CN107400364A - A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance - Google Patents

A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance Download PDF

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Publication number
CN107400364A
CN107400364A CN201710652965.2A CN201710652965A CN107400364A CN 107400364 A CN107400364 A CN 107400364A CN 201710652965 A CN201710652965 A CN 201710652965A CN 107400364 A CN107400364 A CN 107400364A
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CN
China
Prior art keywords
parts
retardance
silicon rubber
fire
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710652965.2A
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Chinese (zh)
Inventor
刘江滨
张明初
曹中
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Anhui Yi De Electronics Co Ltd
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Anhui Yi De Electronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Yi De Electronics Co Ltd filed Critical Anhui Yi De Electronics Co Ltd
Priority to CN201710652965.2A priority Critical patent/CN107400364A/en
Publication of CN107400364A publication Critical patent/CN107400364A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of special silicone rubber formula, specifically a kind of high porcelain Ceramic silicon rubber formula of high fire-retardance, its component is by weight proportioning:Methyl vinyl silicone rubber 110 2 is 100 parts, and white carbon is 40-65 parts, and hydroxy silicon oil is 0.05-0.09 part, diatomite is 50-150 parts, silica flour is 50-100 parts, and aluminium hydroxide/magnesium hydroxide (1/9-6/4) is 40-60 parts, and mica powder is 20-30 parts.A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance of the present invention, silicon rubber made of the formula have a high flame retardant, and oxygen index (OI) is up to 55, sinter that housing hardness is very hard, and percussion has metallic sound after the high porcelain Ceramic silicon rubber burning of high fire-retardance into;It is environment-protecting and non-poisonous.

Description

A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance
Technical field
The present invention relates to a kind of specific rubber formula, specifically a kind of high porcelain Ceramic silicon rubber of high fire-retardance is matched somebody with somebody Side.
Background technology
In recent years, with people awareness of safety continuous reinforcement, both at home and abroad to the fireproof grade of electric wire It is required that also further improve.To reach the requirement of fireproof classification standard, various different structures and material are have developed both at home and abroad Fire-resistant wire and cable.Such as:Mica tape fire-resisting cable, magnesium oxide mineral insulation cable (MI cables), flexible fire-proof cable, fire prevention Mud inorganic mineral fireproof cable.Have developed fire-resisting ceramic silicone rubber made insulating refractory again since 2005, passed through Practical application in the past few years, although fire-resisting ceramic silicone rubber many aspects it is different degrees of to solve above-mentioned several fire prevention resistance to The defects of fiery cable material be present and, but the cable that fireproof higher grade, current fire-resisting ceramic silicone rubber It is difficult to, prior art anti-flammability is not high, and oxygen index (OI) is less than 35, housing hardness deficiency.A kind of high porcelain of high fire-retardance of the present invention Change Ceramic silicon rubber formula, silicon rubber made of the formula has high flame retardant, and oxygen index (OI) is up to 55, the high porcelainization pottery of high fire-retardance It is very hard to sinter housing hardness after porcelain SiClx rubber combustion into, percussion has metallic sound;It is environment-protecting and non-poisonous, meet European Union ROHS and REACH It is required that.
The content of the invention
For the problems of the prior art, a kind of high porcelain Ceramic silicon rubber formula of high fire-retardance of the invention, the formula Manufactured silicon rubber has high flame retardant, and oxygen index (OI) is up to 55, shelling is sintered after the high porcelain Ceramic silicon rubber burning of high fire-retardance Body hardness is very hard, and percussion has metallic sound;It is environment-protecting and non-poisonous, meet European Union's ROHS and REACH requirement.
The technical solution adopted for the present invention to solve the technical problems is:A kind of high porcelain Ceramic silicon rubber of high fire-retardance is matched somebody with somebody Side, its component are by weight proportioning:
Methyl vinyl silicone rubber 110-2 is 100 parts, and white carbon is 40-65 parts, and hydroxy silicon oil is 0.05-0.09 part, Diatomite is 50-150 parts, and silica flour is 50-100 parts, and aluminium hydroxide/magnesium hydroxide (1/9-6/4) is 40-60 parts, cloud Female powder is 20-30 parts.
The beneficial effects of the invention are as follows:A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance of the present invention, the formula system Into silicon rubber there is high flame retardant, oxygen index (OI) is up to 55, and housing is sintered into after the high porcelain Ceramic silicon rubber burning of high fire-retardance Hardness is very hard, and percussion has metallic sound;It is environment-protecting and non-poisonous, meet European Union's ROHS and REACH requirement.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Embodiment is closed, the present invention is expanded on further.
A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance of the present embodiment, its component are by weight proportioning:
Example number
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the description in above-mentioned embodiment and specification simply illustrates the present invention Principle, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these change and Improvement is both fallen within the scope of protection of present invention.The claimed scope of the invention is by appended claims and its equivalent Thing defines.

