and is warming up to 70 DEG C, is incubated 3h, filtering, is washed after 55 DEG C of dry 14h, be cooled to room temperature and obtain
Mould proof auxiliary agent.
Viscosity- increasing agent is prepared by following technique：By weight by 15 parts of waxy corn starch and 8 parts of mass fractions
It is well mixed for 15% sodium hydroxide solution, is warming up to 55 DEG C, be incubated 20min, it is 5% then to add 5 parts of mass fractions
The maleic anhydride aqueous solution is well mixed, and is warming up to 90 DEG C, is incubated 10min, adjusts pH to 7.5, and it is equal then to add 3 parts of sucrose mixing
It is even, 20min is stirred in 650r/min rotating speeds, then adds 4 parts of palm waxs, 3 parts of cellulose ethers, 5 parts of triethanolamines, 1 portion of bay
Alcohol ether phosphate, 5 parts of ethylene glycol and 2 parts of empgen BBs are well mixed, and are warming up to 85 DEG C, 1h are incubated, then in 850r/
Min rotating speeds stir 20min, are cooled to room temperature, then add 5 parts of alumina silicate and are well mixed, be heated to 75 DEG C, are incubated 3.5h, in
1500r/min rotating speeds stir 3.5h, are cooled to room temperature and produce viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 80 DEG C, be incubated 3h, stirred in 850r/min rotating speeds
3h, it is cooled to room temperature and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 120 DEG C, are incubated 40min, are then stirred 40min in 650r/min rotating speeds, are cooled to
Room temperature obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 110 DEG C, are incubated 3h, are stirred in 850r/min rotating speeds
50min, it is cooled to room temperature and obtains the mould proof adhesive of high viscosity for handicraft processing.
Embodiment 3
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
It is 120 parts of vinylacetate, 15 parts of dibutyl phthalate, 6 parts of allyl methacrylate, 1 part of NMA, different
6 parts of propyl alcohol, 3 parts of ammonium persulfate, 4 parts of nano titanium oxide, 3 parts of nano zine oxide, 5 parts of zinc sulphide, maleimide tributyl
2 parts of tin oxide, 5 parts of N- alkylated Is pyridine, 3 parts of cosmocil stearate, quaternary ammonium salt terminal are modified the poly- silicon of dimethyl
6 parts of oxygen alkane, 4 parts of silane resin acceptor kh-550,6 parts of mould proof auxiliary agent, 2 parts of viscosity- increasing agent, 4 parts of polyvinyl alcohol, deionized water 15
Part.
Mould proof auxiliary agent is prepared by following technique：By weight by 15 parts of N- (4- hydroxy-3-methoxies-benzyl) propylene
Acid amides and 2 parts of DMAs are well mixed, and 20min is stirred in 850r/min rotating speeds, are then warming up to 85 DEG C, insulation
1h, nitrogen is then passed through, adds 6 parts of acrylamides, 3 parts of ethyl acrylates and 4 parts of azodiisobutyronitriles and be well mixed, in
450r/min rotating speeds stir 14h, be cooled to room temperature, then add 3 parts of attapulgites, 3 parts of Tea Saponins, 2 parts of chlorinated paraffins, 5 parts
Ferrocenecarboxylic acid, 2 parts of hexamethyl phosphoramides, 4 parts of sodium hydrogensulfites, 2 parts of boric acid, 5 parts of methyl benzotriazazoles and 4 parts of silane idols
Connection agent KH-550 is well mixed, and is warming up to 80 DEG C, is incubated 1h, filtering, is washed after 65 DEG C of dry 10h, be cooled to room temperature and obtain
Mould proof auxiliary agent.
