CN105839413A - Fiber fabric gum dipping liquid, and preparation method and application thereof - Google Patents
Fiber fabric gum dipping liquid, and preparation method and application thereof Download PDFInfo
- Publication number
- CN105839413A CN105839413A CN201610437989.1A CN201610437989A CN105839413A CN 105839413 A CN105839413 A CN 105839413A CN 201610437989 A CN201610437989 A CN 201610437989A CN 105839413 A CN105839413 A CN 105839413A
- Authority
- CN
- China
- Prior art keywords
- fabric
- dipping solution
- latex
- parts
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to fiber fabric gum dipping liquid, and a preparation method and application thereof, and belongs to the technical field of weaving garments. The fiber fabric gum dipping liquid is prepared from 4 to 8 parts of epoxy resin, 0.2 to 0.8 part of curing agents, 60 to 100 parts of gum cream and 100 parts of deionized water. The ingredients are sequentially added into a reaction container to be sufficiently stirred for reaction, and then, the fiber fabric gum dipping liquid is obtained. Sources of raw materials used by the recipe of the fiber fabric gum dipping liquid are wide; nontoxicity and harmlessness are realized; the preparation process flow process is simple; the fiber fabric gum dipping liquid can be stably stored for a long time under the room temperature condition; the storage and the industrial application are convenient.
Description
Technical field
The present invention relates to a kind of fabric dipping solution and its preparation method and application, belong to textile garment technology
Field.
Background technology
Instantly, fiber/rubber composite is widely applied in fields such as tire, conveyer belt and flexible pipes,
But because it uses condition harsh, the bond properties of fiber/rubber interface becomes key issue.In rubber work
In industry, that rubber is the most frequently used with the interface processing means of fabric is exactly Resorcin-Formaldehyde-Latex (RFL)
Dipping system, this method has continued to use more than 60 year.RFL system can be at rubber and fiber interlayer
Form transition zone glued membrane, rubber and fibrous layer are played cementation.But the resorcinol pair in RFL system
Human liver and the most toxic effect of cardiovascular；And formaldehyde is bigger to the harm of human body, international at 2009 Nian Bei
DKFZ is classified as and causes one of leukemic chemicals.
All the time, RFL system has been done substantial amounts of research by research worker, on each side affecting RFL system
Face parameter all conducts in-depth research, and in recent years, the direction increasingly come into one's own is by fabric
Dipping system goes resorcinol and formolation, but, do not have a kind of method can substitute RFL system all the time.
Under the social background of green, environmental protection, it is badly in need of developing a kind of novel " green impregnation system " and substitutes and pass
The RFL system of system, to reduce environment and the injury of human body, fiber dipping solution involved in the present invention is not only
The bond properties requirement between fabric and rubber can be met, and substantially reduce environment and human body
Harm.
Summary of the invention
It is an object of the invention to overcome above-mentioned weak point, it is provided that a kind of novel impregnation system, substitute and pass
Toxic component in system RFL impregnation system.The present invention uses epoxy resin and firming agent and latex mixing gained
Dipping solution fabric is carried out dipping process, not only meet the interface between fabric and rubber glue
Close performance requirement, and solve the environmental problem that tradition RFL impregnation system is brought.
The technical scheme provided according to the present invention, a kind of fabric dipping solution, formula proportion is by weight
As follows: epoxy resin 4～8 parts, firming agent 0.2～0.8 part, latex 60～100 parts and deionized water 100
Part；It is sequentially added into four in reaction vessel after being sufficiently stirred for reaction, obtains fabric dipping solution.
Described epoxy resin is bisphenol A type epoxy resin, epoxidation linear phenolic resin, ethylene glycol bisthioglycolate shrink
Glycerin ether, diethylene glycol diglycidyl ether, triethylene-glycol diglycidyl ether, Polyethylene Glycol
Diglycidyl ether, 1,2-PD diglycidyl ether, polypropylene glycol diglycidyl ether, Isosorbide-5-Nitrae-fourth two
Alcohol diglycidyl ether, diglycidyl ether, neopentylglycol diglycidyl ether, propanetriol-diglycidyl-ether,
The double contracting of trimethylolpropane glycidyl ether, tetraphenolic ethane tetraglycidel ether epoxy resin, resorcinol
One or more in water ethoxylated glycerol type epoxy resin or double resorcinol formal four glycidyl ether.
