CN107385910A - Fiber composite natral Anti-bacterial and Crease agent and preparation method thereof - Google Patents
Fiber composite natral Anti-bacterial and Crease agent and preparation method thereof Download PDFInfo
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- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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Abstract
The invention discloses fiber composite natral Anti-bacterial and Crease agent and preparation method thereof, the raw material of the finishing agent includes the component of following parts by weight：5 11 parts of inulin, 26 parts of willow leaf extract, 1 4.5 parts of paulownia flower extract, 2.3 6 parts of Caesalpinia spinosaKuntze extract, 1.6 4.2 parts of oolong tea extract, 2.1 3.5 parts of sunglo carboxymethyl cellulose, 2.4 5 parts of tannic acid, 1.8 4 parts of hydroxy acrylic acid, 1.2 3.6 parts of propionic acid malt phenolic ester, 2.4 5.3 parts of APG, 0.3 1 parts of concentrated hydrochloric acid, 1.2 2.3 parts of ethylene glycol, 80 150 parts of water.Finishing agent provided by the present invention possesses good antibacterial and wrinkle resistance, and water resistance is good, and its bacteriostasis rate and creasy recovery angle remain at higher level after washing 60 times, at the same flat appearance degree up to 3.5 and more than, combination property is good, has a extensive future.
Description
Technical field
The invention belongs to technical field of textile chemical engineering, and in particular to the fiber agent of composite natral Anti-bacterial and Crease and its system
Preparation Method.
Background technology
In numerous textile fabric kinds, the regenerated cellulose such as silk, cotton, fiber crops and viscose, tencel in natural fiber
Product is increasingly favored by consumer.But all presence of the textile of these fiber species easily wrinkle, fabric elasticity is poor,
It is yielding and the shortcomings of itself is without antibiotic property, greatly reduce the quality of product.
In broad terms, the one or several kinds of chemistry for the special wearability that fiber is to confer to fiber with function additive add
Add agent, be the importance for lifting fiber added value.Generally according to its function classification, the function additive of fiber can be divided into wrinkle resistant
Finishing agent, antiseptic, color fixing agent, softening agent, ultra-violet absorber and antistatic additive etc..
The conventional antiseptic of fiber mainly includes the nothings such as Nano Silver, nano zine oxide, nano-ceramic powder, titanium dioxide at present
The organic antibacterial agent such as machine antiseptic and biguanides, although these antiseptics obtain certain good antibacterial effect,
Metal mold antiseptic therein may produce discoloration and influence the color and luster of fiber, and some metallics are also possible to human body in addition
Organ produce certain genotoxic potential；And organic antibacterial agent therein can also be present that the antibacterial cycle is short, poor chemical stability with
And the problems such as safety in utilization.Preferable resistant fiber microbial inoculum is except possessing good antibacterial effect, it is necessary to meets：1）Should not be right
The mankind and environment have excessive toxicity, should not cause allergic and stimulate, safe to use；2）Must be to properties of textile or outward appearance
In the absence of negative effect, it is necessary to good with flat textile product processing compatibility；3）Wash resistant and drying and it should be able to be not easy from fabric
Middle leaching.
It is whole that traditional crease-shedding finishing agent includes natural high polymer chitosan, reactive organic silicone finishing agent, polybasic carboxylic acid class
Manage agent etc..Wherein, citric acid is used as most widely used polybasic carboxylic acid class finishing agent because its is cheap and formaldehydeless, but its
There is also the deficiencies of fabric yellowing and poor anti-wrinkle effect.
Because natural Chinese medicinal herb plant origin is extensive, amount is big and species is more, and the fiber after the arrangement of its natural promoter can
Possess antibacterial, antistatic, antifouling, antimycotic, anti-inflammatory and the function such as hypo-allergenic, at the same it is also safe to use and do not produce drug resistance,
It disclosure satisfy that production safety, the application demand of bioactivity textile nontoxic, environmentally friendly, non-stimulated to skin.In consideration of it, we
Develop a kind of fiber composite natral Anti-bacterial and Crease agent and preparation method thereof for having antibacterial and crease resistant functions and resistance to deformation concurrently.
The content of the invention
It is an object of the invention to provide fiber composite natral Anti-bacterial and Crease agent and preparation method thereof, more than solution
At least one technical problem.