Claims (1)

1. a kind of high porcelain Ceramic silicon rubber formula of high fire-retardance, it is characterised in that its component is by weight proportioning:
Methyl vinyl silicone rubber 110-2 is 100 parts, and white carbon is 40-65 parts, and hydroxy silicon oil is 0.05-0.09 part, diatom Soil is 50-150 parts, and silica flour is 50-100 parts, and aluminium hydroxide/magnesium hydroxide (1/9-6/4) is 40-60 parts, mica powder For 20-30 parts.
CN201710652965.2A 2017-08-02 2017-08-02 A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance Pending CN107400364A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710652965.2A CN107400364A (en) 2017-08-02 2017-08-02 A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710652965.2A CN107400364A (en) 2017-08-02 2017-08-02 A kind of high porcelain Ceramic silicon rubber formula of high fire-retardance

Publications (1)

Publication Number Publication Date
CN107400364A true CN107400364A (en) 2017-11-28

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Country Status (1)

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CN (1) CN107400364A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795058A (en) * 2018-06-27 2018-11-13 国网河南省电力公司西峡县供电公司 A kind of power cable fire proofing
CN111471304A (en) * 2020-06-03 2020-07-31 苏州法思特新材料有限公司 Flame-retardant and fire-resistant silicon rubber material and preparation method and application thereof
CN112210217A (en) * 2020-09-28 2021-01-12 东莞海之澜硅胶科技有限公司 Anti-vibration ceramic silicon rubber and preparation method thereof
CN113355047A (en) * 2021-06-25 2021-09-07 上海珏晟新材料科技有限公司 Flame-retardant liquid silica gel for bonding electrical elements and preparation method thereof
CN114605839A (en) * 2022-04-18 2022-06-10 山东大学 Ceramizable silicone rubber with obvious XRD new crystallization peak after calcination and preparation method thereof
CN116063028A (en) * 2022-12-30 2023-05-05 福建礼恩科技有限公司 High-performance ceramic silicone rubber fireproof mud

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876049A (en) * 2012-10-16 2013-01-16 江苏天辰硅材料有限公司 Ceramic silicon rubber and preparation method thereof
CN106633915A (en) * 2016-12-26 2017-05-10 成都硅宝科技股份有限公司 Highly flame-retardant halogen-free environment-friendly silicone rubber and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876049A (en) * 2012-10-16 2013-01-16 江苏天辰硅材料有限公司 Ceramic silicon rubber and preparation method thereof
CN106633915A (en) * 2016-12-26 2017-05-10 成都硅宝科技股份有限公司 Highly flame-retardant halogen-free environment-friendly silicone rubber and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795058A (en) * 2018-06-27 2018-11-13 国网河南省电力公司西峡县供电公司 A kind of power cable fire proofing
CN111471304A (en) * 2020-06-03 2020-07-31 苏州法思特新材料有限公司 Flame-retardant and fire-resistant silicon rubber material and preparation method and application thereof
CN112210217A (en) * 2020-09-28 2021-01-12 东莞海之澜硅胶科技有限公司 Anti-vibration ceramic silicon rubber and preparation method thereof
CN113355047A (en) * 2021-06-25 2021-09-07 上海珏晟新材料科技有限公司 Flame-retardant liquid silica gel for bonding electrical elements and preparation method thereof
CN114605839A (en) * 2022-04-18 2022-06-10 山东大学 Ceramizable silicone rubber with obvious XRD new crystallization peak after calcination and preparation method thereof
CN116063028A (en) * 2022-12-30 2023-05-05 福建礼恩科技有限公司 High-performance ceramic silicone rubber fireproof mud

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Application publication date: 20171128

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