Described firming agent is imidazole curing agent and/or amine curing agent.
Described imidazole curing agent is particularly as follows: 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-undecyl miaow
Azoles, 2-heptadecyl imidazole, 2-phenylimidazole, 1 benzyl 2 methyl imidazole, 1-1-cyanoethyl-2-methylimidazole,
One or more in 1-cyanoethyl-2-ethyl-4-methylimidazole or 1-cyanoethyl-2-undecyl imidazole；
Amine curing agent is specially one or more in diethylenetriamine, triethylene tetramine or TEPA.
Described latex be vinylpyridine latex, styrene-butadiene latex, butadiene styrene vinyl pyridine latex, chlorosulfonated polyethylene latex,
One or more in polychloroprene latex, NBR latex or hydrogenated butyronitrile latex.The solid content of described latex is
20%～40%.
The preparation method of described fabric dipping solution, step by weight is as follows: by 4～8 parts of asphalt mixtures modified by epoxy resin
Fat and 0.2～0.8 part of firming agent join in reaction vessel, uniform stirring at 20～80 DEG C, react 20～180min；
Add deionized water 100 parts, uniform stirring 30～90min under room temperature so that it is mix homogeneously, fully dissolve；
Continuously add latex 60～100 parts, continue stirring 1～6h under room temperature, obtain fabric dipping solution.
The application of described fabric dipping solution, is placed in fabric in fabric dipping solution and carries out impregnation,
At room temperature impregnation 1～8min；Then it is dried at 110～240 DEG C, solidifies 1～15min, make dipping solution attached
In fabric surface, obtain latex bonded fibre fabric.
Described fabric is cotton fiber, artificial silk, nylon, polyamide, polyester, aramid fiber or supra polymer
The blended fabric of one or more fibers in weight polyethylene fiber.
Higher bonding is had with natural rubber and synthetic rubber through the fabric handled by the dipping solution of the present invention
Intensity, synthetic rubber includes: butadiene-styrene rubber, butadiene rubber, nitrile rubber, ethylene propylene diene rubber, propylene
Acid esters rubber, butyl rubber etc..
Beneficial effects of the present invention:
1, the dipping solution formula of the present invention achieves without resorcinol and formaldehydelessization, uses epoxy resin with solid
The curing reaction of agent, not only reaction condition is gentle, technique is simple, and greatly reduces environment and people
The harm of body.
2, the present invention mentions epoxy resin and firming agent can react generation network size structure, on the one hand with fibre
There is stronger active force on dimensional fabric surface, on the other hand can participate in the sulfuration of rubber, so that fabric
And between rubber, have preferable adhesive effect.
3, dipping solution is long for not only storage period, and the fabric after impregnation is preferable with the bond properties of rubber,
Use requirement can be met.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further elaborated, and the scope of the present invention is not with concrete real
Mode of executing is for limiting, but is limited by the scope of claims.
Embodiment 1
Prepared by dipping solution: take 4g bisphenol A type epoxy resin (commercially available) and 0.2g 2-ethyl-4-methylimidazole
(commercially available), in beaker, uniform stirring under the conditions of 80 DEG C, reaction carries out 30min；It is subsequently adding 100g
Deionized water, is sufficiently stirred for 30min under room temperature so that it is mix homogeneously, fully dissolves；It is eventually adding 60g
Solid content is the butadiene-vinylpyridine copylymer latex (commercially available) of 40%, stirs under room temperature, can obtain dipping solution after 1h.
Dipping process: polyester canvas (commercially available) is impregnated in above-mentioned gained dipping solution 1min, afterwards at 110 DEG C
Baking oven in place 15min, make dipping solution be attached to polyester canvas surface.
Prepared by disbonded test batten: the polyester canvas after dipping process is cut into the batten of two pieces of 25cm × 25cm,
By upper and lower for two layers polyester canvas and centre all by adhesive glue (the Wuxi Bao Tongke thick for 0.7mm mixed
Skill limited company provides) carry out interlayer laminating, then descend two sides to attach the 8mm thickness that mixes thereon
Rubber cover (offer of Wuxi Bao Tong Science and Technology Co., Ltd.) forms complete peel test batten.Then will
It is placed on vulcanizing press and vulcanizes, and curing temperature is 140 DEG C, and sulfide stress is 15MPa, during sulfuration
Between be 30min.
