CN107399864A - A kind of height total system containing salt oil-containing wastewater and technique - Google Patents
A kind of height total system containing salt oil-containing wastewater and technique Download PDFInfo
- Publication number
- CN107399864A CN107399864A CN201710705658.6A CN201710705658A CN107399864A CN 107399864 A CN107399864 A CN 107399864A CN 201710705658 A CN201710705658 A CN 201710705658A CN 107399864 A CN107399864 A CN 107399864A
- Authority
- CN
- China
- Prior art keywords
- filtrate
- containing wastewater
- oil
- membrane
- salt oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4691—Capacitive deionisation
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a kind of high total system containing salt oil-containing wastewater and technique, wherein processing system, which includes sand filtering device, ultrafiltration apparatus and membrane capacitance deionizer, handling process, includes：Height is handled containing salt oil-containing wastewater by sand filtering device, removing can oil slick, oil emulsion and suspension in waste water；Waste water by ultrafiltration apparatus, further removes oils and suspension in waste water again；Last waste water enters membrane capacitance deionization system, carries out desalting processing；The present invention carries out sand filtration processing as filtrate using natural siliceous sand to raw water, can remove part oils and suspension in water body；Using hyperfiltration treatment, almost all of oils and suspension in water body can be removed, effectively controls existing membrane pollution problem during follow-up desalting processing；The present invention takes membrane capacitance deionization technology effectively to remove salt, energy consumption is low as last desalting processing technique.
Description
Technical field
The invention belongs to technical field of sewage, more particularly to a kind of high total system containing salt oil-containing wastewater and work
Skill.
Background technology
Oily waste water is a kind of to have a large capacity and a wide range and endanger serious waste water.The oil plant that its main source has petroleum industry produces
Raw oily waste water;Caused cooling-lubricant and emulsifiable oil waste water in machinery manufacturing industry;Textile industry, food processing industry, food and drink
Industry etc. can also discharge substantial amounts of oily waste water.Salt comparision contents are high in usual this kind of oily waste water, complicated component, without processing
Directly discharge can cause serious environmental pollution.
This high saliferous oiliness sewage treatment gets up relatively difficult, and the processing for oily waste water, based on oil is in water
The difference of existence form, generally there are filtration method, Bubble-floating Method, absorption method and membrane separation process etc..For the high waste water of salt content, lead to
Often counter-infiltration, electrodialysis, membrane capacitance method etc. is taken to handle, but oily substance present in these brine wastes, to film
Seriously polluted, easy cleaning, operating cost be not higher, it is therefore desirable to further develop function admirable, the preferable technique for the treatment of effeciency,
Contain salt oil-containing wastewater to handle this kind of height, reduce cost.
The content of the invention
The present invention provides a kind of high total system containing salt oil-containing wastewater and technique, to solve in the prior art for height
Problem present in saliferous oiliness sewage treatment.
To achieve the above object, the technical solution adopted by the present invention is：
A kind of height total system containing salt oil-containing wastewater, including sand filtering device, ultrafiltration apparatus and membrane capacitance deionizer, institute
State that sand filtering device is provided with water inlet 14 including top, bottom is provided with filtrate (liquid 15, its internal sand filtration for being filled with filtrate 1
Device 13, the top down of sand filter 13 are provided with the elevating mechanism 2 moved up and down in sand filter 13 from above filtrate 1,
The sand filter 13 is bottom up to be provided with the rabbling mechanism 4 being stirred to filtrate 1；The ultrafiltration apparatus includes passing through pipeline
The polysulfone hollow fiber ultrafiltration membrane system 5 and header tank 6 of 16 connections；The membrane capacitance deionizer includes what is connected by pipeline 16
Membrane capacitance component 8 and water outlet fluid reservoir 10, the membrane capacitance component 8 connect dc source 7, and the connection of water outlet fluid reservoir 10 is set
Be equipped with the electric conductivity detector 11 of controller 12, the electric conductivity detector 11 record in real time water outlet conductivity change and transmit to
Controller 12；The filtrate (liquid 15 of the sand filter 13 connects polysulfone hollow fiber ultrafiltration membrane system 5, the header tank by pipeline 16
6 pass through the junctional membrane capacitance component 8 of pipeline 16.