Viscosity- increasing agent is prepared by following technique：By weight by 35 parts of waxy corn starch and 4 parts of mass fractions
It is well mixed for 25% sodium hydroxide solution, is warming up to 45 DEG C, be incubated 40min, it is 15% then to add 2 parts of mass fractions
The maleic anhydride aqueous solution is well mixed, and is warming up to 80 DEG C, is incubated 30min, adjusts pH to 6.5, and it is equal then to add 6 parts of sucrose mixing
It is even, 30min is stirred in 450r/min rotating speeds, then adds 1 part of palm wax, 6 parts of cellulose ethers, 2 parts of triethanolamines, 4 portions of bays
Alcohol ether phosphate, 3 parts of ethylene glycol and 5 parts of empgen BBs are well mixed, and are warming up to 75 DEG C, 3h are incubated, then in 650r/
Min rotating speeds stir 50min, are cooled to room temperature, then add 1 part of alumina silicate and are well mixed, be heated to 85 DEG C, are incubated 1.5h, in
2500r/min rotating speeds stir 1.5h, are cooled to room temperature and produce viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 90 DEG C, be incubated 1h, stirred in 1050r/min rotating speeds
1h, it is cooled to room temperature and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 140 DEG C, are incubated 20min, are then stirred 20min in 850r/min rotating speeds, are cooled to
Room temperature obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 130 DEG C, are incubated 1h, are stirred in 1050r/min rotating speeds
20min, it is cooled to room temperature and obtains the mould proof adhesive of high viscosity for handicraft processing.
Embodiment 4
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
It is 85 parts of vinylacetate, 22 parts of dibutyl phthalate, 3 parts of allyl methacrylate, 3 parts of NMA, different
4 parts of propyl alcohol, 5 parts of ammonium persulfate, 2 parts of nano titanium oxide, 4.5 parts of nano zine oxide, 2 parts of zinc sulphide, the fourth of maleimide three
4 parts of base tin oxide, 2 parts of N- alkylated Is pyridine, 5 parts of cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl and gathered
3 parts of siloxanes, 7 parts of silane resin acceptor kh-550,4 parts of mould proof auxiliary agent, 4 parts of viscosity- increasing agent, 2 parts of polyvinyl alcohol, deionized water
32 parts.
Mould proof auxiliary agent is prepared by following technique：By weight by 8 parts of N- (4- hydroxy-3-methoxies-benzyl) propylene
Acid amides and 4 parts of DMAs are well mixed, and 35min is stirred in 680r/min rotating speeds, are then warming up to 78 DEG C, insulation
2.5h, nitrogen is then passed through, adds 2 parts of acrylamides, 4.5 parts of ethyl acrylates and 2.5 parts of azodiisobutyronitriles and be well mixed,
11h is stirred in 520r/min rotating speeds, is cooled to room temperature, then adds 4.5 parts of attapulgites, 1.5 parts of Tea Saponins, 4 parts of chlorination stones
Wax, 3.5 parts of ferrocenecarboxylic acids, 4 parts of hexamethyl phosphoramides, 2 parts of sodium hydrogensulfites, 3.5 parts of boric acid, 3.5 parts of nitrogen of methyl benzo three
Azoles and 5.5 parts of silane resin acceptor kh-550s are well mixed, and are warming up to 72 DEG C, are incubated 2.5h, filtering, are washed after 58 DEG C of dryings
13h, it is cooled to room temperature and obtains mould proof auxiliary agent.
