CN107384273A - A kind of super large emery wheel reinforcing glass fiber mat bonding agent - Google Patents
A kind of super large emery wheel reinforcing glass fiber mat bonding agent Download PDFInfo
- Publication number
- CN107384273A CN107384273A CN201710427644.2A CN201710427644A CN107384273A CN 107384273 A CN107384273 A CN 107384273A CN 201710427644 A CN201710427644 A CN 201710427644A CN 107384273 A CN107384273 A CN 107384273A
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- CN
- China
- Prior art keywords
- silane coupler
- parts
- silane
- emery wheel
- bonding agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
- B24D3/285—Reaction products obtained from aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of super large emery wheel reinforcing glass fiber mat bonding agent, the bonding agent is prepared from the following raw materials in parts by weight:0.05~0.15 part of 2123 34~38 parts of phenolic resin, 2,127 34~38 parts of phenolic resin, 22~24 parts of ethanol, 0.5~1.5 part of methenamine and silane coupler;Wherein, the silane coupler selects silane coupler KH 550, silane coupler KH 560 and silane coupler DL 602 mixture, and silane coupler KH 550, silane coupler KH 560 and silane coupler DL 602 mass ratio are 2.4~2.8:1.7~2.1:1.The advantage of the invention is that:The invention provides a kind of stable performance and the bonding agent of emery wheel mesh sheet intensity and adhesive effect can be improved, so as to which the wearability and service life of emery wheel can be improved using the bonding agent of the formula.
Description
Technical field
The invention belongs to adhesive techniques field, more particularly to a kind of super large emery wheel reinforcing glass fiber mat bonding
Agent.
Background technology
Emery wheel mesh sheet is the bone in resin wheel, and particularly important effect is played to the intensity of whole emery wheel, directly certainly
Determine the quality of emery wheel.Emery wheel mesh sheet be using emery wheel screen cloth be coated with bonding agent drying after punching form, it is necessary to when laminating non-woven fabrics,
Black paper and plastic sheeting, there is excellent tensile strength and flex stiffiness energy, be the optimal enhancing base materials of various resin wheels.And sand
Take turns the superior service life and tear resistance for directly affecting emery wheel of adhesive performance of mesh sheet.
Traditional emery wheel mesh sheet bonding agent is all manufacturer to be formed with reactor reaction, and storage time is short, bonding agent with
Methanol is solvent, and transport and storage all have very big potential safety hazard.And it can be caused in the building-up process of bonding agent a large amount of
Waste water, waste liquid, very big influence is caused to environment.And traditional caking agent formula is single, cause emery wheel backing wire piece and sand
The adhesion of son and resin is weak, with reference to not close, causes the not wear-resisting of emery wheel, service life is low.
On emery wheel mesh sheet bonding agent, have been reported in the prior art.As the B of patent CN 103481210 disclose one
Kind emery wheel mesh sheet bonding agent and preparation method thereof, the bonding agent is by thermoplastic phenolic resin 80-110 parts, curing agent 1-6
Part, thermosetting phenolic resin liquid 20-40 parts, alcohol 60-140 parts, toughener 0.5-2 parts, coupling agent 0.5-2 parts,
Plasticizer 0.5-2 parts form.Its preparation method is that alcohol is added in agitator, adds thermoplastic phenolic resin while stirring
Fat, 3-4 hours are stirred, treat that phenolic resin block all dissolves, add the thermosetting phenolic resin liquid containing coupling agent, plasticizer
And alcoholic toughener, stirring 3-4 hours add curing agent, continue to stir 4-6 hours, obtain the bonding agent;But should
The caking agent formula of emery wheel mesh sheet is very single, causes the adhesion of emery wheel backing wire piece and sand and resin weak, with reference to not close, leads
The not wear-resisting of emery wheel is caused, service life is low.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of stable performance and emery wheel mesh sheet intensity and bonding effect can be improved
The bonding agent of fruit, so as to improve the wearability of emery wheel and service life.
In order to solve the above technical problems, the technical scheme is that:A kind of super large emery wheel reinforcing glass fiber mat is used
Bonding agent, its innovative point are:The bonding agent is prepared from the following raw materials in parts by weight:2123 34~38 parts of phenolic resin,
0.05~0.15 part of 2127 34~38 parts of phenolic resin, 22~24 parts of ethanol, 0.5~1.5 part of methenamine and silane coupler;
Wherein, the silane coupler is from silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602
Mixture, and the mass ratio of silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602 be 2.4~
2.8:1.7~2.1:1.