Embodiment 2
Prepared by dipping solution: take 6g Ethylene glycol diglycidyl ether (commercially available) and 0.5g 2-ethyl-4-methylimidazole
(commercially available), in beaker, uniform stirring under the conditions of 20 DEG C, reaction carries out 180min；It is subsequently adding 100g
Deionized water, is sufficiently stirred for 90min under room temperature so that it is mix homogeneously, fully dissolves；It is eventually adding 80g
Solid content is the butadiene-vinylpyridine copylymer latex (commercially available) of 30%, stirs under room temperature, can obtain dipping solution after 3.5h.
Dipping process: polyester canvas (commercially available) is impregnated in above-mentioned gained dipping solution 3min, afterwards at 180 DEG C
Baking oven in place 8min, make dipping solution be attached to polyester canvas surface.
Prepared by disbonded test batten: the polyester canvas after dipping process is cut into the batten of two pieces of 25cm × 25cm,
By upper and lower for two layers polyester canvas and centre all by adhesive glue (the Wuxi Bao Tongke thick for 0.7mm mixed
Skill limited company provides) carry out interlayer laminating, then descend two sides to attach the 8mm thickness that mixes thereon
Rubber cover (offer of Wuxi Bao Tong Science and Technology Co., Ltd.) forms complete peel test batten.Then will
It is placed on vulcanizing press and vulcanizes, and curing temperature is 130 DEG C, and sulfide stress is 15MPa, during sulfuration
Between be 40min.
Embodiment 3
Prepared by dipping solution: take 8g Ethylene glycol diglycidyl ether (commercially available) and 0.8g triethylene tetramine (commercially available)
In beaker, uniform stirring under the conditions of 50 DEG C, reaction carries out 100min；It is subsequently adding 100g deionization
Water, is sufficiently stirred for 60min under room temperature so that it is mix homogeneously, fully dissolves；It is eventually adding 100g solid content
It is the butadiene-vinylpyridine copylymer latex (commercially available) of 20%, stirs under room temperature, dipping solution after 6h, can be obtained.
Dipping process: polyester canvas (commercially available) is impregnated in above-mentioned gained dipping solution 5min, afterwards at 240 DEG C
Baking oven in place 1min, make dipping solution be attached to polyester canvas surface.
Prepared by disbonded test batten: the polyester canvas after dipping process is cut into the batten of two pieces of 25cm × 25cm,
By upper and lower for two layers polyester canvas and centre all by adhesive glue (the Wuxi Bao Tongke thick for 0.7mm mixed
Skill limited company provides) carry out interlayer laminating, then descend two sides to attach the 8mm thickness that mixes thereon
Rubber cover (offer of Wuxi Bao Tong Science and Technology Co., Ltd.) forms complete peel test batten.Then will
It is placed on vulcanizing press and vulcanizes, and curing temperature is 130 DEG C, and sulfide stress is 15MPa, during sulfuration
Between be 40min.
Comparative example
Dipping process: take tradition RFL impregnation system impregnated polyester canvas (commercially available) and directly use, nothing
Need impregnation.
Prepared by disbonded test batten: the polyester canvas after dipping process is cut into the batten of two pieces of 25cm × 25cm,
By upper and lower for two layers polyester canvas and centre all by adhesive glue (the Wuxi Bao Tongke thick for 0.7mm mixed
Skill limited company provides) carry out interlayer laminating, then descend two sides to attach the 8mm thickness that mixes thereon
Rubber cover (offer of Wuxi Bao Tong Science and Technology Co., Ltd.) forms complete peel test batten.Then will
It is placed on vulcanizing press and vulcanizes, and curing temperature is 140 DEG C, and sulfide stress is 15MPa, during sulfuration
Between be 30min.
Disbonded test illustrates: batten is cut into the size of 25mm × 250mm, according to GB GB/T6759-86
Batten is carried out peeling off test by the method for regulation, obtains the peel strength of batten.Binding efficiency illustrates: binding efficiency
After referring to disbonded test, the area of attached rubberized canvas and the area ratio of whole canvas.
Above-mentioned use equipment is conventional production equipment.