Viscosity- increasing agent is prepared by following technique：By weight by 18 parts of waxy corn starch and 7 parts of mass fractions
It is well mixed for 18% sodium hydroxide solution, is warming up to 52 DEG C, be incubated 25min, it is 8% then to add 4 parts of mass fractions
The maleic anhydride aqueous solution is well mixed, and is warming up to 88 DEG C, is incubated 15min, adjusts pH to 7.2, and it is equal then to add 4 parts of sucrose mixing
It is even, 22min is stirred in 620r/min rotating speeds, then adds 3 parts of palm waxs, 4 parts of cellulose ethers, 4 parts of triethanolamines, 2 portions of bays
Alcohol ether phosphate, 4.5 parts of ethylene glycol and 3 parts of empgen BBs are well mixed, and are warming up to 82 DEG C, are incubated 1.5h, Ran Houyu
820r/min rotating speeds stir 25min, are cooled to room temperature, then add 4 parts of alumina silicate and are well mixed, and are heated to 78 DEG C, insulation
3.2h, 3.2h is stirred in 1800r/min rotating speeds, room temperature is cooled to and produces viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 82 DEG C, be incubated 2.5h, stirred in 880r/min rotating speeds
2.5h is mixed, room temperature is cooled to and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 125 DEG C, are incubated 35min, are then stirred 35min in 680r/min rotating speeds, are cooled to
Room temperature obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 115 DEG C, are incubated 2.5h, are stirred in 880r/min rotating speeds
45min, it is cooled to room temperature and obtains the mould proof adhesive of high viscosity for handicraft processing.
Embodiment 5
A kind of mould proof adhesive of high viscosity for handicraft processing proposed by the present invention, its raw material include by weight：
It is 115 parts of vinylacetate, 18 parts of dibutyl phthalate, 5 parts of allyl methacrylate, 2 parts of NMA, different
5 parts of propyl alcohol, 4 parts of ammonium persulfate, 3 parts of nano titanium oxide, 3.5 parts of nano zine oxide, 4 parts of zinc sulphide, the fourth of maleimide three
3 parts of base tin oxide, 4 parts of N- alkylated Is pyridine, 4 parts of cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl and gathered
5 parts of siloxanes, 5 parts of silane resin acceptor kh-550,5 parts of mould proof auxiliary agent, 3 parts of viscosity- increasing agent, 3 parts of polyvinyl alcohol, deionized water
18 parts.
Mould proof auxiliary agent is prepared by following technique：By weight by 12 parts of N- (4- hydroxy-3-methoxies-benzyl) propylene
Acid amides and 3 parts of DMAs are well mixed, and 25min is stirred in 820r/min rotating speeds, are then warming up to 82 DEG C, insulation
1.5h, nitrogen is then passed through, adds 5 parts of acrylamides, 3.5 parts of ethyl acrylates and 3.5 parts of azodiisobutyronitriles and be well mixed,
13h is stirred in 480r/min rotating speeds, is cooled to room temperature, then adds 3.5 parts of attapulgites, 2.5 parts of Tea Saponins, 3 parts of chlorination stones
Wax, 4.5 parts of ferrocenecarboxylic acids, 3 parts of hexamethyl phosphoramides, 3 parts of sodium hydrogensulfites, 2.5 parts of boric acid, 4.5 parts of nitrogen of methyl benzo three
Azoles and 4.5 parts of silane resin acceptor kh-550s are well mixed, and are warming up to 78 DEG C, are incubated 1.5h, filtering, are washed after 62 DEG C of dryings
11h, it is cooled to room temperature and obtains mould proof auxiliary agent.
Viscosity- increasing agent is prepared by following technique：By weight by 32 parts of waxy corn starch and 5 parts of mass fractions
It is well mixed for 22% sodium hydroxide solution, is warming up to 48 DEG C, be incubated 35min, it is 12% then to add 3 parts of mass fractions
The maleic anhydride aqueous solution is well mixed, and is warming up to 82 DEG C, is incubated 25min, adjusts pH to 6.8, and it is equal then to add 5 parts of sucrose mixing
It is even, 28min is stirred in 480r/min rotating speeds, then adds 2 parts of palm waxs, 5 parts of cellulose ethers, 3 parts of triethanolamines, 3 portions of bays
Alcohol ether phosphate, 3.5 parts of ethylene glycol and 4 parts of empgen BBs are well mixed, and are warming up to 78 DEG C, are incubated 2.5h, Ran Houyu
680r/min rotating speeds stir 45min, are cooled to room temperature, then add 2 parts of alumina silicate and are well mixed, and are heated to 82 DEG C, insulation
1.8h, 1.8h is stirred in 2200r/min rotating speeds, room temperature is cooled to and produces viscosity- increasing agent.