Technical scheme is come as follows：
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：Inulin 5-11 parts, willow leaf extraction
Thing 2-6 parts, paulownia flower extract 1-4.5 parts, Caesalpinia spinosaKuntze extract 2.3-6 parts, oolong tea extract 1.6-4.2 parts, sunglo carboxylic
Methylcellulose 2.1-3.5 parts, tannic acid 2.4-5 parts, hydroxy acrylic acid 1.8-4 parts, propionic acid malt phenolic ester 1.2-3.6 parts, alkane
Base glucosides 2.4-5.3 parts, concentrated hydrochloric acid 0.3-1 parts, ethylene glycol 1.2-2.3 parts, water 80-150 parts.
In above-mentioned technical proposal, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 5-
In the concentrated sulfuric acid and methanol mixed solution of 10 times of parts by weight, 1-5h, the wherein concentrated sulfuric acid and methanol volume are stirred at 70-85 DEG C
Than for 1:10-20；It is subsequently placed in salpeter solution the microwave at 80-110 DEG C and heats 10-20min, successively by ultrasonic disperse
30-60min, centrifuge and dialyse, be finally freeze-dried and produce sunglo carboxymethyl cellulose.
In above-mentioned technical proposal, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 8
In the concentrated sulfuric acid and methanol mixed solution of times parts by weight, 4h is stirred at 78 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:
16；It is subsequently placed in salpeter solution the microwave at 95 DEG C and heats 15min, successively by ultrasonic disperse 50min, centrifuges and saturating
Analysis, is finally freeze-dried and produces sunglo carboxymethyl cellulose.
In above-mentioned technical proposal, the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
Extraction step be：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 leachings
In the ethanol solution for entering 65wt.%, soak at room temperature 8-15 hours, it is respectively that the solution after immersion is micro- in 60-80 DEG C of 300W
30-60min is heated under the conditions of ripple, after filtering, freeze-drying, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze is respectively obtained and carries
Take thing and oolong tea extract.
In above-mentioned technical proposal, raw material includes the component of following parts by weight：Inulin 5.8-10.2 parts, willow leaf extract 2.4-
5.3 parts, paulownia flower extract 1.8-4 parts, Caesalpinia spinosaKuntze extract 2.7-5.3 parts, oolong tea extract 1.9-4 parts, sunglo carboxylic first
Base cellulose 2.7-3.2 parts, tannic acid 2.8-4.3 parts, hydroxy acrylic acid 2.2-3.8 parts, propionic acid malt phenolic ester 1.8-3.3 parts,
APG 2.8-5 parts, concentrated hydrochloric acid 0.4-0.9 parts, ethylene glycol 1.4-2.1 parts, water 95-140 parts.
Another technical scheme of the present invention is come as follows：
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 40- is stirred at 80-110 DEG C
120min, room temperature is cooled to, produces product A；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
In above-mentioned technical proposal, step（1）In, stir 75min at 95 DEG C.
As a result of above technical scheme, beneficial effects of the present invention are：
Finishing agent provided by the present invention possesses good antibacterial and wrinkle resistance, and water resistance is good, its bacteriostasis rate after washing 60 times
Remain at more than 85%, creasy recovery angle is maintained at more than 216.7 °, while flat appearance degree up to 3.5 and more than, combination property
It is good, have a extensive future.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.Following examples are used to illustrate the present invention,
But it is not limited to the scope of the present invention.
Embodiment 1
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：5 parts of inulin, willow leaf extract 2
Part, 1 part of paulownia flower extract, 2.3 parts of Caesalpinia spinosaKuntze extract, 1.6 parts of oolong tea extract, 2.1 parts of sunglo carboxymethyl cellulose,
2.4 parts of tannic acid, 1.8 parts of hydroxy acrylic acid, 1.2 parts of propionic acid malt phenolic ester, 2.4 parts of APG, 0.3 part of concentrated hydrochloric acid, second two
1.2 parts of alcohol, 80 parts of water.
Wherein, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 5 times of parts by weight
In the concentrated sulfuric acid and methanol mixed solution, 1h is stirred at 70 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:10；It is subsequently placed in
Microwave heats 10min at 80 DEG C in salpeter solution, successively by ultrasonic disperse 30min, centrifuges and dialyses, finally freeze
It is drying to obtain sunglo carboxymethyl cellulose.
Wherein, the extraction step of the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
It is：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 immerse 65wt.%
Ethanol solution in, at room temperature soak 8 hours, respectively by 300W heated under microwave conditions of the solution after immersion at 60 DEG C
30min, after filtering, freeze-drying, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea and carry
Take thing.