Table 1: the bond properties contrast of the embodiment of the present invention and comparative example's gained batten
As shown in table 1, the impregnation system of comparative example is traditional RFL impregnation system, embodiment 1-3
Impregnation system be impregnation system prepared by the present invention.It can be seen that dipping solution prepared by the present invention processed
The room temperature peel strength of fabric and rubber, high temperature peel strength, aging peel strength all can reach
The level of comparative example, and considerably beyond standard GBT20021-2005_9: cloth and the bonding of cloth under room temperature
Intensity: longitudinal test piece meansigma methods >=4.5N/mm, longitudinal test piece minimum peak >=3.9N/mm；150 DEG C of high temperature height
The lower cloth of temperature and the bonding strength of cloth: longitudinal test piece meansigma methods >=2.1N/mm, longitudinal test piece minimum peak >=
1.6N/mm。
Claims (9)
1. a fabric dipping solution, is characterized in that formula proportion is as follows: epoxy resin 4 ~ 8 parts, 0.2 ~ 0.8 part of firming agent, 60 ~ 100 parts of latex and deionized water 100 parts；It is sequentially added into four in reaction vessel after being sufficiently stirred for reaction, obtains fabric dipping solution.
2. fabric dipping solution as claimed in claim 1, it is characterized in that: described epoxy resin is bisphenol A type epoxy resin, epoxidation linear phenolic resin, Ethylene glycol diglycidyl ether, diethylene glycol diglycidyl ether, triethylene-glycol diglycidyl ether, polyethyleneglycol diglycidylether, 1, 2-propylene glycol diglycidylether, polypropylene glycol diglycidyl ether, 1, 4-butanediol diglycidyl ether, diglycidyl ether, neopentylglycol diglycidyl ether, propanetriol-diglycidyl-ether, trimethylolpropane glycidyl ether, tetraphenolic ethane tetraglycidel ether epoxy resin, one or more in resorcinol bisglycidyl ether type epoxy resin or double resorcinol formal four glycidyl ether.
3. fabric dipping solution as claimed in claim 1, is characterized in that: described firming agent is imidazole curing agent and/or amine curing agent.
4. as claimed in claim 3 fabric dipping solution, is characterized in that: described imidazole curing agent is particularly as follows: one or more in 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-undecyl imidazole, 2-heptadecyl imidazole, 2-phenylimidazole, 1 benzyl 2 methyl imidazole, 1-1-cyanoethyl-2-methylimidazole, 1-cyanoethyl-2-ethyl-4-methylimidazole or 1-cyanoethyl-2-undecyl imidazole；
Amine curing agent is specially one or more in diethylenetriamine, triethylene tetramine or TEPA.
5. fabric dipping solution as claimed in claim 1, is characterized in that: described latex is one or more in vinylpyridine latex, styrene-butadiene latex, butadiene styrene vinyl pyridine latex, chlorosulfonated polyethylene latex, polychloroprene latex, NBR latex or hydrogenated butyronitrile latex.
6. fabric dipping solution as claimed in claim 1, is characterized in that: the solid content of described latex is 20% ~ 40%.
7. the preparation method of fabric dipping solution described in claim 1, is characterized in that step is as follows by weight: join in reaction vessel by 4 ~ 8 parts of epoxy resin and 0.2 ~ 0.8 part of firming agent, uniform stirring at 20 ~ 80 DEG C, reacts 20 ~ 180min；Add deionized water 100 parts, uniform stirring 30 ~ 90min under room temperature so that it is mix homogeneously, fully dissolve；Continuously add 60 ~ 100 parts of latex, continue stirring 1 ~ 6h under room temperature, obtain fabric dipping solution.
8. the application of fabric dipping solution described in claim 1, is characterized in that: is placed in by fabric in fabric dipping solution and carries out impregnation, at room temperature impregnation 1 ~ 8min；Then it is dried at 110 ~ 240 DEG C, solidifies 1 ~ 15min, make dipping solution be attached to fabric surface, obtain latex bonded fibre fabric.
