CN107400349A - A kind of high molecule plastic - Google Patents
A kind of high molecule plastic Download PDFInfo
- Publication number
- CN107400349A CN107400349A CN201710747599.9A CN201710747599A CN107400349A CN 107400349 A CN107400349 A CN 107400349A CN 201710747599 A CN201710747599 A CN 201710747599A CN 107400349 A CN107400349 A CN 107400349A
- Authority
- CN
- China
- Prior art keywords
- parts
- high molecule
- carbon black
- compatilizer
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of high molecule plastic, including plastic substrate and additive, it is characterised in that：Described additive includes fire retardant, plasticizer, filler, crosslinking agent, compatilizer, antioxidant, silane coupler, carbon black, nano-sized magnesium hydroxide, Firebrake ZB, glass fibre, glass fibre, Tissuemat E；The parts by weight of each composition are：1000 parts of plastic substrate, 150 200 parts of fire retardant, 90 150 parts of plasticizer, 40 60 parts of filler, 60 80 parts of crosslinking agent, 60 85 parts of compatilizer, 40 60 parts of anti-oxidant DLTP, 25 60 parts of silane coupler, 100 150 parts of carbon black, 150 180 parts of nano-sized magnesium hydroxide, 100 150 parts of Firebrake ZB, 50 80 parts of glass fibre, 50 80 parts of Tissuemat E；After being modified enhancing by adding multiple additives in polydiphenyl ether plastics in the present invention, polydiphenyl ether plastics is set to have the advantages that fire-retardant, good mechanical property, plasticity is good, good product quality.
Description
Technical field
The present invention relates to plastic applications, more particularly to a kind of high molecule plastic.
Background technology
At present, the application of plastics is throughout the every field of industrial or agricultural, life, and the main thermoplastic materials total amount in the whole world in 1999 is
Up to 1.1 hundred million tons, and average annual growth rate up on 5.3%, 2000 year West Europe electronic enterprises with plastics up to 23,000,000 tons, together
When plastics the also more and more extensive such as produced in USA plastics of application in have 5% be plastics, electronic enterprises plastics
Have 15% above is plastics.The fire-retardant high polymer of present plastics multidigit, it is not easy to be ignited, and can reduce unexpected fire, or drawing
Then substantially without flame the intensity of a fire can be avoided to become big, in addition, plastics can also reduce flame propagation velocity and burning velocity.
The fire retardant in high polymer material is mainly brominated flame retardant at present.Because brominated flame retardant in combustion can
Substantial amounts of brominated toxic and harmful gas is produced, so as to greatly be endangered to mankind's health care belt.With expanding economy, the mankind
The progress of civilization, fire-retardant non-halogen cry more and more higher, therefore, the fire-retardant non-halogen direction for turning into Future Development.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of fire-retardant, good mechanical property, plasticity is good, resistance of good product quality
Fire high molecule plastic.
In order to solve the above technical problems, the technical scheme is that：A kind of high molecule plastic, including plastic substrate and
Additive, its innovative point are：Described additive includes fire retardant, plasticizer, filler, crosslinking agent, compatilizer, antioxygen
Agent, silane coupler, carbon black, nano-sized magnesium hydroxide, Firebrake ZB, glass fibre, Tissuemat E；The parts by weight of each composition
For：1000 parts of plastic substrate, fire retardant 150-200 parts, plasticizer 90-150 parts, filler 40-60 parts, crosslinking agent
60-80 parts, compatilizer 60-85 parts, anti-oxidant DLTP 40-60 parts, silane coupler 25-60 parts, carbon black 100-150 parts,
Nano-sized magnesium hydroxide 150-180 parts, Firebrake ZB 100-150 parts, glass fibre 50-80 parts, Tissuemat E 50-80 parts；
Described plastic substrate is polydiphenyl ether plastics.
Further, described fire retardant is taken for the one or more of tricresyl phosphate, antimony oxide and melamine
The mixture matched somebody with somebody.
Further, described plasticizer is diethyl phthalate, repefral and O-phthalic
The mixture of one or more of collocation of dioctyl phthalate.
Further, described filler is one or more of collocation of kaolin, talcum powder, alumina powder and carbon black
Mixture.
Further, described crosslinking agent is trimethylolethane, one kind or several of pentaerythrite and divinylbenzene
The mixture of kind collocation.
Further, described compatilizer is that maleic anhydride connects branch.
The advantage of the invention is that：
1）In the present invention by polydiphenyl ether plastics add multiple additives be modified enhancing after, make polydiphenyl ether plastics have resistance
The advantages that combustion, good mechanical property, plasticity are good, good product quality.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this
It is bright to be limited among described scope of embodiments.