Further, the bottom of elevating mechanism 2 is provided with platen 3, and the bottom surface of the platen 3 props up the upper table of filtrate 1
Face.
Further, the top of elevating mechanism 2 and the bottom of rabbling mechanism 4 are connected to respective drive device
17。
Further, the pipeline 16 between the polysulfone hollow fiber ultrafiltration membrane system 5 and header tank 6 is provided with water valve 18.
Further, the current in the polysulfone hollow fiber ultrafiltration membrane system 5 flow from bottom to top, i.e. the filtrate of sand filter 13
Outlet 15 connects the bottom of polysulfone hollow fiber ultrafiltration membrane system 5 by pipeline 16, and the top of polysulfone hollow fiber ultrafiltration membrane system 5 passes through pipe
Road 16 connects header tank 6.
Further, it is provided with water pump 9 on the pipeline 16 between the header tank 6 and membrane capacitance component 8.
Further, the filtrate 1 used in the sand filter is natural quartz sand filtering material.
Further, the particle diameter of the natural quartz sand filtering material is 0.5-1.2mm.
Further, the internal diameter of the doughnut in the polysulfone hollow fiber ultrafiltration membrane system 5 is 1mm.
A kind of height comprehensive processing technique containing salt oil-containing wastewater, comprises the following steps：
S1, height handled containing salt oil-containing wastewater by sand filtering device, can oil slick, oil emulsion and suspension in removal waste water；
S2, the waste water after step S1 processing further remove oils and suspension in waste water by ultrafiltration apparatus；
S3, the waste water after step S2 processing finally enter membrane capacitance deionization system, carry out desalting processing.
Compared with prior art, the invention has the advantages that：
1st, the present invention carries out sand filtration processing as filtrate using natural siliceous sand to raw water, can remove in water body part oils with
Suspension；Using hyperfiltration treatment, almost all of oils and suspension in water body can be removed, effectively controls follow-up desalting processing
During existing membrane pollution problem.
2 present invention take membrane capacitance deionization technology effectively to remove salt, energy as last desalting processing technique
Consume low.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention；
Wherein：1- filtrates, 2- elevating mechanisms, 3- platens, 4- rabbling mechanisms, 5- polysulfone hollow fiber ultrafiltration membrane systems, 6- header tanks, 7-
Dc source, 8- membrane capacitance components, 9- water pumps, 10- water outlet fluid reservoirs, 11- electric conductivity detectors, 12- controllers, 13- sand filtrations
Device, 14- water inlets, 15- filtrate (liquids, 16- pipelines, 17- drive devices, 18- water valves.
Embodiment
The present invention is further described with reference to embodiment.
As shown in figure 1, a kind of height total system containing salt oil-containing wastewater, including sand filtering device, ultrafiltration apparatus and film electricity
Hold deionizer, the sand filtering device is provided with water inlet 14 including top, bottom is provided with filtrate (liquid 15, fills out inside it
Sand filter 13 filled with filtrate 1, the top down of sand filter 13, which is provided with sand filter 13 from above filtrate 1, does lifting fortune
Dynamic elevating mechanism 2, the sand filter 13 is bottom up to be provided with the rabbling mechanism 4 being stirred to filtrate 1；The ultrafiltration dress
Put polysulfone hollow fiber ultrafiltration membrane system 5 and header tank 6 including being connected by pipeline 16；The membrane capacitance deionizer includes logical
The membrane capacitance component 8 and water outlet fluid reservoir 10 that piping 16 connects, the membrane capacitance component 8 connect dc source 7, the water outlet
Fluid reservoir 10 is connected with the electric conductivity detector 11 of controller 12, and the electric conductivity detector 11 records water outlet conductance in real time
Rate changes and transmitted to controller 12；The filtrate (liquid 15 of the sand filter 13 connects hollow fiber ultrafiltration membrane group by pipeline 16
Part 5, the header tank 6 pass through the junctional membrane capacitance component 8 of pipeline 16.
The bottom of elevating mechanism 2 is provided with platen 3, and the bottom surface of the platen 3 props up the upper surface of filtrate 1, the liter
The top of descending mechanism 2 and the bottom of rabbling mechanism 4 are connected to respective drive device 17.