Further, the silane coupler is even from silane resin acceptor kh-550, silane coupler KH-560 and silane
Join agent DL-602 mixture, and the matter of silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602
Amount is than being 2.6:1.9:1.
Further, the bonding agent is prepared from the following raw materials in parts by weight:2123 36 parts of phenolic resin, 2127 phenolic aldehyde
0.1 part of 36 parts of resin, 23 parts of ethanol, 1.0 parts of methenamine and silane coupler;Wherein, the silane coupler selects silane
Coupling agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silicon
Alkane coupling agent KH-560 and silane coupler DL-602 mass ratio are 2.6:1.9:1.
The advantage of the invention is that:Phenolic resin adhesion, heat resistance, Burning corrosion resistance, the anti-flammability that the present invention selects are excellent
It is different, and material is easy to get, it is cheap;Wherein 2123 phenolic resin have thermoplasticity in the presence of without curing agent, make it
Still there is the ability of reprocessing after impregnated glass fiber, 2127 phenolic resin also have curing characteristics again without curing agent,
Mesh sheet in emery wheel is combined with good cementability to abrasive material, and the dry and wet degree of mesh sheet can be adjusted in order to preferably adapt to gas
Influence of the time factor to mesh sheet;And the present invention uses ethanol not only to reduce the injury to human body as solvent, improve work
Condition, and similar compatibility principle is made full use of, reach the purpose that various components fully dissolve;
In addition, add a kind of silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602 in formula
Compound coupling agent is mixed, contains two kinds of different active genes in KH550 molecules --- amino and epoxide, for being coupled organic high score
Son and inorganic filler, strengthen its caking property, improve the performance such as mechanical, water-fast, anti-aging of product;Silane coupler KH560 is used
In glass fiber reinforced epoxy resin, ABS, phenolic resin, nylon, PBT etc., improve the bonding force of inorganic filler, ground and resin with
The performances such as the mechanical strength of its physical property, especially composite, water proofing property, electric property, heat resistance are improved, and wet
There is higher conservation rate under state;Silane coupler DL-602 is used for phenolic aldehyde, epoxy resin, can improve the intensity of composite;Cause
This, is 2.4~2.8 from mass ratio:1.7~2.1:1 silane resin acceptor kh-550, silane coupler KH-560 and silane is even
Join agent DL-602 mixture as excellent adhesive accelerant, phenolic resin adhesive in emery wheel manufacturing process can be improved
Cohesive, so as to improve the adhesion of emery wheel backing wire piece and sand and resin, and then improve the intensity of emery wheel mesh sheet;It is viscous using this
Emery wheel made of agent prescription is connect, its wearability is strong, so as to extend the service life of emery wheel.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this
It is bright to be limited among described scope of embodiments.
Embodiment 1
0.15 parts by weight silane coupler is added in the phenolic resin of 34 parts by weight 2127(Silane coupler is even from silane
Join agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane
Coupling agent KH-560 and silane coupler DL-602 mass ratio are 2.4: 2.1:1), stir, place standby.
20 parts by weight of ethanol are added in large stirrer, agitator stirring is started, adds the phenolic aldehyde tree of 38 parts by weight 2123
Fat, stir 3~4 hours, add the thermosetting phenolic resin liquid containing coupling agent prepared, uniformly rear add to be mixed solidifies
The parts by weight of agent methenamine 1.5, and container used above is rinsed with 4 parts by weight of ethanol, add agitator and continue stirring 3~4
Hour, blowing barrelling sealing, obtain super large emery wheel reinforcing glass fiber mat bonding agent.
Embodiment 2
0.15 parts by weight silane coupler is added in the phenolic resin of 34 parts by weight 2127(Silane coupler is from silane coupled
Agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane are even
The mass ratio for joining agent KH-560 and silane coupler DL-602 is 2.8:1.7:1), stir, place standby.