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 40min is stirred at 80 DEG C, it is cold
But to room temperature, product A is produced；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
Embodiment 2
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：11 parts of inulin, willow leaf extract
6 parts, 4.5 parts of paulownia flower extract, 6 parts of Caesalpinia spinosaKuntze extract, 4.2 parts of oolong tea extract, sunglo carboxymethyl cellulose 3.5
Part, 5 parts of tannic acid, 4 parts of hydroxy acrylic acid, 3.6 parts of propionic acid malt phenolic ester, 5.3 parts of APG, 1 part of concentrated hydrochloric acid, ethylene glycol
2.3 parts, 150 parts of water.
Wherein, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 10 times of parts by weight
In the concentrated sulfuric acid and methanol mixed solution, 5h is stirred at 85 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:20；It is subsequently placed in
Microwave heats 20min at 110 DEG C in salpeter solution, successively by ultrasonic disperse 60min, centrifuges and dialyses, last cold
Jelly is drying to obtain sunglo carboxymethyl cellulose.
Wherein, the extraction step of the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
It is：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 immerse 65wt.%
Ethanol solution in, at room temperature soak 15 hours, respectively by 300W heated under microwave conditions of the solution after immersion at 80 DEG C
60min, after filtering, freeze-drying, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea and carry
Take thing.
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 120min is stirred at 110 DEG C,
Room temperature is cooled to, produces product A；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
Embodiment 3
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：5.8 parts of inulin, willow leaf extraction
2.4 parts of thing, 1.8 parts of paulownia flower extract, 2.7 parts of Caesalpinia spinosaKuntze extract, 1.9 parts of oolong tea extract, sunglo carboxymethyl cellulose
2.7 parts of element, 2.8 parts of tannic acid, 2.2 parts of hydroxy acrylic acid, 1.8 parts of propionic acid malt phenolic ester, 2.8 parts of APG, concentrated hydrochloric acid 0.4
Part, 1.4 parts of ethylene glycol, 95 parts of water.
Wherein, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 5-10 times of parts by weight
The concentrated sulfuric acid and methanol mixed solution in, stir 1-5h at 70-85 DEG C, wherein the volume ratio of the concentrated sulfuric acid and methanol is 1:10-
20；It is subsequently placed in salpeter solution at 80-110 DEG C microwave and heats 10-20min, successively by ultrasonic disperse 30-60min, from
The heart separates and dialysis, is finally freeze-dried and produces sunglo carboxymethyl cellulose.
Wherein, the extraction step of the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
It is：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 immerse 65wt.%
Ethanol solution in, at room temperature soak 12 hours, respectively by 300W heated under microwave conditions of the solution after immersion at 70 DEG C
45min, after filtering, freeze-drying, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea and carry
Take thing.
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 85min is stirred at 90 DEG C, it is cold
But to room temperature, product A is produced；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
Embodiment 4
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：10.2 parts of inulin, willow leaf extraction
5.3 parts of thing, 4 parts of paulownia flower extract, 5.3 parts of Caesalpinia spinosaKuntze extract, 4 parts of oolong tea extract, sunglo carboxymethyl cellulose 3.2
Part, 4.3 parts of tannic acid, 3.8 parts of hydroxy acrylic acid, 3.3 parts of propionic acid malt phenolic ester, 5 parts of APG, 0.9 part of concentrated hydrochloric acid, second two
2.1 parts of alcohol, 140 parts of water.
Wherein, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 8 times of parts by weight
In the concentrated sulfuric acid and methanol mixed solution, 4h is stirred at 75 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:18；It is subsequently placed in
Microwave heats 15min at 90 DEG C in salpeter solution, successively by ultrasonic disperse 45min, centrifuges and dialyses, finally freeze
It is drying to obtain sunglo carboxymethyl cellulose.
Wherein, the extraction step of the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
It is：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 immerse 65wt.%
Ethanol solution in, at room temperature soak 12 hours, respectively by 300W heated under microwave conditions of the solution after immersion at 75 DEG C
55min, after filtering, freeze-drying, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea and carry
Take thing.
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 90min is stirred at 100 DEG C,
Room temperature is cooled to, produces product A；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
Embodiment 5
Fiber composite natral Anti-bacterial and Crease agent, raw material include the component of following parts by weight：6.8 parts of inulin, willow leaf extraction
4.3 parts of thing, 2.6 parts of paulownia flower extract, 3 parts of Caesalpinia spinosaKuntze extract, 2.2 parts of oolong tea extract, sunglo carboxymethyl cellulose 3
Part, 3.6 parts of tannic acid, 3.4 parts of hydroxy acrylic acid, 2.1 parts of propionic acid malt phenolic ester, 4.6 parts of APG, 0.6 part of concentrated hydrochloric acid, second
1.7 parts of glycol, 120 parts of water.