9. the application of fabric dipping solution as claimed in claim 8, is characterized in that: described fabric is the blended fabric of one or more fibers in cotton fiber, artificial silk, nylon, polyamide, polyester, aramid fiber or superhigh molecular weight polyethylene fibers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610437989.1A CN105839413A (en) | 2016-06-17 | 2016-06-17 | Fiber fabric gum dipping liquid, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610437989.1A CN105839413A (en) | 2016-06-17 | 2016-06-17 | Fiber fabric gum dipping liquid, and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105839413A true CN105839413A (en) | 2016-08-10 |
Family
ID=56576159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610437989.1A Pending CN105839413A (en) | 2016-06-17 | 2016-06-17 | Fiber fabric gum dipping liquid, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105839413A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637989A (en) * | 2016-12-06 | 2017-05-10 | 钦州市高新技术产业服务中心 | Fiber fabric dipping solution and preparation method thereof |
| CN107476079A (en) * | 2017-07-31 | 2017-12-15 | 山东环球渔具股份有限公司 | A kind of glass carbon mixed weaving cloth and preparation method thereof |
| CN107675518A (en) * | 2017-11-08 | 2018-02-09 | 苏州甫众塑胶有限公司 | Conveyer belt framework material and preparation method thereof |
| CN107804979A (en) * | 2017-11-08 | 2018-03-16 | 四川省玻纤集团有限公司 | One kind enhancing rubber basalt fibre size and preparation method of being chopped |
| CN107804978A (en) * | 2017-11-08 | 2018-03-16 | 四川省玻纤集团有限公司 | One kind enhancing rubber basalt fibre size and preparation method |
| CN108486890A (en) * | 2018-02-23 | 2018-09-04 | 高惠平 | The preparation method of automobile tire terylene cord fabric impregnation epoxy resin |
| CN108867063A (en) * | 2018-06-15 | 2018-11-23 | 杨玲玲 | A kind of dipping solution and preparation method thereof improving fabric performance |
| CN109252377A (en) * | 2017-07-13 | 2019-01-22 | 北京化工大学 | A kind of fibre framework materials dipping solution, preparation method and dipping method |
| CN109281178A (en) * | 2018-08-31 | 2019-01-29 | 黄勇 | A kind of fabric fibre dipping solution and preparation method thereof |
| CN109355922A (en) * | 2018-12-18 | 2019-02-19 | 招金矿业股份有限公司蚕庄金矿 | A kind of anti-sand cushion of dust suppression and preparation method thereof |
| CN109736089A (en) * | 2018-12-14 | 2019-05-10 | 南昌大学 | A kind of preparation method of modified polyester fiber silk |
| CN110004732A (en) * | 2019-04-23 | 2019-07-12 | 马育胜 | A kind of preparation method of ageing-resistant high density polyethylene (HDPE) colour bar cloth |
| CN110040984A (en) * | 2019-05-09 | 2019-07-23 | 成都中玻复合材料有限公司 | A kind of basalt fibre rubber composite material size |
| CN110258117A (en) * | 2019-06-04 | 2019-09-20 | 安徽华烨特种材料有限公司 | A kind of ultra-high molecular weight polyethylene impregnated fabric and preparation method thereof |
| CN110904688A (en) * | 2018-09-18 | 2020-03-24 | 北京化工大学 | Environment-friendly impregnation system for fiber surface treatment and preparation method thereof |
| CN111172762A (en) * | 2018-11-13 | 2020-05-19 | 北京化工大学 | Nano-reinforced environment-friendly impregnation system for fiber surface treatment and preparation method thereof |
| CN112064358A (en) * | 2019-06-10 | 2020-12-11 | 北京化工大学 | Environment-friendly impregnation system for fiber surface treatment, preparation method and impregnation method |
| CN112176729A (en) * | 2019-07-03 | 2021-01-05 | 北京化工大学 | Nano-reinforced environment-friendly impregnation system for fiber surface treatment, preparation method and impregnation method |
| WO2022000432A1 (en) * | 2020-07-02 | 2022-01-06 | 北京化工大学 | Environment-friendly fiber impregnation treatment system based on two-bath process, preparation method therefor and application thereof, and preparation method for impregnated fiber fabric |
| WO2023030423A1 (en) | 2021-09-02 | 2023-03-09 | 北京化工大学 | Environmentally friendly impregnation system for fiber surface treatment, and preparation method and impregnation treatment method therefor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002088657A (en) * | 2000-09-11 | 2002-03-27 | Toyoda Spinning & Weaving Co Ltd | Method for producing coated base fabric for industrial material and coat base fabric |