20 parts by weight of ethanol are added in large stirrer, agitator stirring is started, adds the phenolic aldehyde tree of 38 parts by weight 2123
Fat, stir 3~4 hours, add the thermosetting phenolic resin liquid containing coupling agent prepared, uniformly rear add to be mixed solidifies
The parts by weight of agent methenamine 1.5, and container used above is rinsed with 4 parts by weight of ethanol, add agitator and continue stirring 3~4
Hour, blowing barrelling sealing, obtain super large emery wheel reinforcing glass fiber mat bonding agent.
Embodiment 3
0.15 parts by weight silane coupler is added in the phenolic resin of 34 parts by weight 2127(Silane coupler is even from silane
Join agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane
Coupling agent KH-560 and silane coupler DL-602 mass ratio are 2.6:1.9:1), stir, place standby.
20 parts by weight of ethanol are added in large stirrer, agitator stirring is started, adds the phenolic aldehyde tree of 38 parts by weight 2123
Fat, stir 3~4 hours, add the thermosetting phenolic resin liquid containing coupling agent prepared, uniformly rear add to be mixed solidifies
The parts by weight of agent methenamine 1.5, and container used above is rinsed with 4 parts by weight of ethanol, add agitator and continue stirring 3~4
Hour, blowing barrelling sealing, obtain super large emery wheel reinforcing glass fiber mat bonding agent.
Table 1 below is silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602 in embodiment 1-3
Mass ratio contrasts form:
Silane coupler | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Silane resin acceptor kh-550 | 2.4 | 2.8 | 2.6 |
Silane coupler KH-560 | 2.1 | 1.7 | 1.9 |
Silane coupler DL-602 | 1 | 1 | 1 |
For the performance of testing example 1-3 super large emery wheel reinforcing glass fiber mat bonding agents, the super large sand of each embodiment
Take turns reinforcing glass fiber mat and impregnate super large emery wheel reinforcing glass fiber mat with bonding agent, the emery wheel mesh sheet after dipping is carried out
Performance test, as a result as shown in table 2.
The embodiment 1-3 super larges emery wheel reinforcing glass fiber mat of table 2 impregnates super large emery wheel reinforcing glass fiber with bonding agent
The performance test results of mesh sheet
Emery wheel mesh sheet tensile break strength after dipping | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Warp thread | 3208N/25mm | 3249N/25mm | 3286N/25mm |
Weft yarn | 3012N/25mm | 3092N/25mm | 3108N/25mm |
The emery wheel mesh sheet intensity impregnated using embodiment 1-3 bonding agent is greatly improved, and then causes emery wheel to have anti-wear performance;
In addition, embodiment 1-3 is compared, it can be seen that every test performance of embodiment 3 is superior to other two implementations
Example, thus embodiment 3 is most preferred embodiment.
Embodiment 4
0.05 parts by weight silane coupler is added in the phenolic resin of 38 parts by weight 2127(Silane coupler is from silane coupled
Agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane are even
The mass ratio for joining agent KH-560 and silane coupler DL-602 is 2.6:1.9:1), stir, place standby.
20 parts by weight of ethanol are added in large stirrer, agitator stirring is started, adds the phenolic aldehyde tree of 34 parts by weight 2123
Fat, stir 3~4 hours, add the thermosetting phenolic resin liquid containing coupling agent prepared, uniformly rear add to be mixed solidifies
The parts by weight of agent methenamine 0.5, and container used above is rinsed with 2 parts by weight of ethanol, add agitator and continue stirring 3~4
Hour, blowing barrelling sealing, obtain super large emery wheel reinforcing glass fiber mat bonding agent.
Embodiment 5
0.1 parts by weight silane coupler is added in the phenolic resin of 36 parts by weight 2127(Silane coupler is from silane coupled
Agent KH-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane are even
The mass ratio for joining agent KH-560 and silane coupler DL-602 is 2.6:1.9:1), stir, place standby.
20 parts by weight of ethanol are added in large stirrer, agitator stirring is started, adds the phenolic aldehyde tree of 36 parts by weight 2123
Fat, stir 3~4 hours, add the thermosetting phenolic resin liquid containing coupling agent prepared, uniformly rear add to be mixed solidifies
Parts by weight of agent methenamine 1.0, and container used above is rinsed with 3 parts by weight of ethanol, add agitator continue stirring 3~
4 hours, blowing barrelling sealing, obtain super large emery wheel reinforcing glass fiber mat bonding agent.