Pipeline 16 between the polysulfone hollow fiber ultrafiltration membrane system 5 and header tank 6 is provided with water valve 18, the doughnut
Current in hyperfiltration membrane assembly 5 flow from bottom to top, i.e., the filtrate (liquid 15 of sand filter 13 connects doughnut by pipeline 16
The bottom of hyperfiltration membrane assembly 5, the top of polysulfone hollow fiber ultrafiltration membrane system 5 connect header tank 6, the header tank 6 by pipeline 16
It is provided with water pump 9 on pipeline 16 between membrane capacitance component 8, the doughnut in the polysulfone hollow fiber ultrafiltration membrane system 5
Internal diameter is 1mm.
The filtrate 1 used in the sand filter is natural quartz sand filtering material, and the particle diameter of the natural quartz sand filtering material is
0.5-1.2mm。
Embodiment 1
Simulation is high to contain oil content 20mg/L, salt content 1g/L, COD 350mg/L in salt oil-containing wastewater
A kind of height comprehensive processing technique containing salt oil-containing wastewater, comprises the following steps：
Height (oil content 20mg/L, salt content 1g/L, COD 350mg/L) containing salt oil-containing wastewater is simulated, is carried out into sand filtering device
Filtration treatment, remove waste water in can oil slick, oil emulsion and suspension, water quality oil content is about 3.8mg/L, COD contents 92mg/
L, water after preliminary treatment enter hyperfiltration membrane assembly by pipeline and carry out hyperfiltration treatment, nearly all oils in the water body after processing
And suspension is removed, oil content is down to 0.5mg/L, and COD contents are down to 21mg/L；Water after processing is entered by pipeline to catchment
Case enters membrane capacitance component for follow-up desalting processing, water body by pipeline, and dc source provides burning voltage 1.2V, water body electricity
Conductivity value is 3910 μ S/cm；Water after desalination enters water outlet fluid reservoir, and electrical conductivity is finally down to 1200 μ S/cm, and salt rejection rate is
64.5%；After 55min desalting processing, reversal connection is carried out.After carrying out the desalting processing of 12 days, membrane capacitance deionizer
Running status is relatively stable, salt rejection rate 52.3%, remains in that higher desalting efficiency, illustrates that sand filtration and hyperfiltration treatment have
Effect controls the formation of fouling membrane.
Embodiment 1 shows that a kind of high total system containing salt oil-containing wastewater provided by the invention and technique can be effective
Processing height contains salt oil-containing wastewater, has good treatment effect.
Comparative example
Contrasted using the technical scheme of following technical scheme and the embodiment of the present invention 1, the high (oil content containing salt oil-containing wastewater
20mg/L, salt content 1g/L, COD 350mg/L) enter potassium permanganate composites progress chemical tendering and flocculating setting, remove big portion
Point suspension, oil content 17.23mg/L, COD180mg/L in the water quality after processing；Water after processing enters immersion ultrafiltration pond,
Oils, organic matter and colloidal impurity are further removed, oil content is down to 9.25mg/L, COD42mg/L；Finally carry out separation concentration
(counter-infiltration) desalting processing, desalting efficiency 42%.
A kind of high total system containing salt oil-containing wastewater provided by the invention is can be seen that from embodiment 1 and comparative example
And technique can effectively handle height and contain salt oil-containing wastewater, by prolonged operation, this technique still has good treatment effect,
And holistic cost is relatively low, system and arranging is simple.The technique can effectively remove oils and salt in waste water, and equipment is simple,
Cost is relatively low, the waste water after sand filtration is handled, and can effectively slow down the fouling membrane that follow-up film process occurs, and extends the use of film
Life-span.