A kind of preparation method of mould proof adhesive of high viscosity for handicraft processing of the present invention, comprises the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 88 DEG C, be incubated 1.5h, stirred in 1020r/min rotating speeds
1.5h is mixed, room temperature is cooled to and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropyl
Alcohol and ammonium persulfate are well mixed, and are warming up to 135 DEG C, are incubated 25min, are then stirred 25min in 820r/min rotating speeds, are cooled to
Room temperature obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyl aoxidize
Tin, N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupled
Agent KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 125 DEG C, are incubated 1.5h, are stirred in 1020r/min rotating speeds
25min is mixed, room temperature is cooled to and obtains the mould proof adhesive of high viscosity for handicraft processing.
By the mould proof adhesive of high viscosity for being used for handicraft processing and the skill of common adhesives in embodiment 1- embodiments 5
Art index is contrasted, and obtained correction data is as shown in table 1.
Table 1：
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of mould proof adhesive of high viscosity for handicraft processing, it is characterised in that its raw material includes by weight：Acetic acid
Vinyl acetate 80-120 parts, dibutyl phthalate 15-25 parts, allyl methacrylate 2-6 parts, NMA 1-
4 parts, isopropanol 3-6 parts, ammonium persulfate 3-6 parts, nano titanium oxide 1-4 parts, nano zine oxide 3-5 parts, zinc sulphide 1-5 parts,
Maleimide tributyltin oxide 2-5 parts, N- alkylated I pyridine 1-5 parts, cosmocil stearate 3-6 parts, season
Ammonium salt terminal groups modification dimethyl polysiloxane 2-6 parts, silane resin acceptor kh-550 4-8 parts, mould proof auxiliary agent 3-6 parts, viscosity enhancing
Agent 2-5 parts, polyvinyl alcohol 1-4 parts, deionized water 15-35 parts.
2. the high viscosity mould proof adhesive according to claim 1 for handicraft processing, it is characterised in that mould proof auxiliary agent
Raw material include by weight：N- (4- hydroxy-3-methoxies-benzyl) acrylamide 5-15 parts, DMAC N,N' dimethyl acetamide 2-5
Part, acrylamide 1-6 parts, ethyl acrylate 3-5 parts, azodiisobutyronitrile 2-4 parts, attapulgite 3-5 parts, Tea Saponin 1-3 parts,
Chlorinated paraffin 2-5 parts, ferrocenecarboxylic acid 3-5 parts, hexamethyl phosphoramide 2-5 parts, sodium hydrogensulfite 1-4 parts, boric acid 2-4 parts, first
Base BTA 3-5 parts, silane resin acceptor kh-550 4-6 parts.
3. the high viscosity mould proof adhesive according to claim 1 or 2 for handicraft processing, it is characterised in that mould proof
Auxiliary agent is prepared by following technique：N- (4- hydroxy-3-methoxies-benzyl) acrylamides and DMAC N,N' dimethyl acetamide are mixed
Close uniformly, stirring, then heat up, be incubated, be then passed through nitrogen, add acrylamide, ethyl acrylate and azodiisobutyronitrile
It is well mixed, stirring, room temperature is cooled to, then adds attapulgite, Tea Saponin, chlorinated paraffin, ferrocenecarboxylic acid, hempa
Acid amides, sodium hydrogensulfite, boric acid, methyl benzotriazazole and silane resin acceptor kh-550 are well mixed, and are heated up, and are incubated, filtering,
Dried after washing, be cooled to room temperature and obtain mould proof auxiliary agent.