The each component parts by weight that table 3 below is embodiment 3-5 contrast form:
The embodiment 3-5 of table 3 parts by weight
Component | Embodiment 3 | Embodiment 4 | Embodiment 5 |
2123 phenolic resin | 38 | 34 | 36 |
2127 phenolic resin | 34 | 38 | 36 |
Ethanol | 24 | 22 | 23 |
Methenamine | 1.5 | 0.5 | 1.0 |
Silane coupler | 0.15 | 0.05 | 0.1 |
For the performance of testing example 3-5 super large emery wheel reinforcing glass fiber mat bonding agents, the super large sand of each embodiment
Take turns reinforcing glass fiber mat and impregnate super large emery wheel reinforcing glass fiber mat with bonding agent, the emery wheel mesh sheet after dipping is carried out
Performance test, as a result as shown in table 4.
The embodiment 3-5 super larges emery wheel reinforcing glass fiber mat of table 4 impregnates super large emery wheel reinforcing glass fiber with bonding agent
The performance test results of mesh sheet
Emery wheel mesh sheet tensile break strength after dipping | Embodiment 3 | Embodiment 4 | Embodiment 5 |
Warp thread | 3286N/25mm | 3284N/25mm | 3292N/25mm |
Weft yarn | 3108N/25mm | 3109N/25mm | 3128N/25mm |
The emery wheel mesh sheet intensity impregnated using embodiment 3-5 bonding agent is greatly improved, and then causes emery wheel to have anti-wear performance;
In addition, embodiment 3-5 is compared, it can be seen that every test performance of embodiment 5 is superior to other two implementations
Example, thus embodiment 5 is most preferred embodiment.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The skill of the industry
For art personnel it should be appreciated that the present invention is not limited to the above embodiments, described in above-described embodiment and specification is explanation
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (3)
- A kind of 1. super large emery wheel reinforcing glass fiber mat bonding agent, it is characterised in that:The bonding agent is by following parts by weight Several raw materials are made:2123 34~38 parts of phenolic resin, 2,127 34~38 parts of phenolic resin, 22~24 parts of ethanol, methenamine 0.5~1.5 part and 0.05~0.15 part of silane coupler;Wherein, the silane coupler is from silane resin acceptor kh-550, silicon Alkane coupling agent KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane coupler KH-560 Mass ratio with silane coupler DL-602 is 2.4~2.8:1.7~2.1:1.
- 2. super large emery wheel reinforcing glass fiber mat bonding agent according to claim 1, it is characterised in that:The silane Coupling agent selects the mixture of silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602, and silane Coupling agent KH-550, silane coupler KH-560 and silane coupler DL-602 mass ratio are 2.6:1.9:1.
- 3. super large emery wheel reinforcing glass fiber mat bonding agent according to claim 1, it is characterised in that:The bonding Agent is prepared from the following raw materials in parts by weight:2123 36 parts of phenolic resin, 2,127 36 parts of phenolic resin, 23 parts of ethanol, Wu Luotuo 0.1 part of 1.0 parts of product and silane coupler;Wherein, the silane coupler is from silane resin acceptor kh-550, silane coupler KH-560 and silane coupler DL-602 mixture, and silane resin acceptor kh-550, silane coupler KH-560 and silane are even The mass ratio for joining agent DL-602 is 2.6:1.9:1.
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CN201710427644.2A CN107384273A (en) | 2017-06-08 | 2017-06-08 | A kind of super large emery wheel reinforcing glass fiber mat bonding agent |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103481210A (en) * | 2013-09-05 | 2014-01-01 | 宁波大华砂轮有限公司 | Adhesive for grinding wheel meshes and preparation method of adhesive |
CN105566590A (en) * | 2016-01-29 | 2016-05-11 | 河北德大化工有限公司 | Method for preparing modified phenolic resin and application thereof |
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2017
- 2017-06-08 CN CN201710427644.2A patent/CN107384273A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103481210A (en) * | 2013-09-05 | 2014-01-01 | 宁波大华砂轮有限公司 | Adhesive for grinding wheel meshes and preparation method of adhesive |
CN105566590A (en) * | 2016-01-29 | 2016-05-11 | 河北德大化工有限公司 | Method for preparing modified phenolic resin and application thereof |
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Application publication date: 20171124 |