Described above is only the preferred embodiment of the present invention, it should be pointed out that：For the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
- A kind of 1. height total system containing salt oil-containing wastewater, it is characterised in that：Including sand filtering device, ultrafiltration apparatus and membrane capacitance Deionizer, the sand filtering device are provided with water inlet including top（14）, bottom be provided with filtrate (liquid（15）, inside it Filled with filtrate（1）Sand filter（13）, the sand filter（13）Top down is provided with sand filter（13）It is interior from filtrate（1） The elevating mechanism that top moves up and down（2）, the sand filter（13）It is bottom up to be provided with to filtrate（1）What is be stirred stirs Mix mechanism（4）；The ultrafiltration apparatus includes passing through pipeline（16）The polysulfone hollow fiber ultrafiltration membrane system of connection（5）And header tank（6）； The membrane capacitance deionizer includes passing through pipeline（16）The membrane capacitance component of connection（8）With water outlet fluid reservoir（10）, it is described Membrane capacitance component（8）Connect dc source（7）, the water outlet fluid reservoir（10）It is connected with controller（12）Electrical conductivity inspection Survey instrument（11）, the electric conductivity detector（11）Record water outlet conductivity changes and transmitted to controller in real time（12）；The sand Filter（13）Filtrate (liquid（15）Pass through pipeline（16）Connect polysulfone hollow fiber ultrafiltration membrane system（5）, the header tank（6）Pass through Pipeline（16）Junctional membrane capacitance component（8）.
- 2. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The elevating mechanism （2）Bottom is provided with platen（3）, the platen（3）Bottom surface prop up filtrate（1）Upper surface.
- 3. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The elevating mechanism （2）Top and rabbling mechanism（4）Bottom be connected to respective drive device（17）.
- 4. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The doughnut surpasses Filter membrane component（5）And header tank（6）Between pipeline（16）It is provided with water valve（18）.
- 5. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The doughnut surpasses Filter membrane component（5）Interior current flow from bottom to top, i.e. sand filter（13）Filtrate (liquid（15）Pass through pipeline（16）In connection Fibre ultrafiltration membrane module（5）Bottom, polysulfone hollow fiber ultrafiltration membrane system（5）Top pass through pipeline（16）Connect header tank （6）.
- 6. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The header tank（6） With membrane capacitance component（8）Between pipeline（16）On be provided with water pump（9）.
- 7. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：Adopted in the sand filter Filtrate（1）It is natural quartz sand filtering material.
- 8. height total system containing salt oil-containing wastewater according to claim 7, it is characterised in that：The natural siliceous sand The particle diameter of filtrate is 0.5-1.2mm.
- 9. height total system containing salt oil-containing wastewater according to claim 1, it is characterised in that：The doughnut surpasses Filter membrane component（5）The internal diameter of interior doughnut is 1mm.
- 10. a kind of handling process according to any described high total systems containing salt oil-containing wastewater of claim 1-9, it is special Sign is, comprises the following steps：S1, height handled containing salt oil-containing wastewater by sand filtering device, can oil slick, oil emulsion and suspension in removal waste water；S2, the waste water after step S1 processing further remove oils and suspension in waste water by ultrafiltration apparatus；S3, the waste water after step S2 processing finally enter membrane capacitance deionization system, carry out desalting processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710705658.6A CN107399864A (en) | 2017-08-17 | 2017-08-17 | A kind of height total system containing salt oil-containing wastewater and technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710705658.6A CN107399864A (en) | 2017-08-17 | 2017-08-17 | A kind of height total system containing salt oil-containing wastewater and technique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107399864A true CN107399864A (en) | 2017-11-28 |
Family
ID=60396711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710705658.6A Pending CN107399864A (en) | 2017-08-17 | 2017-08-17 | A kind of height total system containing salt oil-containing wastewater and technique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107399864A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240337A (en) * | 2019-05-06 | 2019-09-17 | 苏州久沛环保科技有限公司 | A kind of high saliferous oiliness sewage treatment equipment and waste water treatment process |