Wherein, the preparation process of the sunglo carboxymethyl cellulose is：Sunglo is washed into drying, is placed in 8 times of parts by weight
In the concentrated sulfuric acid and methanol mixed solution, 4h is stirred at 78 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:16；It is subsequently placed in
Microwave heats 15min at 95 DEG C in salpeter solution, successively by ultrasonic disperse 50min, centrifuges and dialyses, finally freeze
It is drying to obtain sunglo carboxymethyl cellulose.
Wherein, the extraction step of the willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract
It is：Take willow leaf, fortune paulownia flower, Caesalpinia spinosaKuntze and oolong tea dry respectively and crush, respectively with solid-liquid ratio 1:25 immerse 65wt.%
Ethanol solution in, at room temperature soak 12 hours, respectively by 300W heated under microwave conditions of the solution after immersion at 75 DEG C
50min, after filtering, freeze-drying, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea and carry
Take thing.
The preparation method of fiber composite natral Anti-bacterial and Crease agent, including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 75min is stirred at 95 DEG C, it is cold
But to room temperature, product A is produced；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
Comparative example 1
This comparative example in place of the difference of embodiment 1 with being：Not comprising inulin, paulownia flower extract and propionic acid malt phenolic ester.
Comparative example 2
This comparative example in place of the difference of embodiment 1 with being：Not comprising sunglo carboxymethyl cellulose and tannic acid.
Performance test
Fabric is respectively adopted to the finishing agent prepared by various embodiments above and comparative example and carries out conventional finishing technique processing,
Then correlated performance test is carried out to the fabric of arrangement, its test result is as shown in the table：
From above test result, finishing agent provided by the present invention possesses good antibacterial and wrinkle resistance, and water resistance is good,
Its bacteriostasis rate remains at more than 85% after washing 60 times, and creasy recovery angle is maintained at more than 216.7 °, while flat appearance degree reaches
3.5 and more than, combination property is good, has a extensive future.
Claims (7)
1. fiber composite natral Anti-bacterial and Crease agent, it is characterised in that raw material includes the component of following parts by weight：Inulin 5-
11 parts, willow leaf extract 2-6 parts, paulownia flower extract 1-4.5 parts, Caesalpinia spinosaKuntze extract 2.3-6 parts, oolong tea extract 1.6-
4.2 parts, sunglo carboxymethyl cellulose 2.1-3.5 parts, tannic acid 2.4-5 parts, hydroxy acrylic acid 1.8-4 parts, propionic acid malt phenolic ester
1.2-3.6 parts, APG 2.4-5.3 parts, concentrated hydrochloric acid 0.3-1 parts, ethylene glycol 1.2-2.3 parts, water 80-150 parts.
2. fiber according to claim 1 composite natral Anti-bacterial and Crease agent, it is characterised in that the sunglo carboxylic first
The preparation process of base cellulose is：Sunglo is washed into drying, is placed in the concentrated sulfuric acid and methanol mixed solution of 5-10 times of parts by weight,
1-5h is stirred at 70-85 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:10-20；It is subsequently placed in salpeter solution in 80-
Microwave heats 10-20min at 110 DEG C, successively by ultrasonic disperse 30-60min, centrifuges and dialyses, be finally freeze-dried
Produce sunglo carboxymethyl cellulose.
3. fiber according to claim 1 composite natral Anti-bacterial and Crease agent, it is characterised in that the sunglo carboxylic first
The preparation process of base cellulose is：Sunglo is washed into drying, is placed in the concentrated sulfuric acid and methanol mixed solution of 8 times of parts by weight,
4h is stirred at 78 DEG C, the wherein volume ratio of the concentrated sulfuric acid and methanol is 1:16；The microwave at 95 DEG C is subsequently placed in salpeter solution to add
Hot 15min, successively by ultrasonic disperse 50min, centrifuge and dialyse, be finally freeze-dried and produce sunglo carboxymethyl cellulose
Element.
4. fiber according to claim 1 composite natral Anti-bacterial and Crease agent, it is characterised in that the willow leaf extraction
Thing, paulownia flower extract, the extraction step of Caesalpinia spinosaKuntze extract and oolong tea extract are：Willow leaf, fortune paulownia flower, thorn are taken respectively
Mysorethorn and oolong tea drying simultaneously crush, respectively with solid-liquid ratio 1:25 immerse in 65wt.% ethanol solution, soak 8- at room temperature
15 hours, respectively by 300W heated under microwave conditions 30-60min of the solution after immersion at 60-80 DEG C, after filtering, freezing was dry
It is dry, respectively obtain willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract and oolong tea extract.