| CN101929506A (en) * | 2010-08-17 | 2010-12-29 | 浙江中达轴承有限公司 | Fiber wound reinforced self-lubricating composite bearing and manufacturing method thereof |
| CN102414362A (en) * | 2009-04-28 | 2012-04-11 | 株式会社普利司通 | Adhesive composition for organic fiber cords, rubber-reinforcing material using same, tire and bonding method |
| CN103981715A (en) * | 2014-05-28 | 2014-08-13 | 航天材料及工艺研究所 | No-solvent type glue solution for testing tensile property of carbon fiber multifilament and application method of no-solvent type glue solution |
-
2016
- 2016-06-17 CN CN201610437989.1A patent/CN105839413A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002088657A (en) * | 2000-09-11 | 2002-03-27 | Toyoda Spinning & Weaving Co Ltd | Method for producing coated base fabric for industrial material and coat base fabric |
| CN102414362A (en) * | 2009-04-28 | 2012-04-11 | 株式会社普利司通 | Adhesive composition for organic fiber cords, rubber-reinforcing material using same, tire and bonding method |
| CN101929506A (en) * | 2010-08-17 | 2010-12-29 | 浙江中达轴承有限公司 | Fiber wound reinforced self-lubricating composite bearing and manufacturing method thereof |
| CN103981715A (en) * | 2014-05-28 | 2014-08-13 | 航天材料及工艺研究所 | No-solvent type glue solution for testing tensile property of carbon fiber multifilament and application method of no-solvent type glue solution |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637989A (en) * | 2016-12-06 | 2017-05-10 | 钦州市高新技术产业服务中心 | Fiber fabric dipping solution and preparation method thereof |
| CN109252377A (en) * | 2017-07-13 | 2019-01-22 | 北京化工大学 | A kind of fibre framework materials dipping solution, preparation method and dipping method |
| CN107476079A (en) * | 2017-07-31 | 2017-12-15 | 山东环球渔具股份有限公司 | A kind of glass carbon mixed weaving cloth and preparation method thereof |
| CN107804978A (en) * | 2017-11-08 | 2018-03-16 | 四川省玻纤集团有限公司 | One kind enhancing rubber basalt fibre size and preparation method |
| CN107804978B (en) * | 2017-11-08 | 2021-01-26 | 四川省玻纤集团有限公司 | Basalt fiber impregnating compound for reinforcing rubber and preparation method thereof |
| CN107804979A (en) * | 2017-11-08 | 2018-03-16 | 四川省玻纤集团有限公司 | One kind enhancing rubber basalt fibre size and preparation method of being chopped |
| CN107675518A (en) * | 2017-11-08 | 2018-02-09 | 苏州甫众塑胶有限公司 | Conveyer belt framework material and preparation method thereof |
| CN108486890A (en) * | 2018-02-23 | 2018-09-04 | 高惠平 | The preparation method of automobile tire terylene cord fabric impregnation epoxy resin |
| CN108867063A (en) * | 2018-06-15 | 2018-11-23 | 杨玲玲 | A kind of dipping solution and preparation method thereof improving fabric performance |
| CN109281178A (en) * | 2018-08-31 | 2019-01-29 | 黄勇 | A kind of fabric fibre dipping solution and preparation method thereof |
| CN110904688A (en) * | 2018-09-18 | 2020-03-24 | 北京化工大学 | Environment-friendly impregnation system for fiber surface treatment and preparation method thereof |
| CN111172762B (en) * | 2018-11-13 | 2021-12-21 | 北京化工大学 | Nano-reinforced environment-friendly impregnation system for fiber surface treatment and preparation method thereof |
| CN111172762A (en) * | 2018-11-13 | 2020-05-19 | 北京化工大学 | Nano-reinforced environment-friendly impregnation system for fiber surface treatment and preparation method thereof |
| CN109736089A (en) * | 2018-12-14 | 2019-05-10 | 南昌大学 | A kind of preparation method of modified polyester fiber silk |
| CN109355922A (en) * | 2018-12-18 | 2019-02-19 | 招金矿业股份有限公司蚕庄金矿 | A kind of anti-sand cushion of dust suppression and preparation method thereof |
| CN110004732A (en) * | 2019-04-23 | 2019-07-12 | 马育胜 | A kind of preparation method of ageing-resistant high density polyethylene (HDPE) colour bar cloth |
| CN110040984A (en) * | 2019-05-09 | 2019-07-23 | 成都中玻复合材料有限公司 | A kind of basalt fibre rubber composite material size |