| CN111039433A (en) * | 2019-12-13 | 2020-04-21 | 浙江天地环保科技有限公司 | System and method for treating ship tail gas desulfurization washing wastewater |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2597464Y (en) * | 2003-01-23 | 2004-01-07 | 武汉市汉江石油物资技术开发有限责任公司 | Fibre ball filter pressing device |
| CN101219836A (en) * | 2007-01-12 | 2008-07-16 | 北京世博恒业科技有限公司 | System and technique for processing oily wastewater with high saline salinity |
| CN203976529U (en) * | 2014-06-03 | 2014-12-03 | 世纪华扬环境工程有限公司 | oil field produced water zero discharge pre-concentration device |
| US8952199B2 (en) * | 2007-07-24 | 2015-02-10 | Dow Global Technologies Llc | Methods of and formulations for reducing and inhibiting the growth of the concentration of microbes in water-based fluids and systems used with them |
| CN106865837A (en) * | 2017-03-01 | 2017-06-20 | 河海大学 | A kind of method of utilization milipore filter and membrane capacitance deionization group technology treatment brackish-water lake storehouse water |
-
2017
- 2017-08-17 CN CN201710705658.6A patent/CN107399864A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2597464Y (en) * | 2003-01-23 | 2004-01-07 | 武汉市汉江石油物资技术开发有限责任公司 | Fibre ball filter pressing device |
| CN101219836A (en) * | 2007-01-12 | 2008-07-16 | 北京世博恒业科技有限公司 | System and technique for processing oily wastewater with high saline salinity |
| US8952199B2 (en) * | 2007-07-24 | 2015-02-10 | Dow Global Technologies Llc | Methods of and formulations for reducing and inhibiting the growth of the concentration of microbes in water-based fluids and systems used with them |
| CN203976529U (en) * | 2014-06-03 | 2014-12-03 | 世纪华扬环境工程有限公司 | oil field produced water zero discharge pre-concentration device |
| CN106865837A (en) * | 2017-03-01 | 2017-06-20 | 河海大学 | A kind of method of utilization milipore filter and membrane capacitance deionization group technology treatment brackish-water lake storehouse water |
Non-Patent Citations (1)
| Title |
|---|
| 雷乐成: "《污水回用新技术及工程设计》", 31 July 2002, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240337A (en) * | 2019-05-06 | 2019-09-17 | 苏州久沛环保科技有限公司 | A kind of high saliferous oiliness sewage treatment equipment and waste water treatment process |
| CN111039433A (en) * | 2019-12-13 | 2020-04-21 | 浙江天地环保科技有限公司 | System and method for treating ship tail gas desulfurization washing wastewater |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN201082877Y (en) | Oil-containing sewage treating apparatus | |
| CN100572306C (en) | Oil-contained waste water treatment system that a kind of saltiness is high and technology | |
| CN100500595C (en) | Apparatus for treating sewage containing oil, and processing technique | |
| CN111807617A (en) | Water-based paint waste liquid treatment and recycling system and method | |
| CN108046448A (en) | A kind of underground mine water treatment system and processing method | |
| CN105236682B (en) | Processing method and processing device containing oil-polluted water | |
| CN107399864A (en) | A kind of height total system containing salt oil-containing wastewater and technique | |
| CN106746364B (en) | Oil field produced water recycling method and device | |
| CN105417802A (en) | Recycling system and recycling method for die-casting waste liquid | |
| CN107963745A (en) | Organic polluting water extracts processing system in underground water | |
| CN105417876B (en) | The treatment process of comprehensive wastewater that a kind of engine manufacture generates | |
| CN104261581B (en) | Integrated oil gas field wastewater processing system | |
| CN104129873B (en) | A kind of drilling mud Waste Water Treatment and method | |
| CN208038181U (en) | A kind of oil exploitation produced water treatment injected oil-containing sewage treatment system up to standard | |
| CN216445153U (en) | Flowing back processing apparatus is returned to oil field fracturing | |
| CN110240337A (en) | A kind of high saliferous oiliness sewage treatment equipment and waste water treatment process | |
| CN105693015A (en) | Treatment method of cutting fluid wastewater of automobile engine | |
| CN202191731U (en) | Automatic oil-water separating device | |
| CN108218027A (en) | A kind of sampling of water quality cleaning equipment | |
| CN107686213A (en) | Oily wastewater treatment method and processing system | |
| CN201380045Y (en) | Pretreatment device and reverse osmosis desalination apparatus for desalination of mine water | |
| CN107365008A (en) | A kind of vehicular pressure break returns waste discharge and abandons liquid treating system | |
| CN206544953U (en) | A kind of emulsion processing equipment | |
| CN204138463U (en) | A kind of drilling mud Waste Water Treatment | |
| CN205999228U (en) | Garbage percolation liquid treating system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171128 |