A kind of high molecule plastic, including plastic substrate and additive, described additive include fire retardant, plasticizer,
Filler, crosslinking agent, compatilizer, antioxidant, silane coupler, carbon black, nano-sized magnesium hydroxide, Firebrake ZB, glass fibre, poly- second
Alkene wax；The parts by weight of each composition are：1000 parts of plastic substrate, fire retardant 150-200 parts, plasticizer 90-150
It is part, filler 40-60 parts, crosslinking agent 60-80 parts, compatilizer 60-85 parts, anti-oxidant DLTP 40-60 parts, silane coupled
Agent 25-60 parts, carbon black 100-150 parts, nano-sized magnesium hydroxide 150-180 parts, Firebrake ZB 100-150 parts, glass fibre 50-80
Part, Tissuemat E 50-80 parts；
Plastic substrate is polydiphenyl ether plastics；
Fire retardant is the mixture of one or more of collocation of tricresyl phosphate, antimony oxide and melamine.
Plasticizer is one kind of diethyl phthalate, repefral and dioctyl phthalate
Or the mixture of several collocation.
Filler is the mixture of one or more of collocation of kaolin, talcum powder, alumina powder and carbon black.
Crosslinking agent is the mixture of one or more of collocation of trimethylolethane, pentaerythrite and divinylbenzene.
Compatilizer is that maleic anhydride connects branch.
Embodiment 1：
The parts by weight of each composition of formula of described flame-retardant high-molecular plastics are：1000 parts of polydiphenyl ether plastics；Tricresyl phosphate
170 parts of toluene ester；120 parts of diethyl phthalate；50 parts of talcum powder；70 parts of pentaerythrite；Maleic anhydride connects
75 parts of branch；50 parts of anti-oxidant DLTP, 40 parts of silane coupler, 120 parts of carbon black, 165 parts of nano-sized magnesium hydroxide, boric acid
120 parts of zinc, 60 parts of glass fibre, 60 parts of Tissuemat E.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation
Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have
Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention
By appended claims and its equivalent thereof.
Claims (6)
1. a kind of high molecule plastic, including plastic substrate and additive, it is characterised in that：Described additive includes fire-retardant
Agent, plasticizer, filler, crosslinking agent, compatilizer, antioxidant, silane coupler, carbon black, nano-sized magnesium hydroxide, Firebrake ZB, glass
Glass fiber, Tissuemat E；The parts by weight of each composition are：1000 parts of plastic substrate, fire retardant 150-200 parts, increase
Mould agent 90-150 parts, filler 40-60 parts, crosslinking agent 60-80 parts, compatilizer 60-85 parts, anti-oxidant DLTP 40-60
Part, silane coupler 25-60 parts, carbon black 100-150 parts, nano-sized magnesium hydroxide 150-180 parts, Firebrake ZB 100-150 parts, glass
Glass fiber 50-80 parts, Tissuemat E 50-80 parts；
Described plastic substrate is polydiphenyl ether plastics.
A kind of 2. high molecule plastic according to claim 1, it is characterised in that：Described fire retardant is phosphate trimethylbenzene
The mixture of one or more of collocation of ester, antimony oxide and melamine.
A kind of 3. high molecule plastic according to claim 1, it is characterised in that：Described plasticizer is phthalic acid two
The mixture of one or more of collocation of ethyl ester, repefral and dioctyl phthalate.
A kind of 4. high molecule plastic according to claim 1, it is characterised in that：Described filler is kaolin, talcum
The mixture of one or more of collocation of powder, alumina powder and carbon black.
A kind of 5. high molecule plastic according to claim 1, it is characterised in that：Described crosslinking agent is trihydroxy methyl second
The mixture of one or more of collocation of alkane, pentaerythrite and divinylbenzene.
A kind of 6. high molecule plastic according to claim 1, it is characterised in that：Described compatilizer connects for maleic anhydride
Branch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710747599.9A CN107400349A (en) | 2017-08-28 | 2017-08-28 | A kind of high molecule plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710747599.9A CN107400349A (en) | 2017-08-28 | 2017-08-28 | A kind of high molecule plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107400349A true CN107400349A (en) | 2017-11-28 |
Family
ID=60397252
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710747599.9A Pending CN107400349A (en) | 2017-08-28 | 2017-08-28 | A kind of high molecule plastic |
Country Status (1)
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| CN (1) | CN107400349A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752966A (en) * | 2018-06-20 | 2018-11-06 | 佛山市禅城区钜艺塑料厂 | A kind of high molecule plastic and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850646A (en) * | 2011-06-27 | 2013-01-02 | 滁州格美特科技有限公司 | Flame-retardant antistatic high-strength thermoplastic composite material and its preparation method |
| CN102850764A (en) * | 2012-08-29 | 2013-01-02 | 潘元平 | Flame-retardant high-polymer plastic formula |
| CN103289164A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Flame-retardant polymer antistatic plastic |
-
2017
- 2017-08-28 CN CN201710747599.9A patent/CN107400349A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850646A (en) * | 2011-06-27 | 2013-01-02 | 滁州格美特科技有限公司 | Flame-retardant antistatic high-strength thermoplastic composite material and its preparation method |
| CN102850764A (en) * | 2012-08-29 | 2013-01-02 | 潘元平 | Flame-retardant high-polymer plastic formula |
| CN103289164A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Flame-retardant polymer antistatic plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752966A (en) * | 2018-06-20 | 2018-11-06 | 佛山市禅城区钜艺塑料厂 | A kind of high molecule plastic and preparation method thereof |
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Application publication date: 20171128 |
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