5. fiber according to claim 1 composite natral Anti-bacterial and Crease agent, it is characterised in that raw material includes following
The component of parts by weight：Inulin 5.8-10.2 parts, willow leaf extract 2.4-5.3 parts, paulownia flower extract 1.8-4 parts, Caesalpinia spinosaKuntze carry
Take thing 2.7-5.3 parts, oolong tea extract 1.9-4 parts, sunglo carboxymethyl cellulose 2.7-3.2 parts, tannic acid 2.8-4.3 parts,
Hydroxy acrylic acid 2.2-3.8 parts, propionic acid malt phenolic ester 1.8-3.3 parts, APG 2.8-5 parts, concentrated hydrochloric acid 0.4-0.9 parts, second
Glycol 1.4-2.1 parts, water 95-140 parts.
6. the fiber preparation method of composite natral Anti-bacterial and Crease agent, it is characterised in that including following preparation process：
（1）Tannic acid is added in ethylene glycol and stirred, concentrated hydrochloric acid is then added dropwise, 40- is stirred at 80-110 DEG C
120min, room temperature is cooled to, produces product A；
（2）Inulin, willow leaf extract, paulownia flower extract, Caesalpinia spinosaKuntze extract, oolong tea extract and APG are added
Into water, stir；
（3）Then add sunglo carboxymethyl cellulose, hydroxy acrylic acid, propionic acid malt phenolic ester and step（1）In product A, stir
Mix well mixed, obtain fiber composite natral Anti-bacterial and Crease agent.
7. the fiber according to claim 5 preparation method of composite natral Anti-bacterial and Crease agent, it is characterised in that step
Suddenly（1）In, stir 75min at 95 DEG C.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109281164A (en) * | 2018-09-28 | 2019-01-29 | 安徽省永欣织带有限公司 | A kind of preparation method of anti-bad smell of perspiration mattress wrapped belt |
| CN110777536A (en) * | 2019-10-29 | 2020-02-11 | 江南大学 | Preparation method and application of multifunctional biomass anti-wrinkle and wrinkle-removing agent |
| CN111485422A (en) * | 2020-04-17 | 2020-08-04 | 苏州丝之源纺织科技有限公司 | Anti-mite antibacterial finishing agent and finishing method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070677A (en) * | 2007-06-07 | 2007-11-14 | 华南农业大学 | Sterilizing shape-memory-fabric finishing agent and finishing method |
| CN103668993A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Antibacterial crease-resistant finishing agent special for textiles |
| CN105064010A (en) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | Novel natural antibacterial finishing agent, and preparation method thereof |
| CN105544208A (en) * | 2015-12-07 | 2016-05-04 | 常熟市永新印染有限公司 | Finishing technology of textile fabric |
| CN105926279A (en) * | 2016-05-30 | 2016-09-07 | 太仓红桥服饰有限公司 | Anti-crease and anti-microbial clothing finishing agent and application thereof |
-
2017
- 2017-08-15 CN CN201710695190.7A patent/CN107385910A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101070677A (en) * | 2007-06-07 | 2007-11-14 | 华南农业大学 | Sterilizing shape-memory-fabric finishing agent and finishing method |
| CN103668993A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Antibacterial crease-resistant finishing agent special for textiles |
| CN105064010A (en) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | Novel natural antibacterial finishing agent, and preparation method thereof |
| CN105544208A (en) * | 2015-12-07 | 2016-05-04 | 常熟市永新印染有限公司 | Finishing technology of textile fabric |
| CN105926279A (en) * | 2016-05-30 | 2016-09-07 | 太仓红桥服饰有限公司 | Anti-crease and anti-microbial clothing finishing agent and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109281164A (en) * | 2018-09-28 | 2019-01-29 | 安徽省永欣织带有限公司 | A kind of preparation method of anti-bad smell of perspiration mattress wrapped belt |
| CN110777536A (en) * | 2019-10-29 | 2020-02-11 | 江南大学 | Preparation method and application of multifunctional biomass anti-wrinkle and wrinkle-removing agent |
| CN111485422A (en) * | 2020-04-17 | 2020-08-04 | 苏州丝之源纺织科技有限公司 | Anti-mite antibacterial finishing agent and finishing method and application thereof |
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