4. the mould proof adhesive of high viscosity for being used for handicraft processing according to claim any one of 1-3, it is characterised in that
Mould proof auxiliary agent is prepared by following technique：By N- (4- hydroxy-3-methoxies-benzyl) acrylamides and N, N- dimethylacetamide
Amine is well mixed, and is stirred 20-40min in 650-850r/min rotating speeds, is then warming up to 75-85 DEG C, is incubated 1-3h, is then passed through
Nitrogen, adds acrylamide, ethyl acrylate and azodiisobutyronitrile and is well mixed, and 10- is stirred in 450-550r/min rotating speeds
14h, room temperature is cooled to, then adds attapulgite, Tea Saponin, chlorinated paraffin, ferrocenecarboxylic acid, hexamethyl phosphoramide, sulfurous
Sour hydrogen sodium, boric acid, methyl benzotriazazole and silane resin acceptor kh-550 are well mixed, and are warming up to 70-80 DEG C, are incubated 1-3h,
Filtering, washs after 55-65 DEG C of dry 10-14h, is cooled to room temperature and obtains mould proof auxiliary agent.
5. the mould proof adhesive of high viscosity for being used for handicraft processing according to claim any one of 1-4, it is characterised in that
The raw material of viscosity- increasing agent includes by weight：Waxy corn starch 15-35 parts, the sodium hydroxide that mass fraction is 15-25%
Solution 4-8 parts, maleic anhydride aqueous solution 2-5 parts that mass fraction is 5-15%, sucrose 3-6 parts, palm wax 1-4 parts, cellulose
Ether 3-6 parts, triethanolamine 2-5 parts, laurel alcohol ether phosphate 1-4 parts, ethylene glycol 3-5 parts, empgen BB 2-5 parts, silicon
Sour aluminium 1-5 parts.
6. the mould proof adhesive of high viscosity for being used for handicraft processing according to claim any one of 1-5, it is characterised in that
Viscosity- increasing agent is prepared by following technique：By the sodium hydroxide solution that waxy corn starch and mass fraction are 15-25%
It is well mixed, 45-55 DEG C is warming up to, is incubated 20-40min, then adds the maleic anhydride aqueous solution that mass fraction is 5-15%
It is well mixed, 80-90 DEG C is warming up to, is incubated 10-30min, adjusts pH to 6.5-7.5, sucrose is then added and is well mixed, in
450-650r/min rotating speeds stir 20-30min, then add palm wax, cellulose ether, triethanolamine, laurel alcohol ether phosphate,
Ethylene glycol and empgen BB are well mixed, and are warming up to 75-85 DEG C, 1-3h are incubated, then in 650-850r/min rotating speeds
20-50min is stirred, is cooled to room temperature, alumina silicate is then added and is well mixed, be heated to 75-85 DEG C, be incubated 1.5-3.5h, in
1500-2500r/min rotating speeds stir 1.5-3.5h, are cooled to room temperature and produce viscosity- increasing agent.
A kind of 7. preparation side of mould proof adhesive of high viscosity for being used for handicraft processing according to claim any one of 1-6
Method, it is characterised in that comprise the following steps：
S1, polyvinyl alcohol and deionized water be well mixed, be warming up to 80-90 DEG C, be incubated 1-3h, turned in 850-1050r/min
Speed stirring 1-3h, is cooled to room temperature and obtains material I；
S2, by vinylacetate, dibutyl phthalate, allyl methacrylate, NMA, isopropanol and
Ammonium persulfate is well mixed, and is warming up to 120-140 DEG C, is incubated 20-40min, then stirs 20- in 650-850r/min rotating speeds
40min, it is cooled to room temperature and obtains material II；
S3, by material I, material II, nano titanium oxide, nano zine oxide, zinc sulphide, maleimide tributyltin oxide,
N- alkylated Is pyridine, cosmocil stearate, quaternary ammonium salt terminal are modified dimethyl polysiloxane, silane coupler
KH-550, mould proof auxiliary agent and viscosity- increasing agent are well mixed, and are warming up to 110-130 DEG C, 1-3h are incubated, in 850-1050r/min
Rotating speed stirs 20-50min, is cooled to room temperature and obtains the mould proof adhesive of high viscosity for handicraft processing.
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