| CN110258117A (en) * | 2019-06-04 | 2019-09-20 | 安徽华烨特种材料有限公司 | A kind of ultra-high molecular weight polyethylene impregnated fabric and preparation method thereof |
| CN112064358A (en) * | 2019-06-10 | 2020-12-11 | 北京化工大学 | Environment-friendly impregnation system for fiber surface treatment, preparation method and impregnation method |
| CN112176729A (en) * | 2019-07-03 | 2021-01-05 | 北京化工大学 | Nano-reinforced environment-friendly impregnation system for fiber surface treatment, preparation method and impregnation method |
| WO2021000918A1 (en) * | 2019-07-03 | 2021-01-07 | 北京化工大学 | Composition for surface treatment of fibers and fiber treatment method |
| CN114341424A (en) * | 2019-07-03 | 2022-04-12 | 北京化工大学 | Composition for fiber surface treatment and fiber treatment method |
| WO2022000432A1 (en) * | 2020-07-02 | 2022-01-06 | 北京化工大学 | Environment-friendly fiber impregnation treatment system based on two-bath process, preparation method therefor and application thereof, and preparation method for impregnated fiber fabric |
| WO2023030423A1 (en) | 2021-09-02 | 2023-03-09 | 北京化工大学 | Environmentally friendly impregnation system for fiber surface treatment, and preparation method and impregnation treatment method therefor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105839413A (en) | Fiber fabric gum dipping liquid, and preparation method and application thereof | |
| CN106120350A (en) | The formula of a kind of canvas dipping solution and canvas impregnation preparation method | |
| CN102634986B (en) | Method for pretreating fibers | |
| GB2510835A (en) | Fire retardant epoxy resin formulations and their use | |
| CN105111545A (en) | Dipping adhesive for flexible industrial canvas and preparation method of dipping adhesive | |
| Huang et al. | A new soy flour-polyepoxide adhesive system for making interior plywood | |
| US9328262B2 (en) | Adhesion promoting layer for composite assemblies | |
| CN105175783A (en) | Surface treatment method for continuous basalt fiber framework material | |
| ATE256162T1 (en) | METHOD FOR MAKING AN ADHESIVE TREATED POLYESTER FIBER CORD | |
| CN109252377A (en) | A kind of fibre framework materials dipping solution, preparation method and dipping method | |
| CN110511459A (en) | A kind of fibre framework materials dipping solution, preparation method and dipping method | |
| CN113047046A (en) | Environment-friendly efficient fiber surface treatment impregnation liquid and preparation method and application thereof | |
| CN106281119A (en) | A kind of antifouling high abrasion honeycomb composite cardboard and manufacture method thereof of preventing fires | |
| CN108485281A (en) | A kind of low dielectric high intensity wave-penetrating composite material and preparation method thereof | |
| KR101762689B1 (en) | Hybrid solvent free modified epoxy lining for chemical resistance of concrete structure and forming method the coating layer using the same | |
| CN102433099B (en) | Preparation method of emulsification and compatibilization of soybean protein adhesive | |
| CN110387744A (en) | A kind of fibre framework materials dipping solution, preparation method and dipping method | |
| CN106758136A (en) | The aromatic polymer fiber of composite performance high containing benzimidazole and preparation method thereof | |
| CN107653677A (en) | A kind of aramid fiber surface inorganic agent | |
| CN103753904B (en) | High tenacity resin-based aramid fiber composite material and production method thereof | |
| CN104844807A (en) | Lignin for dipping fibers and preparation method of lignin and fiber dipping method by lignin | |
| CN109486109B (en) | Flexible epoxy resin root-resistant waterproof composite material | |
| CN107964217B (en) | Carbon fiber reinforced composite resin matrix, carbon fiber reinforced composite and preparation method thereof, and table tennis bat bottom plate | |
| CN109281178A (en) | A kind of fabric fibre dipping solution and preparation method thereof | |
| CN106637989A (en) | Fiber fabric dipping solution and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160810 |
|
| RJ01 | Rejection of invention patent application after publication |